Hybrid bonding of GaAs and Si wafers at low temperature by Ar plasma activation

High-quality bonding of 4-inch GaAs and Si is achieved using plasma-activated bonding technology.The influence of Ar plasma activation on surface morphology is discussed.When the annealing temperature is 300℃,the bonding strength reaches a maximum of 6.2 MPa.In addition,a thermal stress model for GaAs/Si wafers is established based on finite element analysis to obtain the distribution of equivalent stress and deformation variables at different temperatures.The shape varia-tion of the wafer is directly proportional to the annealing temperature.At an annealing temperature of 400℃,the maximum protrusion of 4 inches GaAs/Si wafers is 3.6 mm.The interface of GaAs/Si wafers is observed to be dense and defect-free using a transmission electron microscope.The characterization of interface elements by X-ray energy dispersion spectroscopy indi-cates that the elements at the interface undergo mutual diffusion,which is beneficial for improving the bonding strength of the interface.There is an amorphous transition layer with a thickness of about 5 nm at the bonding interface.The preparation of Si-based GaAs heterojunctions can enrich the types of materials required for the development of integrated circuits,improve the performance of materials and devices,and promote the development of microelectronics technology.

Effect of neutral polymeric bonding agent on tensile mechanical properties and damage evolution of NEPE propellant

Introducing Neutral Polymeric bonding agents(NPBA) into the Nitrate Ester Plasticized Polyether(NEPE)propellant could improve the adhesion between filler/matrix interface, thereby contributing to the development of new generations of the NEPE propellant with better mechanical properties. Therefore,understanding the effects of NPBA on the deformation and damage evolution of the NEPE propellant is fundamental to material design and applications. This paper studies the uniaxial tensile and stress relaxation responses of the NEPE propellant with different amounts of NPBA. The damage evolution in terms of interface debonding is further investigated using a cohesive-zone model(CZM). Experimental results show that the initial modulus and strength of the NEPE propellant increase with the increasing amount of NPBA while the elongation decreases. Meanwhile, the relaxation rate slows down and a higher long-term equilibrium modulus is reached. Experimental and numerical analyses indicate that interface debonding and crack propagation along filler-matrix interface are the dominant damage mechanism for the samples with a low amount of NPBA, while damage localization and crack advancement through the matrix are predominant for the ones with a high amount of NPBA. Finally, crosslinking density tests and simulation results also show that the effect of the bonding agent is interfacial rather than due to the overall crosslinking density change of the binder.

A MULTISCALE MECHANICAL MODEL FOR MATERIALS BASED ON VIRTUAL INTERNAL BOND THEORY

Only two macroscopic parameters are needed to describe the mechanical properties of linear elastic solids, i.e. the Poisson＇s ratio and Young＇s modulus. Correspondingly, there should be two microscopic parameters to determine the mechanical properties of material if the macroscopic mechanical properties of linear elastic solids are derived from the microscopic level. Enlightened by this idea, a multiscale mechanical model for material, the virtual multi-dimensional internal bonds （VMIB） model, is proposed by incorporating a shear bond into the virtual internal bond （VIB） model. By this modification, the VMIB model associates the macro mechanical properties of material with the microscopic mechanical properties of discrete structure and the corresponding relationship between micro and macro parameters is derived. The tensor quality of the energy density function, which contains coordinate vector, is mathematically proved. From the point of view of VMIB, the macroscopic nonlinear behaviors of material could be attributed to the evolution of virtual bond distribution density induced by the imposed deformation. With this theoretical hypothesis, as an application example, a uniaxial compressive failure of brittle material is simulated. Good agreement between the experimental results and the simulated ones is found.

