Continuous basalt fiber(CBF)is an outstanding inorganic fiber produced from nature,which has a wide range of applications in the field of armor protection of national defense military.However,the mechanical response a...Continuous basalt fiber(CBF)is an outstanding inorganic fiber produced from nature,which has a wide range of applications in the field of armor protection of national defense military.However,the mechanical response and failure mechanism of 3D printed CBF reinforced components are still not well understood.Here,the 3D printing thermoplastic composites with high volume fraction CBF have been successfully prepared by fused deposition modelling(FDM)method.The effects of fiber printing direction and polymer matrix type on the tensile and flexural properties of the 3D printed composites have been explored,and the detailed failure morphology has been characterized using scanning electron microscopy and optical microscopy.It was found that under high fiber volume fraction,3D printed CBF reinforced polyamides(PA)composites have the best ability to maintain material integrity of the composites,followed by acrylonitrile butadiene styrene(ABS)and high impact polystyrene(HIPS).Besides,the results from rule of mixtures can accurately predict the longitudinal Young’s modulus of the 3D printed specimens,but there exists a large discrepancy for the prediction of the tensile strength.The microstructure analysis shows that the failure modes of 3D printed composites mainly include fiber debonding,fiber pull-out,stress whitening and matrix cracking.展开更多
To enhance the sulfate attack resistance performance of concrete,Sulfate erosion test was carried out on basalt fiber concrete with different contents,selecting a concentration of 5%sulfate solution and using a dry−we...To enhance the sulfate attack resistance performance of concrete,Sulfate erosion test was carried out on basalt fiber concrete with different contents,selecting a concentration of 5%sulfate solution and using a dry−wet cycle mechanism attack of basalt fiber-reinforced concrete(BFRC).Every 15 dry−wet cycles,the mass,compressive strength,splitting tensile strength,and relative dynamic elastic modulus of BFRC were tested,and the SO_(4)^(2−)con-centration was measured.This work demonstrates that the mass,relative dynamic elastic modulus,compressive and splitting tensile strength of BFRC reveal a trend of climb up and then decline with the process of the dry−wet cycle.Basalt fiber can enhance the sulfate corrosion resistance of concrete by delaying the erosion of concrete induced by SO_(4)^(2−)and increasing the bearing and anti-deformation capacities of concrete by improving its inter-nal structure.Additionally,when mixing 0.2%basalt fiber into concrete,the strength deterioration rate will be reduced when the peak values of splitting tensile and compressive strength appear at 60 and 75 times the alter-nating dry−wet cycles,respectively.Adverse effects will occur when the fiber volume fraction exceeds 0.2%.The research in this paper can provide a foundation for the engineering applications of basalt fiber concrete.展开更多
The development of recycled aggregate concrete(RAC)provides a new approach to limiting the waste of natural resources.In the present study,the mechanical properties and deformability of RACs were improved by adding ba...The development of recycled aggregate concrete(RAC)provides a new approach to limiting the waste of natural resources.In the present study,the mechanical properties and deformability of RACs were improved by adding basalt fibers(BFs)and using external restraints,such as a fiber-reinforced polymer(FRP)jacket or a PVC pipe.Samples were tested under axial compression.The results showed that RAC(50%replacement of aggregate)containing 0.2%BFs had the best mechanical properties.Using either BFs or PVC reinforcement had a slight effect on the loadbearing capacity and mode of failure.With different levels of BFs,the compressive strengths of the specimens reinforced with 1-layer and 3-layer basalt fiber reinforced polymer(BFRP)increased by 6.7%–10.5%and 16.5%–23.7%,respectively,and the ultimate strains increased by 48.5%–80.7%and 97.1%–141.1%,respectively.The peak stress of the 3-layer BFRP-PVC increased by 42.2%,and the ultimate strain improved by 131.3%,relative to the control.This reinforcement combined the high tensile strength of BFRP,which improved the post-peak behavior,and PVC,which enhanced the structural durability.In addition,to investigate the influence of the various constraints on compressive behavior,the stress-strain response was analyzed.Based on the analysis of experimental results,a peak stress-strain model and an amended ultimate stress-strain model were proposed.The models were verified as well;the result showed that the predictions from calculations are generally consistent with the experimental data(error within 10%).The results of this study provide a theoretical basis and reference for future applications of fiber-reinforced recycled concrete.展开更多
