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Amplification mechanism of perturbation energy in controlled backward-facing step flow
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作者 Yadong HUANG Desheng ZHANG Fadong GU 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI CSCD 2021年第10期1479-1494,共16页
A body force resembling the streamwise Lorentz force which decays exponentially in the wall-normalwise direction is applied in the primary and secondary separation bubbles to modify the base flow and thereby adjust th... A body force resembling the streamwise Lorentz force which decays exponentially in the wall-normalwise direction is applied in the primary and secondary separation bubbles to modify the base flow and thereby adjust the amplification rate of the perturbation energy.The amplification mechanisms are investigated numerically via analyzing the characteristics of the terms in the Reynolds-Orr equation which describes the growth rate of the perturbation energy.The results demonstrate that the main convective term always promotes the increase in the growth rate while the viscous terms usually play the reverse role.The contours of the product of the wall-normalwise and streamwise perturbation velocities distribute on both sides of the isoline,which represents the zero wall-normalwise gradient of the streamwise velocity in the base flow,due to the Kelvin-Helmholtz(KH)instability.For the case without control,the isoline downstream the reattachment point of the primary separation bubble is closer to the lower wall,and thus the viscous term near the lower wall might suppress the amplification rate.For the case in which the body force only acts on the secondary separation bubble,the secondary separation bubble is removed,and the magnitude of the negative wall-normalwise gradient of the base flow streamwise velocity decreases along the streamwise direction,and thus the growth rate of the perturbation energy is smaller than that for the case without control.For the case where the body force acts on both the separation bubbles,the secondary separation bubble is removed,the isoline stays in the central part of the channel,and thereby the viscous term has less effects on the amplification rate of which the peak value could be the maximum one for some control number. 展开更多
关键词 backward-facing step(BFS)flow flow control amplification mechanism perturbation energy
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EXPERIMENT STUDY ON SEDIMENT INCIPIENCE IN BACKWARD-FACING STEP FLOW 被引量:3
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作者 LIU Chun-rong Huhe Aode TAO Long-bin 《Journal of Hydrodynamics》 SCIE EI CSCD 2007年第2期173-179,共7页
Flow over a backward-facing step was studied to investigate the effect of large-scale vortex structures on sediment incipience. The transient flow velocity field at the downstream of the backward-facing step was obtai... Flow over a backward-facing step was studied to investigate the effect of large-scale vortex structures on sediment incipience. The transient flow velocity field at the downstream of the backward-facing step was obtained using the technique of Particle Tracking Velocimetry (PTV). The optical amplification technique was employed to measure the instantaneous flow velocities near the bed and the instantaneous bed shear stress was given. The experimental observations revealed a new insight into the oscillation of the large-scale structure and the three-dimensional characteristics of the flow. In particular, very high turbulence intensity, instantaneous horizontal velocity near the bed and the bed shear stress near the reattachment point were observed. The sediment incipient probability obtained from the sequent images of sediment particles near the bed indicates that the critical instantaneous shear stress of the sediment incipience is independent of flow conditions. 展开更多
关键词 backward-facing step flow coherent structure sediment incipience Particle Tracking Velocimetry (PTV)
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Electromagnetic control of the instability in the liquid metal flow over a backward-facing step