A novel diffusion model considering curvature radius at the bonding interface in a titanium/steel explosive clad plate

This article introduces an element diffusion behavior model for a titanium/steel explosive clad plate characterized by a typical curved interface during the heat-treatment process. A series of heat-treatment experiments were conducted in the temperature range from 750℃ to 950℃, and the effects of heat-treatment parameters on the microstructural evolution and diffusion behavior were investigated by optical microscopy, scanning electron microscopy, X-ray diffraction analysis, and electron-probe microanalysis. Carbon atoms within the steel matrix were observed to diffuse toward the titanium matrix and to aggregate at the bonding interface at 850℃ or lower; in contrast, when the temperature exceeded 850℃, the mutual diffusion of Ti and Fe occurred, along with the diffusion of C atoms, resulting in the for- marion of Ti-Fe intermetallics （Fe2Ti/FeTi）. The diffusion distances of C, Ti, and Fe atoms increased with increasing heating temperature and/or holding time. On the basis of this diffusion behavior, a novel diffusion model was proposed. This model considers the effects of various factors, including the curvature radius of the curved interface, the diffusion coefficient, the heating temperature, and the holding rime. The experimental results show good agreement with the calculated values. The proposed model could clearly provide a general prediction of the elements＇ diffusion at both straight and curved interfaces.

Influence of heterogeneity on rock strength and stiffness using discrete element method and parallel bond model

The particulate discrete element method(DEM) can be employed to capture the response of rock,provided that appropriate bonding models are used to cement the particles to each other.Simulations of laboratory tests are important to establish the extent to which those models can capture realistic rock behaviors.Hitherto the focus in such comparison studies has either been on homogeneous specimens or use of two-dimensional(2D) models.In situ rock formations are often heterogeneous,thus exploring the ability of this type of models to capture heterogeneous material behavior is important to facilitate their use in design analysis.In situ stress states are basically three-dimensional(3D),and therefore it is important to develop 3D models for this purpose.This paper revisits an earlier experimental study on heterogeneous specimens,of which the relative proportions of weaker material(siltstone) and stronger,harder material(sandstone) were varied in a controlled manner.Using a 3D DEM model with the parallel bond model,virtual heterogeneous specimens were created.The overall responses in terms of variations in strength and stiffness with different percentages of weaker material(siltstone) were shown to agree with the experimental observations.There was also a good qualitative agreement in the failure patterns observed in the experiments and the simulations,suggesting that the DEM data enabled analysis of the initiation of localizations and micro fractures in the specimens.

Critical behaviours and magnetic properties of three-dimensional bond and anisotropy dilution Blume-Capel model in the presence of an applied field

This paper studies the critical behaviours and magnetic properties of three-dimensional bond and anisotropy dilution Blume-Capel model （BCM） in the presence of an applied field within the effective field theory. The trajectory of tricritical point, reentrant transitions and degenerate patterns of anisotropy are obtained both for the bond and the anisotropy dilutions. The global phase diagrams demonstrate unusually reentrant phenomena. The temperature dependences of magnetization curves undergo remarkable spin glass behaviour at low temperatures, and transform from ferromagnetism to paramagnetism at high temperature in applied fields. Temperature dependence of magnetic susceptibility curve is in qualitative agreement with experimental result.

Theoretical Model of Transformation Superlastic Diffusion Bonding for Eutectoid Steel

Based on current theories of diffusion and creep cavity closure at high temperature, a theoretical analysis of phase transformation diffusion bonding for T8/T8 eutectoid steel is carried out. The diffusion bonding is mainly described as two-stage process: Ⅰ The interfacial cavity with shape change from diamond to cylinder.Ⅱ The radius of the cylindrical cavity are reduced and eliminated gradually. A new theoretical model is established for the process of transformation superplastic diffusion bonding (TSDB) on the basis of a theoretical model for isothermal superplastic diffusion. The model can predict the bonding quality which is affected by technological parameters, such as limit cycling temperature, the compressive stress, the numbers of thermal cycles and temperature cycling through the phase transformation in the thermal cycling and so on. Results show that the maximum temperature, the compressive stress, the numbers of thermal cycles and the rate of temperature changing speed in the thermal cycling have an important influence on TSDB process. Meanwhile, reasonable technological parameters chosen from theoretical analysis is in good agreement with those obtained from experimental results.

