Concrete is the most widely used construction material in the world. The situation in the country is not an exception as most of the infrastructures in Kenya such as buildings, bridges, concrete drainage among others,...Concrete is the most widely used construction material in the world. The situation in the country is not an exception as most of the infrastructures in Kenya such as buildings, bridges, concrete drainage among others, are constructed using concrete. Sadly, the failure of buildings and other concrete structures is very common in Kenya. Blended Portland cement type 32.5 N/mm<sup>2</sup> is the most widely used concrete binder material and is found in all parts of the country. Despite blended cement CEM 32.5 being the most commonly used cement type in construction industry in Kenya and most developing countries as a result of its low price and availability locally, its strength gain has been proven to be lower compared to when other types of cement are used due to quantity of pozzolanic material added to the blend. This paper outlines findings of an experimental investigation on the use of cypress tree extract as an accelerator to enhance rate of gain of strength on Kenyan blended cements. Six different blended cement brands locally available were used during the study. Cement chemical analysis was done using X-ray diffraction method while for the cypress extract, Atomic Absorption Spectrometer machine was used. Physical and mechanical properties were checked based on the British standards. The generation of the concrete mix design was done using the British DOE method and concrete was tested for the compressive strength at 7, 14, 21, 28, 56 and 90 days. It was observed that 15% dosage of the extract expressed as a mass percentage of the cement content gives the most improved compressive strength of concrete, 10.4% at 7 days and 9.5% at 28 days hence the optimum. It was further noted that when Cypress tree extract is used as an accelerator in the mix, the blended cement concrete achieves the design strength at 27 days saving 10 days of the project duration compared to when no accelerator is used while the ultimate strength is achieved at 67 days. The study therefore recommends the use of the cypress tree bark extract at a dosage of 15%, by mass, of the cement content as an accelerator when the structure is to be loaded at 28 days and waiting up to 39 days before loading the structure if no accelerator is used for blended cement concrete.展开更多
The effects of activated coal gangue on compressive strength, porosity and pore size distribution of hardened cement pastes were investigated. Activated coal gangue with two different kaolin contents, one higher and o...The effects of activated coal gangue on compressive strength, porosity and pore size distribution of hardened cement pastes were investigated. Activated coal gangue with two different kaolin contents, one higher and one lower, were used to partially replace Portland cement at 0%, 10%, and 30% by weight. The water to binder ratio(w/b) of 0.5 was used for all the blended cement paste mixes. Experimental results indicate that the blended cement of activated coal gangue mortar with higher kaolin mineral content has a higher compressive strength than that with lower kaolin mineral content. The porosity and pore size of blended cement mortar were significantly affected by the replacement of activated coal gangue.展开更多
Blended cement containing blast furnace slag (BFS) and phosphorous slag( PS) is a new kind of cement. The total content of blended materials could increase if two additives were used. Using the same admixtures , the p...Blended cement containing blast furnace slag (BFS) and phosphorous slag( PS) is a new kind of cement. The total content of blended materials could increase if two additives were used. Using the same admixtures , the properties of the blended cement with 70% additives could reach the standard of 525-grade slag cement according to GB. The strength of cement with 80% additives could reach the standard of 425-grade slag cement. The tests of strength, pore structure, hydration products, inhibiting alkali-aggregate reaction, resistance to sulfate corrosion of BFS-PSC were performed.展开更多
The hydration process,hydration product and hydration heat of blended cement paste mixed with mineral admixture and expansive agent at low W/B ratio are studied by XRD,thermo analysis,and calorimetry instrument,and th...The hydration process,hydration product and hydration heat of blended cement paste mixed with mineral admixture and expansive agent at low W/B ratio are studied by XRD,thermo analysis,and calorimetry instrument,and they were compared with those of pure cement paste.The results show that pure cement and blended cement at low W/B ratio have the same types of hydration products,but their respective amounts of hydration products of various blended cements at same ages and the variation law of the amount of same hydration products with ages are different;The joint effect of tumefaction of gel-ettringite due to water absorption and the expansive pressure on the pore and rift caused by the crystalloid ettringite is the impetus of the volume expansion of cement paste,and the former effect is much greater than the latter one.展开更多
