It is indicated from a study of transport of rare earth ions through the emulsion liquid mem- brane of bis(2,4,4-trimethylpentyl)phosphinic acid-Span 80-toluene that transporting rare earth ions com- pletely and rapid...It is indicated from a study of transport of rare earth ions through the emulsion liquid mem- brane of bis(2,4,4-trimethylpentyl)phosphinic acid-Span 80-toluene that transporting rare earth ions com- pletely and rapidly was realized under the optimum experimental conditions:1.0×10^(-3)～3.0×10^(-3)mol/L bis(2,4,4-trimethylpentyl)phosphinic acid and 2%～4%(W/V)Span 80 in toluene solution as membrane phase,0.50～2.0 mol/L HCl as inner phase,rare earth ion solutions with pH 3.5～5.0 as outer phase.Ac- cording to the differences of transport behavior for rare earth ions,it is possible to separate rare earth ions from mixed solutions of rare earth ions by this liquid membrane system.展开更多
Solvent extraction of trivalent lanthanides (except for Pm with Cyanex 302 [Bis (2,4,4-trimethylpentyl)monothiophosphinic acid] in heptane was studied at various aqueous pH values, extractant concentrations and differ...Solvent extraction of trivalent lanthanides (except for Pm with Cyanex 302 [Bis (2,4,4-trimethylpentyl)monothiophosphinic acid] in heptane was studied at various aqueous pH values, extractant concentrations and different temperatures. Cyanex 302 shows pretty good behaviours on the extraction of lanthanides, especially when extracting heavy lanthanides. However,purified Cyanex 302 exhibits signi ficantly lower extractability to lanthanides than raw extractant. The roles ofdifferent components ofraw Cyanex 302 were discussed to understand the reason of good extractability of the raw extractant. The lanthanides extraction stoichiometry is discussed on the basis ofexperimental results, which can be expressed as follows:展开更多
基金Supported by the National Natural Science Foundation of China
文摘It is indicated from a study of transport of rare earth ions through the emulsion liquid mem- brane of bis(2,4,4-trimethylpentyl)phosphinic acid-Span 80-toluene that transporting rare earth ions com- pletely and rapidly was realized under the optimum experimental conditions:1.0×10^(-3)～3.0×10^(-3)mol/L bis(2,4,4-trimethylpentyl)phosphinic acid and 2%～4%(W/V)Span 80 in toluene solution as membrane phase,0.50～2.0 mol/L HCl as inner phase,rare earth ion solutions with pH 3.5～5.0 as outer phase.Ac- cording to the differences of transport behavior for rare earth ions,it is possible to separate rare earth ions from mixed solutions of rare earth ions by this liquid membrane system.
文摘Solvent extraction of trivalent lanthanides (except for Pm with Cyanex 302 [Bis (2,4,4-trimethylpentyl)monothiophosphinic acid] in heptane was studied at various aqueous pH values, extractant concentrations and different temperatures. Cyanex 302 shows pretty good behaviours on the extraction of lanthanides, especially when extracting heavy lanthanides. However,purified Cyanex 302 exhibits signi ficantly lower extractability to lanthanides than raw extractant. The roles ofdifferent components ofraw Cyanex 302 were discussed to understand the reason of good extractability of the raw extractant. The lanthanides extraction stoichiometry is discussed on the basis ofexperimental results, which can be expressed as follows:
