Wavelength calibration and spectral analysis of vacuum ultraviolet spectroscopy in EAST

A vacuum ultraviolet(VUV)spectroscopy with a focal length of 1 m has been engineered specifically for observing edge impurity emissions in Experimental Advanced Superconducting Tokamak(EAST).In this study,wavelength calibration for the VUV spectroscopy is achieved utilizing a zinc lamp.The grating angle and charge-coupled device(CCD)position are carefully calibrated for different wavelength positions.The wavelength calibration of the VUV spectroscopy is crucial for improving the accuracy of impurity spectral data,and is required to identify more impurity spectral lines for impurity transport research.Impurity spectra of EAST plasmas have also been obtained in the wavelength range of 50–300 nm with relatively high spectral resolution.It is found that the impurity emissions in the edge region are still dominated by low-Z impurities,such as carbon,oxygen,and nitrogen,albeit with the application of fulltungsten divertors on the EAST tokamak.

USING WAVELENGTH ROUTING IN THE OPTICAL INTERCONNECTION COMPUTER NETWORK

The wavelength routing technology applied to computer interconnection networks is introduced in this paper.By analyzing the relation between wavelength and network routing,we describe a concept of wavelength used as network IP address,and propose a wavelength routing topology to extend the scale of a network and realize the scalability of the network.Moreover,a twin wavelength ring network that is being developed in our laboratory to implement and test the function of wavelength routing is presented,and the main units of the twin wavelength ring network are presented also.According to the testing results based on a single wavelength ring network,it proves that the optical interconnection technology is a perfect technology to provide enough communication bandwidth for computer network.

Quantitative Determination of Benoxinate Hydrochloride by Three Wavelength Spectrophotometry

hree wavelength spectrophotometry was used to determine the content ofbenoxinate hydrochloride.Using this method could effectively eliminate the devia-tion of background absorption caused by the change of concentration and the errorof quantitative anaiysis caused by asymmetric peaks, and at the same time the lean-ing degree of base line was corrected.This method was simple, the recovery was98. 62% 101. 86% and the coefficient of variation was 0. 551%.

Joint Distribution of Wave Heights and Wavelengths and Distribution of Wave Steepness

A joint probability density is derived for wavelengths and wave heights. It is asymmetric and depends only on the spectral bandwidth epsilon defined by Cartwright and Longuet-Higgins (1956). After that a theoretical probability density for wave steepness is obtained. It tends to Rayleigh distribution as epsilon --> 0. A comparison between theoretical steepness distribution and laboratory experiment result shows good agreement.

Effect of radiation-induced mean wavelength shift in optical fibers on the scale factor of an interferometric fiber optic gyroscope at a wavelength of 1300 nm

In order to analyze the effect of wavelength-dependent radiation-induced attenuation （RIA） on the mean trans- mission wavelength in optical fiber and the scale factor of interferometric fiber optic gyroscopes （IFOGs）, three types of polarization-maintaining （PM） fibers are tested by using a 60Co γ-radiation source. The observed different mean wave- length shift （MWS） behaviors for different fibers are interpreted by color-center theory involving dose rate-dependent absorption bands in ultraviolet and visible ranges and total dose-dependent near-infrared absorption bands. To evaluate the mean wavelength variation in a fiber coil and the induced scale factor change for space-borne IFOGs under low radiation doses in a space environment, the influence of dose rate on the mean wavelength is investigated by testing four germanium （Ge） doped fibers and two germanium-phosphorus （Ge-P） codoped fibers irradiated at different dose rates. Experimental results indicate that the Ge-doped fibers show the least mean wavelength shift during irradiation and their mean wavelength of optical signal transmission in fibers will shift to a shorter wavelength in a low-dose-rate radiation environment. Finally, the change in the scale factor of IFOG resulting from the mean wavelength shift is estimated and tested, and it is found that the significant radiation-induced scale factor variation must be considered during the design of space-borne IFOGs.

Wavelength Dependence in the Analysis of Carbon Content in Coal by Nanosecond 266 nm and 1064 nm Laser Induced Breakdown Spectroscopy

The wavelength dependence of laser induced breakdown spectroscopy （LIBS） in the analysis of the carbon contents of coal was studied using 266 nm and 1064 nm laser radiations. Compared with the 1064 nm wavelength laser ablation, the 266 nm wavelength laser ablation has less thermal effects, resulting in a better crater morphology on the coal pellets. Besides, the 266 nm wavelength laser ablation also provides better laser-sample coupling and less plasma shielding, resulting in a higher carbon line intensity and better signal reproducibility. The carbon contents in the bituminous coal samples have better linearity with the line intensities of atomic carbon measured by the 266 nm wavelength than those measured by the 1064 nm wavelength. The partial least square （PLS） model was established for the quantitative analysis of the carbon content in coal samples by LIBS. The results show that both of the 266 nm and 1064 nm wavelengths are capable of achieving good performance for the quantitative analysis of carbon content in coal using the PLS method.