The hydrothermal reactivity of silica sand was studied using cement kiln dust (CKD) as an activator in addition to the Portland cement fraction of El-Karnak cement (a blend of ordinary Portland cement and ground sand)...The hydrothermal reactivity of silica sand was studied using cement kiln dust (CKD) as an activator in addition to the Portland cement fraction of El-Karnak cement (a blend of ordinary Portland cement and ground sand). Autoclaved EI-Karnak cement pastes were studied at pressures of 0.507, 1.013 and 1.520 MPa of saturated steam with respect to their compressive strength, kinetics of hydrothermal reaction and the phase composition of the formed hydrates. The role of CKD in affecting the physicochemical and mechanical properties of EI-Karnak cement pastes was studied by autoclaving of several pastes containing 5, 7.5, 10 and 20% CKD at a pressure of 1.013 MPa of saturated steam. CKD was added either as a raw CKD (unwashed) or after washing with water (washed CKD). The results of these physicochemical studies obtained could be related as much as possible to the role of CKD (raw or washed) in affecting the hydrothermal reactivity of silica sand in EI-Karnak cement pastes.展开更多
An amended method for accurate measuring the quantity of calcium silicate hydrate(C-S-H) in pure cement paste and blended cement paste by water adsorption was made, which based on R.A.Olson’s method. Two improvements...An amended method for accurate measuring the quantity of calcium silicate hydrate(C-S-H) in pure cement paste and blended cement paste by water adsorption was made, which based on R.A.Olson’s method. Two improvements to this method, such as using C-S-H gel by hydro-thermal synthesis as standard sample and the stoichiometry of C-S-H gel is partitioned based on hydration time and the amount of mineral admixture. The result of C-S-H gel content in pure cement paste and blended cement paste is higher than by R.A.Olson’s method.展开更多
The amount of inert quartz tailing used in concrete construction is limited due to the low strength development of cementitious materials that may be caused by the quartz tailing. We manage to increase the strength of...The amount of inert quartz tailing used in concrete construction is limited due to the low strength development of cementitious materials that may be caused by the quartz tailing. We manage to increase the strength of blended cement by modifying quartz tailing through solid-phase reaction of quartz tailing with carbide slag at high temperature. The mineral composition and morphology of the modified quartz tailing were examined by X-ray diffraction(XRD) and scanning electron microscopy(SEM). The mechanical properties and microstructure of blended cement mortars containing modified quartz tailing were investigated. Results showed that the strengths of blended cement mortars containing modified quartz tailing were close to those of the corresponding blended cement mortars containing quartz tailing at early age of 3 d, but increased significantly to be similar to that of plain Portland cement mortars at late ages of 90 d. This is attributed to the microstructure densification and the enhancement of interface between quartz tailing and cement paste due to the hydration of b-C_2 S surface layer on modified quartz tailing.展开更多
Extensive growth in the developing countries due to infrastructure development is resulting into massive consumption of concrete thereby increasing the demand on concrete materials. Quite large amounts of fine aggrega...Extensive growth in the developing countries due to infrastructure development is resulting into massive consumption of concrete thereby increasing the demand on concrete materials. Quite large amounts of fine aggregates are required for concrete in developing countries thus shortages of quality river sand is putting pressure on availability of fine aggregates. To fulfill the high demand of fine aggregates, a search for alternative materials is in process. Stone crushing and processing industry is a large industry which generates large amounts of stone dust and slurry which is a waste produced from this process. Tons of such waste generated has no useful purpose except as landfill material. Some preliminary studies have been conducted into use of marble/ limestone waste for use in concrete [1] [2].?This study aims at using stone dust as partial replacement of sand in concrete to observe its effects on workability and other mechanical properties. This would result in useful consumption of this waste product thereby eliminating environmental issues related to its disposal. Partial replacement of 10% and 20% sand replacement with stone dust is carried out with the use of self-compacting concrete with blended cement. Blended cement used contains 50% rice husk ash and 50% Portland cement. Such high