Durable K-ion batteries with 100% capacity retention up to 40,000 cycles

Currently,the major challenge in terms of research on K-ion batteries is to ensure that they possess satisfactory cycle stability and specific capacity,especially in terms of the intrinsically sluggish kinetics induced by the large radius of K+ions.Here,we explore high-performance K-ion half/full batteries with high rate capability,high specific capacity,and extremely durable cycle stability based on carbon nanosheets with tailored N dopants,which can alleviate the change of volume,increase electronic conductivity,and enhance the K+ion adsorption.The as-assembled K-ion half-batteries show an excellent rate capability of 468 mA h g^(−1) at 100 mA g^(−1),which is superior to those of most carbon materials reported to date.Moreover,the as-assembled half-cells have an outstanding life span,running 40,000 cycles over 8 months with a specific capacity retention of 100%at a high current density of 2000 mA g^(−1),and the target full cells deliver a high reversible specific capacity of 146 mA h g^(−1) after 2000 cycles over 2 months,with a specific capacity retention of 113%at a high current density of 500 mA g^(−1),both of which are state of the art in the field of K-ion batteries.This study might provide some insights into and potential avenues for exploration of advanced K-ion batteries with durable stability for practical applications.

Valve Dynamic and Thermal Cycle Model in Stepless Capacity Regulation for Reciprocating Compressor

The existing researches of stepless capacity regulation system by depressing the suction valve for reciprocation compressor always adopt hypothesis that the compressor valves are open or close instantaneously, the valve dynamic has not been taken account into thermal cycle computation, the influence of capacity regulation system on suction valves dynamic performance and cylinder thermal cycle operation has not been considered. This paper focuses on theoretical and experimental analysis of the valve dynamic and thermal cycle for reciprocating compressor in the situation of stepless capacity regulation. The valve dynamics equation, gas forces for normal and back flow, and the cylinder pressure varying with suction valve unloader moment during compression thermal cycle are discussed. A new valve dynamic model based on L-K real gas state equation for reciprocating compressor is first deduced to reduce the calculation errors induced by the ideal gas state equation. The variations of valve dynamic and cylinder pressure during part of compression stroke are calculated numerically. The calculation results reveal the non-normal thermal cycle and operation condition of compressor in stepless capacity regulation situation. The numerical simulation results of the valve dynamic and thermal cycle parameters are also verified by the stepless capacity regulation experiments in the type of 3L-10/8 reciprocating compressor. The experimental results agree with the numerical simulation results, which show that the theoretical models proposed are effective and high-precision. The proposed theoretical models build the theoretical foundation to design the real stepless capacity regulation system.

Amorphous phosphorus chalcogenide as an anode material for lithiumion batteries with high capacity and long cycle life

The ever-increasing demands for modern energy storage applications drive the search for novel anode materials of lithium(Li)-ion batteries(LIBs) with high storage capacity and long cycle life, to outperform the conventional LIBs anode materials. Hence, we report amorphous ternary phosphorus chalcogenide(aP_(4)SSe_(2)) as an anode material with high performance for LIBs. Synthesized via the mechanochemistry method, the a-P_(4)SSe_(2) compound is endowed with amorphous feature and offers excellent cycling stability(over 1500 mA h g^(-1) capacity after 425 cycles at 0.3 A g^(-1)), owing to the advantages of isotropic nature and synergistic effect of multielement forming Li-ion conductors during battery operation. Furthermore,as confirmed by ex situ X-ray diffraction(XRD) and transmission electron microscope(TEM), the a-P_(4)SSe_(2)anode material has a reversible and multistage Li-storage mechanism, which is extremely beneficial to long cycle life for batteries. Moreover, the autogenous intermediate electrochemical products with fast ionic conductivity can facilitate Li-ion diffusion effectively. Thus, the a-P_(4)SSe_(2)electrode delivers excellent rate capability(730 mA h g^(-1)capacity at 3 A g^(-1)). Through in situ electrochemical impedance spectra(EIS) measurements, it can be revealed that the resistances of charge transfer(R_(SEI)) and solid electrolyte interphase(R_(Ct)) decrease along with the formation of Li-ion conductors whilst the ohmic resistance(R_(Ω)) remains unchanged during the whole electrochemical process, thus resulting in rapid reaction kinetics and stable electrode to obtain excellent rate performance and cycling ability for LIBs. Moreover, the formation mechanism and electrochemical superiority of the a-P_(4)SSe_(2)phase, and its expansion to P_(4)S_(3-x)Se_(x)(x = 0, 1, 2, 3) family can prove its significance for LIBs.

