In this study, commercial biaxially oriented polypropylene （BOPP）, polyvinyl chlo- ride （PVC） and poly （methyl methacrylate） （PMMA） films were treated with nitrogen plasma over different exposure times in a Py...In this study, commercial biaxially oriented polypropylene （BOPP）, polyvinyl chlo- ride （PVC） and poly （methyl methacrylate） （PMMA） films were treated with nitrogen plasma over different exposure times in a Pyrex tube surrounded by a DC variable magnetic field. The chemi- cal changes that appeared on the surface of the samples were investigated using Fourier transform infrared （FT4R） spectroscopy and attenuated total reflectance Fourier transform infrared （ATR- FTIR） spectroscopy after treatment for 2 min, 4 min and 6 rain in a nitrogen plasma chamber. Effects of the plasma treatment on the surface topographies and contact angles of the untreated and plasma treated films were also analyzed by atomic force microscopy （AFM） and a contact angle measuring system. The results show that the plasma treated films become more hydrophilic with an enhanced wettability due to the formation of some new polar groups on the surface of the treated films. Moreover, at higher exposure times, the total surface energy in all treated films increased while a reduction in contact angle occurred. The behavior of surface roughness in each sample was completely different at higher exposure times.展开更多
The development of texture during plastic deformation plays an important role in determining the stretch formability of magnesium alloy sheets.In this study,the orientation stability during equibiaxial tension of magn...The development of texture during plastic deformation plays an important role in determining the stretch formability of magnesium alloy sheets.In this study,the orientation stability during equibiaxial tension of magnesium was analyzed based on three dimensional lattice rotations calculated by using a rate-dependent crystal plasticity model and assuming five different combinations of slip modes.The results show that no orientations can satisfy the stability criteria with both zero rotation velocity and convergent orientation flow in all dimensions.However,relatively stable orientations with zero rotation velocity and an overall convergence are found.They are featured by characteristic alignments of specific crystallographic directions in the macroscopic axis of contraction,depending on the slip modes involved in the deformation.It is also shown that the orientation stability varies significantly with the deviation of deformation mode from equibiaxial tension.The simulation results are briefly discussed in comparison with pre-existing experiments.展开更多
文摘In this study, commercial biaxially oriented polypropylene （BOPP）, polyvinyl chlo- ride （PVC） and poly （methyl methacrylate） （PMMA） films were treated with nitrogen plasma over different exposure times in a Pyrex tube surrounded by a DC variable magnetic field. The chemi- cal changes that appeared on the surface of the samples were investigated using Fourier transform infrared （FT4R） spectroscopy and attenuated total reflectance Fourier transform infrared （ATR- FTIR） spectroscopy after treatment for 2 min, 4 min and 6 rain in a nitrogen plasma chamber. Effects of the plasma treatment on the surface topographies and contact angles of the untreated and plasma treated films were also analyzed by atomic force microscopy （AFM） and a contact angle measuring system. The results show that the plasma treated films become more hydrophilic with an enhanced wettability due to the formation of some new polar groups on the surface of the treated films. Moreover, at higher exposure times, the total surface energy in all treated films increased while a reduction in contact angle occurred. The behavior of surface roughness in each sample was completely different at higher exposure times.
基金supported by the National Natural Science Foundation of China (No.50871040)the Program for New Century Excellent Talents,China (NCET-06-0741)
文摘The development of texture during plastic deformation plays an important role in determining the stretch formability of magnesium alloy sheets.In this study,the orientation stability during equibiaxial tension of magnesium was analyzed based on three dimensional lattice rotations calculated by using a rate-dependent crystal plasticity model and assuming five different combinations of slip modes.The results show that no orientations can satisfy the stability criteria with both zero rotation velocity and convergent orientation flow in all dimensions.However,relatively stable orientations with zero rotation velocity and an overall convergence are found.They are featured by characteristic alignments of specific crystallographic directions in the macroscopic axis of contraction,depending on the slip modes involved in the deformation.It is also shown that the orientation stability varies significantly with the deviation of deformation mode from equibiaxial tension.The simulation results are briefly discussed in comparison with pre-existing experiments.