strength SCC with blended cement containing 50% rice husk ash and 50% Portland cement has already been tested to provide better quality concrete [3]. Wide ranging investigations covering most aspects of mechanical behavior and permeability were carried out for various mixes for compressive strengths of 60?MPa & 80?MPa. Compressive strengths of high strength SCC with blended cements and 10% and 20% replacement of sand with stone dust for 60?MPa and 80?MPa were observed to be higher by about 10% to 13% than the control specimen. Higher elastic moduli and reduced permeability were observed along with better sulphate and acid resistance. Better strengths and improved durability of such high strength SCC make it a more acceptable material for major construction projects thereby reducing the burden on environment and use of such waste product for a useful purpose promoting sustainable construction.展开更多
Self-Compacting concrete is a concrete that is able to flow and consolidate under its own weight, completely fill the formwork even in the presence of dense reinforcement, whilst maintaining homogeneity and without th...Self-Compacting concrete is a concrete that is able to flow and consolidate under its own weight, completely fill the formwork even in the presence of dense reinforcement, whilst maintaining homogeneity and without the need for any additional compaction. Self-Compacting concrete is achieved by using high proportions of powder content and super?plasticizers. Due to this, pronounced thermal cracking is anticipated. Thermal cracking in concrete structures is of great concern. The objective of this research is to carry out experiments and investigate fresh and hardened properties of SCC developed using a blend of ordinary Portland cement and ground granulated blast furnace slag (GGBFS), to evaluate the applicability of Japan Concrete Institute (JCI) model?equations and?to find out any similarities and differences between Self-?Compacting concrete and normal vibrated concrete—Portland blast furnace slag concrete class B. Thermal stress analysis of the proposed Self-Compacting concrete and normal vibrated concretes were investigated by simulation using 3D FEM analysis. To carry out these objectives, concrete properties such as autogenous shrinkage, adiabatic temperature rise, drying shrinkage, modulus of elasticity, splitting tensile strength and compressive strength were determined through experiments. From experimental results, it was observed that except for the fresh properties, the hardened properties of Self-Compacting exhibit similar characteristics to those of normal vibrated concrete at almost similar water to binder ratios. It was also established that Self-Compacting concrete at W/B of 32% with a 50% replacement of ground granulated blast furnace slag has better thermal cracking resistance than SCC with 30% GGBFS replacement. It is also found that provided the relevant constants are derived from experimental data, JCI model equations can be applied successfully to evaluate hardened properties of Self-Compacting concrete.展开更多
This paper deals with the effect of blended cement and natural latex copolymer to static and dynamic properties of polymer modified concrete. The polymer was used copolymer of natural latex methacrylate (KOLAM) and co...This paper deals with the effect of blended cement and natural latex copolymer to static and dynamic properties of polymer modified concrete. The polymer was used copolymer of natural latex methacrylate (KOLAM) and copolymer of natural latex styrene (KOLAS) with composition of 1%, 5%, and 10% w/w of weight of blended cement in concrete mixture. They are tested for compressive strength, flexural strength, splitting tensile strength, and modulus elasticity for static analysis, and impact load and energy dissipation profile for dynamic analysis. The result shows that KOLAM with concentration 1% give better performance in static and dynamic properties. The KOLAM 1% gives improvement in flexural strength, splitting tensile strength and modulus elasticity about 4%, 13% and 3% compared to normal concrete. And for dynamic properties, KOLAM 1% could reduce impact load up to 35% and improve energy dissipation capacity about 45% compared to normal concrete. The concentration of KOLAM higher than 1% resulting negative effect to static and dynamic properties, except modulus of elasticity. For KOLAS, there were no positive trends of static and dynamic properties.展开更多
A novel methodology for the formulation design of the multi-component cement additive for the low early strength blend cement was presented by using engineering statistics.Components of cement additive such as trietha...A novel methodology for the formulation design of the multi-component cement additive for the low early strength blend cement was presented by using engineering statistics.Components of cement additive such as triethanolamine,chloride,saccharide and a kind of divalent alcohol were simultaneously tested according to the arrangement of response surface methodology.Mathematical models were established to express the quantitative relationship between the chemical components of cement additive and the compressive strength of treated blend cement.The effectiveness and the possible interactions of these four chemicals contributing to the strength development of blend cement were further explored by the pareto chart and the contour plot.Finally according the performance analysis of four chemicals,the optimized formulations were brought forward and were validated in practical trials by Turkey's multiple comparison.展开更多
