High-pressure minerals and new lunar mineral changesite-(Y) in Chang’e-5 regolith

Forty-five years after the Apollo and Luna missions, China’s Chang’e-5 (CE-5) mission collected ∼1.73 kg of new lunar materials from one ofthe youngest basalt units on the Moon. The CE-5 lunar samples provide opportunities to address some key scientific questions related to theMoon, including the discovery of high-pressure silica polymorphs (seifertite and stishovite) and a new lunar mineral, changesite-(Y). Seifertitewas found to be coexist with stishovite in a silica fragment from CE-5 lunar regolith. This is the first confirmed seifertite in returned lunarsamples. Seifertite has two space group symmetries (Pnc2 and Pbcn) and formed from an α-cristobalite-like phase during “cold” compressionduring a shock event. The aftershock heating process changes some seifertite to stishovite. Thus, this silica fragment records different stagesof an impact process, and the peak shock pressure is estimated to be ∼11 to 40 GPa, which is much lower than the pressure condition forcoexistence of seifertite and stishovite on the phase diagram. Changesite-(Y), with ideal formula (Ca_(8)Y)◻Fe^(2+)(PO_(4))_(7) (where ◻ denotes avacancy) is the first new lunar mineral to be discovered in CE-5 regolith samples. This newly identified phosphate mineral is in the form ofcolumnar crystals and was found in CE-5 basalt fragments. It contains high concentrations of Y and rare earth elements (REE), reaching upto ∼14 wt. % (Y,REE)2O3. The occurrence of changesite-(Y) marks the late-stage fractional crystallization processes of CE-5 basalts combinedwith silicate liquid immiscibility. These new findings demonstrate the significance of studies on high-pressure minerals in lunar materials andthe special nature of lunar magmatic evolution.

Imaging the Architecture of Mineral Systems and the Pathways of Ore-forming Fluids across Mongolia with Magnetotellurics

In the framework of a mineral system approach,a combination of components is required to develop a mineral system.This includes the whole-lithosphere architecture,which controls the transport of ore-forming fluids,and favorable tectonic and geodynamic processes,occurring at various spatial and temporal scales,that influence the genesis and evolution of ore-forming fluids(Huston et al.,2016;Groves et al.,2018;Davies et al.,2020).Knowledge of the deep structural framework can advance the understanding of the development of a mineral system and the emplacement of mineral deposits.Deep geophysical exploration carried out with this aim is increasingly important for targeting new ore deposits in unexplored and underexplored regions(Dentith et al.,2018;Dentith,2019).

Research progress of CO_(2) capture and mineralization based on natural minerals

Natural minerals,such as kaolinite,halloysite,montmorillonite,attapulgite,bentonite,sepiolite,forsterite,and wollastonite,have considerable potential for use in CO_(2) capture and mineralization due to their abundant reserves,low cost,excellent mechanical prop-erties,and chemical stability.Over the past decades,various methods,such as those involving heat,acid,alkali,organic amine,amino sil-ane,and ionic liquid,have been employed to enhance the CO_(2) capture performance of natural minerals to attain high specific surface area,a large number of pore structures,and rich active sites.Future research on CO_(2) capture by natural minerals will focus on the full utiliza-tion of the properties of natural minerals,adoption of suitable modification methods,and preparation of composite materials with high specific surface area and rich active sites.In addition,we provide a summary of the principle and technical route of direct and indirect mineralization of CO_(2) by natural minerals.This process uses minerals with high calcium and magnesium contents,such as forsterite(Mg_(2)SiO_(4)),serpentine[Mg_(3)Si_(2)O(OH)_(4)],and wollastonite(CaSiO_(3)).The research status of indirect mineralization of CO_(2) using hydro-chloric acid,acetic acid,molten salt,and ammonium salt as media is also introduced in detail.The recovery of additives and high-value-added products during the mineralization process to increase economic benefits is another focus of future research on CO_(2) mineralization by natural minerals.

