With regard to micro-light-emitting diodes(micro-LEDs),their excellent brightness,low energy consumption,and ultrahigh resolution are significant advantages.However,the large size of traditional inorganic phosphors an...With regard to micro-light-emitting diodes(micro-LEDs),their excellent brightness,low energy consumption,and ultrahigh resolution are significant advantages.However,the large size of traditional inorganic phosphors and the number of side defects have restricted the practical applications of small sized micro-LEDs.Recently,quantum dot(QD)and nonradiative energy transfer(NRET)have been proposed to solve existing problems.QDs possess nanoscale dimensions and high luminous efficiency,and they are suitable for NRET because they are able to nearly contact the micro-LED chip.The NRET between QDs and micro-LED chip further improves the color conversion efficiency(CCE)and effective quantum yield(EQY)of full-color micro-LED devices.In this review,we discuss the NRET mechanism for QD micro-LED devices,and then nano-pillar LED,nano-hole LED,and nano-ring LED are introduced in detail.These structures are beneficial to the NRET between QD and micro-LED,especially nano-ring LED.Finally,the challenges and future envisions have also been described.展开更多
Quantum random number generators adopting single negligible dead time of avalanche photodiodes (APDs) photon detection have been restricted due to the non- We propose a new approach based on an APD array to improve...Quantum random number generators adopting single negligible dead time of avalanche photodiodes (APDs) photon detection have been restricted due to the non- We propose a new approach based on an APD array to improve the generation rate of random numbers significantly. This method compares the detectors' responses to consecutive optical pulses and generates the random sequence. We implement a demonstration experiment to show its simplicity, compactness and scalability. The generated numbers are proved to be unbiased, post-processing free, ready to use, and their randomness is verified by using the national institute of standard technology statistical test suite. The random bit generation efficiency is as high as 32.8% and the potential generation rate adopting the 32× 32 APD array is up to tens of Gbits/s.展开更多
Two new schiff base N,N'-bis((2-phenyl-2H-1,2,3-triazol-4-yl)methylene)-1,3-propanediamine (1) and N,N'-bis((2-phenyl-2H-1,2,3-triazol-4-yl)methylene) -1,4-butanediamine (2) were synthesized by condensat...Two new schiff base N,N'-bis((2-phenyl-2H-1,2,3-triazol-4-yl)methylene)-1,3-propanediamine (1) and N,N'-bis((2-phenyl-2H-1,2,3-triazol-4-yl)methylene) -1,4-butanediamine (2) were synthesized by condensation of 2-phenyl-1,2,3-triazole-4-carboxaldehyde with diamine, and characterized by elemental analysis, IR, IH NMR and MS spectra. Their crystal structures were determined by X-ray single crystal diffraction. Both crystals belong to the monoclinic system, space group P21/c. For compound 1(C21H20N8, Mr=384.45): a = 16.314(3), b =5.7168(11), c = 21.316(4) A, β = 105.3(2)°, Z = 4, V = 1917.6(7) A^3, De =1.332 g/cm^3, F(000) = 808,μ = 0.086 mm 1, R = 0.0533 and wR = 0.1460; for compound 2 (C22H22N8, Mr=398.48): a = 8.6156(17), b = 5.2964(11), c = 22.665(5)A, β = 100.54(3)°, Z = 2, V = 1016.8(4) A^3, De= 1.302 g/cm^3, F (000) = 420, μ = 0.083 mm^-1, R = 0.0373 and wR = 0.1155. Based on the crystal data, quantum chemistry calculation was performed on the two title compounds by means of Gaussian 98 program. The molecular orbital energies and atomic net charges population were obtained. Furthermore, we antilyzed their active atoms. The investigation can serve as a theoretical guide to study the synthesis and activity of the title compounds.展开更多
During the last two decades, III-nitride-based quantum dots(QDs) have attracted great attentions for optoelectronic applications due to their unique electronic properties. In this paper, we first present an overview o...During the last two decades, III-nitride-based quantum dots(QDs) have attracted great attentions for optoelectronic applications due to their unique electronic properties. In this paper, we first present an overview on the techniques of fabrication for III-nitride-based QDs. Then various optoelectronic devices such as QD lasers, QD light-emitting diodes(LEDs), QD infrared photodetectors(QDIPs) and QD intermediate band(QDIB) solar cells(SCs) are discussed. Finally, we focus on the future research directions and how the challenges can be overcome.展开更多