Changes of Some Capacities and Failure Mode of Ni/MH Batteries During Cycling

The changes of capacities of positive and negative electrodes, reserve capacities of charging and discharging, and the weight of batteries during cycling have been determined. The increase of the discharging reserve capacity due to the conjugated electrochemical reactions of the oxidation of hydrogen storage alloy is estimated. The results show that the failure mode of Ni/MH batteries developed is as follows: during the increase of cycles, the hydrogen storage alloy is oxidized continuously and the charging reserve capacity is decreased rapidly while the discharging reserve capacity is increased gradually, thus the internal pressure is increasing, first H 2 leaks out from the battery, then the mixture of H 2 and O 2. The leakage of gases and the total reaction of oxidation of the alloy consume H 2O, and the surface oxides on the alloy increase, so that the internal resistance of the battery increases.

Mechanism for capacity fading of 18650 cylindrical lithium ion batteries

The mechanism for capacity fading of18650lithium ion full cells under room-temperature(RT)is discussedsystematically.The capacity loss of18650cells is about12.91%after500cycles.The cells after cycles are analyzed by XRD,SEM,EIS and CV.Impedance measurement shows an overall increase in the cell resistance upon cycling.Moreover,it also presents anincreased charge-transfer resistance(Rct)for the cell cycled at RT.CV test shows that the reversibility of lithium ioninsertion/extraction reaction is reduced.The capacity fading for the cells cycled can be explained by taking into account the repeatedfilm formation over the surface of anode and the side reactions.The products of side reactions deposited on separator are able toreduce the porosity of separator.As a result,the migration resistance of lithium ion between the cathode and anode would beincreased,leading the fading of capacity and potential.

Research on the feasibility of storage and estimation model of storage capacity of CO_(2)in fissures of coal mine old goaf

The concept of the carbon cycle in the old goaf of a coal mine based on CO_(2)utilization and storage was put forward adhering to the principle of low-carbon development,utilization of space resources in old goafs,and associated gas resources development.Firstly,the evolution characteristics of overburden fissures in the goaf of the case was studied using a two-dimensional physical similarity simulation test,the sealing performance of the caprocks after stabilization was analyzed,and the fissures were counted and classi-fied.Then,the process of gaseous CO_(2)injection in the connected fissure was simulated by Ansys Fluent software,and the migration law and distribution characteristics of CO_(2)under the condition of gaseous CO_(2)injection were analyzed.Finally,the estimation models of free CO_(2)storage capacity in the old goaf were constructed considering the proportion of connected fissure and the effectiveness of CO_(2)injection.The CO_(2)storage capacity in the old goaf of the case coal mine was estimated.The results showed that a caprock group of“hard-thickness low-permeability hard-thickness”was formed after the caprock-fissures system in the goaf of the case tended to be stable vertically.The connected fissure,occlude cracks,and micro-fractures in the goaf accounted for 85.5%,8.5%,and 6%of the total fissures,respectively.Gaseous CO_(2)first migrated to the bottom of the connected fissure after CO_(2)was injected into the goaf,then spread horizontally along the bottom of the connected fissure after reaching the bottom,and finally spread longitudinally after filling the bottom of the entire connected fissure.The theoretical and effective storage capacities of free CO_(2)at normal temperature and pressure in the old goaf of the case were 9757 and 7477 t,respectively.The effective storage capacity of free CO_(2)at normal temperature and pressure in the old goaf after all minefield mined was 193404 t.The research can provide some reference for the coal mining industry to help the goal of“carbon peaking and carbon neutrality”.

