The tests performed with two hundred and thirty-nine (239) samples from the A-X and B-X drillings help to know their sedimentological and chemostratigraphic characters. In sedimentological term formations are composed...The tests performed with two hundred and thirty-nine (239) samples from the A-X and B-X drillings help to know their sedimentological and chemostratigraphic characters. In sedimentological term formations are composed of sand, sandstone, limestone, siltstone and argillite that alternate along the drill. In chemostratigraphic term two megasequences (MS1 and MS2) have been identified. A correlation of chemostratigraphic data completed by the lithology results allowed a subdivision of oil wells that shows two main types of deposits environments. First, a proximal marine environment to continental and to Albian marked by a detrital flow deducted from the concentrations evolution of indicator elements of terrigenous material that are K, Mg, and Rb. On the other hand, a deep to shallow marine environment of Cenomanian to Paleocene marked by the presence of predominantly clay sediments and abundant glauconite in the lower Senonian. Nevertheless, there is a transition or intermediate environment that is characterized by the presence of glauconite and detrital flows.展开更多
The Late Permian Emeishan Large Igneous Province (ELIP) is commonly regarded as being located in the western part of the Yangtze craton, SW China, with an asymmetrical shape and a small area. This area, however, is ju...The Late Permian Emeishan Large Igneous Province (ELIP) is commonly regarded as being located in the western part of the Yangtze craton, SW China, with an asymmetrical shape and a small area. This area, however, is just a maximum estimation because some parts of the ELIP were not recognized or dismembered and destroyed during the Triassic to Cenozoic tectonism. In this paper, the chemostratigraphical data of the Zongza block, the Garze-Litang belt and the Songpan-Garze block suggest that the Late Permian basalts in these areas have remarkable similarities to the ELIP basalts in petrography and geochemistry. Flood basalts in the Sanjiangkou area are composed of the lower part of the low-Ti (LT) tholeiite and the upper part of the high-Ti (HT) tholeiite, which is the same as the flood basalts on the western margin of the Yangtze craton. Flood basalts in the Zongza and Songpan-Garze areas, which are far from the Yangtze craton, consist of HT tholeiite only. This is the same as the flood basalts within the Yangtze craton. Therefore we argue that these contemporary basalts all originated from the Emeishan mantle plume, and the ELIP could have a significant westward extension with an outcropped area of over 500,000 km2. This new scenario shows that the LT tholeiite occurs on the western margin of the Yangtze craton, while the HT tholeiite overlying the LT basalts occupies the whole area of the ELIP.展开更多
The base of the Middle Ordovician （i.e. Dapingian Stage） has been defined at the first appearance datum （FAD） of conodont Baltoniodus？ triangularis at Huanghuachang, Yichang, China,but the precise correlation of ...The base of the Middle Ordovician （i.e. Dapingian Stage） has been defined at the first appearance datum （FAD） of conodont Baltoniodus？ triangularis at Huanghuachang, Yichang, China,but the precise correlation of the boundary to regions of other facies remain to be resolved. Herein we review the biostratigraphy and chemostratigraphy of the Huanghuachang Global Standard Stratotype-Section and Point （GSSP） section, and present our latest stratigraphic work on the nearby Chenjiahe s ection in Yichang, and the Hengtang Quarry section, Jiangshan, Zhejiang, which is regarded as representative of slope facies. The conodont and graptolite biostratigraphy as well as chemostratigraphy of the Chenjiahe section indicate that the base of the Middle Ordovician also falls within the graptolite Azygograptus suecicus Zone, and coincides with a high or maximum δ13C value within a minor positive carbon isotope excursion, suggesting that the base boundary can be readily recognized across the entire Yangtze Gorges area. The integrated graptolite and conodont biostratigraphy and chemostratigraphy of the Hengtang section, Jiangshan, indicates that the basal boundary probably falls within the graptolite lsograptus caduceus imitatus Zone that overlies the Azygograptus suecicus Zone, and coincides with a remarkable drop of δ13C. This difference indicates that a multi-disciplinary approach is critical to identify the base boundary in those regions where the Baltoniodus ？ triangularis is absent.展开更多
