Exploration and Practice of Nitrogen Addition Process for LF Refining Ladle Bottom Blowing Nitrogen Steel Liquid

This article discusses and analyzes the law of nitrogen increase in liquid steel and the main factors affect-ing the nitrogen increasing of molten steel,through the way of adding nitrogen to molten steel by bottom blowing nitrogen gas in LF refining process.It is considered that the main factors affecting the nitrogen increasing instability of molten steel are the initial temperature of LF refining,nitrogen relative element,surface active elements[O]and[S]of steel liquid,and bottom blowing rate of ladle.The large-scale production practice shows that T[O]not more than 50×10-6 and[S]is not more than 0.020 in LF refining at the initial temperature of not less than 1570.The liquid steel nitrogen enrichment test is carried out by ladle bottom blowing nitrogen gas after 20 min of refining,the flow rate is set as(6.0~7.0)NL/min per ton,and it is turned to 2 NL/min at 6 min before the end of refining,the nitrogen increasing rate of liquid steel is basically stable at(5~6)×10-6 per minute.

Cold model on bubble growth and detachment in bottom blowing process

The bubble growth and detachment behavior in the bottom blowing process were investigated. Four multi-hole nozzle configurations with different opening ratios were assessed experimentally using high-speed photography and digital image processing. For these configurations, the experiments reveal that the bubble growth consists of a petal-like stage, an expansion stage and a detachment stage. The petal-like shape is qualitatively described through the captured images, while the non-spherical bubbles are analyzed by the aspect ratio. The bubble size at the detachment is quantified by the maximum caliper distance and the bubble equivalent diameter. Considering the dependence on the opening ratio, different prediction models for the ratio of maximum caliper distance to hydraulic diameter of the nozzle outlet and the dimensionless bubble diameter are established. The comparative analysis results show that the proposed prediction model can accurately predict the bubble detachment size under the condition of multi-hole nozzles.

Effect of different bottom blowing elements on stirring characteristics of molten bath in converter

The bottom blowing element is the key equipment to ensure the bottom blowing effect of the converter.Three types of bottom blowing elements,dispersive type(D1),double circular seam(D2)and straight cylinder type(D3),were built,and the effects of bottom blowing element type on molten bath flow,wall erosion and furnace bottom erosion were simulated.It was found that when the bottom blowing elements of dispersive type(D1)and double circular seam(D2)were used,the dead zone area in the lower part of the molten bath was smaller,and the high-speed zone area was larger;therefore,the stirring effect on the bottom melt was better.When the straight cylinder type(D3)bottom blowing element was used,the gas penetrated the molten bath at a faster rate to reach the surface of molten bath and failed to disperse in the bottom molten bath,and the wall shear stress near the nozzle outlet was larger.When argon was blown by three different bottom blowing elements,the area of the wall shear stress greater than 3 Pa was 4.8,5.6 and 8.7 cm2,respectively,within 0.2 m of the bottom blowing nozzle outlet.

Physical simulation of bubble refinement in bottom blowing process with mechanical agitation

In order to increase the contact area and promote the mass transfer process of gas and liquid,the process of the bubble refine-ment in a metallurgical reactor with mechanical agitation was studied by physical simulation.Based on the capillary number,a prediction equation for the bubble refinement was established.The effects of the gas flow rate,the stirring speed and thestirring depth on the bubble refinement in the reactor were discussed in detail.The distribution of the bubble diameter in thereactor was obtained under different conditions.The results show that when the stirring speed reaches 300 r/min,the bubblediamcter mainly distributes in the range of 1-2 mm.A higher gas flow rate may increase the number of bubbles in the meltand promote the bubble refinement process.The mechanism of bubble refinement under mechanical agitation was analyzed.and the results indicated that the stirring speed.,the blade area and the blade inclination are the main influencing factors.