Numerical Analysis of Ice Rubble with a Freeze-Bond Model in Dilated Polyhedral Discrete Element Method

Freezing in ice rubble is a common phenomenon in cold regions,which can consolidate loose blocks and change their mechanical properties.To model the cohesive effect in frozen ice rubble,and to describe the fragmentation behavior with a large external forces exerted,a freeze-bond model based on the dilated polyhedral discrete element method(DEM)is proposed.Herein,imaginary bonding is initialized at the contact points to transmit forces and moments,and the initiation of the damage is detected using the hybrid fracture model.The model is validated through the qualitative agreement between the simulation results and the analytical solution of two bonding particles.To study the effect of freeze-bond on the floating ice rubble,punch-through tests were simulated on the ice rubble under freezing and nonfreezing conditions.The deformation and resistance of the ice rubble are investigated during indenter penetration.The influence of the internal friction coefficient on the strength of the ice rubble is determined.The results indicate that the proposed model can properly describe the consolidated ice rubble,and the freeze-bond effect is of great significance to the ice rubble properties.

DEM investigation of weathered rocks using a novel bond contact model

The distinct element method（DEM） incorporated with a novel bond contact model was applied in this paper to shed light on the microscopic physical origin of macroscopic behaviors of weathered rock, and to achieve the changing laws of microscopic parameters from observed decaying properties of rocks during weathering. The changing laws of macroscopic mechanical properties of typical rocks were summarized based on the existing research achievements. Parametric simulations were then conducted to analyze the relationships between macroscopic and microscopic parameters, and to derive the changing laws of microscopic parameters for the DEM model. Equipped with the microscopic weathering laws, a series of DEM simulations of basic laboratory tests on weathered rock samples was performed in comparison with analytical solutions. The results reveal that the relationships between macroscopic and microscopic parameters of rocks against the weathering period can be successfully attained by parametric simulations. In addition, weathering has a significant impact on both stressestrain relationship and failure pattern of rocks.

Simulation of rock deformation and mechanical characteristics using clump parallel-bond models

To properly simulate hard rock with a high ratio of the uniaxial compressive strength to tensile strength(UCS/TS) and realistic strength-failure envelope,the rock deformation and mechanical characteristics were discussed in detail when the particle simulation method with the clump parallel-bond model(CPBM) was used to conduct a series of numerical experiments at the specimen scale.Meanwhile,the effects of the loading procedure and crack density on the mechanical behavior of a specimen,which was modeled by the particle simulation method with the CPBM,were investigated.The related numerical results have demonstrated that:1) The uniaxial compressive strength(UCS),tensile strength(TS) and elastic modulus are overestimated when the conventional loading procedure is used in the particle simulation method with the CPBM; 2) The elastic modulus,strength and UCS/TS decrease,while Poisson ratio increases with the increase of the crack density in the particle simulation method with the CPBM; 3) The particle simulation method with the CPBM can be used to reproduce a high value of UCS/TS(>10),as well as a high friction angle and reasonable cohesion strength; 4) As the confining pressure increases,both the peak strength of the simulated specimen and the number of microscopic cracks increase,but the ratio of tensile cracks number to shear cracks number decreases in the particle simulation method with the CPBM; 5) Compared with the conventional parallel-bond model,the CPBM can be used to reproduce more accurate results for simulating the rock deformation and mechanical characteristics.

Thermal-hydraulic modeling and analysis of hydraulic system by pseudo-bond graph

To increase the efficiency and reliability of the thermodynamics analysis of the hydraulic system, the method based on pseudo-bond graph is introduced. According to the working mechanism of hydraulic components, they can be separated into two categories: capacitive components and resistive components. Then, the thermal-hydraulic pseudo-bond graphs of capacitive C element and resistance R element were developed, based on the conservation of mass and energy. Subsequently, the connection rule for the pseudo-bond graph elements and the method to construct the complete thermal-hydraulic system model were proposed. On the basis of heat transfer analysis of a typical hydraulic circuit containing a piston pump, the lumped parameter mathematical model of the system was given. The good agreement between the simulation results and experimental data demonstrates the validity of the modeling method.

A Study on Modifying the Calculation Model of Valid Opening Size of Heat-bonded Nonwoven Fabrics

It has been found that there are marked errors in the value of valid opening size of heat-bonded nonwoven fabrics between theoretical calculations and engineering measurements. A new modified theoretical model is advanced in this paper. The equivalent diameter of the pore of a fibre web is used to calculate the valid opening size instead of the maximum diameter of inscribed circle used, because the fibres in practical fibre webs are flexible elastomers with definite diameters and the pore of fibre web may produce deformation in screening teat and engineering usage. The results show that the theoretical calculations coincide well with the engineering measurements. This method offers a theoretical basis for computer simulation to the performance of filters of heatbonded nonwoven fabrics.