Application of Remote Sensing and GIS in Mineral Alteration Mapping and Lineament Extraction Case of Oudiane Elkharoub (Requibat Shield, Northern of Mauritania)

The integration of remotely sensed data allowed the successful characterization of the mineral alteration zones of the Oudiane Elkharoub area in the Northeastern part of Reguibat Shield using image transformation techniques. As both chemical and geochemical analyses showed significant Au, Ag, Cu, Pb, Mn, Cr, Ni, Th and Y anomalies, it’s very interesting to apply the remote sensing and GIS in mineral resources mapping. The remote sensing is a direct adjunct to the field, lithologic and structural mapping, and more recently, GIS has played an important role in the study of mineralization areas. The integration of several evidential maps highlighted the plausible areas with high concentrations of chlorite, epidote, kaolinite, calcite, alunite, hematite, illite and sulfur among other key mineral alterations that reflect the intensity of hydrothermal effects and the probable sites of ore bodies. The methodological approach integrates geological information acquired from Aster and Landsat 8 OLI/TIRS (Operational Land Imager/Thermal InfraRed Sensor) images and a multi-criteria GIS analysis. The superimposition of various lineament and hydrothermal alteration maps and the consideration of precious and base metal indicators allowed the zoning of sites likely to contain mineral concentrations. Remote sensing becomes an important tool for locating mineral deposits in its own right, when the primary and secondary processes of mineralization result in the formation of spectral anomalies. Reconnaissance lithological mapping is usually the first step of mineral resource mapping. This is complimented with structural mapping, as mineral deposits usually occur along or adjacent to geologic structures, and alteration mapping, as mineral deposits are commonly associated with hydrothermal alteration of the surrounding rocks. Ground truthing and laboratory studies including XRD analysis were utilized to verify the results.

Determination and Quantification of Proximate and Mineral Composition for 20 Improved Sorghum Varieties Grown in Machache, Lesotho

Twenty varieties of improved sorghum were grown in Machache at the Department of Agricultural Research station, located (29˚22'60"S and 27˚52'0"E) in the central foothills of Lesotho in Maseru district. The varieties were planted in a randomized complete block design. At maturity, they were harvested, dried, threshed, milled and analyzed in the crop science laboratory at the National University of Lesotho. The proximate and mineral contents were analyzed from samples in a completely randomized design with three replicates. The proximate composition parameters measured were crude proteins, crude fiber, crude fat, moisture content, and carbohydrates. The minerals analyzed were, phosphorus, sodium, calcium, magnesium, potassium, copper, zinc, iron, and magnesium. The results showed the nutritional contents ranging from (4.7% - 16.16%), (0.35% - 2.10%), (1.25% - 4.00%), (71.60% - 84.06%), (5.53% - 10.18%), for protein, fat, fiber and carbohydrate, and moisture content, respectively. Mineral content ranged from (1342.96 - 3500.34 mg/kg), (25.97 - 185.25 mg/kg), (50.71 - 511.71 mg/kg), (29.35 - 4542.13 mg/kg), (577.19 - 3041.52 mg/kg), (0.25 - 4.07 mg/kg), (1.96 - 18.61 mg/kg), (67.14 - 122.96 mg/kg), (4.73 - 11.39 mg/kg) for phosphorus, sodium, calcium, magnesium, potassium, copper, zinc, iron, and manganese respectively. The following varieties were found to have the highest and appreciable amounts of nutrients and minerals that are crucial in the country diet;protein content was KARI Mtama 1, zinc, IESX 16 2533-SB-SSI-19, and iron IESX 16 2535-SB-SSI-34.

Assessment of Some Secondary Metabolites, Minerals and Alcohol Content of Noni Juice Obtained by Fermentation of Morinda citrifolia L. Fruit from Senegal

