Ash-rich pyroclastic flows from the cataclysmic eruption of Mount Mazama (~7700 yr. B. P.), Cascade volcanic arc, Oregon, entered and blocked the narrow, bedrock-lined canyon of the Williamson River approximately 35 t...Ash-rich pyroclastic flows from the cataclysmic eruption of Mount Mazama (~7700 yr. B. P.), Cascade volcanic arc, Oregon, entered and blocked the narrow, bedrock-lined canyon of the Williamson River approximately 35 to 44 km from the source volcano. The blockage impounded a body of water which then released producing four stratigraphic units in the downstream debris fan. The four stratigraphic units are a boulder core comprised of locally sourced bedrock boulders and three sand-rich units including a fine-grained sand unit, a sandy pumice gravel (±basalt/hydrovolcanic tuff) unit, and a pumice pebble-bearing, crystal-rich sand unit. Hand-drilled auger holes up to ~1.6 m deep were used to obtain samples of the sand-rich units. Units were delimited using surface and down-hole observations, composition and texture, estimated density, statistical parameters of grain size, and vertical and lateral distribution of properties. Overtopping followed by rapid incision into the ash-rich pyroclastic flows progressively cleared the canyon, but a bedrock knickpoint near the head of the canyon limited the volume of debris available for transport to about 0.04 km<sup>3</sup> to 0.08 km<sup>3</sup>. Co-deposition of bedrock boulders and lithic-rich sand was followed by rapid deposition with minimal reworking of remobilized pyroclastics. Continued draining of the impounded lake sent hyperconcentrated flows onto the debris fan depositing pumice-rich gravels that graded upward to crystal-rich sands.展开更多
The exploration of novel multivariate heterostructures has emerged as a pivotal strategy for developing high-performance electromagnetic wave(EMW)absorption materials.However,the loss mechanism in traditional heterost...The exploration of novel multivariate heterostructures has emerged as a pivotal strategy for developing high-performance electromagnetic wave(EMW)absorption materials.However,the loss mechanism in traditional heterostructures is relatively simple,guided by empirical observations,and is not monotonous.In this work,we presented a novel semiconductor-semiconductor-metal heterostructure sys-tem,Mo-MXene/Mo-metal sulfides(metal=Sn,Fe,Mn,Co,Ni,Zn,and Cu),including semiconductor junctions and Mott-Schottky junctions.By skillfully combining these distinct functional components(Mo-MXene,MoS_(2),metal sulfides),we can engineer a multiple heterogeneous interface with superior absorption capabilities,broad effective absorption bandwidths,and ultrathin matching thickness.The successful establishment of semiconductor-semiconductor-metal heterostructures gives rise to a built-in electric field that intensifies electron transfer,as confirmed by density functional theory,which collaborates with multiple dielectric polarization mechanisms to substantially amplify EMW absorption.We detailed a successful synthesis of a series of Mo-MXene/Mo-metal sulfides featuring both semiconductor-semiconductor and semiconductor-metal interfaces.The achievements were most pronounced in Mo-MXene/Mo-Sn sulfide,which achieved remarkable reflection loss values of-70.6 dB at a matching thickness of only 1.885 mm.Radar cross-section calculations indicate that these MXene/Mo-metal sulfides have tremendous potential in practical military stealth technology.This work marks a departure from conventional component design limitations and presents a novel pathway for the creation of advanced MXene-based composites with potent EMW absorption capabilities.展开更多
Constructing a built-in electric field has emerged as a key strategy for enhancing charge separation and transfer,thereby improving photoelectrochemical performance.Recently,considerable efforts have been devoted to t...Constructing a built-in electric field has emerged as a key strategy for enhancing charge separation and transfer,thereby improving photoelectrochemical performance.Recently,considerable efforts have been devoted to this endeavor.This review systematically summarizes the impact of built-in electric fields on enhancing charge separation and transfer mechanisms,focusing on the modulation of built-in electric fields in terms of depth and orderliness.First,mechanisms and tuning strategies for built-in electric fields are explored.Then,the state-of-the-art works regarding built-in electric fields for modulating charge separation and transfer are summarized and categorized according to surface and interface depth.Finally,current strategies for constructing bulk built-in electric fields in photoelectrodes are explored,and insights into future developments for enhancing charge separation and transfer in high-performance photoelectrochemical applications are provided.展开更多
