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Zr-Nb合金在LiOH水溶液中耐腐蚀性的研究 被引量:8
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作者 刘文庆 周邦新 李强 《核动力工程》 EI CAS CSCD 北大核心 2002年第1期68-70,共3页
比较了Zr-Nb合金与Zr-Sn-Nb-Fe及Zr-4合金的耐腐蚀性,讨论了Nb对Zr-Nb合金在不同介质中耐腐蚀性的影响。实验证明Nb的腐蚀产物可以部分溶解于LiOH水溶液中,因而Zr-Nb合金在LiOH水溶液中腐蚀时,合金中β-Nb第二相腐蚀后生成的腐蚀产物会... 比较了Zr-Nb合金与Zr-Sn-Nb-Fe及Zr-4合金的耐腐蚀性,讨论了Nb对Zr-Nb合金在不同介质中耐腐蚀性的影响。实验证明Nb的腐蚀产物可以部分溶解于LiOH水溶液中,因而Zr-Nb合金在LiOH水溶液中腐蚀时,合金中β-Nb第二相腐蚀后生成的腐蚀产物会部分溶解于LiOH水溶液,在氧化膜中形成孔洞,从而导致Zr-Nb合金在LiOH水溶液中的耐腐蚀性变差。 展开更多
关键词 Zr-Nb合金 耐腐蚀性能 锆铌合金 氢氧化锂溶液 压水堆 包壳材料
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Corrosion Resistance of Zr-1Nb Alloy in Lithium Hydroxide Aqueous Solution
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作者 Wenqing Liu, Bangxin Zhou, Qiang Li (Materials Institute, Shanghai University, Shanghai 200072, China) 《Rare Metals》 SCIE EI CAS CSCD 2001年第2期78-80,共3页
The corrosion resistance of Zr-1Nb alloy was compared with that of Zr-Sn-Nb-Fe and Zr-4 alloys, and the effect of hydrochemistry on the corrosion resistance of Zr-1Nb alloy was discussed. Experimental results show tha... The corrosion resistance of Zr-1Nb alloy was compared with that of Zr-Sn-Nb-Fe and Zr-4 alloys, and the effect of hydrochemistry on the corrosion resistance of Zr-1Nb alloy was discussed. Experimental results show that niobium oxide is partly soluble in LiOH aqueous solution. Therefore, when Zr-1Nb alloy is corroded in LiOH aqueous solution, a soluble niobate produced by the reaction between the corrosion products of beta -Nb particles and LiOH results in the formation of pores in the zirconium oxide films and causes the degradation of the corrosion resistance of Zr-1Nb alloy tested in LiOH aqueous solution. 展开更多
关键词 Zr-1Nb alloys beta-niobium corrosion resistance
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