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四方相纳米钛酸钡粉体的制备及性能研究
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作者 上官明楠 王超莹 +3 位作者 赵昀云 张秀云 朱归胜 徐华蕊 《绝缘材料》 CAS 北大核心 2024年第2期53-59,共7页
在传统固相法制备四方相纳米钛酸钡粉体中,碳酸钡前驱体的分散性与粒径对所得钛酸钡的形貌、粒径以及介电性能起重要作用。本研究以氢氧化钡与干冰为原料,通过控制氢氧化钡的浓度,制备了碳酸钡粉体,然后以此为原料,制备了钛酸钡粉体和陶... 在传统固相法制备四方相纳米钛酸钡粉体中,碳酸钡前驱体的分散性与粒径对所得钛酸钡的形貌、粒径以及介电性能起重要作用。本研究以氢氧化钡与干冰为原料,通过控制氢氧化钡的浓度,制备了碳酸钡粉体,然后以此为原料,制备了钛酸钡粉体和陶瓷,并研究了钛酸钡陶瓷的介电性能。结果表明:本研究制得粒径为180 nm的短棒状碳酸钡粉体,和粒径为400 nm的高分散、高均匀、纯四方相的钛酸钡粉体。在1250℃下煅烧制得钛酸钡陶瓷,其介电常数为4885,介质损耗因数为0.0189。 展开更多
关键词 碳酸钡 钛酸钡 绝缘介质层 固相法
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烧结烟气条件下微波催化直接分解NO脱硝试验
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作者 易钰涵 康建刚 +4 位作者 余春沐 杨本涛 魏进超 周继承 徐文涛 《烧结球团》 北大核心 2024年第2期99-106,共8页
复杂烧结烟气条件下,实现低温高效直接分解NO具有极大挑战性。在低温过量O_(2)且含SO_(2)和CO_(2)气氛下,本文通过研制CeO_(2)/MgCo_(2)O_(4)-40% BaCO_(3)催化剂用于微波催化高效直接分解NO,并考察该催化剂的脱硝和抗硫性能;通过XRD和... 复杂烧结烟气条件下,实现低温高效直接分解NO具有极大挑战性。在低温过量O_(2)且含SO_(2)和CO_(2)气氛下,本文通过研制CeO_(2)/MgCo_(2)O_(4)-40% BaCO_(3)催化剂用于微波催化高效直接分解NO,并考察该催化剂的脱硝和抗硫性能;通过XRD和TEM表征分析催化剂失活以及改性后失活得到改善的原因。结果表明:当进入气体中CO_(2)体积分数为5%时,该微波催化剂的脱硝率几乎保持稳定;引入CeO_(2)后,该微波催化剂的抗硫性能明显提升,在SO 2体积分数为0.1%气氛下,当反应温度仅为250℃时,该微波催化剂可实现99.9%的NO转化率和99.9%的N 2选择性;TEM结果表明,反应前后,该催化剂的形貌特征无明显差异。本文建立的微波催化直接分解NO的脱硝新方法,可为复杂烧结烟气条件下绿色深度脱硝提供新途径。 展开更多
关键词 NO直接分解 微波催化 CeO_(2)/MgCo_(2)O_(4)-40%baco_(3) 脱硝性能 抗硫性能 抗二氧化碳性能
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Damping Properties of Piezoelectric and Electrical Conductive of BaTiO_3/VGCF/CPE Composites: Effect of Carbon Fiber 被引量:3
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作者 晏雄 张慧萍 住田雅夫 《Journal of Donghua University(English Edition)》 EI CAS 2001年第3期11-13,共3页
A new damping composite of CPE/BaTiO3/VGCF has been developed on the basis of the piezo- effect and conductivity mechanism. The conductivity of composites varied with the VGCF content are tested and analyzed.The resul... A new damping composite of CPE/BaTiO3/VGCF has been developed on the basis of the piezo- effect and conductivity mechanism. The conductivity of composites varied with the VGCF content are tested and analyzed.The results indicate that the conductivity of composites grows up slowly as the VGCF content is in the range of 10%-20%. It is very useful for industrial application to control the conductivity of composites by adjusting the VGCF content. In addition, at the range of - 50 - 120°C,the dependence of loss factor on the VGCF content varied with the temperature are tested and analyzed by dynamic mechanical and dielectric behavior measurement of the composites, and expected results are obtained. 展开更多
关键词 Chlorinating polyethylene (CPE) barium TITANATE ( BaTiO3 ) Carbon fiber Dynamic mechanical behavior Dielectric behavior Electric conductivity PERCOLATION threshold Damping material.
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Barium Hydroxide Octahydrate (Ba(OH)<sub>2</sub>&middot;8H<sub>2</sub>O) as a Substitute Alternative for Barium Carbonate (BaCO<sub>3</sub>) in Synthesis Superconductor of Nd<sub>1</sub>Ba<sub>2</sub>Cu<sub>3</sub>O<sub>7-δ</sub>Phase
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作者 M. Sumadiyasa I. B. S. Manuaba P. Suardana 《Journal of Materials Science and Chemical Engineering》 2018年第7期117-124,共8页
One of the basic ingredients in conventional preparation of cuprates-based superconducting materials such as the Nd-Ba-Cu-O superconducting system, especially the Nd1Ba2Cu3O7-δ phase is Barium Carbonate (BaCO3). It h... One of the basic ingredients in conventional preparation of cuprates-based superconducting materials such as the Nd-Ba-Cu-O superconducting system, especially the Nd1Ba2Cu3O7-δ phase is Barium Carbonate (BaCO3). It has the potential to produce the carbon dioxide (CO2) air pollutant. Therefore it is necessary to look for other materials as the source of Ba atom which does not produce CO2 gas. In this research has been successfully made the Nd1Ba2Cu3O7-δ phase with the Barium Hydroxide Octahydrate (Ba(OH)2·8H2O) as a source of Ba atom. The results of the characterization XRD has been shown the main peaks of the Nd1Ba2Cu3O7-δ phase. Refinement of the XRD data by using Rietica software, obtained the value of GofF (Goodness of Fit) = 1.7023 and lattice parameter a ≈ b < c/3 with a value of c/3 = 3.9275 A. 展开更多
关键词 Nd1Ba2Cu3O7-δ PHASE BA Atom barium carbonate barium Hydroxide Octahydrate GofF
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