Sedimentary sequences preserve the records of changes in major controls of sedimentation namely,tectonics,climate,relative sea level and sediment production and preservation.The potential to characterize these changes...Sedimentary sequences preserve the records of changes in major controls of sedimentation namely,tectonics,climate,relative sea level and sediment production and preservation.The potential to characterize these changes in spatial and temporal scales has led to the development of the branch of chemostratigraphy.Chemostratigraphic study of sedimentary sequences commenced from recognizing identical/contrasting geochemical features across major geochronological boundaries,and evolved into one of the essential tools in exploration,characterization,and well development strategies.Chemostratigraphy incorporates applications on continuous,real-time geochemical mapping and direction of lateral drilling,and machine learning,among others.As the sedimentary systems operate on a variety of temporal scales that range from few hours(tidal cycles)to few tens of millions of years,within which many perturbations such as catastrophic and diagenetic events take place,that lead to unique geochemical signature which can be correlated at appropriate spatial and temporal scales.The application of chemostratigraphic technique in hydrocarbon exploration and reservoir characterization has gained momentum in recent years,particularly with the advent of developments in analytical instrumentation.This has also led to the integration of a variety of data from field sedimentary structures,mineralogy,major,trace and isotopic chemical compositions of whole rock,selected components of rocks,organic and inorganic components of oil and gas,etc.,for reservoir characterization more accurately than ever.The geochemical fingerprinting of oil and gas reservoir components plays a major role in the identification of source rocks,discrimination of oil families,characterization of reservoir,source,and seal segments in petroleum systems.Future trends indicate the relevance and growing applications of machine learning techniques,artificial intelligence in real-time assessment,monitoring and planning of hydrocarbon exploration and production.展开更多
Shallow-platform settings with marked differences in paleoplatform bottom physiography influence the degree of connection with oceanic waters and overall circulation patterns,even when sharing the same palaeoclimatic ...Shallow-platform settings with marked differences in paleoplatform bottom physiography influence the degree of connection with oceanic waters and overall circulation patterns,even when sharing the same palaeoclimatic conditions.Two Kimmeridgian shallow-marine settings have been explored to test the sensitivity and reliability of carbonate chemostratigraphy to detect such differences.An integrated overview of the obtained elemental trends depicted four major facies,shared along specific stratigraphic intervals of both depositional records.Diagenesis obliterated original geochemical signals only throughout the siliciclastics-rich interval,corresponding to the most landward setting.For the remaining facies,elemental features could be attributed to the differential action of forcing mechanisms operating along the south-Iberian paleomargin during Kimmeridgian times.The highest degree of continental influence can be recognized by a strong relationship between Fe and Mn for the most proximal setting,which fades out along the mixed carbonate-fine siliciclastic rhythmic deposition in more open settings.A characteristic geochemical signature of progressively more positiveδ^(13)C values and significantly higher Sr content is identified for the interval dominated by biogenic sponge buildups.Such a local response is related to local forcing by upwelling in the surroundings of a coral fringe.The geochemical signature of a hydrothermal origin can be clearly differentiated from the influence of mere terrigenous pulses.Accordingly,the decoupling of Fe and Mn along marginal settings is the clue to detecting major events of palaeogeographic restructuring.Observed temporal variations in Mg content along both studied sections are attributed to tectonic activity influencing nearshore/coastal water masses.By integrating chemostratigraphic information and complementary evidence,the palaeoenvironmental mechanisms promoting differentiated sedimentary records along ancient subtropical,shallow,coastal settings can be disentangled.展开更多
Cap Carbonates overlie the Marinoan Snowball Earth-related glacial diamictite, and possibly record the drastic surface environmental change and biological evolution after the Snowball Earth. We conducted on-land drill...Cap Carbonates overlie the Marinoan Snowball Earth-related glacial diamictite, and possibly record the drastic surface environmental change and biological evolution after the Snowball Earth. We conducted on-land drilling from the Liantuo Formation, through the Nantuo, to the lower Doushantuo Formation in the Three Gorges area of South China to collect fresh, continuous samples in the Three Gorges area. We obtained high-resolution chemostratigraphies of ~13C and 6180 values of carbonates from the topmost part of the Nantuo Formation to the Cap Carbonate, in order to decode the detailed surface environmental change in the shallow marine setting. The δ3C chemostratigraphy possesses some