This paper studies quantum discord of two qutrits coupled to their own environments independently and coupled to the same environment simultaneously under quantum-jump-based feedback control. Our results show that spo...This paper studies quantum discord of two qutrits coupled to their own environments independently and coupled to the same environment simultaneously under quantum-jump-based feedback control. Our results show that spontaneous emission, quantum feedback parameters, classical driving, initial state, and detection efficiency all affect the evolution of quantum discord in a two-qutrit system. We find that under the condition of designing proper quantum-jump-based feedback parameters, quantum discord can be protected and prepared. In the case where two qutrits are independently coupled to their own environments, classical driving, spontaneous emission, and low detection efficiency have negative effect on the protection of quantum discord. For different initial states, it is found that the evolution of quantum discord under the control of appropriate parameters is similar. In the case where two qutrits are simultaneously coupled to the same environment,the classical driving plays a positive role in the generation of quantum discord, but spontaneous emission and low detection efficiency have negative impact on the generation of quantum discord. Most importantly, we find that the steady discord depends on feedback parameters, classical driving, and detection efficiency, but not on the initial state.展开更多
We propose a novel strategy numed basis-splitting scheme to split the intercepted quanta into several portions based on different bases, for eavesdropping in the process of quantum cryptography. Compared with intercep...We propose a novel strategy numed basis-splitting scheme to split the intercepted quanta into several portions based on different bases, for eavesdropping in the process of quantum cryptography. Compared with intercept- resend strategy, our simulation results of the basis-splitting scheme under the non-ideal condition show a greater performance, especially with the increase of the length of shifted bits. Consequently our scheme can aid eaves- dropper to gather much more useful information.展开更多
Quantum key distribution(QKD) generates information-theoretical secret keys between two parties based on the physical laws of quantum mechanics. Following the advancement in quantum communication networks, it becomes ...Quantum key distribution(QKD) generates information-theoretical secret keys between two parties based on the physical laws of quantum mechanics. Following the advancement in quantum communication networks, it becomes feasible and economical to combine QKD with classical optical communication through the same fiber using dense wavelength division multiplexing(DWDM) technology. This study proposes a detailed scheme of TF-QKD protocol with DWDM technology and analyzes its performance, considering the influence of quantum channel number and adjacent quantum crosstalk on the secret key rates. The simulation results show that the scheme further increases the secret key rate of TF-QKD and its variants. Therefore, this scheme provides a method for improving the secret key rate for practical quantum networks.展开更多
In the paper [2010 Chin. Phys. B 19 050306], Yang et al. put forward a novel three-party quantum secret sharing protocol of secure direct communication based on x-type entangled states, they claimed that the scheme is...In the paper [2010 Chin. Phys. B 19 050306], Yang et al. put forward a novel three-party quantum secret sharing protocol of secure direct communication based on x-type entangled states, they claimed that the scheme is secure. However, in this paper, we study the security of the protocol and find that it is insecure. Applying intercept and resend attack, the agent Bob can obtain Alice's secret without the help from the other agent Charlie. In the end, we give our effective modification for its improvement.展开更多
Quantum-dot cellular automaton (QCA) is a novel nanotechnology that provides a very different computation platform than traditional CMOS, in which polarization of electrons indicates the digital information. This pape...Quantum-dot cellular automaton (QCA) is a novel nanotechnology that provides a very different computation platform than traditional CMOS, in which polarization of electrons indicates the digital information. This paper demonstrates designing combinational circuits based on quantum-dot cellular automata (QCA) nanotechnology, which offers a way to implement logic and all interconnections with only one homogeneous layer of cells. In this paper, the authors have proposed a novel design of XOR gate. This model proves designing capabilities of combinational circuits that are compatible with QCA gates within nano-scale. Novel adder circuits such as half adders, full adders, which avoid the fore, mentioned noise paths, crossovers by careful clocking organization, have been proposed. Experiment results show that the performance of proposed designs is more efficient than conventional designs. The modular layouts are verified with the freely available QCA Designer tool.展开更多