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作者 黄亚冬 付佳维 陈龙淼 《Chinese Physics B》 SCIE EI CAS CSCD 2022年第12期306-314,共9页
The tile-type electromagnetic actuator(TEA)and stripe-type electromagnetic actuator(SEA)are applied to the active control of the perturbation energy in the liquid metal flow over a backward-facing step(BFS).Three cont... The tile-type electromagnetic actuator(TEA)and stripe-type electromagnetic actuator(SEA)are applied to the active control of the perturbation energy in the liquid metal flow over a backward-facing step(BFS).Three control strategies consisting of base flow control(BFC),linear model control(LMC)and combined model control(CMC)are considered to change the amplification rate of the perturbation energy.CMC is the combination of BFC and LMC.SEA is utilized in BFC to produce the streamwise Lorentz force thus adjusting the amplification rate via modifying the flow structures,and the magnitude of the maximum amplification rate could reach to 6 orders.TEA is used in LMC to reduce the magnitude of the amplification rate via the wall-normalwise Lorentz force,and the magnitude could be decreased by 2 orders.Both TEA and SEA are employed in CMC where the magnitude of the amplification rate could be diminished by 3 orders.In other words,the control strategy of CMC could capably alter the flow instability of the liquid metal flow. 展开更多
关键词 electromagnetic actuator backward-facing step flow flow instability flow control
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Numerical simulation of flow separation over a backward-facing step with high Reynolds number 被引量:5
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作者 Fang-fang Wang Shi-qiang Wu Sen-lin Zhu 《Water Science and Engineering》 EI CAS CSCD 2019年第2期145-154,共10页
Large eddy simulation (LES) explicitly calculates the large-scale vortex field and parameterizes the small-scale vortices.In this study,LES and κ-ε models were developed for a specific geometrical configuration of b... Large eddy simulation (LES) explicitly calculates the large-scale vortex field and parameterizes the small-scale vortices.In this study,LES and κ-ε models were developed for a specific geometrical configuration of backward-facing step (BFS).The simulation results were validated with particle image velocimetry (PIV) measurements and direct numerical simulation (DNS).This LES simulation was carried out with a Reynolds number of 9000 in a pressurized water tunnel with an expansion ratio of 2.00.The results indicate that the LES model can reveal largescale vortex motion although with a larger grid-cell size.However,the LES model tends to overestimate the top wall separation and the Reynolds stress components for the BFS flow simulation without a sufficiently fine grid.Overall,LES is a potential tool for simulating separated flow controlled by large-scale vortices. 展开更多
关键词 Large EDDY SIMULATION κ-ε model backward-facing step Direct numerical SIMULATION Large-scale VORTICES Particle image VELOCIMETRY
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Effects of Baffle on Entropy Generation in Separated Convection Flow Adjacent to Inclined Backward-Facing Step
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作者 Asad Bahrami Seyyed Abdolreza Gandjalikhan Nassab Maliheh Hashemipour 《Journal of Electronics Cooling and Thermal Control》 2012年第4期53-61,共9页
Numerical simulations of a two-dimensional laminar forced convection flow adjacent to inclined backward-facing step in a rectangular duct are presented to examine effects of baffle on flow, heat transfer and entropy g... Numerical simulations of a two-dimensional laminar forced convection flow adjacent to inclined backward-facing step in a rectangular duct are presented to examine effects of baffle on flow, heat transfer and entropy generation distributions. The main aim of using baffles is to enhance the value of convection coefficient on the bottom wall. But the useful energy can be destroyed due to intrinsic irreversibilities in the flow