unique characteristics： （1） stable δ13C values as a whole, but ubiquitous low δ13C anomalies through the Cap Carbonate, （2） increase of the δ13C values from -3 to ＋5‰ across the C2/C3 boundary, （3） no δ13C anomaly between the CI and C2 boundary, and （4） presence of an anomalous high δ13C value （＋2.3%0） and a faint positive correlation between δ13C and δ18O values in the C1 unit. Evidence of quite low δ13C anomalies （with a nadir of -41‰）, ubiquitous negative δ13C anomalies through the Cap Carbonate, and a high 613C anomaly accompanied with a faint positive correlation between δ13C and δ18O values in the C1 unit supports decomposition and formation of methane hydrate during Cap Carbonate formation. The drastic increase of δ13C values from the upper C2 to C3 units in- dicates enhancement of primary productivity and organic carbon burial, possibly due to high continental fluxes after the Snowball Earth event, evidenced by high Sr isotope values. The increase is restricted to the proximal side of the inner shelf in South China, and the timing of the increase of δ13C values of carbonates is earlier at Three Gorges area than any other area, suggesting that the enhancement of primary productivity started in the proximal environment because of higher continental influxes. The increase in oxygen contents of seawater due to the enhanced primary productivity possibly resulted in the emergence of multicellular animals soon after Cap Carbonate deposition.展开更多
The gold deposits of Triassic period in the northwestern Guangxi are all located in the marine, fine -grained ,fragmental rock series containing organic matter ,i.e .the distribution districts of black rock series . T...The gold deposits of Triassic period in the northwestern Guangxi are all located in the marine, fine -grained ,fragmental rock series containing organic matter ,i.e .the distribution districts of black rock series . The fine-grained gold deposits occur in organic matter -bearing C, D,E,or D,E divisions of the classical Bouma sequences. The evolution degree of organic matters through oil window stage reached the over -mature degree. Both the bio-sources of the organic matters and the distribution of gold in the organic matters disclose the close association between gold , living beings and organic matters . The thermal evolution of organic matters led to the gold to be activized . migrated and enriched , and finally formed gold deposits in the fault belt and crushed zone of black rock series .展开更多
Biomanufacturing(BM)is a multidisciplinary area incorporating the characteristics of living organisms and engineering principles to create valuable products for various sectors,including medicine,energy,and the enviro...Biomanufacturing(BM)is a multidisciplinary area incorporating the characteristics of living organisms and engineering principles to create valuable products for various sectors,including medicine,energy,and the environment.BM has undergone a remarkable transformation in the last two decades,entering the era of BM4.0 and becoming a pivotal driver of the sustainable revolution.Notably,Japan has made significant advances in BM,contributing to its development through the creation of innovative materials,advanced processes,and interdisciplinary applications.However,because of certain development policies,this research has not been widely recognized on an international level.This paper provides a comprehensive summary of the research progress made by renowned Japanese laboratories and researchers in biomedical materials,bio-three-dimensional(3D)printing,and biomedical applications in the last five years.Their unique contributions are introduced and analyzed,illuminating the distinctive approaches and breakthroughs within each domain.Additionally,this review highlights the current challenges and prospects of BM.The viewpoints presented in this paper are intended to serve as a valuable reference for scholars studying BM in Japan.展开更多
文摘The tests performed with two hundred and thirty-nine (239) samples from the A-X and B-X drillings help to know their sedimentological and chemostratigraphic characters. In sedimentological term formations are composed of sand, sandstone, limestone, siltstone and argillite that alternate along the drill. In chemostratigraphic term two megasequences (MS1 and MS2) have been identified. A correlation of chemostratigraphic data completed by the lithology results allowed a subdivision of oil wells that shows two main types of deposits environments. First, a proximal marine environment to continental and to Albian marked by a detrital flow deducted from the concentrations evolution of indicator elements of terrigenous material that are K, Mg, and Rb. On the other hand, a deep to shallow marine environment of Cenomanian to Paleocene marked by the presence of predominantly clay sediments and abundant glauconite in the lower Senonian. Nevertheless, there is a transition or intermediate environment that is characterized by the presence of glauconite and detrital flows.