Deepwater oil and gas exploration is the key to sustainable breakthroughs in petroleum exploration worldwide.The Central Canyon gas field has confirmed the Lingshui Sag is a hydrocarbon-generating sag,and the deepwate...Deepwater oil and gas exploration is the key to sustainable breakthroughs in petroleum exploration worldwide.The Central Canyon gas field has confirmed the Lingshui Sag is a hydrocarbon-generating sag,and the deepwater reservoirs in the Lingshui Sag still have more fabulous oil and gas exploration potential.Based on drilling data and three-dimensional(3D)seismic data,this paper uses seismic facies analysis,seismic attribute analysis,and coherence slice analysis to identify the types of submarine fans(lobe-shaped and band-shaped submarine fans)that developed in the Lingshui Sag during the Middle Miocene,clarify the source-to-sink system of the submarine fans and discuss the genesis mechanism of the submarine fans.The results show that:(1)the deepwater source-to-sink system of the Lingshui Sag in the Middle Miocene mainly consisted of a“delta(sediment supply)-submarine canyon(sediment transport channel)-submarine fan(deepwater sediment sink)”association;(2)the main factor controlling the formation of the submarine fans developed in the Lingshui Sag was on the relative sea level decline;and(3)the bottom current reworked the lobe-shaped submarine fan that developed in the northern Lingshui Sag and formed the band-shaped submarine fan with a greater sand thickness.This paper aims to provide practical geological knowledge for subsequent petroleum exploration and development in the deepwater area of the Qiongdongnan Basin through a detailed analysis of the Middle Miocene submarine fan sedimentary system developed in the Lingshui Sag.展开更多
Lithium sulfur(Li-S)battery is a kind of burgeoning energy storage system with high energy density.However,the electrolyte-soluble intermediate lithium polysulfides(Li PSs)undergo notorious shuttle effect,which seriou...Lithium sulfur(Li-S)battery is a kind of burgeoning energy storage system with high energy density.However,the electrolyte-soluble intermediate lithium polysulfides(Li PSs)undergo notorious shuttle effect,which seriously hinders the commercialization of Li-S batteries.Herein,a unique VSe_(2)/V_(2)C heterostructure with local built-in electric field was rationally engineered from V_(2)C parent via a facile thermal selenization process.It exquisitely synergizes the strong affinity of V_(2)C with the effective electrocatalytic activity of VSe_(2).More importantly,the local built-in electric field at the heterointerface can sufficiently promote the electron/ion transport ability and eventually boost the conversion kinetics of sulfur species.The Li-S battery equipped with VSe_(2)/V_(2)C-CNTs-PP separator achieved an outstanding initial specific capacity of 1439.1 m A h g^(-1)with a high capacity retention of 73%after 100 cycles at0.1 C.More impressively,a wonderful capacity of 571.6 mA h g^(-1)was effectively maintained after 600cycles at 2 C with a capacity decay rate of 0.07%.Even under a sulfur loading of 4.8 mg cm^(-2),areal capacity still can be up to 5.6 m A h cm^(-2).In-situ Raman tests explicitly illustrate the effectiveness of VSe_(2)/V_(2)C-CNTs modifier in restricting Li PSs shuttle.Combined with density functional theory calculations,the underlying mechanism of VSe_(2)/V_(2)C heterostructure for remedying Li PSs shuttling and conversion kinetics was deciphered.The strategy of constructing VSe_(2)/V_(2)C heterocatalyst in this work proposes a universal protocol to design metal selenide-based separator modifier for Li-S battery.Besides,it opens an efficient avenue for the separator engineering of Li-S batteries.展开更多
树是连通的无圈图,研究树的拉普拉斯矩阵具有重要的图论和实际意义.设G是一个有n个点和m个边的图,A(G)和D(G)分别是图G的邻接矩阵和对角度矩阵,那么G的拉普拉斯矩阵定义为L(G)=D(G)-A(G).LI矩阵定义为LI(G)=L(G)-(2m/n)I_(n),其中I_(n)...树是连通的无圈图,研究树的拉普拉斯矩阵具有重要的图论和实际意义.设G是一个有n个点和m个边的图,A(G)和D(G)分别是图G的邻接矩阵和对角度矩阵,那么G的拉普拉斯矩阵定义为L(G)=D(G)-A(G).LI矩阵定义为LI(G)=L(G)-(2m/n)I_(n),其中I_(n)是单位矩阵.图的LI矩阵的Ky Fan k-范数代表了拉普拉斯特征值和拉普拉斯特征值平均值之间距离的有序和.研究了双星图的LI矩阵的Ky Fan k-范数,证明了双星图的LI矩阵的Ky Fan k-范数满足文献[6]中提出的猜想.展开更多
