Instantaneous creep in face-centered cubic metals, 5N Al（99.999%）, 2N Al （99%） and 4N Cu （99.99%） with different grain sizes, was firstly investigated by sudden stress-change experiments at ultra- low strain rat...Instantaneous creep in face-centered cubic metals, 5N Al（99.999%）, 2N Al （99%） and 4N Cu （99.99%） with different grain sizes, was firstly investigated by sudden stress-change experiments at ultra- low strain rates ε ≤10-10 s-1 and temperature T 〈 0.32 Tn. The experimental results indicate that the observed instantaneous creep is strongly dependent on grain size, the concentration of impurity, and stacking fault energy. Creep in high-purity aluminum, 5N Al, with a very large grain size, d 〉 1600μm, shows non-viscous behavior, and is controlled by the recovery of dislocations in the boundary of dislocation cells. On the other hand, for 5N A1 with a small grain size, d=30μm, and low-purity aluminum, 2N A1, with d8= 25μm, creep shows viscous behavior and may be related to ＇low temperature grain boundary sliding＇. For high-purity copper, 4N Cu, with d= 40 grn and lower stacking fault energy, creep shows a non-viscous behavior, and is controlled by the recovery process of dislocations. For all of the samples, creep shows anelastic behavior.展开更多
The dimpling defects caused by conventional hemispherical punch in doubly curved sheet metal reconfigurable die forming process were considered.The rotatable cubic punch (RCP) was developed to suppress the dimpling de...The dimpling defects caused by conventional hemispherical punch in doubly curved sheet metal reconfigurable die forming process were considered.The rotatable cubic punch (RCP) was developed to suppress the dimpling defects more effectively and conveniently.The former punch contacts with the work-piece through a point-surface contact and the latter punch contacts with the work-piece through a surface-surface contact.A series of stamping experiments were carried out using three different punches (hemispherical punch,RCP,chamfered-RCP) with three different loads.Some finite element simulations about the stamping experiments were carried out.The dimple scales were evaluated through the dimple depths.The corresponding data were obtained by 3-D scanning and FE result analysis respectively.A 3-D plate forming machine was developed,in which chamfered-RCP was adopted.Plate forming experiments were carried out on this machine.The stamped samples show a clear basis for the performance of chamfered-RCP.The study provided a means to guide the design of punches for dimpling suppression used in reconfigurable die.展开更多
Isotropic yield surfaces of bcc and fec metals have been simulated with TBH theory.Using the five-dimensional stress space proposed recently by Lequeu et al.,the yield subsurfaces on any two of the three shear stresse...Isotropic yield surfaces of bcc and fec metals have been simulated with TBH theory.Using the five-dimensional stress space proposed recently by Lequeu et al.,the yield subsurfaces on any two of the three shear stresses can be considered as the inscribed circles of their corresponding subsurfaces on n plane.Based on this concept,Hershey,Hosford and Hill (HHH) yield func- tion has been transformed into the formula where the parameters are uniquely determined by two crystallographic factors:the mean Taylor factor in plane strain (M_p) and the critical shear stress (τ_) on slip systems.展开更多
The dynamical progresses involved in ultra-short laser pulse ablation of face-centered cubic metals under stress confinement condition are described completely using molecular dynamics method. The laser beam absorptio...The dynamical progresses involved in ultra-short laser pulse ablation of face-centered cubic metals under stress confinement condition are described completely using molecular dynamics method. The laser beam absorption and thermal energy turning into kinetics energy of. atoms are taken into account to give a detailed picture of laser metal interaction. Superheating phenomenon is observed, and the phase change from solid to liquid is characterized by a destroyed atom configuration and a decreased number density. The steep velocity gradients are found in the systems of Cu and Ni after pulse in consequence of located heating and exponential decrease of fluences following the Lambert-Beer expression. The shock wave velocities are predicted to be about 5 000 m/s in Cu and 7 200 m/s in Ni. The higher ablation rates are obtained from simulations compared with experimental data as a result of a well-defined crystalline surface irradiated by a single pulse. Simulation results show that the main mechanisms of ablation are evaporation and thermoelastic stress due to located heating.展开更多
First-principles calculations by means of the full-potential linearized augmented plane wave method using the generalized gradient approximation with correlation effect correction（GGA＋U） within the framework of spi...First-principles calculations by means of the full-potential linearized augmented plane wave method using the generalized gradient approximation with correlation effect correction（GGA＋U） within the framework of spin polarized density functional theory（DFT＋U） are used to study the structural,electronic,and magnetic properties of cubic perovskite compounds RbXF3（X = Mn,V,Co,and Fe）.It is found that the calculated structural parameters,i.e.,lattice constant,bulk modulus,and its pressure derivative are in good agreement with the previous results.Our results reveal that the strong spin polarization of the 3d states of the X atoms is the origin of ferromagnetism in RbXF3.Cohesive energies and the magnetic moments of RbXF3 have also been calculated.The calculated electronic properties show the half-metallic nature of RbCoF3 and RbFeF3,making these materials suitable for spintronic applications.展开更多