The fruit of Morinda citrifolia L., commonly known as noni, has an extensive history of use as a food and traditional medicine around the world. Adding value to Morinda citrifolia L. products, particularly the fruit, could be one way of building resilience in vulnerable farming households. The aim of this study was to determine the secondary metabolite and mineral composition of noni juice obtained by fermenting the fruit of Morinda citrifolia L. Fruits were collected in August 2022 from the local field in Thiès region, West of Senegal. Extraction yields were determined and the secondary metabolites were determined using conventional analytical methods. Calcium, magnesium, iron, sodium and potassium were determined by atomic absorption spectrophotometer coupled with a CCD detector. The results show that an average fruit mass (503.2 ± 110.96 g) consists of 171.44 ± 50.01 g pulp and 34.06 ± 10.35 g seeds. The traditional extraction yield of noni juice is 16.46% after three weeks of fermentation. The contents of total polyphenols, flavonoids and tannins obtained in noni are 608.97 ± 4.53 mg EAG/100mL, 7.78 ± 0.01 mg EQ/100mL and 0.191 ± 0.01 mg EC/100mL respectively. The ethanol content of noni varies from 3.57 to 5.23 mL/100mL during extraction. Noni has a high calcium content with a concentration of 383.79 ± 33.23 mg/L. This is followed by a good concentration of magnesium, potassium and sodium, at 278.47 ± 26.30, 187.43 ± 10.7 and 155.95 ± 28.66 mg/L respectively. Noni also has an iron content of 202.15 ± 0.05 mg/L.

Basalt Petrology, Water Chemistry, and Their Impact on the CO_(2) Mineralization Simulation at Leizhou Peninsula Sites, Southern China

Mineral carbonation, which precipitates dissolved carbon dioxide(CO_(2)) as carbonate minerals in basaltic groundwater environments, is a potential technique for negative emissions. The Leizhou Peninsula in southwest Guangdong province has extensive basalt, indicating a promising potential for CO_(2) storage through rapid mineralization. However, understanding of the basic geological setting, potential, and mechanisms of CO_(2) mineralization in the basalts of the Leizhou Peninsula is still limited. The mineralization processes associated with CO_(2)storage at two candidate sites in the area are investigated in this paper: Yongshi Farm and Tianyang Basin(of the dried maar lake). Petrography,rock geochemistry, basalt petrophysical properties, and groundwater hydrochemistry analyses are included in the study. Numerical simulation is used to examine the reaction process and its effects. The results show that basalts in the study areas mainly comprise plagioclase, pyroxene, and Fe–Ti oxides, revealing a total volume fraction exceeding 85%. Additionally, small amounts of quartz and fayalite are available, with volume fractions of 5.1% and 1.0%, respectively. The basalts are rich in divalent metal cations, which can form carbonate minerals, with an average of approximately 6.2 moles of metal cations per 1 kg of rock. The groundwater samples have a pH of 7.5–8.2 and are dominated by the Mg–Ca–HCO3 type. The basalts demonstrate a porosity range of 10.9% to 28.8%, with over 70% of interconnected pores. A 20-year geochemical simulation revealed that CO_(2) injection dissolves primary minerals, including anorthite, albite, and diopside, while CO_(2)mineralization dissolves precipitation secondary minerals, such as calcite, siderite, and dolomite. Furthermore, a substantial rise in pH from 7.6to 10.6 is observed in the vicinity of the injected well, accompanied by a slight reduction in porosity from 20% to 19.8%. Additionally, 36.8% of the injected CO_(2) underwent complete mineralization within five years, revealing an increasing percentage of 66.1% if the experimental period is extended to 20 years. The presence of abundant divalent metal cations in basalts and water-bearing permeable rocks in the Leizhou Peninsula supports the potential for mineral carbonation in basalts, as indicated by the geochemical simulation results. Additional research is necessary to identify the factors that influence the CO_(2) mineralization, storage, and sensitivity analysis of basalt in the Leizhou Peninsula.

Geochemistry, mineral paragenesis and geothermal conditions of oreforming fluids from the Ain El Bey Cu–Fe deposit: potential occurrence of native gold and precious metal traces (North African orogenic belt, Northern Tunisia)