Composite cement samples were prepared by mixing clinker, gypsum with burnt coal gangues which was calcined at various temperatures. The mechanical strength and Ca(OH)2 content in the cement paste were tested, and t...Composite cement samples were prepared by mixing clinker, gypsum with burnt coal gangues which was calcined at various temperatures. The mechanical strength and Ca(OH)2 content in the cement paste were tested, and the paste composition and microstructure were analyzed by thermogravimetry-differential thermal analysis (TG-DSC), X-ray diffraction(XRD), scanning electronic microscopy (SEM) and pore structure analysis. Results demonstrate that the thermal activated coal gangue could accelerate the early hydration of cement clinker obviously, which promotes the gangue hydration itself. The early hydrated products of the cement are C-S-H gel, Ca(OH)2 and AFt. The cement with 30% (in mass) the gangue exhibits higher mechanical strength, and among all the cement samples the one with the gangue burnt at 700 ℃ displays the highest hydration rate, mechanical strength, the most gel pores and the lowest total porosity.展开更多
A new kind of mortar made of ground granulated blast-furnace slag (GGBFS), gypsum, clinker and steel slag sand (〈4.75 mm) was developed. The ratio of steel slag sand to GGBFS was 1 : 1 and the amount of gypsum w...A new kind of mortar made of ground granulated blast-furnace slag (GGBFS), gypsum, clinker and steel slag sand (〈4.75 mm) was developed. The ratio of steel slag sand to GGBFS was 1 : 1 and the amount of gypsum was 4% by weight while the dosage of clinker ranged from 0% to 24%. The optimization formulation of such mortar was studied. The content of steel slag sand should be less than 50% according to the volume stability of blended mortar, and the dosage of clinker is about 10% based on the strength development. Besides strength, the hydration heat, pore structure and micro pattern of blended mortar were also determined. The experimental results show the application of steel slag sand may reduce the dosage of cement clinker and increase the content of industrial waste product such as GGBFS, and the clinker is also a better admixture for blended mortar using steel slag sand.展开更多
文摘Concrete is the most widely used construction material in the world. The situation in the country is not an exception as most of the infrastructures in Kenya such as buildings, bridges, concrete drainage among others, are constructed using concrete. Sadly, the failure of buildings and other concrete structures is very common in Kenya. Blended Portland cement type 32.5 N/mm<sup>2</sup> is the most widely used concrete binder material and is found in all parts of the country. Despite blended cement CEM 32.5 being the most commonly used cement type in construction industry in Kenya and most developing countries as a result of its low price and availability locally, its strength gain has been proven to be lower compared to when other types of cement are used due to quantity of pozzolanic material added to the blend. This paper outlines findings of an experimental investigation on the use of cypress tree extract as an accelerator to enhance rate of gain of strength on Kenyan blended cements. Six different blended cement brands locally available were used during the study. Cement chemical analysis was done using X-ray diffraction method while for the cypress extract, Atomic Absorption Spectrometer machine was used. Physical and mechanical properties were checked based on the British standards. The generation of the concrete mix design was done using the British DOE method and concrete was tested for the compressive strength at 7, 14, 21, 28, 56 and 90 days. It was observed that 15% dosage of the extract expressed as a mass percentage of the cement content gives the most improved compressive strength of concrete, 10.4% at 7 days and 9.5% at 28 days hence the optimum. It was further noted that when Cypress tree extract is used as an accelerator in the mix, the blended cement concrete achieves the design strength at 27 days saving 10 days of the project duration compared to when no accelerator is used while the ultimate strength is achieved at 67 days. The study therefore recommends the use of the cypress tree bark extract at a dosage of 15%, by mass, of the cement content as an accelerator when the structure is to be loaded at 28 days and waiting up to 39 days before loading the structure if no accelerator is used for blended cement concrete.