by the baffle. In the present work, the amount of energy loss is estimated by the computation of entropy generation. The values of velocity and temperature which are the inputs of the entropy generation equation are obtained by the numerical solution of momentum and energy equations with blocked-off method using computational fluid dynamic technique. Discretized forms of the governing equations in the (x, y) plane are obtained by the control volume method and solved using the SIMPLE algorithm. Numerical expressions, in terms of Nusselt number, entropy generation number, Bejan number and coefficient of friction are derived in dimensionless form. Results show that although a baffle mounted onto the upper wall increases the magnitude of Nusselts number on the bottom wall, but a considerable increase in the amount of entropy generation number takes place because of this technique. For validation, the numerical results for the Nusselt number and entropy generation number are compared with theoretical findings by other investigators and reasonable agreement is found. 展开更多
关键词 ENTROPY Generation Inclined BACKWARD step BAFFLE CONVECTION flow
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Response of turbulent fluctuations to the periodic perturbations in a flow over a backward facing step 被引量:2
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作者 Zhuoyue Li Honglei Bai Nan Gao 《Theoretical & Applied Mechanics Letters》 CAS CSCD 2015年第5期191-195,共5页
The flow structures in a separated shear layer actuated by a synthetic jet actuator were studied using experimental methods. When forced at a frequency much lower than the natural shedding frequency (fH/U = 0.042 orf... The flow structures in a separated shear layer actuated by a synthetic jet actuator were studied using experimental methods. When forced at a frequency much lower than the natural shedding frequency (fH/U = 0.042 orfXr/U = 0.24), the vertical flapping motion of the shear layer downstream of the separation point became prominent. The size of the peak in the pressure spectra at the forcing frequency (Sta = fAH//U) measured near the separation point (x/H = 1) increased linearly with the forcing ampli- tude (u'/U) suggesting a linear response of the pressure fluctuations to the forcing by the synthetic jet. The linear response did not hold for the pressure fluctuations away from the jet exit as the magnitude of the peak for StA measured at x/H = 3 soon saturated when the forcing amplitude became larger than 0.3. 展开更多
关键词 Active flow controlSynthetic jetBackward facing step
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Air Entrainment and Pressure Fields over Stepped Spillway in Skimming Flow Regime 被引量:1
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作者 Anant I. Dhatrak Sandip P. Tatewar 《Journal of Power and Energy Engineering》 2014年第4期53-57,共5页
This paper deals with some aspects of the air entrainment process along the chute of spillway and study of pressure fluctuations. The experimental study has been carried out using stepped spillway model located in the... This paper deals with some aspects of the air entrainment process along the chute of spillway and study of pressure fluctuations. The experimental study has been carried out using stepped spillway model located in the campus of Government College of Engineering, Amravati (India). It is observed that air concentration is increasing with discharge as well as with number of step. Air concentration is increasing along the length of spillway. It is also observed that the bottom mean air concentration increases with step height in the upstream reach of stepped spillway, which is prone to cavitation. The pressure profiles exhibit a wavy pattern down the stepped chute and pressure on each step increases with ratio of critical depth to step height (yc/h). 展开更多
关键词 stepped SPILLWAY Air ENTRAINMENT SKIMMING flow REGIME PRESSURE FLUCTUATIONS
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Numerical investigation of air-entrainment in skimming flow over stepped spillways 被引量:1
