Coupling reaction usually refers to the direct C–C bond formation between two carbon fragments.Generally, cross-coupling reactions between nucleophiles and electrophiles have been extensively studied and become the c...Coupling reaction usually refers to the direct C–C bond formation between two carbon fragments.Generally, cross-coupling reactions between nucleophiles and electrophiles have been extensively studied and become the classic model for bond constructions. Another reaction model, bond formation from two nucleophiles through oxidative cross-coupling, has received more and more attention over the past few years. This paper will discuss the concept of oxidative cross-coupling and give an overview of its recent development.展开更多
基金supported by the National Basic Research Program of China(2012CB725302)the National Natural Science Foundation of China(21390400,21272180,21302148)+1 种基金the Research Fund for the Doctoral Program of Higher Education of China(20120141130002)the Ministry of Science and Technology of China(2012YQ120060)
文摘Coupling reaction usually refers to the direct C–C bond formation between two carbon fragments.Generally, cross-coupling reactions between nucleophiles and electrophiles have been extensively studied and become the classic model for bond constructions. Another reaction model, bond formation from two nucleophiles through oxidative cross-coupling, has received more and more attention over the past few years. This paper will discuss the concept of oxidative cross-coupling and give an overview of its recent development.