The Ain El Bey abandoned mine, in North-West Tunisia, fits into the geodynamic context of the European and African plate boundary. Ore deposit corresponds to veins and breccia of multiphase Cu–Fe-rich mineralization related to various hydrothermal fluid circulations. Petromineralogical studies indicate a rich mineral paragenesis with a minimum of seven mineralization phases and, at least, six pyrite generations. As is also the case for galena and native silver, native gold is observed for the first time as inclusion in quartz which opens up, thus, new perspectives for prospecting and evaluating the potential for noble metals associated with the mineralization. Scanning Electron Microscope--Energy Dispersive Spectroscopy and Transmission electron microscopy analyses show, in addition, a large incorporation of trace elements, including Ag and Au, in mineral structures such as fahlores(tetrahedrite-tennantite) and chalcopyrite ones. The mineral/mineral associations, used as geothermometers, gave estimated temperatures for the mineralizing fluids varying from 254 to 330 ℃ for phase Ⅲ, from 254 to 350 ℃ for phase Ⅳ, and from 200 to 300 ℃ for phases Ⅴ and Ⅵ. The seventh and last identified mineralization phase, marked by a deposit of native gold, reflects a drop in the mineralizing fluid’s temperature(< 200 ℃) compatible with boiling conditions. Such results open up perspectives for the development of precious metal research and the revaluation of the Cu–Fe ore deposit at the Ain El Bey abandoned mine, as well as at the surrounding areas fitting in the geodynamic framework of the Africa-Europe plate boundary.

Mineral Geochemistry of Apatite in the Jiama PorphyrySkarn Deposit,Tibet and its Geological Significance

The Jiama deposit,a significant porphyry-skarn-type copper polymetallic deposit located within the Gangdese metallogenic belt in Tibet,China,exemplifies a typical porphyry metallogenic system.However,the mineral chemistry of its accessory minerals remains under-examined,posing challenges for resource assessment and ore prospecting.Utilizing electron microprobe analysis and LA-ICP-MS analysis,this study investigated the geochemical characteristics of apatite in ore-bearing granite and monzogranite porphyries,as well as granodiorite,quartz diorite,and dark diorite porphyries in the deposit.It also delved into the diagenetic and metallogenic information from these geochemical signatures.Key findings include:(1)The SiO_(2) content,rare earth element(REE)contents,and REE partition coefficients of apatite indicate that the dark diorite porphyry possibly does not share a cogenetic magma source with the other four types of porphyries;(2)the volatile F and Cl contents in apatite,along with their ratio,indicate the Jiama deposit,formed in a collisional setting,demonstrates lower Cl/F ratios in apatite than the same type of deposits formed in a subduction environment;(3)compared to non-ore-bearing rock bodies in other deposits formed in a collisional setting,apatite in the Jiama deposit exhibits lower Ce and Ga contents.This might indicate that rock bodies in the Jiama deposit have higher oxygen fugacity.Nevertheless,the marginal variation in oxygen fugacity between ore-bearing and non-ore-bearing rock bodies within the deposit suggests oxygen fugacity may not serve as the decisive factor in the ore-hosting potential of rock bodies in the Jiama deposit.

Geology and mineralization of the Dongping supergiant alkalic-hosted Au-Te deposit(>100 t Au)in Northern Hebei Province,China:A review

The Dongping deposit is the largest alkalic-hosted gold deposit in China containing>100 t of Au.This paper presents a new understanding for Dongping ore system,based on the previous studies.The mineralization originally occurred at 400-380 Ma,simultaneous with emplacement of the Shuiquangou alkaline complex,and was overprinted by the hydrothermal activity in the Yanshanian.Isotope compositions of ores indicate metals of the deposit are mainly provided by the Shuiquangou complex.Ore-forming fluids are characterized by increasing oxygen fugacity and decreasing sulfur fugacity,while tellurium fugacity increased in the Stage II-2 and decreased in Stage II-3.These systematic changes are closely related to the processes of mineral precipitation and fluid evolution.Sulfide precipitation from Stage Ⅰ to Stage Ⅱ was triggered by fluid boiling,which leads to the precipitation of Pb-Bi-Te,due to decrement of sulfur fugacity.Condensation of gas phase containing high concentration of H_2Te leads to precipitation of Te-Au-Ag minerals and native tellurium.Based on these hypotheses,this paper present a polyphase metallogenic model as follow.During the Devonian,fluids were released from alkaline magmas,which carried ore-forming materials form the surrounding rocks and precipitate the early ores.During the Jurassic-Cretaceous,fluorine-rich fluids exsolved from highly factionated Shangshuiquan granite,which extracted and concentrated Au from the Shuiquangou complex and the Sanggan Group metamorphic rocks,and finally formed the Dongping gold deposit.

