Six aromatic polyesters were prepared for gas separation membranes, and their permeation properties for hydrogen, oxygen, nitrogen, carbon dioxide, and methane were measured at 30 degrees C and 1 atmosphere by low pre...Six aromatic polyesters were prepared for gas separation membranes, and their permeation properties for hydrogen, oxygen, nitrogen, carbon dioxide, and methane were measured at 30 degrees C and 1 atmosphere by low pressure manometric method. The correlation between the gas transport behavior and molecular structure of aromatic polyester membrane is discussed. These data are interpreted qualitatively in terms of the calculated packing density, gas-polymer interaction, concentration of aryl bromine on backbone, and effect of silane group on main chain of polymer.展开更多
A novel mixed matrix nanofiltration membrane was constructed by coating a casting solution containing polyvinylidene fluoride(PVDF),polyethylene glycol(PEG)as hydrophilic agent,zeolitic like framework-67(ZIF-67),ethyl...A novel mixed matrix nanofiltration membrane was constructed by coating a casting solution containing polyvinylidene fluoride(PVDF),polyethylene glycol(PEG)as hydrophilic agent,zeolitic like framework-67(ZIF-67),ethylenediamine as cross-linking agent on Ag-nanoparticle-decorated polyester textile(PT)support(PT/AgNPs/PVDF-PEG/ZIF-67).PT/Ag-NPs/PVDF-PEG/ZIF-67 morphology,crystalline structure,surface chemical composition and hydrophilicity of PT/Ag-NPs/PVDF-PEG/ZIF-67 were fully characterized by field emission scanning electron microscopy(FE-SEM),X-ray diffraction(XRD),Fourier transform infrared spectroscopy(FT-IR)and water contact angle technique,respectively.PT/Ag-NPs/PVDF-PEG/ZIF-67 was applied in cross module set-up for removal of contaminated water containing rose bengal(RB)dye.The effect of operational parameters such as dye concentration,solution pH and flow rate on performance of PT/Ag-NPs/PVDF-PEG/ZIF-67 were investigated and optimized by central composite design(CCD).Casting solution containing 0.5 wt.%ZIF-67 as optimum value showed the good wettability,high pure water flux(PWF;35.8 L·m-2·h-1),flux recovery ratio(FRR;90%),dye removal efficiency(96.41%).The selectivity factor of 12.72 and 14.42 was found to be for RB in the presence of amido black and methylene blue as interferent dyes,respectively,which showed a good selective recognition ability for RB dye.展开更多
An easy hydrolysis degradable polyester (EHDP) is synthesized; the fiber produced from which can be hydrolyzed by dilute basic solution easily. The properties of these kind polyesters are measured. The results show th...An easy hydrolysis degradable polyester (EHDP) is synthesized; the fiber produced from which can be hydrolyzed by dilute basic solution easily. The properties of these kind polyesters are measured. The results show that this kind polymer is suitable to be spun into filament The EHDP can be spun into staple fiber and manufactured into non-woven fabric. This fabric is used as disposable clothes. In composite spinning, the PET (polyethylen glycol terephthalate) or PA (polyamide) is used as continuous phase, and EHDP used as dispersed phase. Then the fabric of this kind fiber is treated by basic solution; the ultra-fine fiber fabric is obtained.The fineness of the fiber is about 0.045 dtex. In blend spinning, EHDP is mixed with polypropylene (PP) to produce hollow fiber with micro-holes in radical direction. This fiber is a usable material in filter especially in medical use.展开更多
Using the hydrogen-bonding interaction between graphene oxide（GO） and sulfonated polyethersulfone （SPES）, we constructed the multilayer structure of GO and SPES on the polyester tiber mats via layer-by-layer self-...Using the hydrogen-bonding interaction between graphene oxide（GO） and sulfonated polyethersulfone （SPES）, we constructed the multilayer structure of GO and SPES on the polyester tiber mats via layer-by-layer self-assembly. In each self-assembled layer, sulfonic acid groups are arranged along the a^s of fiber, which provides the long-range proton transmission channels, promoting the rapidly proton conduction. The performances of the composite membranes based on SPES and multilayer assembled polyester fiber mats were studied. The results show that the proton conductivity of composite membranes increases with the increasing assembly layers. At the same time, the mechanical properties and methanol-resistance of the composite membranes were obviously improved.展开更多
文摘Six aromatic polyesters were prepared for gas separation membranes, and their permeation properties for hydrogen, oxygen, nitrogen, carbon dioxide, and methane were measured at 30 degrees C and 1 atmosphere by low pressure manometric method. The correlation between the gas transport behavior and molecular structure of aromatic polyester membrane is discussed. These data are interpreted qualitatively in terms of the calculated packing density, gas-polymer interaction, concentration of aryl bromine on backbone, and effect of silane group on main chain of polymer.