Constructing heterostructure is considered as an effective strategy to address the sluggish electronic and ionic kinetics of anode materials for sodium ion batteries(SIBs).However,realizing the orientated growth and u...Constructing heterostructure is considered as an effective strategy to address the sluggish electronic and ionic kinetics of anode materials for sodium ion batteries(SIBs).However,realizing the orientated growth and uniform distribution of the heterostructure is still a great challenge.Herein,the regulated novel CoSe_(2)/NiSe_(2)heterostructure confined in N-doped carbon nanofibers(CoSe_(2)/NiSe_(2)@N-C)are prepared by using Co/Ni-ZIF template,in which,the CoSe_(2)/NiSe_(2)heterostructures realize uniform distribution on a micro level.Benefiting from the unique heterostructure and N-doped carbon nanofibers,the CoSe_(2)/NiSe_(2)@N-C deliveries superior rate capability and durable cycle lifespan with a reversible capacity of 400.5 mA h g^(-1)after 5000 cycles at 2 A g^(-1).The Na-ion full battery with CoSe_(2)/NiSe_(2)@N-C anode and layered oxide cathode displays a remarkable energy density of 563 W h kg^(-1)with 241.1 W kg^(-1)at 0.1 A g^(-1).The theoretical calculations disclose that the periodic and directional built-in electric-field along with the heterointerfaces of CoSe_(2)/NiSe_(2)@N-C can accelerate electrochemical reaction kinetics.The in(ex)situ experimental measurements reveal the reversible conversion reaction and stable structure of CoSe_(2)/NiSe_(2)@N-C during Na+insertion/extraction.The study highlights the potential ability of precisely controlled heterostructure to stimulate the electrochemical performances of advanced anode for SIBs.展开更多
It is of great significance to study the effects of desert plants on soil enzyme activities and soil organic carbon(SOC)for maintaining the stability of the desert ecosystem.In this study,we studied the responses of s...It is of great significance to study the effects of desert plants on soil enzyme activities and soil organic carbon(SOC)for maintaining the stability of the desert ecosystem.In this study,we studied the responses of soil enzyme activities and SOC fractions(particulate organic carbon(POC)and mineral-associated organic carbon(MAOC))to five typical desert plant communities(Convolvulus tragacanthoides,Ephedra rhytidosperma,Stipa breviflora,Stipa tianschanica var.gobica,and Salsola laricifolia communities)in the proluvial fan in the eastern foothills of the Helan Mountain in Ningxia Hui Autonomous Region,China.We recorded the plant community information mainly including the plant coverage and herb and shrub species,and obtained the aboveground biomass and plant species diversity through sample surveys in late July 2023.Soil samples were also collected at depths of 0–10 cm(topsoil)and 10–20 cm(subsoil)to determine the soil physicochemical properties and enzyme activities.The results showed that the plant coverage and aboveground biomass of S.laricifolia community were significantly higher than those of C.tragacanthoides,S.breviflora,and S.tianschanica var.gobica communities(P<0.05).Soil enzyme activities varied among different plant communities.In the topsoil,the enzyme activities of alkaline phosphatase(ALP)andβ-1,4-glucosidas(βG)were significantly higher in E.rhytidosperma and S.tianschanica var.gobica communities than in other plant communities(P<0.05).The topsoil had higher POC and MAOC contents than the subsoil.Specifically,the content of POC in the topsoil was 18.17%–42.73%higher than that in the subsoil.The structural equation model(SEM)indicated that plant species diversity,soil pH,and soil water content(SWC)were the main factors influencing POC and MAOC.The soil pH inhibited the formation of POC and promoted the formation of MAOC.Conversely,SWC stimulated POC production and hindered MAOC formation.Our study aimed to gain insight into the effects of desert plant communities on soil enzyme activities and SOC fractions,as well as the drivers of SOC fractions in the proluvial fan in the eastern foothills of the Helan Mountain and other desert ecosystems.展开更多