Carrying Capacity of Water Leisure Environment in Eco-cities-A Case Study of Ancient Canal Scenic Area in Yangzhou City

Water leisure tourism is an emerging theme in urban planning, and its planning mode and operation level directly influence the eco-cycle degree of urban development. Tourism activities inevitably impact environmental quality of urban water spaces, and the research on the environmental carrying capacity of such spaces has also become an important prerequisite of tourism planning. Taking the Yangzhou Ancient Canal Scenic Area for an example, the paper constructed the estimated indicators of water leisure tourism environmental carrying capacity on the basis of analyzing scenic geographical resources and tourism economic conditions, and calculated the scenic area's water leisure tourism environmental integrated carrying capacity by the method of barrel extrapolation, providing a reasonable foundation for evaluating the planning conditions in the eco-cycle urban water leisure tourism planning.

Pseudocapacitive Heteroatom-Doped Carbon Cathode for Aluminum-Ion Batteries with Ultrahigh Reversible Stability

Aluminum(Al)-ion batteries have emerged as a potential alternative to conventional ion batteries that rely on less abundant and costly materials like lithium.Nonetheless,given the nascent stage of advancement in Al-ion batteries(AIBs),attaining electrode materials that can leverage both intercalation capacity and structural stability remains challenging.Herein,we demonstrate a C3N4-derived layered N,S heteroatom-doped carbon,obtained at different pyrolysis temperatures,as a cathode material for AIBs,encompassing the diffusion-controlled intercalation and surface-induced capacity with ultrahigh reversibility.The developed layered N,S-doped corbon(N,S-C)cathode,synthesized at 900℃,delivers a specific capacity of 330 mAhg^(-1)with a relatively high coulombic efficiency of~85%after 500 cycles under a current density of 0.5 A g^(-1).Owing to its reinforced adsorption capability and enlarged interlayer spacing by doping N and S heteroatoms,the N,S-C900 cathode demonstrates outstanding energy storage capacity with excellent rate performance(61 mAhg^(-1)at 20 A g^(-1))and ultrahigh reversibility(90 mAhg^(-1)at 5Ag^(-1)after 10000cycles).

基于冗余度和方差的P-Cycle圈构造算法的研究

铁路光传送网络是高速铁路地面基础设施的神经中枢,为避免网络故障给铁路运营带来巨大损失,重点研究光传送网P-Cycle(Pre-configured Cycle)保护技术,提出在圈扩展时以所有候选圈上未保护工作容量的方差、冗余度两个指标为比较标准的RVPA(Redundancy and Variance Based P-Cycle Construction Algorithm)算法。圈扩展的过程中,算法将选择方差与冗余度能同时满足条件的候选圈作为本轮扩展圈,有效限制了完成保护的P-Cycle圈个数;圈扩展停止条件中,当UPL与参数M、冗余度的大小关系满足条件时,则停止圈扩展,从而限制圈上节点数,使圈个数与圈长度得到有效均衡;在仿真过程中,利用泛欧网络拓扑COST239对RVPA算法进行仿真,并对比分析不同M值下的性能。仿真结果表明,在相同空闲资源与待保护工作容量设定下,参数M取0.5时效果最优,并且RVPA算法的保护容量效率、所需圈的个数、算法整体耗时、总冗余度均优于已有的POCA(P-Cycle Optimization Configuration Heuristic Algorithm)算法。

Optimal decision of retailer for replenishment cycle under a deteriorating product supply chain