Metallogenesis of the Baidi Au-Sb deposit, southwest Guizhou Province, China: mineralogical and geochemical evidence from sulfur-bearing minerals

The Baidi Au-Sb deposit, which contains 8 t of Au and 10,979 Mt of Sb, is a typical and rare paragenetic deposit located in southwestern Guizhou Province, China.Previous studies have focused on individual ores, but have not combined them to identify their paragenetic mechanism or metallogenic regularity. Therefore, we used field investigations, microscopic observations, and in situ analyses to identify the spatial distribution, mineral paragenesis, compositional evolution, and metallogenic material sources of the ore bodies. We also determined the Au and Sb paragenetic characteristics and the metallogenesis of the deposit. The main Au-bearing minerals in the deposit were early(Apy1–2) and late(Apy3) stage arsenopyrites, as well as pre-mineralization(Py1), mineralization(Py2–5), and late mineralization(Py6–7) stage pyrites. The main Sb-bearing minerals were stibnite(Snt), skinnerite, bournonite,and valentinite. The minerals formed in the order of Py1,Py2–3 + Apy1, Py4–5 + Apy2, Snt, and Py6–7 + Apy3.The δ34S values of the arsenopyrites and pyrites ranged from-5 to 5‰, while those of stibnite were mostly less than-5‰ in the later mineralization stages. Sulfur was provided by deep magmatic hydrothermal fluids, but sedimentary sulfur was added in the later stages. Moreover,the trace elemental contents fluctuated and eventually became similar to those of the sedimentary strata. By comprehensively considering the ores along with the geological characteristics of the deposit, we determined that deep magma provided the Au during ore formation. Later tectonic changes provided Sb from the sedimentary strata,which precipitated along fault expansion areas and produced Au and Sb paragenesis.

Petrogenesis, oxidation state and volatile content of Dongga tonalite in the Gangdese belt, Xizang: Implication for porphyry Cu mineralization

The Gangdese belt in Xizang has experienced both Jurassic subduction and Cenozoic continental collision processes, making it a globally renowned region for magmatic rocks and porphyry copper deposits. Numerous Jurassic intrusions have been identified in the belt. Apart from the quartz diorite porphyry in the large Xietongmen deposit, the Cu mineralization potential of other Jurassic intrusions in this belt remains unclear. This study presents zircon U–Pb dating and trace elements, apatite major and trace elements as well as published whole-rock geochemical and isotopic data of the Dongga tonalite in the central part of the Gangdese belt, aiming to reveal the petrogenesis, oxidation state, volatile content, and Cu mineralization potential of this intrusion. The Dongga tonalite has a zircon U–Pb age of 179.4 ± 0.9 Ma. It exhibits high whole-rock V/Sc values(8.76–14.6), relatively low apatite CeN/CeN*ratios(1.04–1.28), elevated zircon(Eu/Eu*)Nvalues(an average of 0.44), high Ce4+/Ce3+values(205–1896), and high ?FMQ values(1.3–3.7), collectively suggesting a high magmatic oxygen fugacity. The Dongga tonalite features amphibole phenocrysts, relatively high whole-rock Sr/Y ratios(20.3–58.9), and lower zircon Ti temperatures (502–740 ℃), reflecting a high magmatic water content. Estimation of magmatic sulfur content(0.002–0.024 wt%) based on apatite SO3contents indicates an enriched magma sulfur content. Combined with previous studies and the collected Sr–Nd–Hf isotopes, the Dongga tonalite is derived from juvenile lower crust related with subduction of the Neo-Tethys oceanic slab. When compared with Xietongmen orebearing porphyries, the Dongga tonalite exhibits remarkable similarities with the Xietongmen ore-bearing porphyries in terms of magma source, tectonic background, magmatic redox state, and volatile components, which indicates that the Dongga tonalite has a high porphyry Cu mineralization potential, and therefore, provides important guidance for the future mineralization exploration.