Investigation of Highly Designable Dented Structures in HP Model with Hydrogen Bond Energy

Some highly designable protein structures have dented on the surface of their native structures, and are not full compactly folded. According to hydrophobic-polar （HP） model the most designable structures are full compactly folded. To investigate the designability of the dented structures, we introduce the hydrogen bond energy in the secondary structures by using the secondary-structure-favored HP model proposed by Ou-yang etc. The result shows that the average designability increases with the strength of the hydrogen bond. The designabilities of the structures with same dented shape increase exponentially with the number of secondary structure sites. The dented structures can have the highest designabilities for a certain value of hydrogen bond energy density.

Estimating heat capacities of liquid organic compounds based on elements and chemical bonds contribution

Molecular property depends on the property, the number of the elements, and the interaction between elements(such as chemical bonds). Based on the above-mentioned idea, two methods to estimate the isobaric heat capacity of liquids organic compounds were developed. Ten elements groups and 32 chemical bond groups were defined by considering the structure of organic compounds. The group contribution values and correlation parameters were regressed by the ridge regression method with the experiment data of 1137 compounds. The heat capacity can be calculated by summating the contributions of the elements and chemical bond groups. The two methods were compared with existing group contribution methods, such as Chickos, Zabransky-Ruzicka, and Zdenka Kolska. The results show that those new estimation methods' overall average relative deviations were 5.81% and 5.71%, which were lower than the other three methods. Those methods were more straightforward in compound splitting.Those new methods can be used to estimate the liquid heat capacity of silicon-containing compounds,which the other three methods cannot estimate. The new methods are more accessible, broader, and more accurate. Therefore, this research has important scientific significance and vast application prospects.

Reducing the anisotropy of a Brazilian disc generated in a bonded-particle model

The Brazilian test is a widely used method for determining the tensile strength of rocks and for calibrating parameters in bondedparticle models（BPMs）. In previous studies, the Brazilian disc has typically been trimmed from a compacted rectangular specimen. The present study shows that different tensile strength values are obtained depending on the compressive loading direction. Several measures are proposed to reduce the anisotropy of the disc. The results reveal that the anisotropy of the disc is significantly influenced by the compactibility of the specimen from which it is trimmed. A new method is proposed in which the Brazilian disc is directly generated with a particle boundary, effectively reducing the anisotropy. The stiffness（particle and bond） and strength（bond） of the boundary are set at less than and greater than those of the disc assembly, respectively,which significantly decreases the stress concentration at the boundary contacts and prevents breakage of the boundary particle bonds. This leads to a significant reduction in the anisotropy of the disc and the discreteness of the tensile strength. This method is more suitable for carrying out a realistic Brazilian test for homogeneous rock-like material in the BPM.

Integration of three-dimensional continuum model and two-dimensional bonded block model for studying the damage process in a granite pillar at the Creighton Mine,Sudbury,Canada

Bonded blockmodel(BBM)has shownpotential in replicating rockmass behavior aswell as the rockesupport interactionmechanism,but their practical application is limited totwo dimensions due to the high associated computational demand.To allow for the use of BBM in simulating three-dimensional(3D)problems,this study proposes an integrated 3D continuumetwo-dimensional(2D)discontinuum approach,in context of rock pillars.A cross-section of a granite pillar was simulated using a BBM with a load path from a calibrated mine-scale FLAC^(3D)model.Pillar support as employed in the mine was also incorporated in different stages during the simulation.Themodel was calibrated by varying the input parameters until the displacements at six locations within the pillarmatchedthosemeasuredby amulti-point borehole extensometer(MPBX)inthe field.The calibratedmodel was subsequently used to understand how the support and load path influenced the damage evolution in the pillar.The shear component of the load pathwas found to have amajor effect on the severity and extent of the damaged regions.When the support density was increased in the model,the lateral displacements along the pillar walls were significantly suppressed in a somewhat unpredictable manner.Thiswas explained by the interaction between the supports and the damaged regions at the corners,which ultimately modified the stresses along the pillar periphery.The amount of displacement reduction obtained by increasing the support density illustrates the potential of BBMto be used as a support design tool.