It is generally accepted that anomalous slip(AS) takes place by hexagonal dislocation networks(HDNs) in body centered cubic(BCC) metals,but the role of the HDN formation process in AS has rarely been investigated so f...It is generally accepted that anomalous slip(AS) takes place by hexagonal dislocation networks(HDNs) in body centered cubic(BCC) metals,but the role of the HDN formation process in AS has rarely been investigated so far.In this work,the critical yield conditions of the HDNs and isolated dislocations were first calculated,respectively,by molecular statics simulations in two BCC metals.Based on these data,a novel mechanism,entitled as the "conjugated dislocation sources"(CDS),to analyze the formation of the HDNs was proposed for the first time and then incorporated into the criterion of the occurrence of AS.Our prediction is in agreement with experimental observations.Contrary to previous study,it has been revealed that the multiplication of isolated screw dislocations involved in AS has to be considered for correctly understanding the AS origin.展开更多
High-entropy alloys greatly expand the alloy design range and offer new possibilities for improving material performance.Based on the worldwide research efforts in the last decade,the excellent mechanical properties a...High-entropy alloys greatly expand the alloy design range and offer new possibilities for improving material performance.Based on the worldwide research efforts in the last decade,the excellent mechanical properties and promising radiation and corrosion resistance of this group of materials have been demonstrated.High-entropy alloys with body-centered cubic(BCC)structures,especially refractory high-entropy alloys,are considered as promising materials for high-temperature applications in advanced nuclear reactors.However,the extreme reactor conditions including high temperature,high radiation damage,high stress,and complex corrosive environment require a comprehensive evaluation of the material properties for their actual service in nuclear reactors.This review summarizes the current progress on BCC high-entropy alloys from the aspects of neutron economy and activation,mechanical properties,high-temperature stability,radiation resistance,as well as corrosion resistance.Although the current development of BCC high-entropy alloys for nuclear applications is still at an early stage as the large design space of this group of alloys has not been fully explored,the current research findings provide a good basis for the understanding and prediction of material behaviors with different compositions and microstructures.Further in-depth understanding of the degradation mechanisms and characterization of material properties in response to conditions close to reactor environment are necessary.A critical down-selection of potential candidates is also crucial for further comprehensive evaluation and engineering validation.展开更多
基金Funded by the Tianjin Research Program of Application Foundation and Advanced Technology(12JCYBJC32100)the Scientific Research Foundation for the Returned Overseas Chinese Scholars,State Education Ministryin part by Grants-in-Aid from the Japan Society for the Promotion of Science(JSPS)
文摘Instantaneous creep in face-centered cubic metals, 5N Al（99.999%）, 2N Al （99%） and 4N Cu （99.99%） with different grain sizes, was firstly investigated by sudden stress-change experiments at ultra- low strain rates ε ≤10-10 s-1 and temperature T 〈 0.32 Tn. The experimental results indicate that the observed instantaneous creep is strongly dependent on grain size, the concentration of impurity, and stacking fault energy. Creep in high-purity aluminum, 5N Al, with a very large grain size, d 〉 1600μm, shows non-viscous behavior, and is controlled by the recovery of dislocations in the boundary of dislocation cells. On the other hand, for 5N A1 with a small grain size, d=30μm, and low-purity aluminum, 2N A1, with d8= 25μm, creep shows viscous behavior and may be related to ＇low temperature grain boundary sliding＇. For high-purity copper, 4N Cu, with d= 40 grn and lower stacking fault energy, creep shows a non-viscous behavior, and is controlled by the recovery process of dislocations. For all of the samples, creep shows anelastic behavior.
基金the National Natural Science Foundation of China(Nos.51379167 and 51779200)。
文摘The dimpling defects caused by conventional hemispherical punch in doubly curved sheet metal reconfigurable die forming process were considered.The rotatable cubic punch (RCP) was developed to suppress the dimpling defects more effectively and conveniently.The former punch contacts with the work-piece through a point-surface contact and the latter punch contacts with the work-piece through a surface-surface contact.A series of stamping experiments were carried out using three different punches (hemispherical punch,RCP,chamfered-RCP) with three different loads.Some finite element simulations about the stamping experiments were carried out.The dimple scales were evaluated through the dimple depths.The corresponding data were obtained by 3-D scanning and FE result analysis respectively.A 3-D plate forming machine was developed,in which chamfered-RCP was adopted.Plate forming experiments were carried out on this machine.The stamped samples show a clear basis for the performance of chamfered-RCP.The study provided a means to guide the design of punches for dimpling suppression used in reconfigurable die.