文摘The Late Permian Emeishan Large Igneous Province (ELIP) is commonly regarded as being located in the western part of the Yangtze craton, SW China, with an asymmetrical shape and a small area. This area, however, is just a maximum estimation because some parts of the ELIP were not recognized or dismembered and destroyed during the Triassic to Cenozoic tectonism. In this paper, the chemostratigraphical data of the Zongza block, the Garze-Litang belt and the Songpan-Garze block suggest that the Late Permian basalts in these areas have remarkable similarities to the ELIP basalts in petrography and geochemistry. Flood basalts in the Sanjiangkou area are composed of the lower part of the low-Ti (LT) tholeiite and the upper part of the high-Ti (HT) tholeiite, which is the same as the flood basalts on the western margin of the Yangtze craton. Flood basalts in the Zongza and Songpan-Garze areas, which are far from the Yangtze craton, consist of HT tholeiite only. This is the same as the flood basalts within the Yangtze craton. Therefore we argue that these contemporary basalts all originated from the Emeishan mantle plume, and the ELIP could have a significant westward extension with an outcropped area of over 500,000 km2. This new scenario shows that the LT tholeiite occurs on the western margin of the Yangtze craton, while the HT tholeiite overlying the LT basalts occupies the whole area of the ELIP.
基金support from the Chinese Academy of Sciences (KZCX2-YW-122, CAS/SAFEA Program)the Ministry of Science and Technology of China (2006FY120300-4, 2008ZX05008-001)+2 种基金A.M. is grateful to the Deutsche Forschungsgemeinschaft (DFG Mu 2352/1)the Robert-Bosch-Stiftung (grant no. Nr. 32.5.8003.0009.0)the Uni-Bund Erlangen for their support
文摘The base of the Middle Ordovician （i.e. Dapingian Stage） has been defined at the first appearance datum （FAD） of conodont Baltoniodus？ triangularis at Huanghuachang, Yichang, China,but the precise correlation of the boundary to regions of other facies remain to be resolved. Herein we review the biostratigraphy and chemostratigraphy of the Huanghuachang Global Standard Stratotype-Section and Point （GSSP） section, and present our latest stratigraphic work on the nearby Chenjiahe s ection in Yichang, and the Hengtang Quarry section, Jiangshan, Zhejiang, which is regarded as representative of slope facies. The conodont and graptolite biostratigraphy as well as chemostratigraphy of the Chenjiahe section indicate that the base of the Middle Ordovician also falls within the graptolite Azygograptus suecicus Zone, and coincides with a high or maximum δ13C value within a minor positive carbon isotope excursion, suggesting that the base boundary can be readily recognized across the entire Yangtze Gorges area. The integrated graptolite and conodont biostratigraphy and chemostratigraphy of the Hengtang section, Jiangshan, indicates that the basal boundary probably falls within the graptolite lsograptus caduceus imitatus Zone that overlies the Azygograptus suecicus Zone, and coincides with a remarkable drop of δ13C. This difference indicates that a multi-disciplinary approach is critical to identify the base boundary in those regions where the Baltoniodus ？ triangularis is absent.