The purpose of this study is to investigate the effect of the concentration of silane coupling solution on the tensile strength of basalt fiber and the interfacial properties of basalt fiber reinforced polymer composi...The purpose of this study is to investigate the effect of the concentration of silane coupling solution on the tensile strength of basalt fiber and the interfacial properties of basalt fiber reinforced polymer composites.The surface treatment of basalt fibers was carried out using an aqueous alcohol solution method.Basalt fibers were subjected to surface treatment with 3-Methacryloxypropyl trimethoxy silane at 0.5 wt.%,1 wt.%,2 wt.%,4 wt.%and 10 wt.%.The basalt monofilament tensile tests were carried out to investigate the variation in strength with the concentration of the silane coupling agent.The microdroplet test was performed to examine the effect of the concentration of the silane coupling agent on interfacial strength of basalt reinforced polymer composites.The film was formed on the surface of the basalt fiber treated silane coupling agent solution.The tensile strength of basalt fiber increased because the damaged fiber surface was repaired by the firm of silane coupling agent.The firm was effective in not only the surface protection of basalt fiber but also the improvement on the interfacial strength of fiber-matrix interface.However,the surface treatment using the high concentration silane coupling agent solution has an adverse effect on the mechanical properties of the composite materials,because of causing the degradation of the interfacial strength of the composite materials.展开更多
The fatigue property of asphalt mixtures under complicated environment (low-temperature bending performance, chloride penetration, freezing-thawing cycle and their coupling effect) and the improvement effect for rel...The fatigue property of asphalt mixtures under complicated environment (low-temperature bending performance, chloride penetration, freezing-thawing cycle and their coupling effect) and the improvement effect for relevant property of basalt fiber-reinforcing asphalt mixture under complicated environment are studied. Two grading types of asphalt mixtures, AC-16I and AC-13I, are chosen, whose optimum asphalt-aggregate ratio and optimum dosage of basalt fiber are determined by the Marshall test. The standard specimens are made firstly, and then the low temperature bending tests of asphalt mixture and basalt fiber-reinforced asphalt mixture under the coupling effect of the chloride erosion and freezing-thawing cycle have been carried out. Finally, the fatigue property tests of asphalt mixture and basalt fiber-reinforced asphalt mixture under complex environment are performed on MTS material testing system. The results indicate that the tensile strength, the maximum curving tensile stress, the curving stiffness modulus, and fatigue properties of asphalt mixture are influenced by the coupling effect of the chloride erosion and freezing-thawing cycle. The low-temperature bending performance and fatigue property of asphalt mixtures under complicated environment can be greatly improved by adding moderate basalt fiber. The dense gradation asphalt mixture possesses stronger ability to resist adverse environmental effects under the same condition.展开更多
To study the applicability of the basalt fiber through various experimental works in thermal and chemical environments, glass fiber and carbon fiber were compared and discussed. The tensile strength testing was used t...To study the applicability of the basalt fiber through various experimental works in thermal and chemical environments, glass fiber and carbon fiber were compared and discussed. The tensile strength testing was used to investigate the corrosive resistance of basalt fiber, meanwhile, surface study by scanning electron microscopy and microanalysis with complementary X-ray diffraction analysis (SEM/EDS) was also used to ascertain the durability of basalt fiber. The basalt fiber showed better strength retention than the glass fiber at relatively high temperature. Its tensile strength increased when exposed at 300 ~C for several hours, and still maintain about 70% of the initial strength at 400 ~C, whereas that of the glass fiber decreased dramatically. The better stability of the basalt fiber was observed in hydrothermal and chemical environment. The tensile strength of the basalt fiber increased by 20% after the immersion in boiling water and remained well in acid solution, when it comes to glass fiber, the tensile strength decreased to some extent. Although the alkali resistance of basalt fiber was poor at the initial stage, it shows better resistance than the glass fiber after long time treatment.展开更多