基金the National Basic Research Program of China(No.2001CB610703)the Basic Research of Preparation and Application of High Performance Cement
文摘The effects of activated coal gangue on compressive strength, porosity and pore size distribution of hardened cement pastes were investigated. Activated coal gangue with two different kaolin contents, one higher and one lower, were used to partially replace Portland cement at 0%, 10%, and 30% by weight. The water to binder ratio(w/b) of 0.5 was used for all the blended cement paste mixes. Experimental results indicate that the blended cement of activated coal gangue mortar with higher kaolin mineral content has a higher compressive strength than that with lower kaolin mineral content. The porosity and pore size of blended cement mortar were significantly affected by the replacement of activated coal gangue.
文摘Blended cement containing blast furnace slag (BFS) and phosphorous slag( PS) is a new kind of cement. The total content of blended materials could increase if two additives were used. Using the same admixtures , the properties of the blended cement with 70% additives could reach the standard of 525-grade slag cement according to GB. The strength of cement with 80% additives could reach the standard of 425-grade slag cement. The tests of strength, pore structure, hydration products, inhibiting alkali-aggregate reaction, resistance to sulfate corrosion of BFS-PSC were performed.
文摘The hydration process,hydration product and hydration heat of blended cement paste mixed with mineral admixture and expansive agent at low W/B ratio are studied by XRD,thermo analysis,and calorimetry instrument,and they were compared with those of pure cement paste.The results show that pure cement and blended cement at low W/B ratio have the same types of hydration products,but their respective amounts of hydration products of various blended cements at same ages and the variation law of the amount of same hydration products with ages are different;The joint effect of tumefaction of gel-ettringite due to water absorption and the expansive pressure on the pore and rift caused by the crystalloid ettringite is the impetus of the volume expansion of cement paste,and the former effect is much greater than the latter one.
文摘The hydrothermal reactivity of silica sand was studied using cement kiln dust (CKD) as an activator in addition to the Portland cement fraction of El-Karnak cement (a blend of ordinary Portland cement and ground sand). Autoclaved EI-Karnak cement pastes were studied at pressures of 0.507, 1.013 and 1.520 MPa of saturated steam with respect to their compressive strength, kinetics of hydrothermal reaction and the phase composition of the formed hydrates. The role of CKD in affecting the physicochemical and mechanical properties of EI-Karnak cement pastes was studied by autoclaving of several pastes containing 5, 7.5, 10 and 20% CKD at a pressure of 1.013 MPa of saturated steam. CKD was added either as a raw CKD (unwashed) or after washing with water (washed CKD). The results of these physicochemical studies obtained could be related as much as possible to the role of CKD (raw or washed) in affecting the hydrothermal reactivity of silica sand in EI-Karnak cement pastes.
基金Funded by the Ministry of Science and Technology of the People's Republic of China (No. 2001CD610704-2) Wuhan City Chenguan Plan (No. 20055003059231)
文摘An amended method for accurate measuring the quantity of calcium silicate hydrate(C-S-H) in pure cement paste and blended cement paste by water adsorption was made, which based on R.A.Olson’s method. Two improvements to this method, such as using C-S-H gel by hydro-thermal synthesis as standard sample and the stoichiometry of C-S-H gel is partitioned based on hydration time and the amount of mineral admixture. The result of C-S-H gel content in pure cement paste and blended cement paste is higher than by R.A.Olson’s method.