For an open quantum system containing two qubits under homodyne-based feedback control, we investigate the dynamical behaviors of quantum-memory-assisted entropic uncertainty.Moreover, we analyze the influence of feed...For an open quantum system containing two qubits under homodyne-based feedback control, we investigate the dynamical behaviors of quantum-memory-assisted entropic uncertainty.Moreover, we analyze the influence of feedback modes and coefficients on the entropic uncertainty.Numerical investigations show that the memory qubit should be placed in a non-dissipative channel if the single dissipative channel condition can be chosen, which helps reduce the entropic uncertainty of the system.For the homodyne feedback control F =λσx(or F =λσy), due to different roles of the entangled qubits A and B, when they are subject to feedback control with different feedback coefficients λ, the exchange of feedback coefficients will cause variations of the entropic uncertainty.When the feedback coefficient corresponding to the memory qubit B is larger(λB >λA), the steady value of the entropic uncertainty will be small, which is conducive to enhancing the robustness of the system.However, for the feedback control F =λσz, the difference between the feedback coefficients has no effect on the steady values of the entropic uncertainty.展开更多
This paper presents a modified secure direct communication protocol by using the blind polarization bases and particles' random transmitting order. In our protocol, a sender (Alice) encodes secret messages by rotat...This paper presents a modified secure direct communication protocol by using the blind polarization bases and particles' random transmitting order. In our protocol, a sender (Alice) encodes secret messages by rotating a random polarization angle of particle and then the receiver (Bob) sends back these particles as a random sequence. This ensures the security of communication.展开更多
Quantum cryptography exploits the quantum mechanical properties of communication lines to enhance the security of the so-called key distribution. In this work, we explain the role played by quantum mechanics in crypto...Quantum cryptography exploits the quantum mechanical properties of communication lines to enhance the security of the so-called key distribution. In this work, we explain the role played by quantum mechanics in cryptographic tasks and also investigate how secure is quantum cryptography. More importantly, we show by a simple security proof that for any state sent by the sender, the eavesdropper can only guess the output state with a probability that will allow her not to learn more than half of the classical Shannon information shared between the legitimate parties. This implies that with high probability, the shared key is secure.展开更多
GaN-based irregular multiple quantum well (IMQW) structures assembled two different types of QWs emitting complementary wavelengths for dichromatic white light-emitting diodes (LEDs) are optimized in order to obta...GaN-based irregular multiple quantum well (IMQW) structures assembled two different types of QWs emitting complementary wavelengths for dichromatic white light-emitting diodes (LEDs) are optimized in order to obtain near white light emissions. The hole distributions and spontaneous emission spectra of the IMQW structures are analysed in detail by fully considering the effects of strain, well-coupling, valence band-mixing and polarization effect through employing a newly developed theoretical model from the k. p theory. Several structure parameters such as well material component, well width, layout of the wells and the thickness of harrier between different types of QWs are employed to analyse how these parameters together with the polarization effect influence the electronic and the optical properties of IMQW structure. Numerical results show that uniform hole distributions in different types of QWs are obtained when the number of the QWs emitting blue light is two, the number of the QWs emitting yellow light is one and the barrier between different types of QWs is 8nm in thickness. The near white light emission is realized using GaN-based IMQW structure with appropriate design parameters and injection level.展开更多
Formation and dissociation mechanisms of C-C+ base pairs in acidic and alkaline environments are investigated, employing ab initio quantum chemical calculations. Our calculations suggest that, in an acidic environmen...Formation and dissociation mechanisms of C-C+ base pairs in acidic and alkaline environments are investigated, employing ab initio quantum chemical calculations. Our calculations suggest that, in an acidic environment, a cytosine monomer is first protonated and then dimerized with an unprotonated cytosine monomer to form a C-C+ base pair; in an alkaline environment, a protonated cytosine dimer is first unprotonated and then dissociated into two cytosine monomers. In addition, the force for detaching a C-C+ base pair was found to be inversely proportional to the distance between the two cytosine monomers. These results provide a microscopic mechanism to qualitatively explain the experimentally observed reversible formation and dissociation of i-motifs.展开更多