The characters of basalt fiber are analyzed and compared with commonly used fibers. The rheological behaviors of the basalt fiber reinforced asphalt mastic are investigated by the dynamic shear rheological tests and t...The characters of basalt fiber are analyzed and compared with commonly used fibers. The rheological behaviors of the basalt fiber reinforced asphalt mastic are investigated by the dynamic shear rheological tests and the repeated creep tests. The results show that basalt fiber has excellent reinforced performances, such as high asphalt absorption ratio, low water absorption ratio, high tensile strength, high elastic modulus and high temperature stability. The rutting factor of the fiber reinforced asphalt mastic is higher than the plain asphalt mastic and the reinforced effects are more remarkable under high temperature. The rheological performances of the asphalt mastic demonstrate a good linear relationship between different temperature and loading frequency. The creep stiffness modulus of the asphalt mastic at different loading time can be expressed by power function. Improved Burgers model is used to represent the rheological behaviors of the asphalt mastic with basalt fiber and the model parameters are estimated.展开更多
The woven basalt fiber composites(WBFC) and the unidirectional [0°/90°/45°/-45°]s basalt fiber composites(UBFC) were prepared by hot-pressing.Three-point bending test,low velocity impact test,and b...The woven basalt fiber composites(WBFC) and the unidirectional [0°/90°/45°/-45°]s basalt fiber composites(UBFC) were prepared by hot-pressing.Three-point bending test,low velocity impact test,and ballistic test were performed to the prepared composites.After the tests,the specimens were recovered and analyzed for micromorphology.Three-point bending tests show that both the bending strength and stiffness of the WBFC surpass those of the UBFC.Low velocity impact test results show that the low velocity impact resistance to hemispherical impactor of the UBFC is higher than that of the WBFC,but the low velocity impact resistance to sharp impactor of the UBFC is lower than that of the WBFC.For the ballistic test,it can be found that the ballistic property of the UBFC is higher than that of the WBFC. After the tests,microscopic analysis of the specimens was applied,and their failure mechanism was discussed.The main failure modes of the UBFC are delamination and fibers breakage under the above loading conditions while the main failure mode of the WBFC is fibers breakage.Although delamination damage can be found in the WBFC under the above loading conditions,the degree of delamination is far less than that of the UBFC.展开更多
In this paper, a micro-mechanical model is implemented in software for the prediction of local mechanical properties of discontinuous short fiber reinforced composites. The model, based on the Mori and Tanaka method, ...In this paper, a micro-mechanical model is implemented in software for the prediction of local mechanical properties of discontinuous short fiber reinforced composites. The model, based on the Mori and Tanaka method, shear-lag, computational model, Nielsen-Chen model and Miwa’s model is used to predict the elastic behaviour of basalt short fiber reinforced with Al alloy composites. The Al/basalt Metal Matrix Composites (MMCs) contain basalt short fiber from 2.5% to 10% in steps of 2.5 wt.% and are fabricated using squeeze infiltration technique. The effects of fiber length and orientation on elastic properties of Al/basalt MMCs are investigated. A comparison between the experimental data and the theoretical data based on physical models is made, and the significance of the findings is discussed. The results show that as short basalt fiber content was increased from 2.5% to 10% by wt.%, an improvement in Young’s modulus of 13.26% has been observed. Optical microscopy was used to examine the general microstructure and fiber distribution in the composite produced. Scanning Electron Microscopy (SEM) was performed on the fractured surface to understand the failure mechanisms.展开更多
In this investigation, basalt mineral fiber softening agent was prepared in order to obtain desirable flexible performance. Stability and physical chemistry natures of softening agent were evaluated by particle size d...In this investigation, basalt mineral fiber softening agent was prepared in order to obtain desirable flexible performance. Stability and physical chemistry natures of softening agent were evaluated by particle size distribution, dilution, storage and folding endurance etc. Constitutes of basalt and wood fibers were determined by energy dispersion analysis X-ray which served as an accessory of scanning electron microscopy (SEM-EDAX). Naturally degradable ecocomposite was prepared by basalt and wood fibers. The results of SEM observation illustrated that the wood and basalt fibers were blended uniformly. The impact factors of beating degree, content of wood fibers and adhesive etc. were discussed. The structure of the naturally degradable ecocomposite was contrasted with that of pure wood fibers and the cause of excellent filtration performance was analyzed. Compared with traditional methods, it was of saving wood resource, a large amount of water and reducing second pollution. As a consequence, the ecocomposite harmonized with environment and accorded with requirement of benignly friendly environment.展开更多