Spectroscopic Characterization, Molecular Modeling and DFT/TD-DFT/PCM Calculations of Novel Hydrogen-Bonded Charge Transfer Complex between Chloranilic Acid and 2-Amino-4,6-Dimethylpyridine

A charge transfer hydrogen bonded complex between the electron donor (proton acceptor) 2-amino-4,6-dimethylpyridine with the electron acceptor (proton donor) chloranilic acid has been synthesized and studied experimentally and theoretically. The stability constant recorded high values indicating the high stability of the formed complex. In chloroform, ethanol, methanol and acetonitrile were found the stoichiometric ratio 1:1. The solid complex was prepared and characterized by different spectroscopy techniques. FTIR, 1H and 13C NMR studies supported the presence of proton and charge transfers in the formed complex. Complemented with experimental results, molecular modelling using the density functional theory (DFT) calculations was carried out in the gas, chloroform and methanol phases where the existence of charge and hydrogen transfers. Finally, a good consistency between experimental and theoretical calculations was found confirming that the applied basis set is the suitable one for the system under investigation.

Convertible Bond Pricing Based on Exponential Variance Gamma Model

Due to the‘spike and tail’ phenomenon of asset returns,the applicability of the Black-Scholes model for pricing convertible bonds has been questioned,and the variance gamma model can cope well with this phenomenon and solve the ‘volatility smile dilemma’.This paper combines the variance gamma model with the least squares Monte Carlo simulation method to empirically analyze the Everbright convertible bond based on its high activity in the Chinese market.In this paper,the predicted price and the actual price are compared,and the applicability of the variance gamma model in the Chinese convertible bond market is analyzed.Empirical results show that the fitting price predicted by the variance gamma model is consistent with the actual price trend,indicating that the method is applicable to the Chinese convertible bond market.

Bond of Seawater Scoria Aggregate Concrete to Stainless Reinforcement

This study investigates the bond between seawater scoria aggregate concrete(SSAC)and stainless reinforcement(SR)through a series of pull-out tests.A total of 39 specimens,considering five experimental parameters—con-crete type(SSAC,ordinary concrete(OC)and seawater coral aggregate concrete(SCAC)),reinforcement type(SR,ordinary reinforcement(OR)),bond length(3,5 and 8 times bar diameter),concrete strength(C25 and C30)and concrete cover thickness(42 and 67 mm)—were prepared.The typical bond properties(failure pattern,bond strength,bond-slip curves and bond stress distribution,etc.)of seawater scoria aggregate concrete-stainless rein-forcement(SSAC-SR)specimen were systematically studied.Generally,the failure pattern changed with the con-crete type used,and the failure surface of SSAC specimen was different from that of OC specimen.SSAC enhanced the bond strength of specimen,while its effect on the deformation of SSAC-SR was negative.On aver-age,the peak slip of SSAC specimens was 20%lower while the bond strength was 6.7%higher compared to OC specimens under the similar conditions.The effects of variables on the bond strength of SSAC–SR in increasing order are concrete type,bond length,concrete strength and cover thickness.The bond-slip curve of SSAC-SR specimen consisted of micro-slipping,slipping and declining stages.It can be obtained that SSAC reduced the curve curvature of bond-slip,and the decline of curve became steep after adopting SR.The typical distribution of bond stress along bond length changed with the types of concrete and reinforcement used.Finally,a specific expression of the bond stress-slip curve considering the effects of various variables was established,which could provide a basis for the practical application of reinforced SSAC.

Early Debonding Detection of Rebar-Concrete Interface due to External Loading Utilizing AC Impedance Spectroscopy

A novel method for detecting early damage at the steel-concrete interface due to external loading based on AC impedance spectroscopy technology was proposed.Firstly,alkali pretreatment was introduced to ensure the accuracy and repeatability of the AC impedance test.Secondly,the AC impedance spectroscopy between the steel bar and concrete surface of different bonding positions was tested,and then the physical quantities reflecting the bonding damage condition were obtained by equivalent circuit fitting.Theoretical debonding position calculation and AC conductive structure analysis indicate that the change of interface resistance and interface capacitance can seize the development of bonding damage during the loading process.As the interface damage develops,obvious changes in interface resistance and interface capacitance are observed,and they cannot be recovered after unloading.