Minerals in edible insects:a review of content and potential for sustainable sourcing

In response to the rapid increase in world population and subsequent demands for food,edible insects represent an alternative food source for humans that is rich in proteins,amino acids and minerals.Entomophagy is a tradition in many countries including China and Thailand,and edible insects have attracted a lot of attention in Western World due to their suitable nutrient composition,high mineral content(e.g.,Fe,Zn,Ca,Mg)and potential use as a supplement in human diet.In this study,we surveyed mineral content in seven insect orders and 67 species of mass produced and wild-harvested edible insects.The total content of essential elements in edible insects was very high in Tenebrio molitor,Bombyx mori,and Zonocerus variegatus.The heavy metal content(summarized for eight species)was below the maximum limit allowed for safe consumption.Sustainable supply of minerals derived from insect biomass is complicated due to the high variations of mineral content in insects and the potential of its change due to processing.

Characteristics of Gold Mineralization at the Baguiomo Gold Panning Site, Koudougou Region, Burkina Faso, West Africa

The Birimian Baguiomo formations are located in the northern part of the Boromo greenstone belt. In this belt, the volcanic rocks (tholeiitic basalt, calcalkaline basalt, andesite) hosting the gold mineralization are located in the Kwademen-Baguiomo shear zone. This mineralization, located only a few kilometers from the Kwademen gold deposit, is uncharacterized and, together with the latter, could constitute a gold potential capable of being economically exploitable. It is in this sense that this work is carried out with a view to characterizing the gold mineralization of the Baguiomo gold panning site. To carry out this work, we have made direct field measurements, combined with microstructures, and combined all this with data from geochemical rock analysis of the basalts that are the main host formations. Geochemical data show that tholeitic basalts formed from a mantle plume that was emplaced in an oceanic plateau context. Calc-alkaline basalts and andesites are comparable to Paleoproterozoic tholeitic basalts (PTH3), which are slightly enriched in light rare earths. Fertility tests show that these basalts concentrate between 3 and 6 ppb of gold at the time of accretion, which is sufficient for remobilization of this primary gold during the Eburnian orogeny to yield a deposit of around 4 - 5 Moz. Gold mineralization is associated with pyrite crystals when the latter are disseminated in the rock mass, whereas it is associated with hematite in quartz veins concordant with S1 shear deformation. It is mainly the pyrite crystals in the pressure shadows that contain the gold grains, whose development would be synchronous with micro-shear zone reactivation during the first phase of D1B deformation. The second phase of D2B deformation, which is a crenulation or fracture schistosity, does not significantly affect the shear deformation that controls mineralization.

Principles of Technology for Bottling Medicinal Mineral Waters of Sairme Using the Example of Source №3a

Sairme mineral water, one of the famous mineral waters in Georgia, is renowned for its exceptional healing properties. The distinctiveness and therapeutic benefits of the naturally sourced mineral water, known as “Sairme”, stem from its rich array of microelements, notably including iron and manganese. Since 1948, the bottling of Sairme mineral water has been a prominent activity. Named after the Sairme deposit, this mineral water is packaged in various formats to cater to diverse consumer preferences. The bottling process involves transporting the mineral water from wells to the bottling plant through pipelines. Prior to bottling, the mineral water undergoes meticulous processing stages in adherence to current Georgian and international regulations. This process ensures that the concentration of trace elements in the bottled water is minimized, maintaining its purity and quality. Given the importance of preserving the microelements present in bottled mineral water, our research is dedicated to optimizing the technological process. Our objective is to safeguard the valuable microelements while ensuring the highest standards of quality and safety in the final product.