Calibration-free wavelength modulation spectroscopy for gas concentration measurements under low-absorbance conditions

We derive the expressions of the first and second harmonic signals on the basis of absorption spectral and lock-in theories, and determine the gas concentration according to the ratio of second and first harmonic signals. It is found that the X and Y components of the harmonic signals are influenced by the phase shift between the detection and reference signal, and the phase shift can be any value in a range from 0 to 2π, which is different from the results obtained previously. Meanwhile, an additional item caused by the residual amplitude modulation will make a great contribution to the second harmonic signal, and may not be neglected under low absorbance conditions. Theoretical analysis indicates that subtracting back-ground signal from the second harmonic signal can remove the influence of this item, and can improve the measurement accuracy of gas concentration. On this basis, we select the transition of CO2 at 6527.64 cm-1 to analyse the approximation errors during the derivation by numerical simulation and then measure the CO2 concentration under low absorbance conditions, with absorbance varying from 1‰ to 6‰.

A New Method to Determine Central Wavelength and Optimal Bandwidth for Predicting Plant Nitrogen Uptake in Winter Wheat

Plant nitrogen （N） uptake is a good indicator of crop N status. In this study, a new method was designed to determine the central wavelength, optimal bandwidth and vegetation indices for predicting plant N uptake （g N m-2） in winter wheat （Triticum aestivum L.）. The data were collected from the ground-based hyperspectral reflectance measurements in eight field experiments on winter wheat of different years, eco-sites, varieties, N rates, sowing dates, and densities. The plant N uptake index （PNUI） based on NDVI of 807 nm combined with 736 nm was selected as the optimal vegetation index, and a linear model was developed with R2 of 0.870 and RMSE of 1.546 g N m-2 for calibration, and R2 of 0.834, RMSE of 1.316 g N m-2, slope of 0.934, and intercept of 0.001 for validation. Then, the effect of the bandwidth of central wavelengths on model performance was determined based on the interaction between central wavelength and bandwidth expansion. The results indicated that the optimal bandwidth varies with the changes of the central wavelength and with the interaction between the two bands in one vegetation index. These findings are important for prediction and diagnosis of plant N uptake more precise and accurate in crop management.

Effects of the long wavelength-filtered continuousspectrum on natural refractive development in juvenile guinea pigs

AIM: To investigate the effects of spectral composition and light intensity on natural refractive development in guinea pigs.METHODS: A total of 124 pigmented guinea pigs(2-week-old) were randomly assigned to three groups at high(Hi;4000 lx), medium(Me;400 lx) and low(Lo;50 lx) light intensities under a 12:12 light/dark cycle for 6 wk. Each group was subdivided into subgroups with the following spectra: broad spectrum Solux halogen light(BS), 600 nm above-filtered continuous spectrum(600F), 530 nm above-filtered continuous spectrum(530F), and 480 nm above-filtered continuous spectrum(480F;HiBS: n=10, Hi600F: n=10, Hi530F: n=10, Hi480F: n=10, MeBS: n=10, Me600F: n=10, Me530F: n=10, Me480F: n=10, LoBS: n=11, Lo600F: n=12, Lo530F: n=10, Lo480F: n=11). Refractive error, corneal curvature radius, and axial dimensions were determined by cycloplegic retinoscopy, photokeratometry, and A-scan ultrasonography before and after 2, 4, and 6 wk of treatment. Average changes from both eyes in the ocular parameters and refractive error were compared among different subgroups.RESULTS: After 6 wk of exposure, high-intensity lighting enhanced hyperopic shift;medium-and low-intensity lighting enhanced myopic shift(P<0.05). Under the same spectrum, axial increase was larger in the low light intensity group than in the medium and high light intensity groups(HiBS: 0.65±0.02 mm, MeBS: 0.67±0.01 mm, LoBS:0.82±0.02 mm;Hi600 F: 0.64±0.02 mm, Me600F: 0.67±0.01 mm, Lo600F: 0.81±0.01 mm;Hi530F: 0.64±0.02 mm, Me530F: 0.67±0.01 mm, Lo530F: 0.73±0.02 mm;Hi480F: 0.64±0.01 mm, Me480F: 0.66±0.01 mm, Lo480F: 0.72±0.02 mm;P<0.05). Under 400 lx, there was a faster axial increase in the MeBS group than in the Me480F group(P<0.05). Under 50 lx, axial length changes were significantly larger in LoBS and Lo600F than in Lo530F and Lo480F(P<0.01).CONCLUSION: Under high-intensity lighting, high light intensity rather than spectrum distributions that inhibits axial increase. Under medium-and low-intensity lighting, filtering out the long wavelength inhibits axial growth in juvenile guinea pigs.