Influence of bottom blowing oxygen on dust emission in converter steelmaking

With the importance of the steelmaking industry in the economy and its negative impacts on the environment,reducing dust emissions is a vital focus in this field.Thus,the theory of dust generation in converter steelmaking process was analyzed and the influence of bottom blowing oxygen on dust generation was obtained through experimental research.The industrial test was carried out in a 120-t bottom combined blown O_(2)–CaO steelmaking converter.The results show that lowering the lance position can reduce the amount of dust.This emission rate of the converter is also found to be in direct proportion to the decarburization rate.As a result,the proposed bottom blowing O_(2)–CaO steelmaking converter can technically reduce the amount of dust and improve the recovery rate of iron.With more bottom blowing oxygen,the dust content is lower with the dust peak appearing earlier.The evaporation theory,followed by the bubble theory,plays the primary role in the dust generation of bottom blowing oxygen steelmaking.It points out the direction for the technology research and development of reducing dust generation.

Research on Refractories Technology to Meet the Demands of Steel-making Process

Based on the refractories research of Baosteel, the demands for refractories from the developing steel-making technology as high security, high efficiency, energy saving and environment .friendly are introduced.

Development of CO_(2) capture and utilization technology in steelmaking plant

The performance of a recycling process for CO_(2) capture and utilization of exhaust gas in the steelmaking plant was reported.A facility capable of capturing CO_(2) at 3200 m^(3)/h was established in the steelmaking plant,resulting in the CO_(2) production of 50,000 t/a.The CO_(2) concentration of the exhaust gas from the lime kiln increased from 25.0 to 99.8 vol.%using the comprehensive method of the pressure swing adsorption and cryogenic separation.The captured and purified CO_(2) was successfully applied in the converter process by the top blowing and bottom blowing.The utilization of CO_(2) was 3.5 m^(3)/t through these two modes.After optimizing parameters of CO_(2)-O_(2) mixed top blowing,the value of[C]×[O]and the content of TFe in slag were reduced by 1.33×10-4 and 1.27%,respectively,and the dephosphorization rate of the molten steel increased by 2.31%.For the CO_(2) bottom blowing,the[N]content in the molten steel was significantly reduced by 5.7×10^(-6).

A review on bath fluid flow stirring technologies in EAF steelmaking

In the contemporary electric arc furnace(EAF)steelmaking industry,increasing contents and temperature homogenization via fluid flow stirring is found to be an effective method of improving production quality and smelting efficiency.It is a trend for different factories with bowl-shaped furnaces to apply the bath fluidity enhancement technology.EAF has plenty of advantages in modern steelmaking industry,and the improvements on the EAF steelmaking process have come up with two major tasks,namely reduction in energy consumption and tap-to-tap time.The latter task requires an essential understanding of every phase in EAF steelmaking process.The flat bath phase with poor bath fluid flow was crucial to the product quality and metallurgical efficiency considering EAF’s bowl-shaped structure.The research of three stirring bath methods,oxygen jets injection,electromagnetic stirring,and bottom blowing,were introduced,and then the detailed parameters of each method with their influences on molten bath fluidity were presented.

Effect of magnesium injection process on hot metal desulfurization

To solve the technical problems of hot metal desulfurization by injecting magnesium particulate, a new method of hot metal desulfurization by bottom-blowing magnesium vapor combined with mechanical agitation was put forward. The effects of three different desulfurization processes on the desulfurization efficiency were studied in view of thermodynamics and kinetics. It was found that the utilization efficiency of magnesium can reach 82.6% and desulfurization efficiency can reach 86.2% during the first 4 min using the method of magnesium vapor injection combined with mechanical agitation. The gasification of magnesium powder leads to significant splashing and magnesium losses in the process of magnesium powder injection, resulting in a low utilization efficiency of magnesium of 51.8% and a low desulfurization efficiency of 55.76%. Activation energy for a first-order kinetic relationship between magnesium powder and sulfur was measured from the experiments, which was 142.82 kJ/mol in the temperature range of 1573-1723 K. The activation energy of the reaction between magnesium vapor and sulfur was around 54.8-65.0 kJ/mol in the temperature range of 1573-1723 K, which indicates that the desulfurization with magnesium vapor proceeds relatively easier than the desulfurization with magnesium powder.