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作者 Jiemin Zhan Jianbo Zhang Yejun Gong 《Theoretical & Applied Mechanics Letters》 CAS CSCD 2016年第3期139-142,共4页
As a widely used flood energy dissipator, the stepped spillway can significantly dissipate the kinetic or hydraulic energy due to the air-entrainment in skimming flow over the steps. The free-surface aeration involves... As a widely used flood energy dissipator, the stepped spillway can significantly dissipate the kinetic or hydraulic energy due to the air-entrainment in skimming flow over the steps. The free-surface aeration involves the sharp deformation of the free surface and the complex turbulent shear flows. In this study, the volume of fluid (VOF), mixture, and Eulerian methods are utilized to simulate the air-entrainment by coupling with the Reynolds-averaged Navier-Stokes/large eddy simulation (RANS/LES) turbulence models. The free surface deformation, air volume fraction, pressure, and velocity are compared for the three different numerical methods. Only the Eulerian+RANS method fails to capture the free-surface aeration. The air volume fraction predicted by the VOF+LES method best matches the experimental measurement, while the mixture+LES method predicts the inception point of the air entrainment more accurately. 展开更多
关键词 Skimming flow stepped spillways Air-entrainment Large eddy simulation
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Physical modelling and scale effects of air-water flows on stepped spillways 被引量:5
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作者 CHANSON Hubert GONZALEZ Carlos A. 《Journal of Zhejiang University-Science A(Applied Physics & Engineering)》 SCIE EI CAS CSCD 2005年第3期243-250,共8页
During the last three decades, the introduction of new construction materials (e.g. RCC (Roller Compacted Concrete), strengthened gabions) has increased the interest for stepped channels and spillways. However stepped... During the last three decades, the introduction of new construction materials (e.g. RCC (Roller Compacted Concrete), strengthened gabions) has increased the interest for stepped channels and spillways. However stepped chute hydraulics is not simple, because of different flow regimes and importantly because of very-strong interactions between entrained air and turbu- lence. In this study, new air-water flow measurements were conducted in two large-size stepped chute facilities with two step heights in each facility to study experimental distortion caused by scale effects and the soundness of result extrapolation to pro- totypes. Experimental data included distributions of air concentration, air-water flow velocity, bubble frequency, bubble chord length and air-water flow turbulence intensity. For a Froude similitude, the results implied that scale effects were observed in both facilities, although the geometric scaling ratio was only Lr=2 in each case. The selection of the criterion for scale effects is a critical issue. For example, major differences (i.e. scale effects) were observed in terms of bubble chord sizes and turbulence levels al- though little scale effects were seen in terms of void fraction and velocity distributions. Overall the findings emphasize that physical modelling of stepped chutes based upon a Froude similitude is more sensitive to scale effects than classical smooth-invert chute studies, and this is consistent with basic dimensional analysis developed herein. 展开更多
关键词 泄洪道 物理模型 刻度 空气-水流体 设计方案 水下隧道
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Direct observation of bunching of elementary steps on protein crystals under forced flow conditions
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作者 Gen Sazaki Guoliang Dai 《Theoretical & Applied Mechanics Letters》 CAS CSCD 2015年第4期173-176,共4页