Developing efficient energy storage for sodium-ion batteries(SIBs)by creating high-performance heterojunctions and understanding their interfacial interaction at the atomic/molecular level holds promise but is also ch...Developing efficient energy storage for sodium-ion batteries(SIBs)by creating high-performance heterojunctions and understanding their interfacial interaction at the atomic/molecular level holds promise but is also challenging.Besides,sluggish reaction kinetics at low temperatures restrict the operation of SIBs in cold climates.Herein,cross-linking nanoarchitectonics of WS_(2)/Ti_(3)C_(2)T_(x) heterojunction,featuring built-in electric field(BIEF),have been developed,employing as a model to reveal the positive effect of heterojunction design and BIEF for modifying the reaction kinetics and electrochemical activity.Particularly,the theoretical analysis manifests the discrepancy in work functions leads to the electronic flow from the electron-rich Ti_(3)C_(2)T_(x) to layered WS_(2),spontaneously forming the BIEF and“ion reservoir”at the heterogeneous interface.Besides,the generation of cross-linking pathways further promotes the transportation of electrons/ions,which guarantees rapid diffusion kinetics and excellent structure coupling.Consequently,superior sodium storage performance is obtained for the WS_(2)/Ti_(3)C_(2)T_(x) heterojunction,with only 0.2%decay per cycle at 5.0 A g^(-1)(25℃)up to 1000 cycles and a high capacity of 293.5 mA h g^(-1)(0.1A g^(-1)after 100 cycles)even at-20℃.Importantly,the spontaneously formed BIEF,accompanied by“ion reservoir”,in heterojunction provides deep understandings of the correlation between structure fabricated and performance obtained.展开更多
As energy efficiency and indoor comfort increasingly become key standards in modern residential and office environments,research on intelligent fan speed control systems has become particularly important.This study ai...As energy efficiency and indoor comfort increasingly become key standards in modern residential and office environments,research on intelligent fan speed control systems has become particularly important.This study aims to develop a temperature-feedback-based fan speed optimization strategy to achieve higher energy efficiency and user comfort.Firstly,by analyzing existing fan speed control technologies,their main limitations are identified,such as the inability to achieve smooth speed transitions.To address this issue,a BP-PID speed control algorithm is designed,which dynamically adjusts fan speed based on indoor temperature changes.Experimental validation demonstrates that the designed system can achieve smooth speed transitions compared to traditional fan systems while maintaining stable indoor temperatures.Furthermore,the real-time responsiveness of the system is crucial for enhancing user comfort.Our research not only demonstrates the feasibility of temperature-based fan speed optimization strategies in both theory and practice but also provides valuable insights for energy management in future smart home environments.Ultimately,this research outcome will facilitate the development of smart home systems and have a positive impact on environmental sustainability.展开更多
The practical application of lithium-sulfur(Li-S)batteries is greatly hindered by soluble polysulfides shuttling and sluggish sulfur redox kinetics.Rational design of multifunctional hybrid materials with superior ele...The practical application of lithium-sulfur(Li-S)batteries is greatly hindered by soluble polysulfides shuttling and sluggish sulfur redox kinetics.Rational design of multifunctional hybrid materials with superior electronic conductivity and high electrocatalytic activity,e.g.,heterostructures,is a promising strategy to solve the above obstacles.Herein,a binary metal sulfide MnS-MoS_(2) heterojunction electrocatalyst is first designed for the construction of high-sulfur-loaded and durable Li-S batteries.The MnS-MoS_(2) p-n heterojunction shows a unique structure of MoS_(2) nanosheets decorated with ample MnS nanodots,which contributes to the formation of a strong built-in electric field at the two-phase interface.The MnS-MoS_(2) hybrid host shows strong soluble polysulfide affinity,enhanced electronic conductivity,and exceptional catalytic effect on sulfur reduction.Benefiting from the synergistic effect,the as-derived S/MnS-MoS_(2) cathode delivers a superb rate capability(643 m A h g^(-1)at 6 C)and a durable cyclability(0.048%decay per cycle over 1000 cycles).More impressively,an areal capacity of 9.9 m A h cm^(-2)can be achieved even under an extremely high sulfur loading of 14.7 mg cm^(-2)and a low electrolyte to sulfur ratio of 2.9μL mg^(-1).This work provides an in-depth understanding of the interfacial catalytic effect of binary metal compound heterojunctions on sulfur reaction kinetics.展开更多