An equilibrium-based YinYang bipolar dynamic Generalization of CPT (G-CPT) symmetry is introduced based on energy/information conservational quantum emergence-submergence. As a bottleneck of quantum computing, quantum...An equilibrium-based YinYang bipolar dynamic Generalization of CPT (G-CPT) symmetry is introduced based on energy/information conservational quantum emergence-submergence. As a bottleneck of quantum computing, quantum decoherence or collapse has been plaguing quantum mechanics for decades. It is suggested that the crux of the problem can trace its origin back to the incompleteness of CPT symmetry due to the lack of holistic representation for equilibrium-based bipolar coexistence. In this work, the notion of quantum emergence-submergence is coined as two opposite processes with bipolar energy/information conservation. The new notion leads to G-CPT symmetry supported by a Bipolar Quantum Cellular Automata (BQCA) interpretation of quantum mechanics. It is shown that the new interpretation further leads to the unification of electromagnetic particle-antiparticle bipolarity and gravitational action-reaction bipolarity as well as CPT symmetry and CP violation into a philosophically, geometrically and logically different quantum gravity theory. On one hand, G-CPT symmetry enables a Bipolar Quantum Agent (BQA) to emerge as a bipolar quantum superposition or entanglement coupled to a globally coherent BQCA;on the other hand, G-CP violation supports a causal theory of BQA submergence or decoupling from the global coherence. In turn, BQAs can submerge from one world but emerge in another within YinYang bipolar quantum geometry. It is suggested that all logical, physical, social, biological and mental worlds are bipolar quantum entangled under G-CPT symmetry. It is contended that G-CPT symmetry constitutes an analytical paradigm of quantum mechanics and quantum gravity—a fundamental departure from “what goes around comes around”. The new paradigm leads to a number of predictions and challenges.展开更多
基金supports from the National Natural Science Foundation of China(11904302,61921005)Major Project of the Science and Technology in Fujian Province of China(2019HZ020013)Major Science and Technology Projects in Xiamen of China(3502Z20191015).
文摘With regard to micro-light-emitting diodes(micro-LEDs),their excellent brightness,low energy consumption,and ultrahigh resolution are significant advantages.However,the large size of traditional inorganic phosphors and the number of side defects have restricted the practical applications of small sized micro-LEDs.Recently,quantum dot(QD)and nonradiative energy transfer(NRET)have been proposed to solve existing problems.QDs possess nanoscale dimensions and high luminous efficiency,and they are suitable for NRET because they are able to nearly contact the micro-LED chip.The NRET between QDs and micro-LED chip further improves the color conversion efficiency(CCE)and effective quantum yield(EQY)of full-color micro-LED devices.In this review,we discuss the NRET mechanism for QD micro-LED devices,and then nano-pillar LED,nano-hole LED,and nano-ring LED are introduced in detail.These structures are beneficial to the NRET between QD and micro-LED,especially nano-ring LED.Finally,the challenges and future envisions have also been described.
基金Supported by the Chinese Academy of Sciences Center for Excellence and Synergetic Innovation Center in Quantum Information and Quantum Physics,Shanghai Branch,University of Science and Technology of Chinathe National Natural Science Foundation of China under Grant No 11405172
文摘Quantum random number generators adopting single negligible dead time of avalanche photodiodes (APDs) photon detection have been restricted due to the non- We propose a new approach based on an APD array to improve the generation rate of random numbers significantly. This method compares the detectors' responses to consecutive optical pulses and generates the random sequence. We implement a demonstration experiment to show its simplicity, compactness and scalability. The generated numbers are proved to be unbiased, post-processing free, ready to use, and their randomness is verified by using the national institute of standard technology statistical test suite. The random bit generation efficiency is as high as 32.8% and the potential generation rate adopting the 32× 32 APD array is up to tens of Gbits/s.