In situ U-Pb dating and trace elements of magmatic rutile from Mujicun Cu-Mo deposit,North China Craton:Insights into porphyry mineralization

Porphyry Cu(Mo-Au)deposit is one of the most important types of copper deposit and usually formed under magmatic arc-related settings,whilst the Mujicun porphyry Cu-Mo deposit in North China Craton uncommonly generated within intra-continental settings.Although previous studies have focused on the age,origin and ore genesis of the Mujicun deposit,the ore-forming age,magma source and tectonic evolution remain controversial.Here,this study targeted rutile(TiO_(2))in the ore-hosting diorite porphyry from the Mujicun Cu-Mo deposit to conduct in situ U-Pb dating and trace element composition studies,with major views to determine the timing and magma evolution and to provide new insights into porphyry Cu-Mo metallogeny.Rutile trace element data show flat-like REE patterns characterized by relatively enrichment LREEs and depleted HREEs,which could be identified as magmatic rutile.Rutile U-Pb dating yields lower intercept ages of 139.3–138.4 Ma,interpreted as post magmatic cooling timing below about 500℃,which are consistent or slightly postdate with the published zircon U-Pb ages of diorite porphyry(144.1–141.7 Ma)and skarn(146.2 Ma;139.9 Ma)as well as the molybdenite Re-Os ages of molybdenum ores(144.8–140.0 Ma).Given that the overlap between the closure temperature of rutile U-Pb system and ore-forming temperature of the Mujicun deposit,this study suggests that the ore-forming ages of the Mujicun deposit can be constrained at 139.3–138.4 Ma,with temporal links to the late large-scale granitic magmatism at 138–126 Ma in the Taihang Orogen.Based on the Mg and Al contents in rutile,the magma of ore-hosting diorite porphyry was suggested to be derived from crust-mantle mixing components.In conjunction with previous studies in Taihang Orogen,this study proposes that the far-field effect and the rollback of the subducting Paleo-Pacific slab triggered lithospheric extension,asthenosphere upwelling,crust-mantle interaction and thermo-mechanical erosion,which jointly facilitated the formation of dioritic magmas during the Early Cretaceous.Subsequently,the dioritic magmas carrying crust-mantle mixing metallic materials were emplaced and precipitated at shallow positions along NNE-trending ore-controlling faults,eventually resulting in the formation of the Mujicun Cu-Mo deposit within an intracontinental extensional setting.

OSDA-free synthesis of FeZSM-22 zeolite from natural minerals for n-octane hydroisomerization

A seed-directed approach to synthesizing Fe ZSM-22 zeolite without organic structure directing agent(OSDA)was developed by using Fe-rich diatomite as all aluminum and iron sources.The Fe ZSM-22zeolite with optimal crystallinity and purity can be obtained by systematically adjusting feed composition and synthesis conditions.Characterizations show that Fe ZSM-22 zeolite synthesized with OSDA-free owns high crystallinity,obvious thin needle-shaped morphology and high Bronsted/Lewis acid ratio.Significantly,when used for n-octane hydroisomerization reaction,its derived catalyst exhibits the best catalytic performance reflected by the highest selectivity to C_(8)isomers compared to the two reference catalysts prepared based on a Fe-containing and a Fe-free ZSM-22 synthesized through an OSDA-directed route from natural diatomite and conventional chemicals,respectively.This work provides an alternative route to sustainably synthesizing heteroatomic zeolites with high performance.

Geology and mineralization of the Hongqiling large magmatic nickel-copper-cobalt deposit(22×10^(4)t)in Jilin Province,China:A review