Bunching of elementary steps by solution flow is still not yet clarified for protein crystals. Hence, in this study, we observed elementary steps on crystal surfaces of model protein hen egg-white lysozyme (HEWL) un... Bunching of elementary steps by solution flow is still not yet clarified for protein crystals. Hence, in this study, we observed elementary steps on crystal surfaces of model protein hen egg-white lysozyme (HEWL) under forced flow conditions, by our advanced optical microscopy. We found that in the case of a HEWL solution of 99.99% purity, forced flow changed bunched steps into elementary ones (debunching) on tetragonal HEWL crystals. In contrast, in the case of a HEWL solution of 98.5% purity, forced flow significantly induced bunching of elementary steps. These results indicate that in the case of HEWL crystals, the mass transfer of impurities is more significantly enhanced by forced solution flow than that of solute HEWL molecules. We also showed that forced flow induced the incorporation of microcrystals into a mother crystal and the subsequent formation of screw dislocations and spiral growth hillocks. 展开更多
关键词 In situ observation step bunching step debunching Elementary steps Forced flow Protein crystal
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EXPERIMENTAL INVESTIGATION ON THE TURBULENT COHERENT STRUCTURES OF LAMINAR SEPARATION FLOW OVER A BACKWARD FACING STEP
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作者 Wang Jinjun Lian Qixiang Lan Shilong(Fluid Mechanics Institute, Beijing University of Aeronautics and Astronautics, Beijing, China, 100083) 《Chinese Journal of Aeronautics》 SCIE EI CAS CSCD 1996年第3期175-181,共7页
The experimental investigation is conducted with LDV and hydrogen bubble technique in water flow. The shear layer thickness. the vorticity thickness. the maximulll value of turbulence intensities. the turbulent coher... The experimental investigation is conducted with LDV and hydrogen bubble technique in water flow. The shear layer thickness. the vorticity thickness. the maximulll value of turbulence intensities. the turbulent coherent structure. the variations of wall shear stress and the boundary layer shape factor are obtained. In the redevelopment region. the detailed analysis is first made for the streak structures in the near wall region and the turbulent boundary layer is formed at (x-xr) / h = 20. 展开更多
关键词 backward facing steps laminar boundary layer separated flow turbulent boundary layer reattached flow
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3D anatomy and flow dynamics of net-depositional cyclic steps on the world’s largest submarine fan:a joint 3D seismic and numerical approach
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作者 Da-Li Shao Guo-Zhang Fan +5 位作者 Hai-Qiang Wang Hong-Xia Ma Guo-Ping Zuo Liang-Bo Ding Zheng Cai Wei-Qiang Li 《Petroleum Science》 SCIE CAS CSCD 2021年第1期10-28,共19页
Supercritical flows are ubiquitous in natural environments;however,there is rare 3D anatomy of their deposits.This study uses high-quality 3D seismic datasets from the world’s largest submarine fan,Bengal Fan,to inte... Supercritical flows are ubiquitous in natural environments;however,there is rare 3D anatomy of their deposits.This study uses high-quality 3D seismic datasets from the world’s largest submarine fan,Bengal Fan,to interpret 3D architectures and flow processes of Pliocene undulating bedforms that were related to supercritical flows.Bengal undulating bedforms as documented in this study were developed in unconfined settings,and are seismically imaged as strike-elongated,crescentic bedforms in plan view and as rhythmically undulating,upstream migrating,erosive,discontinuous reflections in section view.Their lee sides are overall 3 to 4 times steeper(0.280 to 1.19°in slope)and 3 to 4 times shorter(117 to 419 m in length)than their stoss flanks and were ascribed to faster(high flow velocities of 2.70 to 3.98 m/s)supercritical flows(Froude numbers of 1.53 to 2.27).Their stoss sides,in contrast,are overall 3 to 4 times gentler(0.120 to 0.270 in slope)and 3 to 4 times longer(410 to 1139 m in length)than their lee flanks and were related to slower(low velocities of 2.35 to 3.05 m/s)subcritical flows(Froude numbers of 0.58 to 0.97).Bengal wave-like features were,thus,created by supercriticalto-subcritical flow transformations through internal hydraulic jumps(i.e.,cyclic steps).They have crests that are positive relative to the surrounding region of the seafloor,suggesting the predominant deposition of draping sediments associated with net-depositional cyclic steps.Turbidity currents forming Bengal wave-like features were,thus,dominated by deposition,resulting in net-depositional cyclic steps.Sandy deposits associated with Bengal net-depositional cyclic steps are imaged themselves as closely spaced,strike-elongated high RMS-attribute patches,thereby showing closely spaced,long and linear,strike-elongated distribution patterns. 展开更多