Zhao Rukuo's Zhu Fan Zhi in the Southern Song dynasty was the first book in the history of China to systematically describe the “Maritime Silk Road”, recording the geography, products, customs, trade, etc. of mo...Zhao Rukuo's Zhu Fan Zhi in the Southern Song dynasty was the first book in the history of China to systematically describe the “Maritime Silk Road”, recording the geography, products, customs, trade, etc. of more than 50 foreign countries and regions. The book included a large amount of medical literature, introducing medical customs and the production of drugs in various places, as well as the efficacy of some medicine. These materials are of unique value for understanding the medicine trade in the Song dynasty, and even the medical culture along the “Maritime Road of Aromatic Medicine”.展开更多
To overcome the serious technological issues affecting lithium-sulfur(Li-S) batteries,such as sluggish sulfur redox kinetics and the detrimental shuttle effect,heterostructure engineering has been investigated as a st...To overcome the serious technological issues affecting lithium-sulfur(Li-S) batteries,such as sluggish sulfur redox kinetics and the detrimental shuttle effect,heterostructure engineering has been investigated as a strategy to effectively capture soluble lithium polysulfide intermediates and promote their conversion reaction by integrating highly polar metal oxides with catalytically active metals sulfides.However,to fully exploit the outstanding properties of heterostructure-based composites,their detailed structure and interfacial contacts should be designed rationally.Herein,optimally arranged TiO_(2)and MoS_(2)-based heterostructures(TiO_(2)@MoS_(2)) are fabricated on carbon cloth as a multifunctional interlayer to efficiently trap polysulfide intermediates and accelerate their redox kinetics.Owing to the synergistic effects between TiO_(2)and MoS_(2)and the uniform heterointerface distribution that induces the ideally oriented built-in electric field,Li-S batteries with TiO_(2)@MoS_(2)interlayers exhibit high rate capability(601 mA h g^(-1)at 5 C),good cycling stability(capacity-fade rate of 0.067% per cycle over 500 cycles at2 C),and satisfactory areal capacity(5.2 mA h cm^(-2)) under an increased sulfur loading of 5.2 mg cm^(-2).Moreover,by comparing with a MoS_(2)@TiO_(2)interlayer composed of reversely arranged heterostructures,the effect of the built-in electric field’s direction on the electrocatalytic reactions of polysulfide intermediates is thoroughly investigated for the first time.The superior electrocatalytic activities of the rationally arranged TiO_(2)@MoS_(2)interlayer demonstrate the importance of optimizing the built-in electric field of heterostructures for producing high-performance Li-S batteries.展开更多
This study focuses on a single-stage axial flow fan, investigating the effect of three kinds of wave leading edge stator blades on its noise reduction. The DDES method and the duct acoustic analogy theory based on the...This study focuses on a single-stage axial flow fan, investigating the effect of three kinds of wave leading edge stator blades on its noise reduction. The DDES method and the duct acoustic analogy theory based on the penetrable data surface were used for noise prediction. The results showed that the three kinds of wave leading edge blades were effective in reducing the rotor-stator interaction tonal noise and also have a certain inhibitory effect on broadband noise. The A10W15 stator blade can effectively reduce broadband noise in the frequency range of 2200 - 4200 Hz. When the amplitude is increased to 20, the noise reduction effect is further enhanced. However, when the amplitude is increased to 30, the broadband noise reduction effect is no longer significant. Further research shows that the wave leading edge stator blades can significantly change the pressure fluctuation distribution on the leading edge and suction surface, which control the modal energy distribution. Finally, this paper analyzed multiple factors affecting the broadband noise reduction, such as the noise source cut-off and cut-on effect and correlation. The purpose of this paper is to explore the laws of the influence of wave leading edge blades on the duct noise of real fan, and to reveal its noise control mechanism. .展开更多