The Hongqiling large nickel-copper-cobalt deposit(hereafter referred to as the Hongqiling deposit),a typical mafic-ultramafic copper-nickel deposit in China,boasts proven Ni(Ni)resources of approximately 22×10^(4)t,associated copper resources of 2×10^(4)t,and associated cobalt(Co)resources of 0.5×10^(4)t,with Ni reserves ranking 10th among China's magmatic nickel deposits.Geotectonically,the Hongqiling deposit is situated in the superimposed zone between the Xing'an-Mongolian orogenic belt and the circum-Western Pacific's active continental margin belt.Its ore-bearing plutons occur within the metamorphic rocks of the Ordovician Hulan Group,with the emplacement of plutons and the locations of orebodies governed by the deep-seated Huifahe fault and its secondary NW-trending Fujia-Hejiagou-Beixinglong-Changsheng fault zone.In the deposit,the rock assemblages of ore-bearing plutons predominantly encompass gabbro-pyroxenite-olivine pyroxenite-pyroxene peridotite(pluton No.1)and norite-orthopyroxenite-harzburgite(pluton No.7),with ore-bearing lithofacies consisting primarily of olivine pyroxenite and pyroxenite facies.The Hongqiling deposit hosts stratoid,overhanging lentoid,veined,and pure-sulfide veined orebodies.Its ores principally contain metallic minerals including pyrrhotite,pentlandite,chalcopyrite,violarite,and pyrite.Despite unidentified magma sources of ore-bearing mafic-ultramafic rocks,it is roughly accepted that the magmatic evolution in the Hongqiling deposit primarily involved fractional crystallization and crustal contamination.The ore-forming materials were primarily derived from the upper mantle,mixed with minor crustal materials.The ore-bearing mafic-ultramafic rocks in the deposit,primarily emplaced during the Indosinian(208-239 Ma),were formed in an intense extension setting followed by the collisional orogeny between the North China Plate and the Songnen-Zhangguangcai Range Block during the Middle-Late Triassic.From the perspective of the metallogenic geological setting,surrounding rocks,ore-controlling structures,and rock assemblages,this study identified one favorable condition and seven significant indicators for prospecting for Hongqiling-type nickel deposits and developed a prospecting model of the Hongqiling deposit.These serve as valuable references for exploring similar nickel deposits in the region,as well as the deep parts and margins of the Hongqiling deposit.

Systemic modulation of skeletal mineralization by magnesium implant promoting fracture healing: Radiological exploration enhanced with PCA-based machine learning in a rat femoral model

The clinical application of magnesium(Mg)and its alloys for bone fractures has been well supported by in vitro and in vivo trials.However,there were studies indicating negative effects of high dose Mg intake and sustained local release of Mg ions on bone metabolism or repair,which should not be ignored when developing Mg-based implants.Thus,it remains necessary to assess the biological effects of Mg implants in animal models relevant to clinical treatment modalities.The primary purpose of this study was to validate the beneficial effects of intramedullary Mg implants on the healing outcome of femoral fractures in a modified rat model.In addition,the mineralization parameters at multiple anatomical sites were evaluated,to investigate their association with healing outcome and potential clinical applications.Compared to the control group without Mg implantation,postoperative imaging at week 12 demonstrated better healing outcomes in the Mg group,with more stable unions in 3D analysis and high-mineralized bridging in 2D evaluation.The bone tissue mineral density(TMD)was higher in the Mg group at the non-operated femur and lumbar vertebra,while no differences between groups were identified regarding the bone tissue volume(TV),TMD and bone mineral content(BMC)in humerus.In the surgical femur,the Mg group presented higher TMD,but lower TV and BMC in the distal metaphyseal region,as well as reduced BMC at the osteotomy site.Principal component analysis(PCA)-based machine learning revealed that by selecting clinically relevant parameters,radiological markers could be constructed for differentiation of healing outcomes,with better performance than 2D scoring.The study provides insights and preclinical evidence for the rational investigation of bioactive materials,the identification of potential adverse effects,and the promotion of diagnostic capabilities for fracture healing.

Longitudinal investigation of mineral composition in human milk and its correlation with infant anthropometric outcomes among Tibetan mother-infant dyads during the first 6 months postpartum

Nutrients in human milk,including minerals,relate growth and development of breast-fed infants.Tibetan mother-infant dyads possess unique characteristics on early nutrition due to their featured long-lasting lifestyle.This study longitudinally investigated the relationship between the mineral composition in human milk and the Z-scores of infants among Tibetan mother-infant dyads during their first 6 months postpartum through a prospective cohort study.The results show that the minerals of Na,Mg,K,Ca,Cu,Zn,and Se were of higher levels in colostrum than other lactation stages.Several minerals were below the recommended values for infants according to Chinese dietary guidelines.Besides,a large proportion of infant Z-scores were below-2 as lactation period continued.Multivariate statistical analysis revealed that classifications and correlations in varying degrees were observed between minerals in human milk and infant Z-scores.These findings will be advantageous for research upon Chinese early nutrition and progress of tailor-made infant formula.