In order to minimize the total cost of the retailer, an optimal replenishment cycle is studied by considering the deteriorating product, two-level trade credits, the limited storage capacity of their own warehouse and credit-linked order quantity simultaneously. A two-echelon supply chain model, which consists of a supplier and a retailer, is established. Then, the retailer＇s optimal replenishment cycle under all the cases are derived by using the optimization theory and method. On the basis of these, the effects of system parameters on the optimal replenishment cycle are examined by using the numerical studies. The results show that, when the retailer＇s trade credit period is longer （shorter） than the customer＇s trade credit period, the optimal replenishment cycle should he increased （decreased） as the retailer＇s trade credit period increases; if the minimum order quantity is high （low）, the optimal replenishment cycle should be increased （not changed） as the minimum order quantity increases.

Phase Structure and Cycle Stabilities of Mg_2Ni/Mm_(0.3)Ml_(0.7)Ni_(3.55)Co_(0.75)Mn_(0.4)Al_(0.3) Composite Hydrogen Storage Alloys Prepared by Two-step re-melting

Mm0.3Ml0.7Ni3.55Co0.75Mn0.4-Al0.3 alloy has high chemical activity and favorable plateaus pressure. Mg2Ni is in favor of high hydrogen storage capacity and low weight, but it is difficult to be activated. In order to improve the capacity and cycle performances of hydrogen-storage alloy electrodes, Mm0.3Ml0.7Ni3.55Co0.75Mn0.4-Al0.3-x%Mg2Ni(x=0, 5, 10, 30) composite hydrogen storage alloys prepared by two-step re-melting were investigated in this work. The influences of Mg2Ni content on the cycle stabilities were analyzed by electrochemical methods. It was observed by XRD that the main phase of all the alloys is LaNi5 and the crystal lattice parameters of LaNi5 are changed with the increasing of x value, i.e, a-axis and unit cell volume decrease and c-axis decreases nonlinearly. The c-axis of alloy with x=5 is larger than the others. With the increasing of x value, capacity retentions of the composite hydrogen storage alloys rise from 66.21% while x=0 to 82.04% while x=10, but the capacity retention of the composite alloy with 30% Mg2Ni declines because of its decreasing axial ratio. More over, the composite alloy with 5% Mg2Ni shows the best cycle stability and higher discharge capacity, and it is an appropriate candidate for battery materials.

Analysis of Medical Waste Incinerator Performance Based on Fuel Consumption and Cycle Times

A detailed assessment of an incinerator based on fuel consumption and cycle time data is presented in this paper. The study was conducted at Temeke district hospital for 22 months consecutively covering 654 days of daily data collection on fuel consumption and cycle times. The composition for the medical waste incinerated varied between 15% and 35% for sharps waste and between 65% and 85% for other waste, with mean values of 25% and 75%, respectively. The results revealed poor performance of the incinerator due to higher fuel consumption (above 30 L/cycle). The incineration cycle times were observed to range between 2 and 4 hours, all of which were too high for the loading rates observed (55 - 214 kg). A strong dependency of diesel oil consumption on cycle time was observed due to lack of temperature control leading to continuous fuel flow into the burners. The incineration capacity was very low compared to other incinerators in terms of tons per year. This paper gives an insight on the factors affecting incinerator performance assessed based on diesel oil consumption and cycle times. It can be generalized that the incinerator performance was poor due to several factors ranging from poor incinerator design, operator skills, waste management practices, waste storage practices, etc. The hospital was advised to install a new incinerator with short incineration cycle time (30 - 40 minutes) and lower fuel consumption (10 L/cycle) at a loading rate of 200 kg/cycle.

Al_2O_3 coated LiCoO_2 as cathode for high-capacity and long-cycling Li-ion batteries

Lithium-ion batteries(LIBs) as energy storage devices play an important role in all aspects of our life. The increasing energy demand of the society requires LIBs with higher energy density and better performance. We here develop a new and easy-to-scaleup sol-gel method to coat a surface protection layer on commercial LiCoO2cathode. We demonstrate that a proper thickness can improve the cycling life with a higher cut-off potential(4.5 V), larger energy capacity(180 mAh/g at 0.5 C) and better energy density(35% more compared to non-coated LiCoO2). The mechanism of the protection layer is also revealed by a combination of electron microscopy and synchrotron X-ray spectroscopy.