Sensitive absorption measurements of hydrogen sulfide at 1.578 μm using wavelength modulation spectroscopy

Sensitive detection of hydrogen sulfide（H2S） has been performed by means of wavelength modulation spectroscopy（WMS） near 1.578 μm. With the scan amplitude and the stability of the background baseline taken into account, the response time is 4 s for a 0.8 L multi-pass cell with a 56.7 m effective optical path length. Moreover, the linearity has been tested in the 0–50 ppmv range. The detection limit achievable by the Allan variance is 224 ppb within 24 s under room temperature and ambient pressure conditions. This tunable diode laser absorption spectroscopy（TDLAS） system for H2 S detection has the feasibility of real-time online monitoring in many applications.

A Dual Wavelength Differential First Derivative Spectrophotometric Method for Identification and Determination of Carbon Monoxide Generated During the Microsomal Metabolism of Xenobiotics in vitro

A dual wavelength differential first derivative spectrophotometric method has been developed to standardize the concentration of a saturated aqueous solution of carbon monoxide (CO) as the standard and to identify and to determine CO formed during the microsomal metabolism of xenobiotics in vitro. The method can significantly eliminate the background interference in the assay media and increase the quantitative accuracy and the sensitivity. There is a good linear relationship between CO concentration in the range of 2～10 μmol·L 1 CO and the distance D between the first derivative peak at 415 nm amd valley at 426 nm with r=0.9999(n=5),the regression equation being C (mmol·L 1 )=17.6D 0.4, the detection limit lower than 0.1 μmol·L 1 CO. The average recoveries of CO from the assay system and the sample were 102.1%, RSD=2.9% (n=7) and 79.7%, RSD=6.8% (n=12),respectively. The RSD of within day was 4.4%(n=18),and the RSD of day to day was 6.1%(n=16). By this method, four trihaloanilines and one trihalobenzene were tested, the results showed that only 2,4,5 trifluoroaniline could be converted to CO by the incubation with rat hepatic microsomes, NADPH and oxygen, the ability of phenobarbital or dexamethasone to induce rat hepatic microsomes to catalyze CO formation was 3 or 8 times higher than that of the control.

Telecom wavelength single photon sources

Single photon sources are key components for quantum technologies such as quantum communication, computing and metrology. A key challenge towards the realization of global quantum networks are transmission losses in optical fibers. Therefore, single photon sources are required to emit at the low-loss telecom wavelength bands. However, an ideal telecom wavelength single photon source has yet to be discovered. Here, we review the recent progress in realizing such sources. We start with single photon emission based on atomic ensembles and spontaneous parametric down conversion, and then focus on solid-state emitters including semiconductor quantum dots, defects in silicon carbide and carbon nanotubes. In conclusion, some state-of-the-art applications are highlighted.

Growth and characteristics of InAsSb epilayers with a cutoff wavelength of 4.8 μm prepared by one-step liquid phase epitaxy

InAsSb epilayers with a cutoff wavelength of 4.8 μm have been successfully grown on InAs substrates by one-step liquid phase epitaxy （LPE） technology. The epilayers were characterized by X-ray diffraction （XRD）, Fourier transform infrared （PTIR） transmittance measurements and scanning electron microscopy （SEM）. The influence of different growth conditions on the optical and structural properties of the materials was studied. The results revealed that the good crystalline quality, mirror smooth surface and flat interface of InAsSb epilayers were achieved. They benefited from optimized growth conditions, i.e., sufficient homogeneity of the growth melt and a very slow cooling rate.

Synthesis and Luminescence of SrZnO_2∶Eu^(3+), Li^+ Phosphor by Long Wavelength UV Excitation

SrZnO2 ： Eu^3 ＋ , Li^＋ phosphor powder by long wavelength UV excitation was synthesized by conventional solid-state reaction method. XRD and PL were employed to characterize their properties. The resuits show that Eu^3＋ ions preferentially occupy Sr^2＋ asymmetry cationic sites, thus emitting 612 nm red light originated from ^5D0 to ^7F2 transition. The luminescent intensity can be greatly enhanced with incorporation of Li^＋ ions. The excitation efficiency in range of 350 - 400 nm also increases greatly due to incorporating Li ^＋ ions. SrZnO2 ： Eu^3 ＋ , Li^＋ is a promising redemitting phosphor by long wavelength UV excitation.

Highly-sensitive NO,NO2,and NH3 measurements with an open-multipass cell based on mid-infrared wavelength modulation spectroscopy

A compact prototype based on mid-infrared wavelength modulation spectroscopy（WMS）is developed for the simul-taneous monitoring of NO,NO2,and NH3 in the urban area.Three quantum cascade lasers（QCLs）with central frequencies around 1900.0 cm^-1,1600.0 cm^-1,and 1103.4 cm^-1are used for NO,NO2,and NH3detections,respectively,by timedivision multiplex.An open-path multi-pass cell of 60-m optical path length is applied to the instrument for high sensitivity and reducing the response time to less than 1 s.The prototype achieves a sub-ppb detection limit for all the three target gases with an average time of about 100 s.The instrument is installed in the Jiangsu environmental monitoring center to conduct performance tests on ambient air.Continuous 24-hour measurements show good agreement with the results of a reference instrument based on the chemiluminescence technique.

