The different carbon nanotube(CNT)particles(^(@)A and^(@)V)were bed materials in the pseudo-2D tapered fluidized bed(TFB)with/without a distributor.A detailed investigation of the motion mechanism of bubbles was carri...The different carbon nanotube(CNT)particles(^(@)A and^(@)V)were bed materials in the pseudo-2D tapered fluidized bed(TFB)with/without a distributor.A detailed investigation of the motion mechanism of bubbles was carried out.The high-speed photography and image analysis techniques were used to study bubble characteristic and mixing behavior in the tapered angle of TFB without a distributor.The fractal analysis method was used to analyze the degree of particles movement.Results showed that an S-shaped motion trajectory of bubbles was captured in the bed of^(@)V particles.The population of observational bubbles in the bed of^(@)V particles was more than that of^(@)A particles,and the bubble size was smaller in the bed of^(@)V particles than that of^(@)A particles.The motion mechanism of bubbles had been shown to be related to bed materials and initial bed height in terms of analysis and comparison of bubble diameter,bubble aspect ratio and bubble shape factor.Importantly,compared to the TFB with a distributor,the TFB without a distributor had been proved to be beneficial to the CNT fluidization according to the study of bubble characteristic and the degree of the particle movement.Additionally,it was found that the mixing behavior of^(@)V particles was better than^(@)A particles in the tapered angle of TFB without a distributor.展开更多
The three-dimensional(3D) behavior characteristics of bubble rising in gas-liquid two-phase flow are of great importance to study bubbly flow mechanism and guide engineering practice. Based on the dual-perspective ima...The three-dimensional(3D) behavior characteristics of bubble rising in gas-liquid two-phase flow are of great importance to study bubbly flow mechanism and guide engineering practice. Based on the dual-perspective imaging of virtual binocular stereo vision, the 3D behavior characteristics of bubbles in gas-liquid two-phase flow are studied in detail, which effectively increases the projection information of bubbles to acquire more accurate behavior features. In this paper, the variations of bubble equivalent diameter, volume, velocity and trajectory in the rising process are estimated, and the factors affecting bubble behavior characteristics are analyzed. It is shown that the method is real-time and valid, the equivalent diameter of the rising bubble in the stagnant water is periodically changed, and the crests and troughs in the equivalent diameter curve appear alternately. The bubble behavior characteristics as well as the spiral amplitude are affected by the orifice diameter and the gas volume flow.展开更多
Heavy particulate matter (PM) pollution and high energy consumption are the bottlenecks of hydrometallurgy, especially in the electrolysis process. Therefore, an urgent need is to explore PM reduction methods with pro...Heavy particulate matter (PM) pollution and high energy consumption are the bottlenecks of hydrometallurgy, especially in the electrolysis process. Therefore, an urgent need is to explore PM reduction methods with production performance co-benefits. This study presents three PM reduction methods based on controlling operating parameters, i.e., lowering electrolyte temperature, H2SO4 concentration, and current density of the cathode. The optimized conditions were also investigated using the response surface methodology to balance the PM reduction effect and Zn production. The results showed that lowering electrolyte temperature is the most efficient, with an 89.0% reduction in the PM generation flux (GFPM). Reducing H2SO4 concentration led to the minimum side effects on the current efficiency of Zn deposition (CEZn) or power consumption (PC). With the premise of non-deteriorating CEZn and PC, GFPM can be reduced by 86.3% at the optimal condition (electrolyte temperature = 295 K, H2SO4 = 110 g/L, current density = 373 A/m^(2)). In addition, the reduction mechanism was elucidated by comprehensively analyzing bubble characteristics, electrochemical reactions, and surface tension. Results showed that lower electrolyte temperature inhibited the oxygen evolution reaction (OER) and compressed gas volume. Lower H2SO4 concentration inhibited the hydrogen evolution reaction (HER) and reduced electrolyte surface tension. Lower current density inhibited both OER and HER by decreasing the reaction current. The inhibited gas evolutions reduced the microbubbles’ number and size, thereby reducing GFPM. These results may provide energy-efficient PM reduction methods and theoretical hints of exploring cleaner PM reduction approaches for industrial electrolysis.展开更多
There is some disagreement in the published literature regarding the definition and the measurement of housing bubbles in China. Extending the analytical framework of Black et al. (2006), the present paper measures ...There is some disagreement in the published literature regarding the definition and the measurement of housing bubbles in China. Extending the analytical framework of Black et al. (2006), the present paper measures the housing bubbles of China's 35 major cities from the second quarter of 1999 to the second quarter of 2010. The results indicate that the housing bubbles in China's 35 major cities were relatively small in the sample interval, but the bubbles in eastern metropolises, such as Beijing, Shanghai, Shenzhen, Hangzhou and Ningbo, have been relatively big since 2005. The changing tendency of housing bubbles in most cities highly corresponds with the changes in real estate policies. This paper decomposes the housing bubbles of the 35 cities, and finds a great proportion of irrational bubbles rather than rational intrinsic bubbles generated by price speculation. Based on empirical analysis, this paper proposes policy recommendations for preventing the generation and expansion of housing bubbles.展开更多
基金This work is supported by the National Natural Science Foundation of China(51676103)Taishan Scholar Project of Shandong Province(ts20190937).
