Baker抯 yeast mediated reduction of optically active diketone is described. The two keto groups are efficiently dif-ferentiated and the ee value of the recovered material is considerably raised. It affords highly opti...Baker抯 yeast mediated reduction of optically active diketone is described. The two keto groups are efficiently dif-ferentiated and the ee value of the recovered material is considerably raised. It affords highly optically active key intermediates efficiently for the synthesis of natural polyhydroxylated agarofuran products.展开更多
基金Project supported by the National Natural Science Foundation of China (No. 20272021).
文摘Baker抯 yeast mediated reduction of optically active diketone is described. The two keto groups are efficiently dif-ferentiated and the ee value of the recovered material is considerably raised. It affords highly optically active key intermediates efficiently for the synthesis of natural polyhydroxylated agarofuran products.