基金the financial support from the National Key Research and Development Program of China(grant no.2020YFA0711800)National Natural Science Foundation of China(grant no.11802027)+2 种基金State Key Laboratory of Explosion Science and Technology(grant no.YPJH20-6,QNKT20-01,JCRC18-01)BITBRFFR Joint Research Program(BITBLR2020018)Beijing Institute of Technology Research Fund。
文摘Continuous basalt fiber(CBF)is an outstanding inorganic fiber produced from nature,which has a wide range of applications in the field of armor protection of national defense military.However,the mechanical response and failure mechanism of 3D printed CBF reinforced components are still not well understood.Here,the 3D printing thermoplastic composites with high volume fraction CBF have been successfully prepared by fused deposition modelling(FDM)method.The effects of fiber printing direction and polymer matrix type on the tensile and flexural properties of the 3D printed composites have been explored,and the detailed failure morphology has been characterized using scanning electron microscopy and optical microscopy.It was found that under high fiber volume fraction,3D printed CBF reinforced polyamides(PA)composites have the best ability to maintain material integrity of the composites,followed by acrylonitrile butadiene styrene(ABS)and high impact polystyrene(HIPS).Besides,the results from rule of mixtures can accurately predict the longitudinal Young’s modulus of the 3D printed specimens,but there exists a large discrepancy for the prediction of the tensile strength.The microstructure analysis shows that the failure modes of 3D printed composites mainly include fiber debonding,fiber pull-out,stress whitening and matrix cracking.
基金supports for the study were provided by the Natural Sciences Foundation Committee of China(Grant No.41472254,Jinming Xu,http://www.nsfc.gov.cn)。
文摘To enhance the sulfate attack resistance performance of concrete,Sulfate erosion test was carried out on basalt fiber concrete with different contents,selecting a concentration of 5%sulfate solution and using a dry−wet cycle mechanism attack of basalt fiber-reinforced concrete(BFRC).Every 15 dry−wet cycles,the mass,compressive strength,splitting tensile strength,and relative dynamic elastic modulus of BFRC were tested,and the SO_(4)^(2−)con-centration was measured.This work demonstrates that the mass,relative dynamic elastic modulus,compressive and splitting tensile strength of BFRC reveal a trend of climb up and then decline with the process of the dry−wet cycle.Basalt fiber can enhance the sulfate corrosion resistance of concrete by delaying the erosion of concrete induced by SO_(4)^(2−)and increasing the bearing and anti-deformation capacities of concrete by improving its inter-nal structure.Additionally,when mixing 0.2%basalt fiber into concrete,the strength deterioration rate will be reduced when the peak values of splitting tensile and compressive strength appear at 60 and 75 times the alter-nating dry−wet cycles,respectively.Adverse effects will occur when the fiber volume fraction exceeds 0.2%.The research in this paper can provide a foundation for the engineering applications of basalt fiber concrete.
基金supported by the Natural Science Foundation Project of Liaoning Provincial Department of Education of China under Grant No.JJL201915404,Zhejiang Provincial Natural Science Foundation of China under Grant No.LQ22E080024 and Zhejiang Province Department of Education Fund of China under Grant No.Y202146776.
文摘The development of recycled aggregate concrete(RAC)provides a new approach to limiting the waste of natural resources.In the present study,the mechanical properties and deformability of RACs were improved by adding basalt fibers(BFs)and using external restraints,such as a fiber-reinforced polymer(FRP)jacket or a PVC pipe.Samples were tested under axial compression.The results showed that RAC(50%replacement of aggregate)containing 0.2%BFs had the best mechanical properties.Using either BFs or PVC reinforcement had a slight effect on the loadbearing capacity and mode of failure.With different levels of BFs,the compressive strengths of the specimens reinforced with 1-layer and 3-layer basalt fiber reinforced polymer(BFRP)increased by 6.7%–10.5%and 16.5%–23.7%,respectively,and the ultimate strains increased by 48.5%–80.7%and 97.1%–141.1%,respectively.The peak stress of the 3-layer BFRP-PVC increased by 42.2%,and the ultimate strain improved by 131.3%,relative to the control.This reinforcement combined the high tensile strength of BFRP,which improved the post-peak behavior,and PVC,which enhanced the structural durability.In addition,to investigate the influence of the various constraints on compressive behavior,the stress-strain response was analyzed.Based on the analysis of experimental results,a peak stress-strain model and an amended ultimate stress-strain model were proposed.The models were verified as well;the result showed that the predictions from calculations are generally consistent with the experimental data(error within 10%).The results of this study provide a theoretical basis and reference for future applications of fiber-reinforced recycled concrete.