Three-wavelength generation from cascaded wavelength conversion in monolithic periodically poled lithium niobate

Tunable coherent emission is generated in a single-pass, cascaded wavelength conversion process from mode-locked laser-pumped monolithic periodically poled lithium niobate（PPLN）. Three ranges of wavelength, including visible output from 628 nm to 639 nm, near-infrared output from 797 nm to 816 nm, and mid-infrared output from 3167 nm to 3459 nm,were obtained from the monolithic PPLN, which consists of a 10-mm section for 532-nm-pumped optical parametric generation（OPG） and a 7-mm section for 1064-nm-pumped sum frequency generation（SFG）. A pump-to-signal conversion efficiency of 23.4% for OPG at 50°C and a quantum efficiency of 26.2% for SFG at 200°C were obtained.

Wavelength dependence four-wave mixing spectroscopy in a micrometric atomic vapour

This paper presents a theoretical study of wavelength dependence four-wave-mixing （FWM） spectroscopy in a micrometric thin atomic vapour. It compares three cases termed as mismatched case I, matched case and mismatched case II for the probe wavelength less, equal and greater than the pump wavelength respectively. It finds that Dicke- narrowing can overcome width broadening induced by Doppler effects and polarisation interference of thermal atoms, and high resolution FWM spectra can be achieved both in matched and mismatched wavelength for many cases. It also finds that the magnitude of the FWM signal can be dramatically modified to be suppressed or to be enhanced in comparison with that of matched wavelength in mismatched case I or II. The width narrowing and the magnitude suppression or enhancement can be demonstrated by considering enhanced contribution of slow atoms induced by atom-wall collision and transient effect of atom-light interaction in a micrometric thin vapour.

Very long wavelength infrared focal plane arrays with 50% cutoff wavelength based on type-Ⅱ In As/GaSb superlattice

A very long wavelength infrared（VLWIR） focal plane array based on In As/Ga Sb type-Ⅱ super-lattices is demonstrated on a Ga Sb substrate. A hetero-structure photodiode was grown with a 50% cut-off wavelength of 15.2 μm, at 77 K.A 320×256 VLWIR focal plane array with this design was fabricated and characterized. The peak quantum efficiency without an antireflective coating was 25.74% at the reverse bias voltage of-20 mV, yielding a peak specific detectivity of 5.89×10^10cm·Hz^1/2·W^-1. The operability and the uniformity of response were 89% and 83.17%. The noise-equivalent temperature difference at 65 K exhibited a minimum at 21.4 mK, corresponding to an average value of 56.3 mK.

Wavelength modulation spectroscopy for measurements of gas parameters in combustion field

A novel wavelength modulation spectroscopy sensor for studying gas properties near 1.4 μm is developed, validated and used in a direct-connect supersonic combustion test facility. In this sensor there are two H2O transitions near 7185.60 cm^-1 and 7454.45 cm^-1 that are used to enable the measurements along the line-of-sight. According to an iterative algorithm, the gas pressure, temperature and species mole fraction can be measured simultaneously. The new sensor is used in the isolator and extender of the supersonic combustion test facility. In the isolator, the sensor resolves the transient and measured pressure, temperature and H2O mole fraction with accuracies of 2.5%, 8.2%, and 7.2%, respectively. Due to the non-uniform characteristic in the extender, the measured results cannot precisely characterize gas properties, but they can qualitatively describe the distinctions of different zones or the changes or fluctuations of the gas parameters.

InAsSb thick epilayers applied to long wavelength photoconductors

InAs0.052Sb0.948 epilayers with cutoff wavelengths longer than 8 μm were successfully grown on InAs substrates using melt epitaxy （ME）. Scanning electron microscopy observations show that the interface between the epilayers and substrates is flat, indicating the good quality of the epilayers, and the thickness of the epilayers is 40 μm. Photoconductors were fabricated using InAs0.052Sb0.948 thick epilayers grown by ME. Ge optical lenses were set on the photoconductors. At room temperature, the photoresponse wavelength range was 2-10μm. The peak detectivity Dλp reached 5.4 × 10^9 cm-Hz^1/2.W^-1 for the immersed detectors. The detectivity D^＊ was 9.3 × 10^8 and 1.3 × 10^8 cm.Hz^1/2.W^-1 at the wavelength of 8 and 9 μm, respectively. The good performance of the uncooled InAsSb detectors was experimentally validated.