文摘Isotropic yield surfaces of bcc and fec metals have been simulated with TBH theory.Using the five-dimensional stress space proposed recently by Lequeu et al.,the yield subsurfaces on any two of the three shear stresses can be considered as the inscribed circles of their corresponding subsurfaces on n plane.Based on this concept,Hershey,Hosford and Hill (HHH) yield func- tion has been transformed into the formula where the parameters are uniquely determined by two crystallographic factors:the mean Taylor factor in plane strain (M_p) and the critical shear stress (τ_) on slip systems.
基金the Ministerial Level Advanced Research Foundation (ABAQ440261)
文摘The dynamical progresses involved in ultra-short laser pulse ablation of face-centered cubic metals under stress confinement condition are described completely using molecular dynamics method. The laser beam absorption and thermal energy turning into kinetics energy of. atoms are taken into account to give a detailed picture of laser metal interaction. Superheating phenomenon is observed, and the phase change from solid to liquid is characterized by a destroyed atom configuration and a decreased number density. The steep velocity gradients are found in the systems of Cu and Ni after pulse in consequence of located heating and exponential decrease of fluences following the Lambert-Beer expression. The shock wave velocities are predicted to be about 5 000 m/s in Cu and 7 200 m/s in Ni. The higher ablation rates are obtained from simulations compared with experimental data as a result of a well-defined crystalline surface irradiated by a single pulse. Simulation results show that the main mechanisms of ablation are evaporation and thermoelastic stress due to located heating.
文摘First-principles calculations by means of the full-potential linearized augmented plane wave method using the generalized gradient approximation with correlation effect correction（GGA＋U） within the framework of spin polarized density functional theory（DFT＋U） are used to study the structural,electronic,and magnetic properties of cubic perovskite compounds RbXF3（X = Mn,V,Co,and Fe）.It is found that the calculated structural parameters,i.e.,lattice constant,bulk modulus,and its pressure derivative are in good agreement with the previous results.Our results reveal that the strong spin polarization of the 3d states of the X atoms is the origin of ferromagnetism in RbXF3.Cohesive energies and the magnetic moments of RbXF3 have also been calculated.The calculated electronic properties show the half-metallic nature of RbCoF3 and RbFeF3,making these materials suitable for spintronic applications.
基金financially supported by the Youth Innovation Promotion Association CAS (Grant No.2021192)National Natural Science Foundation of China (NSFC) (Grant Nos.51871223, 52130002 and 51790482)the KC Wong Education Foundation (GJTD-2020-09)。
文摘It is generally accepted that anomalous slip(AS) takes place by hexagonal dislocation networks(HDNs) in body centered cubic(BCC) metals,but the role of the HDN formation process in AS has rarely been investigated so far.In this work,the critical yield conditions of the HDNs and isolated dislocations were first calculated,respectively,by molecular statics simulations in two BCC metals.Based on these data,a novel mechanism,entitled as the "conjugated dislocation sources"(CDS),to analyze the formation of the HDNs was proposed for the first time and then incorporated into the criterion of the occurrence of AS.Our prediction is in agreement with experimental observations.Contrary to previous study,it has been revealed that the multiplication of isolated screw dislocations involved in AS has to be considered for correctly understanding the AS origin.
基金supported by the National Key Research and Development Program of China(Grant Nos.2019YFA0209900 and 2017YFB0304403)the National Natural Science Foundation of China(Grant No.12075179)+1 种基金the Nuclear Material Technology Innovation Center Project(Grant No.ICNM 2020 ZH05)the Continuous Basic Scientific Research Project(Grant No.WDJC-2019-10)
文摘High-entropy alloys greatly expand the alloy design range and offer new possibilities for improving material performance.Based on the worldwide research efforts in the last decade,the excellent mechanical properties and promising radiation and corrosion resistance of this group of materials have been demonstrated.High-entropy alloys with body-centered cubic(BCC)structures,especially refractory high-entropy alloys,are considered as promising materials for high-temperature applications in advanced nuclear reactors.However,the extreme reactor conditions including high temperature,high radiation damage,high stress,and complex corrosive environment require a comprehensive evaluation of the material properties for their actual service in nuclear reactors.This review summarizes the current progress on BCC high-entropy alloys from the aspects of neutron economy and activation,mechanical properties,high-temperature stability,radiation resistance,as well as corrosion resistance.Although the current development of BCC high-entropy alloys for nuclear applications is still at an early stage as the large design space of this group of alloys has not been fully explored,the current research findings provide a good basis for the understanding and prediction of material behaviors with different compositions and microstructures.Further in-depth understanding of the degradation mechanisms and characterization of material properties in response to conditions close to reactor environment are necessary.A critical down-selection of potential candidates is also crucial for further comprehensive evaluation and engineering validation.