In Situ Formation of LiF-Rich Carbon Interphase on Silicon Particles for Cycle-Stable Battery Anodes

Silicon(Si)is a potential high-capacity anode material for the next-generation lithium-ion battery with high energy density.However,Si anodes suff er from severe interfacial chemistry issues,such as side reactions at the electrode/electrolyte interface,leading to poor electrochemical cycling stability.Herein,we demonstrate the fabrication of a conformal fl uorine-containing carbon(FC)layer on Si particles(Si-FC)and its in situ electrochemical conversion into a LiF-rich carbon layer above 1.5 V(vs.Li^(+)/Li).The as-formed LiF-rich carbon layer not only isolates the active Si and electrolytes,leading to the suppression of side reactions,but also induces the formation of a robust solid-electrolyte interface(SEI),leading to the stable interfacial chemistry of as-designed Si-FC particles.The Si-FC electrode has a high initial Coulombic effi ciency(CE)of 84.8%and a high reversible capacity of 1450 mAh/g at 0.4 C(1000 mA/g)for 300 cycles.In addition,a hybrid electrode consisting of 85 wt%graphite and 15 wt%Si-FC,and mass 2.3 mg/cm^(2) loading delivers a high areal capacity of 2.0 mAh/cm^(2) and a high-capacity retention of 93.2%after 100 cycles,showing the prospects for practical use.

Structural,volumetric and water retention behaviors of a compacted clay upon saline intrusion and freeze-thaw cycles

This study investigates the evolution of the structural,volumetric and water retention behaviors of a compacted clay during soaking and desiccation considering the influences of freeze-thaw(FT)cycles and saline intrusion.Compacted specimens were subjected to different FT cycles and then submerged in NaCl solution with different concentrations to facilitate the saline intrusion and measure the swelling behaviors.Shrinkage curve and filter paper tests were thereafter performed to reveal the clay’s volumetric and water-retention characteristics during desiccation.Mercury intrusion porosimetry and field emission scanning electron microscopy tests were conducted to observe the evolution of the clay’s microstructure.Experimental results show that the clay’s micropores decrease and macropores increase after FT cycles,which is associated with the migration of water,growth of ice crystals,and development of FT-induced cracks during FT cycles.Similar observations were obtained from specimens after the saline intrusion,which is attributed to the osmotic and osmotically-induced consolidation.FT-induced cracks significantly reduce the clay’s swelling and shrinkage potentials.FT cycles result in the shrinkage of micropores which leads to a reduction in the water retention capacity in the low suction range(capillary regime).The salinization suppresses the swelling of the clay and prolongs its primary and secondary swelling stages.The shrinkage potential initially increases and then decreases with increasing saline concentration.Salinization has significant influences on the osmotic suction and thus alters the clay’s water-retention curves in terms of total suction.It demonstrates little impact on the clay’s water-retention curves in terms of matric suction.

数字经济发展降低了企业财务风险吗?——基于吸收能力与生命周期的视角分析

使用2011—2020年沪深两市A股上市公司的数据,在运用熵权法构建数字经济指数的基础上,实证检验数字经济发展对企业财务风险的影响以及内在机制。研究发现:(1)数字经济对企业财务风险具有显著的抑制作用,吸收能力在数字经济抑制企业财务风险的过程中具有部分中介效应。(2)处在生命周期不同阶段的企业,数字经济的发展对企业财务风险的影响也不相同。对于成长型和成熟型企业,数字经济的发展对抑制企业财务风险具有显著作用,且吸收能力具有中介效应;对于陷入衰退期的企业,数字经济的发展对降低公司的财务风险没有显著影响,且吸收能力不具有中介效应。(3)数字经济的有效性需要企业内部基本条件的支持。当企业的数字转型良好时,数字经济在遏制企业财务风险方面的作用更加明显。总的来说,数字经济的发展有利于企业提高吸收能力,降低财务风险。研究揭示了财务风险产生的原因,以及数字经济在降低财务风险方面各种差异的作用和机制,为缓解企业财务风险提供了可靠的实证依据和政策启示,具有重要的现实意义。