文摘The purpose of this study is to investigate the effect of the concentration of silane coupling solution on the tensile strength of basalt fiber and the interfacial properties of basalt fiber reinforced polymer composites.The surface treatment of basalt fibers was carried out using an aqueous alcohol solution method.Basalt fibers were subjected to surface treatment with 3-Methacryloxypropyl trimethoxy silane at 0.5 wt.%,1 wt.%,2 wt.%,4 wt.%and 10 wt.%.The basalt monofilament tensile tests were carried out to investigate the variation in strength with the concentration of the silane coupling agent.The microdroplet test was performed to examine the effect of the concentration of the silane coupling agent on interfacial strength of basalt reinforced polymer composites.The film was formed on the surface of the basalt fiber treated silane coupling agent solution.The tensile strength of basalt fiber increased because the damaged fiber surface was repaired by the firm of silane coupling agent.The firm was effective in not only the surface protection of basalt fiber but also the improvement on the interfacial strength of fiber-matrix interface.However,the surface treatment using the high concentration silane coupling agent solution has an adverse effect on the mechanical properties of the composite materials,because of causing the degradation of the interfacial strength of the composite materials.
基金Fund by Collaborative Innovation Center of Water Conservancy&Transportation Infrastructure Safety,Henan Province,China Postdoctoral Science Fund(No.20110491008)Science and Technology Planning Project of Department of Transportation of Henan Province(No.2013-2-12)The State Key Laboratory Open Fund of Harbor,Coastal and Offshore Engineering(No.LP1113)
文摘The fatigue property of asphalt mixtures under complicated environment (low-temperature bending performance, chloride penetration, freezing-thawing cycle and their coupling effect) and the improvement effect for relevant property of basalt fiber-reinforcing asphalt mixture under complicated environment are studied. Two grading types of asphalt mixtures, AC-16I and AC-13I, are chosen, whose optimum asphalt-aggregate ratio and optimum dosage of basalt fiber are determined by the Marshall test. The standard specimens are made firstly, and then the low temperature bending tests of asphalt mixture and basalt fiber-reinforced asphalt mixture under the coupling effect of the chloride erosion and freezing-thawing cycle have been carried out. Finally, the fatigue property tests of asphalt mixture and basalt fiber-reinforced asphalt mixture under complex environment are performed on MTS material testing system. The results indicate that the tensile strength, the maximum curving tensile stress, the curving stiffness modulus, and fatigue properties of asphalt mixture are influenced by the coupling effect of the chloride erosion and freezing-thawing cycle. The low-temperature bending performance and fatigue property of asphalt mixtures under complicated environment can be greatly improved by adding moderate basalt fiber. The dense gradation asphalt mixture possesses stronger ability to resist adverse environmental effects under the same condition.
文摘To study the applicability of the basalt fiber through various experimental works in thermal and chemical environments, glass fiber and carbon fiber were compared and discussed. The tensile strength testing was used to investigate the corrosive resistance of basalt fiber, meanwhile, surface study by scanning electron microscopy and microanalysis with complementary X-ray diffraction analysis (SEM/EDS) was also used to ascertain the durability of basalt fiber. The basalt fiber showed better strength retention than the glass fiber at relatively high temperature. Its tensile strength increased when exposed at 300 ~C for several hours, and still maintain about 70% of the initial strength at 400 ~C, whereas that of the glass fiber decreased dramatically. The better stability of the basalt fiber was observed in hydrothermal and chemical environment. The tensile strength of the basalt fiber increased by 20% after the immersion in boiling water and remained well in acid solution, when it comes to glass fiber, the tensile strength decreased to some extent. Although the alkali resistance of basalt fiber was poor at the initial stage, it shows better resistance than the glass fiber after long time treatment.