文摘Sedimentary sequences preserve the records of changes in major controls of sedimentation namely,tectonics,climate,relative sea level and sediment production and preservation.The potential to characterize these changes in spatial and temporal scales has led to the development of the branch of chemostratigraphy.Chemostratigraphic study of sedimentary sequences commenced from recognizing identical/contrasting geochemical features across major geochronological boundaries,and evolved into one of the essential tools in exploration,characterization,and well development strategies.Chemostratigraphy incorporates applications on continuous,real-time geochemical mapping and direction of lateral drilling,and machine learning,among others.As the sedimentary systems operate on a variety of temporal scales that range from few hours(tidal cycles)to few tens of millions of years,within which many perturbations such as catastrophic and diagenetic events take place,that lead to unique geochemical signature which can be correlated at appropriate spatial and temporal scales.The application of chemostratigraphic technique in hydrocarbon exploration and reservoir characterization has gained momentum in recent years,particularly with the advent of developments in analytical instrumentation.This has also led to the integration of a variety of data from field sedimentary structures,mineralogy,major,trace and isotopic chemical compositions of whole rock,selected components of rocks,organic and inorganic components of oil and gas,etc.,for reservoir characterization more accurately than ever.The geochemical fingerprinting of oil and gas reservoir components plays a major role in the identification of source rocks,discrimination of oil families,characterization of reservoir,source,and seal segments in petroleum systems.Future trends indicate the relevance and growing applications of machine learning techniques,artificial intelligence in real-time assessment,monitoring and planning of hydrocarbon exploration and production.
基金supported by Projects CGL2008-05251-E and CGL2012-39835(MINECO)the Research Group RNM-178,Junta de Andalucia,Spain+1 种基金supported by the Post-Doctoral Fellowship SFRH/BPD/92376/2013(Fundacao para a Ciencia e a Tecnologia,Portugal)the research units GeoBiotec-UID/GEO/04035/2013 and MARE-UID/MAR/04292/2013
文摘Shallow-platform settings with marked differences in paleoplatform bottom physiography influence the degree of connection with oceanic waters and overall circulation patterns,even when sharing the same palaeoclimatic conditions.Two Kimmeridgian shallow-marine settings have been explored to test the sensitivity and reliability of carbonate chemostratigraphy to detect such differences.An integrated overview of the obtained elemental trends depicted four major facies,shared along specific stratigraphic intervals of both depositional records.Diagenesis obliterated original geochemical signals only throughout the siliciclastics-rich interval,corresponding to the most landward setting.For the remaining facies,elemental features could be attributed to the differential action of forcing mechanisms operating along the south-Iberian paleomargin during Kimmeridgian times.The highest degree of continental influence can be recognized by a strong relationship between Fe and Mn for the most proximal setting,which fades out along the mixed carbonate-fine siliciclastic rhythmic deposition in more open settings.A characteristic geochemical signature of progressively more positiveδ^(13)C values and significantly higher Sr content is identified for the interval dominated by biogenic sponge buildups.Such a local response is related to local forcing by upwelling in the surroundings of a coral fringe.The geochemical signature of a hydrothermal origin can be clearly differentiated from the influence of mere terrigenous pulses.Accordingly,the decoupling of Fe and Mn along marginal settings is the clue to detecting major events of palaeogeographic restructuring.Observed temporal variations in Mg content along both studied sections are attributed to tectonic activity influencing nearshore/coastal water masses.By integrating chemostratigraphic information and complementary evidence,the palaeoenvironmental mechanisms promoting differentiated sedimentary records along ancient subtropical,shallow,coastal settings can be disentangled.