文摘A novel mixed matrix nanofiltration membrane was constructed by coating a casting solution containing polyvinylidene fluoride(PVDF),polyethylene glycol(PEG)as hydrophilic agent,zeolitic like framework-67(ZIF-67),ethylenediamine as cross-linking agent on Ag-nanoparticle-decorated polyester textile(PT)support(PT/AgNPs/PVDF-PEG/ZIF-67).PT/Ag-NPs/PVDF-PEG/ZIF-67 morphology,crystalline structure,surface chemical composition and hydrophilicity of PT/Ag-NPs/PVDF-PEG/ZIF-67 were fully characterized by field emission scanning electron microscopy(FE-SEM),X-ray diffraction(XRD),Fourier transform infrared spectroscopy(FT-IR)and water contact angle technique,respectively.PT/Ag-NPs/PVDF-PEG/ZIF-67 was applied in cross module set-up for removal of contaminated water containing rose bengal(RB)dye.The effect of operational parameters such as dye concentration,solution pH and flow rate on performance of PT/Ag-NPs/PVDF-PEG/ZIF-67 were investigated and optimized by central composite design(CCD).Casting solution containing 0.5 wt.%ZIF-67 as optimum value showed the good wettability,high pure water flux(PWF;35.8 L·m-2·h-1),flux recovery ratio(FRR;90%),dye removal efficiency(96.41%).The selectivity factor of 12.72 and 14.42 was found to be for RB in the presence of amido black and methylene blue as interferent dyes,respectively,which showed a good selective recognition ability for RB dye.
文摘An easy hydrolysis degradable polyester (EHDP) is synthesized; the fiber produced from which can be hydrolyzed by dilute basic solution easily. The properties of these kind polyesters are measured. The results show that this kind polymer is suitable to be spun into filament The EHDP can be spun into staple fiber and manufactured into non-woven fabric. This fabric is used as disposable clothes. In composite spinning, the PET (polyethylen glycol terephthalate) or PA (polyamide) is used as continuous phase, and EHDP used as dispersed phase. Then the fabric of this kind fiber is treated by basic solution; the ultra-fine fiber fabric is obtained.The fineness of the fiber is about 0.045 dtex. In blend spinning, EHDP is mixed with polypropylene (PP) to produce hollow fiber with micro-holes in radical direction. This fiber is a usable material in filter especially in medical use.
基金Supported by the National Natural Science Foundation of China（No.21574017）.
文摘Using the hydrogen-bonding interaction between graphene oxide（GO） and sulfonated polyethersulfone （SPES）, we constructed the multilayer structure of GO and SPES on the polyester tiber mats via layer-by-layer self-assembly. In each self-assembled layer, sulfonic acid groups are arranged along the a^s of fiber, which provides the long-range proton transmission channels, promoting the rapidly proton conduction. The performances of the composite membranes based on SPES and multilayer assembled polyester fiber mats were studied. The results show that the proton conductivity of composite membranes increases with the increasing assembly layers. At the same time, the mechanical properties and methanol-resistance of the composite membranes were obviously improved.