文摘The different carbon nanotube(CNT)particles(^(@)A and^(@)V)were bed materials in the pseudo-2D tapered fluidized bed(TFB)with/without a distributor.A detailed investigation of the motion mechanism of bubbles was carried out.The high-speed photography and image analysis techniques were used to study bubble characteristic and mixing behavior in the tapered angle of TFB without a distributor.The fractal analysis method was used to analyze the degree of particles movement.Results showed that an S-shaped motion trajectory of bubbles was captured in the bed of^(@)V particles.The population of observational bubbles in the bed of^(@)V particles was more than that of^(@)A particles,and the bubble size was smaller in the bed of^(@)V particles than that of^(@)A particles.The motion mechanism of bubbles had been shown to be related to bed materials and initial bed height in terms of analysis and comparison of bubble diameter,bubble aspect ratio and bubble shape factor.Importantly,compared to the TFB with a distributor,the TFB without a distributor had been proved to be beneficial to the CNT fluidization according to the study of bubble characteristic and the degree of the particle movement.Additionally,it was found that the mixing behavior of^(@)V particles was better than^(@)A particles in the tapered angle of TFB without a distributor.
基金supported by the National Natural Science Foundation of China(Nos.61671321,51475328 and 61372143)the Natural Science Foundation of Tianjin in China(No.17JCYBJC18400)
文摘The three-dimensional(3D) behavior characteristics of bubble rising in gas-liquid two-phase flow are of great importance to study bubbly flow mechanism and guide engineering practice. Based on the dual-perspective imaging of virtual binocular stereo vision, the 3D behavior characteristics of bubbles in gas-liquid two-phase flow are studied in detail, which effectively increases the projection information of bubbles to acquire more accurate behavior features. In this paper, the variations of bubble equivalent diameter, volume, velocity and trajectory in the rising process are estimated, and the factors affecting bubble behavior characteristics are analyzed. It is shown that the method is real-time and valid, the equivalent diameter of the rising bubble in the stagnant water is periodically changed, and the crests and troughs in the equivalent diameter curve appear alternately. The bubble behavior characteristics as well as the spiral amplitude are affected by the orifice diameter and the gas volume flow.
基金supported by the National Natural Science Foundation of China(No.22106081)the Natural Science of Foundation of Shandong Province,China(No.ZR202103040646)+2 种基金the special fund of State Key Joint Laboratory of Environment Simulation and Pollution Control(China)(No.20K09ESPCT)the Major Basic Research Projects of Natural Science Foundation of Shandong Province(China)(No.ZR2020KE025)the Fundamental Research Funds for the Central Universities(China)(No.22120220166).
文摘Heavy particulate matter (PM) pollution and high energy consumption are the bottlenecks of hydrometallurgy, especially in the electrolysis process. Therefore, an urgent need is to explore PM reduction methods with production performance co-benefits. This study presents three PM reduction methods based on controlling operating parameters, i.e., lowering electrolyte temperature, H2SO4 concentration, and current density of the cathode. The optimized conditions were also investigated using the response surface methodology to balance the PM reduction effect and Zn production. The results showed that lowering electrolyte temperature is the most efficient, with an 89.0% reduction in the PM generation flux (GFPM). Reducing H2SO4 concentration led to the minimum side effects on the current efficiency of Zn deposition (CEZn) or power consumption (PC). With the premise of non-deteriorating CEZn and PC, GFPM can be reduced by 86.3% at the optimal condition (electrolyte temperature = 295 K, H2SO4 = 110 g/L, current density = 373 A/m^(2)). In addition, the reduction mechanism was elucidated by comprehensively analyzing bubble characteristics, electrochemical reactions, and surface tension. Results showed that lower electrolyte temperature inhibited the oxygen evolution reaction (OER) and compressed gas volume. Lower H2SO4 concentration inhibited the hydrogen evolution reaction (HER) and reduced electrolyte surface tension. Lower current density inhibited both OER and HER by decreasing the reaction current. The inhibited gas evolutions reduced the microbubbles’ number and size, thereby reducing GFPM. These results may provide energy-efficient PM reduction methods and theoretical hints of exploring cleaner PM reduction approaches for industrial electrolysis.
基金supported by the National Natural Science Foundation of China(No.71173223)the Fundamental Research Funds for the Central Universitiesthe Research Funds of Renmin University of China(No.10XNF049)
文摘There is some disagreement in the published literature regarding the definition and the measurement of housing bubbles in China. Extending the analytical framework of Black et al. (2006), the present paper measures the housing bubbles of China's 35 major cities from the second quarter of 1999 to the second quarter of 2010. The results indicate that the housing bubbles in China's 35 major cities were relatively small in the sample interval, but the bubbles in eastern metropolises, such as Beijing, Shanghai, Shenzhen, Hangzhou and Ningbo, have been relatively big since 2005. The changing tendency of housing bubbles in most cities highly corresponds with the changes in real estate policies. This paper decomposes the housing bubbles of the 35 cities, and finds a great proportion of irrational bubbles rather than rational intrinsic bubbles generated by price speculation. Based on empirical analysis, this paper proposes policy recommendations for preventing the generation and expansion of housing bubbles.