Two types of dual periodic circuits are introduced. The distributions of passbands and stopbands are generated from their dispersion relationships. Based on the study, Brillouin diagrams of three representative specia...Two types of dual periodic circuits are introduced. The distributions of passbands and stopbands are generated from their dispersion relationships. Based on the study, Brillouin diagrams of three representative special cases are drawn; S parameters of these three cases are simulated by Aglient ADS; the S parameters of one of the three cases are verified by an experiment. The phase characteristics are compared with those generated from the dispersion relationship. The theoretical analysis and the experimental verification show that both types of the periodic structures can behave as electromagnetic band gap (EBG) structures, right-handed structures (RHS), and left-handed structures (LHS), when they operate at different frequency ranges. Thus, the possibility of a physical structure showing these three different characteristics at different frequency ranges is proven.展开更多
Two-dimensional function photonic crystals, in which the dielectric constants of medium columns are the functions of space coordinates , are proposed and studied numerically. The band gaps structures of the photonic c...Two-dimensional function photonic crystals, in which the dielectric constants of medium columns are the functions of space coordinates , are proposed and studied numerically. The band gaps structures of the photonic crystals for TE and TM waves are different from the two-dimensional conventional photonic crystals. Some absolute band gaps and semiDirac points are found. When the medium column radius and the function form of the dielectric constant are modulated, the numbers, width, and position of band gaps are changed, and the semi-Dirac point can either occur or disappear. Therefore,the special band gaps structures and semi-Dirac points can be achieved through the modulation on the two-dimensional function photonic crystals. The results will provide a new design method of optical devices based on the two-dimensional function photonic crystals.展开更多
Band gap characteristics of the photonic crystals in terahertz range with square lattice and triangular lattice of GaAs cylinders are comparatively studied by means of plane wave method (PWM). The influence of the r...Band gap characteristics of the photonic crystals in terahertz range with square lattice and triangular lattice of GaAs cylinders are comparatively studied by means of plane wave method (PWM). The influence of the radius on the band gap width is analyzed and the critical values where the band gap appears are put forward. The results show that the maximum band gap width of photonic crystal with triangular lattice of GaAs cylinders is much wider than that of photonic crystal with square lattice. The research provides a theoretic basis for the development of terahertz (THz) devices.展开更多
Six circularly polarized patch antennas with electromagnetic band gap(EBG)arranged at different locations were studied.These EBG antennas were compared in terms of impedance bandwidth,axial ratio(AR)bandwidth and ...Six circularly polarized patch antennas with electromagnetic band gap(EBG)arranged at different locations were studied.These EBG antennas were compared in terms of impedance bandwidth,axial ratio(AR)bandwidth and radiation patterns.When the EBG cells were placed closer to the edge of the substrate,the EBG antenna had a larger front radiation and a narrower bandwidth.Integrating the EBG cells closer to the center of the patch resulted in a wider impedance bandwidth,a wider axial ratio bandwidth and a decreased front gain.展开更多
A new zero-dimensional(0D) thioborate Ba_9B_3GaS_(15) has been discovered by conventional high-temperature solid-state reaction. The compound crystallizes in orthorhombic space group Pbca with a = 8.4759(8),b = ...A new zero-dimensional(0D) thioborate Ba_9B_3GaS_(15) has been discovered by conventional high-temperature solid-state reaction. The compound crystallizes in orthorhombic space group Pbca with a = 8.4759(8),b = 22.266(2),c = 31.426(3) ?,V = 5931(2) ?~3,Z = 8,Mr = 1819.11,Dc = 4.075 g/cm3,μ = 13.684 mm^(-1),F(000) = 6320,S = 1.034,(Δρ)max = 5.039,(Δρ)min = –5.409 e/?~3,the final R = 0.0362 and w R = 0.1053 for 19243 observed reflections with I 〉 2σ(I). The structure is constructed by discrete [BS_3]^(3–) trigonal planes and isolated [GaS_4]^(5–) tetrahedra with Ba^(2+) and isolated S^(2–) filled among them. The UV-Vis-near-IR spectrum reveals a wide band gap of 3.15 eV that agrees with the electronic structure calculation.展开更多
A novel ternary rare-earth sulfide, CsYb7S(11), has been successfully synthesized by high-temperature solid-state reaction of an elemental mixture with modified Cs Cl flux. The single-crystal X-ray diffraction data ...A novel ternary rare-earth sulfide, CsYb7S(11), has been successfully synthesized by high-temperature solid-state reaction of an elemental mixture with modified Cs Cl flux. The single-crystal X-ray diffraction data reveal its orthorhombic symmetry in space group Cmca(no. 64) with a = 15.271(3), b = 13.414(2), c = 18.869(3) A°, V = 3865.2(2) A°^3, Z = 8, Mr = 1696.85, Dc = 5.832 g/cm^3, μ = 36.538 mm^-1, F(000) = 5768, the final R = 0.0225 and w R = 0.0517 for 2258 observed reflections with I 〉 2σ(I), 2.67〈θ〈27.48o, w = 1/[σ^2(Fo^2) +(0.0443 P)2 + 8.7453 P], where P =(Fo^2 + 2Fc^2)/3, S = 1.036,(Δρ)max = 1.609 and(Δρ)min = –1.922. The remarkable structural feature is the dual tricapped Cs2@S18 cube closed cavities far apart within the three-dimensional [Yb7S(11)]-covalent bonding matrix. Magnetic susceptibility measurements show that the title compound exhibits temperature-dependent(50~300 K) para-magnetism and obey the Curie-Weiss law. Moreover, the optical gap of 2.03 Ev for CsYb7S11 was deduced from the UV/Vis reflectance spectroscopy and DFT study indicates an indirect band gap with an electronic transfer excitation of S-3p to Yb-5d orbital.展开更多