基金Funded by the Program for Changjiang Scholars and Innovative Research Team in University(PCSIRT)(No.IRT1146)the Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD)+4 种基金Scientific Research Foundation of Education Department of Anhui Province-(No.KJ2013A257)the State Key Laboratory of MaterialsOriented Chemical Engineering(No.KL12-12)National Natural Science Foundation of China(Nos.51608004,51578004)Opening Foundation of State Key Laboratory of High Performance Civil Engineering Materials(No.2014CEM010)Natural Science Foundation of the Anhui Higher Education Institution(No.KJ2016A818)
文摘The amount of inert quartz tailing used in concrete construction is limited due to the low strength development of cementitious materials that may be caused by the quartz tailing. We manage to increase the strength of blended cement by modifying quartz tailing through solid-phase reaction of quartz tailing with carbide slag at high temperature. The mineral composition and morphology of the modified quartz tailing were examined by X-ray diffraction(XRD) and scanning electron microscopy(SEM). The mechanical properties and microstructure of blended cement mortars containing modified quartz tailing were investigated. Results showed that the strengths of blended cement mortars containing modified quartz tailing were close to those of the corresponding blended cement mortars containing quartz tailing at early age of 3 d, but increased significantly to be similar to that of plain Portland cement mortars at late ages of 90 d. This is attributed to the microstructure densification and the enhancement of interface between quartz tailing and cement paste due to the hydration of b-C_2 S surface layer on modified quartz tailing.
文摘Extensive growth in the developing countries due to infrastructure development is resulting into massive consumption of concrete thereby increasing the demand on concrete materials. Quite large amounts of fine aggregates are required for concrete in developing countries thus shortages of quality river sand is putting pressure on availability of fine aggregates. To fulfill the high demand of fine aggregates, a search for alternative materials is in process. Stone crushing and processing industry is a large industry which generates large amounts of stone dust and slurry which is a waste produced from this process. Tons of such waste generated has no useful purpose except as landfill material. Some preliminary studies have been conducted into use of marble/ limestone waste for use in concrete [1] [2].?This study aims at using stone dust as partial replacement of sand in concrete to observe its effects on workability and other mechanical properties. This would result in useful consumption of this waste product thereby eliminating environmental issues related to its disposal. Partial replacement of 10% and 20% sand replacement with stone dust is carried out with the use of self-compacting concrete with blended cement. Blended cement used contains 50% rice husk ash and 50% Portland cement. Such high strength SCC with blended cement containing 50% rice husk ash and 50% Portland cement has already been tested to provide better quality concrete [3]. Wide ranging investigations covering most aspects of mechanical behavior and permeability were carried out for various mixes for compressive strengths of 60?MPa & 80?MPa. Compressive strengths of high strength SCC with blended cements and 10% and 20% replacement of sand with stone dust for 60?MPa and 80?MPa were observed to be higher by about 10% to 13% than the control specimen. Higher elastic moduli and reduced permeability were observed along with better sulphate and acid resistance. Better strengths and improved durability of such high strength SCC make it a more acceptable material for major construction projects thereby reducing the burden on environment and use of such waste product for a useful purpose promoting sustainable construction.
文摘Self-Compacting concrete is a concrete that is able to flow and consolidate under its own weight, completely fill the formwork even in the presence of dense reinforcement, whilst maintaining homogeneity and without the need for any additional compaction. Self-Compacting concrete is achieved by using high proportions of powder content and super?plasticizers. Due to this, pronounced thermal cracking is anticipated. Thermal cracking in concrete structures is of great concern. The objective of this research is to carry out experiments and investigate fresh and hardened properties of SCC developed using a blend of ordinary Portland cement and ground granulated blast furnace slag (GGBFS), to evaluate the applicability of Japan Concrete Institute (JCI) model?equations and?to find out any similarities and differences between Self-?Compacting concrete and normal vibrated concrete—Portland blast furnace slag concrete class B. Thermal stress analysis of the proposed Self-Compacting concrete and normal vibrated concretes were investigated by simulation using 3D FEM analysis. To carry out these objectives, concrete properties such as autogenous shrinkage, adiabatic temperature rise, drying shrinkage, modulus of elasticity, splitting tensile strength and compressive strength were determined through experiments. From experimental results, it was observed that except for the fresh properties, the hardened properties of Self-Compacting exhibit similar characteristics to those of normal vibrated concrete at almost similar water to binder ratios. It was also established that Self-Compacting concrete at W/B of 32% with a 50% replacement of ground granulated blast furnace slag has better thermal cracking resistance than SCC with 30% GGBFS replacement. It is also found that provided the relevant constants are derived from experimental data, JCI model equations can be applied successfully to evaluate hardened properties of Self-Compacting concrete.