关键词 Sediment waves Net-depositional cyclic steps Supercritical flows Sandy supercritical-flow deposits Bengal Fan
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THE VERIFICATION OF THE CURRENT TRANSIENT EQUATION AT TUBULAR ELECTRODES IN A FLOWING FLUID UNDER POTENTIAL STEP
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作者 Song Ying MO and Ying Sing FUNG Department of Chemistry, University of Hong Kong, Hong Kong 《Chinese Chemical Letters》 SCIE CAS CSCD 1992年第3期191-192,共2页
The equation derived for the response of the current transients in the flowing fluid is verified experimentally.
关键词 THE VERIFICATION OF THE CURRENT TRANSIENT EQUATION AT TUBULAR ELECTRODES IN A flowING FLUID UNDER POTENTIAL step AT
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Analysis of Combined Radiation and Forced Convection Heat Transfer in 3D Laminar Flow over an Inclined Forward Facing Step
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作者 A. Dehghani Rayeni S. A. Gandjalikhan Nassab 《Journal of Electronics Cooling and Thermal Control》 2016年第1期1-18,共18页
In the current study, a numerical investigation of three-dimensional combined convection-radiation heat transfer over an inclined forward facing step (FFS) in a horizontal rectangular duct is presented. The fluid is t... In the current study, a numerical investigation of three-dimensional combined convection-radiation heat transfer over an inclined forward facing step (FFS) in a horizontal rectangular duct is presented. The fluid is treated as a gray, absorbing, emitting and scattering medium. To simulate the incline surface of FFS, the blocked-off method is employed in this study. The set of governing equations for gas flow are solved numerically using the CFD technique to obtain the temperature and velocity fields. Since the gas is considered as a radiating medium, all of the convection, conduction and radiation heat transfer mechanisms are presented in the energy equation. For computation of radiative term in energy equation, the radiative transfer equation (RTE) is solved numerically by the discrete ordinates method (DOM) to find the divergence of radiative heat flux distribution inside the radiating medium. The effects of optical thickness, radiation-conduction parameter and albedo coefficient on heat transfer behavior of the system are carried out. 展开更多
关键词 3-D Laminar Convection flow Forward Facing step RADIATION DOM
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基于子循环自适应串行交错时间匹配算法的油浸式变压器绕组瞬态温升计算
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作者 刘刚 郝世缘 +2 位作者 胡万君 刘云鹏 李琳 《电工技术学报》 EI CSCD 北大核心 2024年第4期1185-1197,共13页
针对传统算法存在的步长调整及耦合点选择问题,该文提出基于子循环自适应串行交错(SCAS)的时间匹配算法。首先,在步长调整方面,通过加入自适应(ATS)-启发式(HTS)混合变步长算法,解决步长无法实时调整的问题;然后,针对耦合点选择问题,该... 针对传统算法存在的步长调整及耦合点选择问题,该文提出基于子循环自适应串行交错(SCAS)的时间匹配算法。首先,在步长调整方面,通过加入自适应(ATS)-启发式(HTS)混合变步长算法,解决步长无法实时调整的问题;然后,针对耦合点选择问题,该文在传统常规串行交错(CSS)时间匹配算法及现有改进方案子循环常规串行交错(SCSS)的基础上,提出SCAS时间匹配算法,采用自适应方案确定计算时间窗及预定耦合点,并引入指数平滑法对其精度进行保证;最后,该文基于110 kV油浸式电力变压器建立二维瞬态单分区分匝绕组模型,并将所提算法与其他传统方法进行对比分析。结果表明:在精度方面,与传统CSS算法相比SCAS算法的流场及温度场最大平均相对误差均不超过0.45%,在可接受误差范围内;在效率方面,SCAS算法总体计算效率较CSS算法提高了近20倍。同时,为了说明所提算法的工程价值,该文搭建基于110 kV变压器绕组模型的温升实验平台,将SCAS时间匹配算法应用于该模型中,实验结果表明:在精度方面,SCAS算法与实验达到稳态时最大绝对误差为2.7 K;在计算效率上,本文所提算法的计算效率较传统算法提升约46倍,计算步数约为传统的1/47,减少了计算冗余。 展开更多
关键词 子循环自适应串行交错 混合变步长 二维瞬态流热耦合问题 快速计算方法 温升实验
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基于两步正则化Gauss-Newton迭代算法的ECT图像重建
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作者 张立峰 陈达 刘卫亮 《计量学报》 CSCD 北大核心 2024年第4期546-551,共6页