The band gap structures by arranging hybrid shunted piezoelectric materialswith resistance inductive (RL) circuit and negative impedance converter (NIC) closely and at in- tervals are presented. The theoretical mo...The band gap structures by arranging hybrid shunted piezoelectric materialswith resistance inductive (RL) circuit and negative impedance converter (NIC) closely and at in- tervals are presented. The theoretical model is built using transfer matrix method. Then the MATLAB computing language is utilized to simulate the band gap structures. Meanwhile, the effects of the resistance, inductance and capacitance on the local resonant gap are studied. By comparing different combinations of resistance, inductance and capacitance as well as different arrangement of circuits, a 13 kHz band gap is reached under the effect of arranging hybrid pe- riodic shunted piezoelectric patches at intervals and the stability of the system is also analyzed. It is proved that utilizing hybrid shunted piezoelectric patches would have a clear impact on the band gap structure of phononic crystal rods. Moreover, the band gap would be clearly enlarged by arranging hybrid piezoelectric patches at intervals.展开更多
Layered organic-inorganic hybrids containing bilayer perovsikte (R-NH3)2(CH3NH3)Pb2I7 (where R=C12H25,C6H5C2H4) were synthesized by reactions in solution. The influences of the solvents and the reactant ratio on...Layered organic-inorganic hybrids containing bilayer perovsikte (R-NH3)2(CH3NH3)Pb2I7 (where R=C12H25,C6H5C2H4) were synthesized by reactions in solution. The influences of the solvents and the reactant ratio on the structures of the products were investigated. The structures and the properties of the hybrids were characterized using X-ray diffraction (XRD) and ultraviolet and visible (UV) adsorption spectra. For comparing with the bilayer perovskite hybrids in structure and band gap magnitude, the hybrids containing monolayer perovskite (R-NH3)2PbI4 were also synthesized and characterized. The results demonstrate that the thickness of inorganic layer has obvious effect on the tunneling magnitude of the band gap but the organic part can be micro actuator of band gap.展开更多
基金Supported by the National Natural Science Foundation of China (Grant No. 60471018)
文摘Two types of dual periodic circuits are introduced. The distributions of passbands and stopbands are generated from their dispersion relationships. Based on the study, Brillouin diagrams of three representative special cases are drawn; S parameters of these three cases are simulated by Aglient ADS; the S parameters of one of the three cases are verified by an experiment. The phase characteristics are compared with those generated from the dispersion relationship. The theoretical analysis and the experimental verification show that both types of the periodic structures can behave as electromagnetic band gap (EBG) structures, right-handed structures (RHS), and left-handed structures (LHS), when they operate at different frequency ranges. Thus, the possibility of a physical structure showing these three different characteristics at different frequency ranges is proven.
基金Project supported by the National Natural Science Foundations of China(Grant No.61275047)the Research Project of Chinese Ministry of Education(Grant No.213009A)the Scientific and Technological Development Foundation of Jilin Province,China(Grant No.20130101031JC)
文摘Two-dimensional function photonic crystals, in which the dielectric constants of medium columns are the functions of space coordinates , are proposed and studied numerically. The band gaps structures of the photonic crystals for TE and TM waves are different from the two-dimensional conventional photonic crystals. Some absolute band gaps and semiDirac points are found. When the medium column radius and the function form of the dielectric constant are modulated, the numbers, width, and position of band gaps are changed, and the semi-Dirac point can either occur or disappear. Therefore,the special band gaps structures and semi-Dirac points can be achieved through the modulation on the two-dimensional function photonic crystals. The results will provide a new design method of optical devices based on the two-dimensional function photonic crystals.
基金supported by the National Basic Research Program (973) under Grant No 2007CB31407
文摘Band gap characteristics of the photonic crystals in terahertz range with square lattice and triangular lattice of GaAs cylinders are comparatively studied by means of plane wave method (PWM). The influence of the radius on the band gap width is analyzed and the critical values where the band gap appears are put forward. The results show that the maximum band gap width of photonic crystal with triangular lattice of GaAs cylinders is much wider than that of photonic crystal with square lattice. The research provides a theoretic basis for the development of terahertz (THz) devices.