基金the National Natural Science Foundation(Nos.20461003,20562011)the Specialized Research Fund for the Doctoral Program of Higher Education of China (No. 20050755003)the Trans-Century Training Program Foundation for Talents from the Ministry of Education of China (No. NCET-04-0987).
文摘Two new schiff base N,N'-bis((2-phenyl-2H-1,2,3-triazol-4-yl)methylene)-1,3-propanediamine (1) and N,N'-bis((2-phenyl-2H-1,2,3-triazol-4-yl)methylene) -1,4-butanediamine (2) were synthesized by condensation of 2-phenyl-1,2,3-triazole-4-carboxaldehyde with diamine, and characterized by elemental analysis, IR, IH NMR and MS spectra. Their crystal structures were determined by X-ray single crystal diffraction. Both crystals belong to the monoclinic system, space group P21/c. For compound 1(C21H20N8, Mr=384.45): a = 16.314(3), b =5.7168(11), c = 21.316(4) A, β = 105.3(2)°, Z = 4, V = 1917.6(7) A^3, De =1.332 g/cm^3, F(000) = 808,μ = 0.086 mm 1, R = 0.0533 and wR = 0.1460; for compound 2 (C22H22N8, Mr=398.48): a = 8.6156(17), b = 5.2964(11), c = 22.665(5)A, β = 100.54(3)°, Z = 2, V = 1016.8(4) A^3, De= 1.302 g/cm^3, F (000) = 420, μ = 0.083 mm^-1, R = 0.0373 and wR = 0.1155. Based on the crystal data, quantum chemistry calculation was performed on the two title compounds by means of Gaussian 98 program. The molecular orbital energies and atomic net charges population were obtained. Furthermore, we antilyzed their active atoms. The investigation can serve as a theoretical guide to study the synthesis and activity of the title compounds.
文摘During the last two decades, III-nitride-based quantum dots(QDs) have attracted great attentions for optoelectronic applications due to their unique electronic properties. In this paper, we first present an overview on the techniques of fabrication for III-nitride-based QDs. Then various optoelectronic devices such as QD lasers, QD light-emitting diodes(LEDs), QD infrared photodetectors(QDIPs) and QD intermediate band(QDIB) solar cells(SCs) are discussed. Finally, we focus on the future research directions and how the challenges can be overcome.
基金Project supported by the National Natural Science Foundation of China(Grant No.11374096)
文摘This paper studies quantum discord of two qutrits coupled to their own environments independently and coupled to the same environment simultaneously under quantum-jump-based feedback control. Our results show that spontaneous emission, quantum feedback parameters, classical driving, initial state, and detection efficiency all affect the evolution of quantum discord in a two-qutrit system. We find that under the condition of designing proper quantum-jump-based feedback parameters, quantum discord can be protected and prepared. In the case where two qutrits are independently coupled to their own environments, classical driving, spontaneous emission, and low detection efficiency have negative effect on the protection of quantum discord. For different initial states, it is found that the evolution of quantum discord under the control of appropriate parameters is similar. In the case where two qutrits are simultaneously coupled to the same environment,the classical driving plays a positive role in the generation of quantum discord, but spontaneous emission and low detection efficiency have negative impact on the generation of quantum discord. Most importantly, we find that the steady discord depends on feedback parameters, classical driving, and detection efficiency, but not on the initial state.
基金Supported by the National Natural Science Foundation of China under Grant Nos 61301171 and 61372076the Fundamental Research Funds for the Central Universities of China under Grant No K5051301018the National 111 Project of Higher Education of China under Grant No B8038
文摘We propose a novel strategy numed basis-splitting scheme to split the intercepted quanta into several portions based on different bases, for eavesdropping in the process of quantum cryptography. Compared with intercept- resend strategy, our simulation results of the basis-splitting scheme under the non-ideal condition show a greater performance, especially with the increase of the length of shifted bits. Consequently our scheme can aid eaves- dropper to gather much more useful information.