平滑风电波动的飞轮协同电池混合储能系统经济性配置

针对风电场的有功功率波动,采用小波包分解的功率平抑算法,得到满足并网要求的低频信号分量和高频的混合储能系统参考功率,并使用低通滤波分频和信号平滑去噪方法获得飞轮储能和电池储能的参考信号,同时考虑放电深度和循环次数对电池储能系统寿命的影响,构建混合储能系统在计划年限内的全生命周期经济性模型,采用多跟踪器优化算法(MTOA)得到最优的混合储能容量配置。最后,结合风电场实际功率数据,仿真分析验证混合储能系统对功率平抑的有效性和经济性。结果表明:混合储能系统既能保证风电场的有功功率波动满足并网要求,又能充分发挥不同储能形式特性,降低系统运行成本。

铅炭电池技术发展及储能应用的思考

目前,铅酸电池存在能量密度低、循环寿命短、电池体积和重量大等缺点,因此在国内储能领域的应用占比较低。铅炭电池是炭材料改性负极的改进型铅蓄电池,相比铅酸蓄电池可以有效延缓失效现象,循环寿命有较好提升。由于铅炭电池具备原材料成本低、回收率高、安全性高等其他电池不可替代的优势,更适用于大规模和长时储能。在再生铅产业良性发展的时代背景下,发挥铅炭电池技术优势,扩大铅炭电池生产,拓展储能领域应用,是优化能源调峰及储用,优化局域能源结构的重要发展方向。未来,在以沙漠、戈壁、荒漠地区为重点的大型风电光伏基地建设开展新型铅炭电池储能试点示范,同时配套建设铅冶炼企业和铅炭电池产业链,有望实现原料端—冶炼端—深加工端—应用需求端—综合回收端的全产业链闭环。

燃料电池船复合储能容量优化与配置经济性分析

复合储能系统可改善由船舶负载功率波动引起的燃料电池寿命损耗问题,但配置成本限制了其在燃料电池船上的广泛应用。为合理配置储能容量,使船舶动力系统设计具备长期的可靠性,提出了一种计及复合储能系统全寿命周期的容量优化配置方法。在构建各电源系统模型的基础上,建立包括购置成本、维护成本、置换成本和能耗成本的复合储能系统全寿命周期成本模型,并采用雨流计数法来评估储能的置换成本。最后依据“Alsterwasser”号燃料电池船的典型功率需求数据,以储能设备的容量参数、燃料电池的输出功率和电源系统的运行参数为优化变量,采用灰狼优化算法进行求解。通过不同储能类型和优化目标下的配置方案对比,验证了所提方法的经济性。

圆钢管型钢再生混凝土组合柱水平承载力计算方法研究

通过对11个圆钢管型钢再生混凝土组合柱进行低周反复荷载试验,分析再生粗骨料取代率、型钢截面形式、轴压比、型钢配钢率及圆钢管壁厚参数对组合柱水平承载力的影响规律;观察了组合柱的破坏形态及特征,研究了圆钢管、型钢翼缘及腹板应变的发展规律,分析了组合柱的地震破坏特征。研究表明,在水平地震作用下组合柱发生典型的压弯塑性铰破坏。在此基础上,结合现有规范提出了基于叠加原理的圆钢管型钢再生混凝土组合柱水平承载力计算方法。计算结果表明,其水平承载力计算值与试验值吻合度较好,能较为准确地预测组合柱的水平承载力。