基金Funded by The National Natural Science Foundation of China(No.51108082)
文摘The characters of basalt fiber are analyzed and compared with commonly used fibers. The rheological behaviors of the basalt fiber reinforced asphalt mastic are investigated by the dynamic shear rheological tests and the repeated creep tests. The results show that basalt fiber has excellent reinforced performances, such as high asphalt absorption ratio, low water absorption ratio, high tensile strength, high elastic modulus and high temperature stability. The rutting factor of the fiber reinforced asphalt mastic is higher than the plain asphalt mastic and the reinforced effects are more remarkable under high temperature. The rheological performances of the asphalt mastic demonstrate a good linear relationship between different temperature and loading frequency. The creep stiffness modulus of the asphalt mastic at different loading time can be expressed by power function. Improved Burgers model is used to represent the rheological behaviors of the asphalt mastic with basalt fiber and the model parameters are estimated.
基金supported by the National Science Foundation of China(No.51571033)supported in part by the National Natural Science Foundation of China under Grant No.11521062。
文摘The woven basalt fiber composites(WBFC) and the unidirectional [0°/90°/45°/-45°]s basalt fiber composites(UBFC) were prepared by hot-pressing.Three-point bending test,low velocity impact test,and ballistic test were performed to the prepared composites.After the tests,the specimens were recovered and analyzed for micromorphology.Three-point bending tests show that both the bending strength and stiffness of the WBFC surpass those of the UBFC.Low velocity impact test results show that the low velocity impact resistance to hemispherical impactor of the UBFC is higher than that of the WBFC,but the low velocity impact resistance to sharp impactor of the UBFC is lower than that of the WBFC.For the ballistic test,it can be found that the ballistic property of the UBFC is higher than that of the WBFC. After the tests,microscopic analysis of the specimens was applied,and their failure mechanism was discussed.The main failure modes of the UBFC are delamination and fibers breakage under the above loading conditions while the main failure mode of the WBFC is fibers breakage.Although delamination damage can be found in the WBFC under the above loading conditions,the degree of delamination is far less than that of the UBFC.
文摘In this paper, a micro-mechanical model is implemented in software for the prediction of local mechanical properties of discontinuous short fiber reinforced composites. The model, based on the Mori and Tanaka method, shear-lag, computational model, Nielsen-Chen model and Miwa’s model is used to predict the elastic behaviour of basalt short fiber reinforced with Al alloy composites. The Al/basalt Metal Matrix Composites (MMCs) contain basalt short fiber from 2.5% to 10% in steps of 2.5 wt.% and are fabricated using squeeze infiltration technique. The effects of fiber length and orientation on elastic properties of Al/basalt MMCs are investigated. A comparison between the experimental data and the theoretical data based on physical models is made, and the significance of the findings is discussed. The results show that as short basalt fiber content was increased from 2.5% to 10% by wt.%, an improvement in Young’s modulus of 13.26% has been observed. Optical microscopy was used to examine the general microstructure and fiber distribution in the composite produced. Scanning Electron Microscopy (SEM) was performed on the fractured surface to understand the failure mechanisms.
文摘In this investigation, basalt mineral fiber softening agent was prepared in order to obtain desirable flexible performance. Stability and physical chemistry natures of softening agent were evaluated by particle size distribution, dilution, storage and folding endurance etc. Constitutes of basalt and wood fibers were determined by energy dispersion analysis X-ray which served as an accessory of scanning electron microscopy (SEM-EDAX). Naturally degradable ecocomposite was prepared by basalt and wood fibers. The results of SEM observation illustrated that the wood and basalt fibers were blended uniformly. The impact factors of beating degree, content of wood fibers and adhesive etc. were discussed. The structure of the naturally degradable ecocomposite was contrasted with that of pure wood fibers and the cause of excellent filtration performance was analyzed. Compared with traditional methods, it was of saving wood resource, a large amount of water and reducing second pollution. As a consequence, the ecocomposite harmonized with environment and accorded with requirement of benignly friendly environment.