基金supported by the State Key Laboratory of Information Photonics and Optical Communications, Beijing University of Posts and Telecommunications (Grant No. IPOC2021ZT10)the National Natural Science Foundation of China (Grant No. 11904333)+1 种基金the Fundamental Research Funds for the Central Universities (Grant No. 2019XD-A02)BUPT Innovation and Entrepreneurship Support Program (Grant No. 2022YC-T051)。
文摘Quantum key distribution(QKD) generates information-theoretical secret keys between two parties based on the physical laws of quantum mechanics. Following the advancement in quantum communication networks, it becomes feasible and economical to combine QKD with classical optical communication through the same fiber using dense wavelength division multiplexing(DWDM) technology. This study proposes a detailed scheme of TF-QKD protocol with DWDM technology and analyzes its performance, considering the influence of quantum channel number and adjacent quantum crosstalk on the secret key rates. The simulation results show that the scheme further increases the secret key rate of TF-QKD and its variants. Therefore, this scheme provides a method for improving the secret key rate for practical quantum networks.
基金Project supported by the National Natural Science Foundation of China(Grant No.60970140)
文摘In the paper [2010 Chin. Phys. B 19 050306], Yang et al. put forward a novel three-party quantum secret sharing protocol of secure direct communication based on x-type entangled states, they claimed that the scheme is secure. However, in this paper, we study the security of the protocol and find that it is insecure. Applying intercept and resend attack, the agent Bob can obtain Alice's secret without the help from the other agent Charlie. In the end, we give our effective modification for its improvement.
文摘Quantum-dot cellular automaton (QCA) is a novel nanotechnology that provides a very different computation platform than traditional CMOS, in which polarization of electrons indicates the digital information. This paper demonstrates designing combinational circuits based on quantum-dot cellular automata (QCA) nanotechnology, which offers a way to implement logic and all interconnections with only one homogeneous layer of cells. In this paper, the authors have proposed a novel design of XOR gate. This model proves designing capabilities of combinational circuits that are compatible with QCA gates within nano-scale. Novel adder circuits such as half adders, full adders, which avoid the fore, mentioned noise paths, crossovers by careful clocking organization, have been proposed. Experiment results show that the performance of proposed designs is more efficient than conventional designs. The modular layouts are verified with the freely available QCA Designer tool.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.61663016 and 11404150)
文摘For an open quantum system containing two qubits under homodyne-based feedback control, we investigate the dynamical behaviors of quantum-memory-assisted entropic uncertainty.Moreover, we analyze the influence of feedback modes and coefficients on the entropic uncertainty.Numerical investigations show that the memory qubit should be placed in a non-dissipative channel if the single dissipative channel condition can be chosen, which helps reduce the entropic uncertainty of the system.For the homodyne feedback control F =λσx(or F =λσy), due to different roles of the entangled qubits A and B, when they are subject to feedback control with different feedback coefficients λ, the exchange of feedback coefficients will cause variations of the entropic uncertainty.When the feedback coefficient corresponding to the memory qubit B is larger(λB >λA), the steady value of the entropic uncertainty will be small, which is conducive to enhancing the robustness of the system.However, for the feedback control F =λσz, the difference between the feedback coefficients has no effect on the steady values of the entropic uncertainty.
基金Project supported by the National Natural Science Foundation of China (Grant No 60667001).
文摘This paper presents a modified secure direct communication protocol by using the blind polarization bases and particles' random transmitting order. In our protocol, a sender (Alice) encodes secret messages by rotating a random polarization angle of particle and then the receiver (Bob) sends back these particles as a random sequence. This ensures the security of communication.