基金partly supported by grants"Multi-step evolution of multicellular animals(No.23340152)""Toward establishment of chemical paleontology(No.23654176)"+1 种基金the Global COE Program"From the Earth to‘Earths’"from the Ministry of Education,Culture,Sports,Science and Technology,Japansupported by a grant from the Mitsubishi Foundation(T.K.).Each is gratefully acknowledged
文摘Cap Carbonates overlie the Marinoan Snowball Earth-related glacial diamictite, and possibly record the drastic surface environmental change and biological evolution after the Snowball Earth. We conducted on-land drilling from the Liantuo Formation, through the Nantuo, to the lower Doushantuo Formation in the Three Gorges area of South China to collect fresh, continuous samples in the Three Gorges area. We obtained high-resolution chemostratigraphies of ~13C and 6180 values of carbonates from the topmost part of the Nantuo Formation to the Cap Carbonate, in order to decode the detailed surface environmental change in the shallow marine setting. The δ3C chemostratigraphy possesses some unique characteristics： （1） stable δ13C values as a whole, but ubiquitous low δ13C anomalies through the Cap Carbonate, （2） increase of the δ13C values from -3 to ＋5‰ across the C2/C3 boundary, （3） no δ13C anomaly between the CI and C2 boundary, and （4） presence of an anomalous high δ13C value （＋2.3%0） and a faint positive correlation between δ13C and δ18O values in the C1 unit. Evidence of quite low δ13C anomalies （with a nadir of -41‰）, ubiquitous negative δ13C anomalies through the Cap Carbonate, and a high 613C anomaly accompanied with a faint positive correlation between δ13C and δ18O values in the C1 unit supports decomposition and formation of methane hydrate during Cap Carbonate formation. The drastic increase of δ13C values from the upper C2 to C3 units in- dicates enhancement of primary productivity and organic carbon burial, possibly due to high continental fluxes after the Snowball Earth event, evidenced by high Sr isotope values. The increase is restricted to the proximal side of the inner shelf in South China, and the timing of the increase of δ13C values of carbonates is earlier at Three Gorges area than any other area, suggesting that the enhancement of primary productivity started in the proximal environment because of higher continental influxes. The increase in oxygen contents of seawater due to the enhanced primary productivity possibly resulted in the emergence of multicellular animals soon after Cap Carbonate deposition.
基金The paper is supported by the National Natural Science Foundation of China
文摘The gold deposits of Triassic period in the northwestern Guangxi are all located in the marine, fine -grained ,fragmental rock series containing organic matter ,i.e .the distribution districts of black rock series . The fine-grained gold deposits occur in organic matter -bearing C, D,E,or D,E divisions of the classical Bouma sequences. The evolution degree of organic matters through oil window stage reached the over -mature degree. Both the bio-sources of the organic matters and the distribution of gold in the organic matters disclose the close association between gold , living beings and organic matters . The thermal evolution of organic matters led to the gold to be activized . migrated and enriched , and finally formed gold deposits in the fault belt and crushed zone of black rock series .
基金This work was supported by the National Natural Science Foundation of China(No.52105072).
文摘Biomanufacturing(BM)is a multidisciplinary area incorporating the characteristics of living organisms and engineering principles to create valuable products for various sectors,including medicine,energy,and the environment.BM has undergone a remarkable transformation in the last two decades,entering the era of BM4.0 and becoming a pivotal driver of the sustainable revolution.Notably,Japan has made significant advances in BM,contributing to its development through the creation of innovative materials,advanced processes,and interdisciplinary applications.However,because of certain development policies,this research has not been widely recognized on an international level.This paper provides a comprehensive summary of the research progress made by renowned Japanese laboratories and researchers in biomedical materials,bio-three-dimensional(3D)printing,and biomedical applications in the last five years.Their unique contributions are introduced and analyzed,illuminating the distinctive approaches and breakthroughs within each domain.Additionally,this review highlights the current challenges and prospects of BM.The viewpoints presented in this paper are intended to serve as a valuable reference for scholars studying BM in Japan.
