Based on non-isothermal experimental results for eight Chinese biomass species, a new kinetic model, named as the 損seudo bi-component separate-stage model (PBSM)? is developed in this note to describe the mass loss b...Based on non-isothermal experimental results for eight Chinese biomass species, a new kinetic model, named as the 損seudo bi-component separate-stage model (PBSM)? is developed in this note to describe the mass loss behavior of biomass thermal decomposition. This model gains an advantage over the commonly used 損seudo single-component overall model (PSOM)?and 損seudo multi-component overall model (PMOM)? By means of integral analysis it is indicated that the new model is suitable to describe the mass loss kinetics of wood and leaf samples under relatively low heating rates (e.g. 10℃/min, used in this work).展开更多
Through this study, the humus produced in the breeding place of Universidad Autonoma de Occidente was thermally characterized. The humus was submitted to a heating program controlled by the Differential Scanning Calor...Through this study, the humus produced in the breeding place of Universidad Autonoma de Occidente was thermally characterized. The humus was submitted to a heating program controlled by the Differential Scanning Calorimetry (DSC) technique to characterize the type of transition, Thermogravimetry (TGA) to study the equilibrium of phasesand Mass Spectrometry (MS) coupled to TGA to identify detached elements in a temperature range. The temperature range used in this study was 30℃ ℃. The energy required for the water desorption in the humus has been found in this study. The humus showed a quick desorption between 30℃ ≤ TDesorption ≤ 110℃ at a heating rate of 10℃/min and presented decomposition around 250℃. Moreover, the kinetics of the desorption of the humus was studied to obtain the activation energy three TGA measures for three different heating rates. The average activation energy was about 26 kJ/Mol. This result was carried out to obtain an estimation of the desorption time of water in the range from room temperature to the decomposition temperature around 350℃.展开更多
基金This work was supported by the National Natural Science Foundation of China (Grant Nos. 59876039 59936140) the National Key Basic ResearchProgramm of China the China-Greece Joint Project 揑nvestigation on the Characteristics of Forest Fire in the Ear
文摘Based on non-isothermal experimental results for eight Chinese biomass species, a new kinetic model, named as the 損seudo bi-component separate-stage model (PBSM)? is developed in this note to describe the mass loss behavior of biomass thermal decomposition. This model gains an advantage over the commonly used 損seudo single-component overall model (PSOM)?and 損seudo multi-component overall model (PMOM)? By means of integral analysis it is indicated that the new model is suitable to describe the mass loss kinetics of wood and leaf samples under relatively low heating rates (e.g. 10℃/min, used in this work).
文摘Through this study, the humus produced in the breeding place of Universidad Autonoma de Occidente was thermally characterized. The humus was submitted to a heating program controlled by the Differential Scanning Calorimetry (DSC) technique to characterize the type of transition, Thermogravimetry (TGA) to study the equilibrium of phasesand Mass Spectrometry (MS) coupled to TGA to identify detached elements in a temperature range. The temperature range used in this study was 30℃ ℃. The energy required for the water desorption in the humus has been found in this study. The humus showed a quick desorption between 30℃ ≤ TDesorption ≤ 110℃ at a heating rate of 10℃/min and presented decomposition around 250℃. Moreover, the kinetics of the desorption of the humus was studied to obtain the activation energy three TGA measures for three different heating rates. The average activation energy was about 26 kJ/Mol. This result was carried out to obtain an estimation of the desorption time of water in the range from room temperature to the decomposition temperature around 350℃.