The perovskite type of compound [n-C_(11)H_(23)N_3]_2ZnCl_4(abr.C_(11)Zn)exhibits two solid-solid phase transitions at T_(c1)=298.7 K and T_(c2)=360.1 K.A temperature dependence study of Raman spectra of C_(11)Zn prov...The perovskite type of compound [n-C_(11)H_(23)N_3]_2ZnCl_4(abr.C_(11)Zn)exhibits two solid-solid phase transitions at T_(c1)=298.7 K and T_(c2)=360.1 K.A temperature dependence study of Raman spectra of C_(11)Zn provides the evidence of occurence of the structural phase transition related to the dynamics of the alkylammonium ions.The room temperature phase is ordered and contains the all-trans alkyl chains.The intermediate temperature phase presents a partial conformational disorder and liquidlike state of all conformational disorder occurs at high-temperature phase.展开更多
文摘The perovskite type of compound [n-C_(11)H_(23)N_3]_2ZnCl_4(abr.C_(11)Zn)exhibits two solid-solid phase transitions at T_(c1)=298.7 K and T_(c2)=360.1 K.A temperature dependence study of Raman spectra of C_(11)Zn provides the evidence of occurence of the structural phase transition related to the dynamics of the alkylammonium ions.The room temperature phase is ordered and contains the all-trans alkyl chains.The intermediate temperature phase presents a partial conformational disorder and liquidlike state of all conformational disorder occurs at high-temperature phase.
