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Electroreduction of Benzoylformic Acid in 1-Ethyl-3-methylimidazolium Bromide Room Temperature Ionic Liquid 被引量:2
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作者 SUN Qian ZHAO Peng +1 位作者 LU Jia-xing HE Ming-yuan 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 2005年第5期634-635,共2页
The chemical industry is under considerable pressure to replace many volatile organic compounds that are widely used as solvents in organic synthesis. This trend leads to the exploration for novel reaction media. Room... The chemical industry is under considerable pressure to replace many volatile organic compounds that are widely used as solvents in organic synthesis. This trend leads to the exploration for novel reaction media. Room temperature ionic liquids as environmentally benign media for organic synthesis and catalytic reactions have been gradually recognized and accepted Owing to their unique chemical and physical properties, ionic liquids become promising candidates as recyclable reaction media for “ Green” applications. These nonvolatile solvents have been used as media or catalysts in dozens of fields, such as organic synthesis, organometallic catalytic reactions, separation and extraction processes. 展开更多
关键词 Ionic liquid ELECTROREDUCTION benzoylformic acid Cyclic vohammetry
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Electrochemical Reduction of Benzoylformic Acid in Ionic Liquid 被引量:5
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作者 陆嘉星 孙茜 何鸣元 《Chinese Journal of Chemistry》 SCIE CAS CSCD 2003年第9期1229-1230,共2页
Ionic liquids possess a number of unique properties that make them ideal electrolytes. Electrochemical reduction of benzoylformic acid in room temperature ionic liquids as reaction media could be conducted with excell... Ionic liquids possess a number of unique properties that make them ideal electrolytes. Electrochemical reduction of benzoylformic acid in room temperature ionic liquids as reaction media could be conducted with excellent performances without any additional supporting electrolyte. Electrolysis at glassy carbon electrode results in the formation of mandelic acid in 91% yield. And the electrochemical behavior of benzoylformic acid was investigated with the technique of cyclic voltammetry. 展开更多
关键词 ionic liquid electrochemical reduction benzoylformic acid
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