文摘Quantum cryptography exploits the quantum mechanical properties of communication lines to enhance the security of the so-called key distribution. In this work, we explain the role played by quantum mechanics in cryptographic tasks and also investigate how secure is quantum cryptography. More importantly, we show by a simple security proof that for any state sent by the sender, the eavesdropper can only guess the output state with a probability that will allow her not to learn more than half of the classical Shannon information shared between the legitimate parties. This implies that with high probability, the shared key is secure.
基金supported by the National Natural Science Foundation of China (Grant No. 60777013)the Nature Science Foundation of Beijing,China (Grant No. 4082023)the Excellent Doctoral Science and Technology Innovation Foundation of Beijing Jiaotong University,China (Grant No. 141063522)
文摘GaN-based irregular multiple quantum well (IMQW) structures assembled two different types of QWs emitting complementary wavelengths for dichromatic white light-emitting diodes (LEDs) are optimized in order to obtain near white light emissions. The hole distributions and spontaneous emission spectra of the IMQW structures are analysed in detail by fully considering the effects of strain, well-coupling, valence band-mixing and polarization effect through employing a newly developed theoretical model from the k. p theory. Several structure parameters such as well material component, well width, layout of the wells and the thickness of harrier between different types of QWs are employed to analyse how these parameters together with the polarization effect influence the electronic and the optical properties of IMQW structure. Numerical results show that uniform hole distributions in different types of QWs are obtained when the number of the QWs emitting blue light is two, the number of the QWs emitting yellow light is one and the barrier between different types of QWs is 8nm in thickness. The near white light emission is realized using GaN-based IMQW structure with appropriate design parameters and injection level.
基金Project supported by the National Basic Research Program of China (973 Program,Grant No.2013CB932804)the National Natural Science Foundation of China (Grant Nos.91227115 and 11121403)the Hundred Talent Program of the Chinese Academy of Sciences (CAS)
文摘Formation and dissociation mechanisms of C-C+ base pairs in acidic and alkaline environments are investigated, employing ab initio quantum chemical calculations. Our calculations suggest that, in an acidic environment, a cytosine monomer is first protonated and then dimerized with an unprotonated cytosine monomer to form a C-C+ base pair; in an alkaline environment, a protonated cytosine dimer is first unprotonated and then dissociated into two cytosine monomers. In addition, the force for detaching a C-C+ base pair was found to be inversely proportional to the distance between the two cytosine monomers. These results provide a microscopic mechanism to qualitatively explain the experimentally observed reversible formation and dissociation of i-motifs.
文摘An equilibrium-based YinYang bipolar dynamic Generalization of CPT (G-CPT) symmetry is introduced based on energy/information conservational quantum emergence-submergence. As a bottleneck of quantum computing, quantum decoherence or collapse has been plaguing quantum mechanics for decades. It is suggested that the crux of the problem can trace its origin back to the incompleteness of CPT symmetry due to the lack of holistic representation for equilibrium-based bipolar coexistence. In this work, the notion of quantum emergence-submergence is coined as two opposite processes with bipolar energy/information conservation. The new notion leads to G-CPT symmetry supported by a Bipolar Quantum Cellular Automata (BQCA) interpretation of quantum mechanics. It is shown that the new interpretation further leads to the unification of electromagnetic particle-antiparticle bipolarity and gravitational action-reaction bipolarity as well as CPT symmetry and CP violation into a philosophically, geometrically and logically different quantum gravity theory. On one hand, G-CPT symmetry enables a Bipolar Quantum Agent (BQA) to emerge as a bipolar quantum superposition or entanglement coupled to a globally coherent BQCA;on the other hand, G-CP violation supports a causal theory of BQA submergence or decoupling from the global coherence. In turn, BQAs can submerge from one world but emerge in another within YinYang bipolar quantum geometry. It is suggested that all logical, physical, social, biological and mental worlds are bipolar quantum entangled under G-CPT symmetry. It is contended that G-CPT symmetry constitutes an analytical paradigm of quantum mechanics and quantum gravity—a fundamental departure from “what goes around comes around”. The new paradigm leads to a number of predictions and challenges.