文摘This paper deals with the effect of blended cement and natural latex copolymer to static and dynamic properties of polymer modified concrete. The polymer was used copolymer of natural latex methacrylate (KOLAM) and copolymer of natural latex styrene (KOLAS) with composition of 1%, 5%, and 10% w/w of weight of blended cement in concrete mixture. They are tested for compressive strength, flexural strength, splitting tensile strength, and modulus elasticity for static analysis, and impact load and energy dissipation profile for dynamic analysis. The result shows that KOLAM with concentration 1% give better performance in static and dynamic properties. The KOLAM 1% gives improvement in flexural strength, splitting tensile strength and modulus elasticity about 4%, 13% and 3% compared to normal concrete. And for dynamic properties, KOLAM 1% could reduce impact load up to 35% and improve energy dissipation capacity about 45% compared to normal concrete. The concentration of KOLAM higher than 1% resulting negative effect to static and dynamic properties, except modulus of elasticity. For KOLAS, there were no positive trends of static and dynamic properties.
基金Funded by National Basic Research Program of China (No.2009CB623100)
文摘A novel methodology for the formulation design of the multi-component cement additive for the low early strength blend cement was presented by using engineering statistics.Components of cement additive such as triethanolamine,chloride,saccharide and a kind of divalent alcohol were simultaneously tested according to the arrangement of response surface methodology.Mathematical models were established to express the quantitative relationship between the chemical components of cement additive and the compressive strength of treated blend cement.The effectiveness and the possible interactions of these four chemicals contributing to the strength development of blend cement were further explored by the pareto chart and the contour plot.Finally according the performance analysis of four chemicals,the optimized formulations were brought forward and were validated in practical trials by Turkey's multiple comparison.
基金Funded by the Key Laboratory Foundation of Ecological-Environment Materials (Yancheng Institute of Technology) of Jiangsu Province (No.XKY2009033)the Natural Science Foundation of Jiangsu Provincial Edu-cation Department (No. 07KJB430123)
文摘Composite cement samples were prepared by mixing clinker, gypsum with burnt coal gangues which was calcined at various temperatures. The mechanical strength and Ca(OH)2 content in the cement paste were tested, and the paste composition and microstructure were analyzed by thermogravimetry-differential thermal analysis (TG-DSC), X-ray diffraction(XRD), scanning electronic microscopy (SEM) and pore structure analysis. Results demonstrate that the thermal activated coal gangue could accelerate the early hydration of cement clinker obviously, which promotes the gangue hydration itself. The early hydrated products of the cement are C-S-H gel, Ca(OH)2 and AFt. The cement with 30% (in mass) the gangue exhibits higher mechanical strength, and among all the cement samples the one with the gangue burnt at 700 ℃ displays the highest hydration rate, mechanical strength, the most gel pores and the lowest total porosity.
基金the National Natural Science Foundation of China(50678139)the Open Foundation Program of Key Laboratory of Silicate Materials Science and Engineering of Ministry of Education(Wuhan University of Technology) China(No.SYSJJ2005-08)
文摘A new kind of mortar made of ground granulated blast-furnace slag (GGBFS), gypsum, clinker and steel slag sand (〈4.75 mm) was developed. The ratio of steel slag sand to GGBFS was 1 : 1 and the amount of gypsum was 4% by weight while the dosage of clinker ranged from 0% to 24%. The optimization formulation of such mortar was studied. The content of steel slag sand should be less than 50% according to the volume stability of blended mortar, and the dosage of clinker is about 10% based on the strength development. Besides strength, the hydration heat, pore structure and micro pattern of blended mortar were also determined. The experimental results show the application of steel slag sand may reduce the dosage of cement clinker and increase the content of industrial waste product such as GGBFS, and the clinker is also a better admixture for blended mortar using steel slag sand.