基金Supported by the National Natural Science Foundation of China(61102022)the Fundamental Research Foundation of Beijing Institute of Technology of China(20120542014)
文摘Six circularly polarized patch antennas with electromagnetic band gap(EBG)arranged at different locations were studied.These EBG antennas were compared in terms of impedance bandwidth,axial ratio(AR)bandwidth and radiation patterns.When the EBG cells were placed closer to the edge of the substrate,the EBG antenna had a larger front radiation and a narrower bandwidth.Integrating the EBG cells closer to the center of the patch resulted in a wider impedance bandwidth,a wider axial ratio bandwidth and a decreased front gain.
基金Supported by the National Natural Science Foundation of China(21233009,21225104,91422303,21301175 and 21171168)
文摘A new zero-dimensional(0D) thioborate Ba_9B_3GaS_(15) has been discovered by conventional high-temperature solid-state reaction. The compound crystallizes in orthorhombic space group Pbca with a = 8.4759(8),b = 22.266(2),c = 31.426(3) ?,V = 5931(2) ?~3,Z = 8,Mr = 1819.11,Dc = 4.075 g/cm3,μ = 13.684 mm^(-1),F(000) = 6320,S = 1.034,(Δρ)max = 5.039,(Δρ)min = –5.409 e/?~3,the final R = 0.0362 and w R = 0.1053 for 19243 observed reflections with I 〉 2σ(I). The structure is constructed by discrete [BS_3]^(3–) trigonal planes and isolated [GaS_4]^(5–) tetrahedra with Ba^(2+) and isolated S^(2–) filled among them. The UV-Vis-near-IR spectrum reveals a wide band gap of 3.15 eV that agrees with the electronic structure calculation.
基金supported by the National Natural Science Foundation of China(21301175,21233009,21571020 and 91422303)the Natural Science Foundation of Fujian Province(2015J01071)
文摘A novel ternary rare-earth sulfide, CsYb7S(11), has been successfully synthesized by high-temperature solid-state reaction of an elemental mixture with modified Cs Cl flux. The single-crystal X-ray diffraction data reveal its orthorhombic symmetry in space group Cmca(no. 64) with a = 15.271(3), b = 13.414(2), c = 18.869(3) A°, V = 3865.2(2) A°^3, Z = 8, Mr = 1696.85, Dc = 5.832 g/cm^3, μ = 36.538 mm^-1, F(000) = 5768, the final R = 0.0225 and w R = 0.0517 for 2258 observed reflections with I 〉 2σ(I), 2.67〈θ〈27.48o, w = 1/[σ^2(Fo^2) +(0.0443 P)2 + 8.7453 P], where P =(Fo^2 + 2Fc^2)/3, S = 1.036,(Δρ)max = 1.609 and(Δρ)min = –1.922. The remarkable structural feature is the dual tricapped Cs2@S18 cube closed cavities far apart within the three-dimensional [Yb7S(11)]-covalent bonding matrix. Magnetic susceptibility measurements show that the title compound exhibits temperature-dependent(50~300 K) para-magnetism and obey the Curie-Weiss law. Moreover, the optical gap of 2.03 Ev for CsYb7S11 was deduced from the UV/Vis reflectance spectroscopy and DFT study indicates an indirect band gap with an electronic transfer excitation of S-3p to Yb-5d orbital.
基金supported by the National Natural Science Foundation of China(11202056)the Fundamental Research Funds for the Central Universities(HEUCFQ20150305)
文摘The band gap structures by arranging hybrid shunted piezoelectric materialswith resistance inductive (RL) circuit and negative impedance converter (NIC) closely and at in- tervals are presented. The theoretical model is built using transfer matrix method. Then the MATLAB computing language is utilized to simulate the band gap structures. Meanwhile, the effects of the resistance, inductance and capacitance on the local resonant gap are studied. By comparing different combinations of resistance, inductance and capacitance as well as different arrangement of circuits, a 13 kHz band gap is reached under the effect of arranging hybrid pe- riodic shunted piezoelectric patches at intervals and the stability of the system is also analyzed. It is proved that utilizing hybrid shunted piezoelectric patches would have a clear impact on the band gap structure of phononic crystal rods. Moreover, the band gap would be clearly enlarged by arranging hybrid piezoelectric patches at intervals.
基金National Natural Science Foundation of China(No.50972113)
文摘Layered organic-inorganic hybrids containing bilayer perovsikte (R-NH3)2(CH3NH3)Pb2I7 (where R=C12H25,C6H5C2H4) were synthesized by reactions in solution. The influences of the solvents and the reactant ratio on the structures of the products were investigated. The structures and the properties of the hybrids were characterized using X-ray diffraction (XRD) and ultraviolet and visible (UV) adsorption spectra. For comparing with the bilayer perovskite hybrids in structure and band gap magnitude, the hybrids containing monolayer perovskite (R-NH3)2PbI4 were also synthesized and characterized. The results demonstrate that the thickness of inorganic layer has obvious effect on the tunneling magnitude of the band gap but the organic part can be micro actuator of band gap.