Recently,a plasma catalyst was employed to efflciently degrade antibiotic residues in the environment.In this study,the plasma generated in a packed bed dielectric barrier reactor combined with TiO_(2)catalyst is used...Recently,a plasma catalyst was employed to efflciently degrade antibiotic residues in the environment.In this study,the plasma generated in a packed bed dielectric barrier reactor combined with TiO_(2)catalyst is used to degrade the antibiotic tiamulin(TIA)loaded on the surface of simulated soil particles.The effects of applied voltage,composition of the working gas,gas flow rate and presence or absence of catalyst on the degradation effect were studied.It was found that plasma and catalyst can produce a synergistic effect under optimal conditions(applied voltage 25 k V,oxygen ratio 1%,gas flow rate 0.6 l min^(-1),treatment time 5 min).The degradation efflciency of the plasma combined with catalyst can reach 78.6%,which is 18.4%higher than that of plasma without catalyst.When the applied voltage is 30 k V,the gas flow rate is 1 l min^(-1),the oxygen ratio is 1%and the plasma combined with TiO_(2)catalyst treats the sample for 5 min the degradation efflciency of TIA reached 97%.It can be concluded that a higher applied voltage and longer processing times not only lead to more degradation but also result in a lower energy efflciency.Decreasing the oxygen ratio and gas flow rate could improve the degradation efflciency.The relative distribution and identity of the major TIA degradation product generated was determined by high-performance liquid chromatography–mass spectrometry analysis.The mechanism of TIA removal by plasma and TiO_(2)catalyst was analyzed,and the possible degradation path is discussed.展开更多
The effects of nitrogen on ozone synthesis are studied in a coaxial cylinder generator with dielectric barrier discharge（DBD） and pack-bed dielectric barrier discharge（PB-DBD）.A series of 10 h discharge experiment...The effects of nitrogen on ozone synthesis are studied in a coaxial cylinder generator with dielectric barrier discharge（DBD） and pack-bed dielectric barrier discharge（PB-DBD）.A series of 10 h discharge experiments are conducted adopting a bare stainless electrode and bare copper electrode.Results show that the material of the electrode can affect the ozone synthesis.It is inferred that the ozone zero phenomenon（OZP） may be induced from ozone decomposing by metallic oxide catalysis.Packing dielectric particles can reduce the OZP.Adding a certain amount of nitrogen into the oxygen feed gas can further eliminate the OZP,and increase the ozone concentration significantly,but decreases the maximum energy efficiency of ozone generators.Initial analysis indicates that the optimal proportion of nitrogen addition is inversely related to the average reduced electric field strength in the discharge region.展开更多
Recently,packed-bed discharge plasma technologies have been widely studied for treatment of volatile organic compounds(VOCs),due to the good performance in improving the degradation and mineralization of VOCs.In this ...Recently,packed-bed discharge plasma technologies have been widely studied for treatment of volatile organic compounds(VOCs),due to the good performance in improving the degradation and mineralization of VOCs.In this paper,a coaxial cylindrical dielectric barrier discharge reactor packed with porous material of micron-sized pores was used for degradation of benzene,and the discharge characteristics and ozone generation characteristics were studied.When the discharge length was 12 cm and the filling length was 5 cm,the packed particles in the discharge area significantly increased the number of micro-discharges,and the current amplitude and density increased with the pore size of packed particles,but the discharge power and ozone concentration showed a trend of first increasing and then decreasing.The discharge power and ozone production reached the maximum when the size of pore former was 75μm,correspondingly,the degradation efficiency of benzene was the highest.展开更多
基金supported by National Natural Science Foundation of China(Nos.51967018,11965018 and 51967017)the Science and Technology Development Fund of Xinjiang Production and Construction(No.2019BC009)the Innovation and Development Special Project of Shihezi University(No.CXFZ202105)。
文摘Recently,a plasma catalyst was employed to efflciently degrade antibiotic residues in the environment.In this study,the plasma generated in a packed bed dielectric barrier reactor combined with TiO_(2)catalyst is used to degrade the antibiotic tiamulin(TIA)loaded on the surface of simulated soil particles.The effects of applied voltage,composition of the working gas,gas flow rate and presence or absence of catalyst on the degradation effect were studied.It was found that plasma and catalyst can produce a synergistic effect under optimal conditions(applied voltage 25 k V,oxygen ratio 1%,gas flow rate 0.6 l min^(-1),treatment time 5 min).The degradation efflciency of the plasma combined with catalyst can reach 78.6%,which is 18.4%higher than that of plasma without catalyst.When the applied voltage is 30 k V,the gas flow rate is 1 l min^(-1),the oxygen ratio is 1%and the plasma combined with TiO_(2)catalyst treats the sample for 5 min the degradation efflciency of TIA reached 97%.It can be concluded that a higher applied voltage and longer processing times not only lead to more degradation but also result in a lower energy efflciency.Decreasing the oxygen ratio and gas flow rate could improve the degradation efflciency.The relative distribution and identity of the major TIA degradation product generated was determined by high-performance liquid chromatography–mass spectrometry analysis.The mechanism of TIA removal by plasma and TiO_(2)catalyst was analyzed,and the possible degradation path is discussed.
基金supported by National Natural Science Foundation of China(No.11675177)Anhui Province ST program(No.1604a0902)
文摘The effects of nitrogen on ozone synthesis are studied in a coaxial cylinder generator with dielectric barrier discharge（DBD） and pack-bed dielectric barrier discharge（PB-DBD）.A series of 10 h discharge experiments are conducted adopting a bare stainless electrode and bare copper electrode.Results show that the material of the electrode can affect the ozone synthesis.It is inferred that the ozone zero phenomenon（OZP） may be induced from ozone decomposing by metallic oxide catalysis.Packing dielectric particles can reduce the OZP.Adding a certain amount of nitrogen into the oxygen feed gas can further eliminate the OZP,and increase the ozone concentration significantly,but decreases the maximum energy efficiency of ozone generators.Initial analysis indicates that the optimal proportion of nitrogen addition is inversely related to the average reduced electric field strength in the discharge region.
基金supported by National Natural Science Foundation of China(Nos.51977024,21577011)。
文摘Recently,packed-bed discharge plasma technologies have been widely studied for treatment of volatile organic compounds(VOCs),due to the good performance in improving the degradation and mineralization of VOCs.In this paper,a coaxial cylindrical dielectric barrier discharge reactor packed with porous material of micron-sized pores was used for degradation of benzene,and the discharge characteristics and ozone generation characteristics were studied.When the discharge length was 12 cm and the filling length was 5 cm,the packed particles in the discharge area significantly increased the number of micro-discharges,and the current amplitude and density increased with the pore size of packed particles,but the discharge power and ozone concentration showed a trend of first increasing and then decreasing.The discharge power and ozone production reached the maximum when the size of pore former was 75μm,correspondingly,the degradation efficiency of benzene was the highest.