电容层析成像(ECT)技术求解图像重建问题属于非线性问题,并且存在严重的不适定性。为提高图像重建精度,提出了一种基于两步正则化Gauss-Newton迭代算法的ECT图像重建方法。针对标准正则化Gauss-Newton迭代算法在图像重建中存在的不收敛... 电容层析成像(ECT)技术求解图像重建问题属于非线性问题,并且存在严重的不适定性。为提高图像重建精度,提出了一种基于两步正则化Gauss-Newton迭代算法的ECT图像重建方法。针对标准正则化Gauss-Newton迭代算法在图像重建中存在的不收敛问题,引入了两步迭代方法;改进了正则化矩阵,提高了解估计的精确度;考虑到Gauss-Newton算法对迭代初值的依赖性,加入了同伦算法。最后,进行仿真和静态实验,并与线性反投影(LBP)算法、Landweber算法、Tikhonov正则化算法进行对比。结果表明,该方法可有效提高图像重建精度。 展开更多
关键词 流量测量 电容层析成像 两步正则化 Gauss-Newton迭代算法 正则化矩阵 同伦算法 两相流
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Probability of Sediment Incipient Motion Under Complex Flows 被引量:1
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作者 刘春嵘 邓丽颖 呼和敖德 《China Ocean Engineering》 SCIE EI 2010年第1期93-104,共12页
Presented in this paper is a mathematical model to calculate the probability of the sediment incipient motion, in which the effects of the fluctuating pressure and the seepage are considered. The instantaneous bed she... Presented in this paper is a mathematical model to calculate the probability of the sediment incipient motion, in which the effects of the fluctuating pressure and the seepage are considered. The instantaneous bed shear velocity and the pressure gradient on the bed downstream of the backward-facing step flow are obtained according to the PIV measurements. It is found that the instantaneous pressure gradient on the bed obeys normal distribution. The probability of the sediment incipient motion on the bed downstream of the backward-facing step flow is given by the mathematical model. The predicted results agree well with the experiment in the region downstream of the reattachment point while a large discrepancy between the theory and experiment is seen in the region near the reattachment point. The possible reasons for this discrepancy are discussed. 展开更多
关键词 PROBABILITY sediment incipience backward-facing step flow SEEPAGE PRESSURE
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GO-FLOW法在产品装配过程可靠性分析中的应用 被引量:4
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作者 张根保 崔有志 +2 位作者 柳剑 唐贤进 葛红玉 《计算机应用研究》 CSCD 北大核心 2011年第11期4199-4201,共3页
借鉴可靠性工程理论,运用GO-FLOW法分析产品装配过程的可靠性。通过分析装配过程各工步之间的关系,建立起产品装配过程可靠性控制的一般框架模型。以齿轮油泵装配过程为例,建立起齿轮油泵装配过程的GO-FLOW图,并分析其信号流、操作符和... 借鉴可靠性工程理论,运用GO-FLOW法分析产品装配过程的可靠性。通过分析装配过程各工步之间的关系,建立起产品装配过程可靠性控制的一般框架模型。以齿轮油泵装配过程为例,建立起齿轮油泵装配过程的GO-FLOW图,并分析其信号流、操作符和运算规则;通过GO-FLOW运算,求出各信号流的故障率和可靠度,找到影响产品装配过程可靠性的关键环节。结果表明,GO-FLOW法在产品装配过程可靠性分析中的应用是方便有效的。 展开更多
关键词 GO-flow 可靠性分析 装配 多工步
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模块知识融合反应工程大作业设计的思考
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作者 钟夏临 黄天孝 +3 位作者 王雅宁 程易 王铁峰 颜彬航 《化工高等教育》 2024年第1期93-101,共9页
化学反应工程是高校化学工程专业的重要核心课之一,致力于研究化学动力学并根据反应特点设计合适的反应器。课程教学团队根据多年教学经验,将课程内容分为理想反应器、非理想流动、非均相催化和工业反应器四个模块,并针对非理想流动与... 化学反应工程是高校化学工程专业的重要核心课之一,致力于研究化学动力学并根据反应特点设计合适的反应器。课程教学团队根据多年教学经验,将课程内容分为理想反应器、非理想流动、非均相催化和工业反应器四个模块,并针对非理想流动与非均相催化模块的知识关联较弱而导致学生无法综合运用所学知识解决复杂反应工程问题的现象,设计了基于模块知识融合的课程大作业。本文阐述了课程大作业对加强模块间知识关联的重要作用,梳理了课程大作业的设计和实施要点,并以催化剂氧空位测量的课程大作业为例,介绍如何通过非理想流动和非均相催化模块知识的融合提升学生解决复杂工程问题的能力,最后总结了课程大作业实施过程中的共性问题并提出了改进建议。 展开更多
关键词 模块知识融合 非理想流动 非均相催化 氧空位 阶跃过渡应答
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分步负载金属法制备铁钴双金属位点高效氧还原电催化剂
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作者 贾旭东 杨博龙 +2 位作者 程前 李雪丽 向中华 《化工学报》 EI CSCD 北大核心 2024年第4期1578-1593,共16页
过渡金属和氮掺杂的碳(M-N-C)由于优异的电催化活性以及较低的生产成本,成为铂基催化剂的替代。然而,目前的M-N-C催化剂通常涉及金属盐、含氮物质和碳载体的结合,在经过热处理和酸洗过程后得到的催化剂在活性位点密度和传质能力上性能... 过渡金属和氮掺杂的碳(M-N-C)由于优异的电催化活性以及较低的生产成本,成为铂基催化剂的替代。然而,目前的M-N-C催化剂通常涉及金属盐、含氮物质和碳载体的结合,在经过热处理和酸洗过程后得到的催化剂在活性位点密度和传质能力上性能不足。采用分步负载金属法制备了Fe、Co双金属掺杂的M-N-C催化剂。利用Zn2+和Co2+的竞争效应,成功合成了小尺寸且均匀的Zn-Co-ZIFs双金属沸石咪唑骨架。随后,在不形成金属团簇的前提下将最大量的Fe原子嵌入C-Zn-Co-ZIFs-H+前体结构中,使其在热解后能产生大量的FeCo—Nx活性位点。这种改进显著增加了FeCo-N-C-2催化剂中Fe活性位点的含量(1.9%,质量分数),并深度优化了其微孔和介孔结构(860 m^(2)·g^(-1))。该催化剂在0.1 mol·L^(-1) HClO_(4)和0.1 mol·L^(-1) KOH溶液中,氧还原反应(ORR)活性展现出了0.806 V和0.921 V的半波电位,并分别在50000、45000 s恒定电位测试后保持了91.21%和95.32%的活性。将其组装于质子交换膜燃料电池(PEMFCs)和碱性锌-空气液流电池(ZAFBs)中,峰值功率密度分别达到了746、164 mW·cm^(-2),显示出优越的性能。 展开更多
关键词 催化剂 分步负载金属法 铁钴双金属位点 电化学 氧还原反应 燃料电池 锌-空气液流电池
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