The catalyst boron trifluoride etherate was used to catalyze the reaction of epoxy resin with polyethylene glycol (PEG), and the effect of the concentration of the catalyst on the reaction is studied. It is shown that...The catalyst boron trifluoride etherate was used to catalyze the reaction of epoxy resin with polyethylene glycol (PEG), and the effect of the concentration of the catalyst on the reaction is studied. It is shown that there exist two competitive reactions : I, self polymerization of epoxy resin via chain growth and II, copolymerization of epoxy resin with PEG via step growth. At high concentration of the catalyst reaction I dominates and reaction II is negligible. On the contrary, at low concentration of the catalyst, reaction II dominates and block copolymers are formed In the intermediate case, the two reactions are comparable with the result that a gel structure is obtained.展开更多
The reaction kinetics of bisphenol-S epoxy resin with methyl-acrylic acid in the presence of quaternary ammonium salt catalyst was studied. The reaction rate constants at different temperatures were determined. The re...The reaction kinetics of bisphenol-S epoxy resin with methyl-acrylic acid in the presence of quaternary ammonium salt catalyst was studied. The reaction rate constants at different temperatures were determined. The reaction is first order with respect to epoxy group, zero order with respect to methylacrylic acid and 0.71 order with respect to quaternary ammonium salt catalyst, respectively. The mechanism of this reaction was discussed.展开更多
Waterborne ultrafine particles of epoxy resin were prepared by phase inversion technique. The results of SEM revealed that the particles diameter was in the range of 50 to 100 nm and the effects on amount of water req...Waterborne ultrafine particles of epoxy resin were prepared by phase inversion technique. The results of SEM revealed that the particles diameter was in the range of 50 to 100 nm and the effects on amount of water required at phase inversion point were also discussed.展开更多
For the concentrated dispersions of epoxy resin prepared by phase inversion emulsification technique, the effects of solid content and temperature on the rheological behavior are studied. It is found that there exists...For the concentrated dispersions of epoxy resin prepared by phase inversion emulsification technique, the effects of solid content and temperature on the rheological behavior are studied. It is found that there exists reversible structural transition in concentrated dispersions subjected to shearing. The viscosity oscillation correlated with high viscoelasticity at lower stress is remarkable in highly concentrated dispersions. There exists storage modules overshot at higher stress during the dynamic stress time ramp test. This could provide some information on dynamics of structure changes during shear action. Besides, the effects of solid content and temperature on the relationship between tangent delta and frequency are essentially different.展开更多
文摘The catalyst boron trifluoride etherate was used to catalyze the reaction of epoxy resin with polyethylene glycol (PEG), and the effect of the concentration of the catalyst on the reaction is studied. It is shown that there exist two competitive reactions : I, self polymerization of epoxy resin via chain growth and II, copolymerization of epoxy resin with PEG via step growth. At high concentration of the catalyst reaction I dominates and reaction II is negligible. On the contrary, at low concentration of the catalyst, reaction II dominates and block copolymers are formed In the intermediate case, the two reactions are comparable with the result that a gel structure is obtained.
文摘The reaction kinetics of bisphenol-S epoxy resin with methyl-acrylic acid in the presence of quaternary ammonium salt catalyst was studied. The reaction rate constants at different temperatures were determined. The reaction is first order with respect to epoxy group, zero order with respect to methylacrylic acid and 0.71 order with respect to quaternary ammonium salt catalyst, respectively. The mechanism of this reaction was discussed.
基金This project is supported by the Scientific Fund of Polymer Physics Laboratory,Institute of Chemistry,Chinese Academy of Sciences.
文摘Waterborne ultrafine particles of epoxy resin were prepared by phase inversion technique. The results of SEM revealed that the particles diameter was in the range of 50 to 100 nm and the effects on amount of water required at phase inversion point were also discussed.
文摘For the concentrated dispersions of epoxy resin prepared by phase inversion emulsification technique, the effects of solid content and temperature on the rheological behavior are studied. It is found that there exists reversible structural transition in concentrated dispersions subjected to shearing. The viscosity oscillation correlated with high viscoelasticity at lower stress is remarkable in highly concentrated dispersions. There exists storage modules overshot at higher stress during the dynamic stress time ramp test. This could provide some information on dynamics of structure changes during shear action. Besides, the effects of solid content and temperature on the relationship between tangent delta and frequency are essentially different.