There are many large-scale Cenozoic sedimentary basins with plentiful river deltas,deep-water fans and carbonate platforms in the southern South China Sea.The Crocker Fan was deposited as a typical submarine fan durin...There are many large-scale Cenozoic sedimentary basins with plentiful river deltas,deep-water fans and carbonate platforms in the southern South China Sea.The Crocker Fan was deposited as a typical submarine fan during the late Eocene–early Miocene,and stretches extensively across the entire Sarawak–Sabah of the northern Borneo area.However,systematic analyses are still lacking regarding its sediment composition and potential source suppliers.No consensus has been reached yet on the provenance evolution and sedimentary infilling processes,which seriously impeded the oil-and-gas exploration undertakings.By combining with sedimentaryfacies identification,heavy mineral assemblages,elemental geochemistry and detrital zircon U-Pb dating,this paper aims to generalize an integrated analysis on the potential provenance terranes and restore source-to-sink pathways of the Crocker Fan.In general,the Crocker Fan was initially formed over the Cretaceous–lower/middle Eocene Rajang Group by an angular Rajang unconformity.The continual southward subduction of the protoSouth China Sea resulted in magmatic activities and subsequent regional deformation and thrusting along the Lupar Line in the northern Borneo.The lowermost Crocker sequence is featured by a thick conglomerate layer sourced from in-situ or adjacent paleo-uplifts.From the late Eocene to the early Miocene,the Crocker Fan was constantly delivered with voluminous detritus from the Malay Peninsula of the western Sundaland.The Zengmu Basin was widely deposited with delta plain and neritic facies sediments,while the Brunei-Sabah Basin,to the farther east,was ubiquitously characterized by turbiditic sequences.The Crocker Fan successions are overall thick layers of modest-grained sandstones,which formed high-quality reservoirs in the southern South China Sea region.展开更多
In this study, we tried to improve the performance by giving a pre-swirling flow to the radial inflow that occurred in the semi-opened axial fan. In addition, the flow fields of rotor outlet were clarified experimenta...In this study, we tried to improve the performance by giving a pre-swirling flow to the radial inflow that occurred in the semi-opened axial fan. In addition, the flow fields of rotor outlet were clarified experimentally, and the effect of pre-swirling flow was considered. The experiment was carried out using a performance test wind tunnel with a square cross section of 880 mm. Three types of casings were prepared, in which the blade tip protruded 0%, 20%, and 40% of the meridional chord length. They were called R25, R15, and R05, respectively, in the casing bellmouth model code. Guide blades for generating a pre-swirling flow were installed on the vertical wall surface of the casing. In addition, a vertical wall was installed 60% upstream of the meridional chord length as an obstacle to prevent axial inflow. The velocity fields of the rotor outlet were measured using a hot-wire anemometer. From the results, the pre-swirling flow did not significantly affect the fan performance. When there was no obstacles wall upstream, there was a partial increase in efficiency, but the difference was not so large. When there was an obstacle wall upstream, the efficiency increased overall in the case of R15, but in the case of R05, the efficiency increased only in the low flow rate region, and conversely decreased in the high flow rate region. By observing the blade outlet flow fields when the performance was improved, it was confirmed that the influence of the tip leakage vortex was weakened.展开更多
Among the common hazards related to alluvial fans,flooding is one of the most important.Nonetheless,in populated alluvial fans,not only the natural processes are effective in floods,but the artificial structures and m...Among the common hazards related to alluvial fans,flooding is one of the most important.Nonetheless,in populated alluvial fans,not only the natural processes are effective in floods,but the artificial structures and modifications can change the behavior of flooding and its potential risks.This study aims to indicate the flood-prone landforms in a set of populated alluvial fans in an arid region and investigate the role of anthropogenic activities in controlling/exacerbating flooding in alluvial fans.To achieve this goal,15 Ground Range Detected in High resolution(GRDH)SAR Sentinel-1 images,covering a total of 24 alluvial fans,were acquired.Pre-processing and post-processing steps were applied to all images to identify flood-prone sections of the studied alluvial fans.The results showed that feeder channels,spreading sites,and wide interfluves are the most flood-prone landforms of alluvial fans.In terms of anthropogenic modifications to mitigate flooding,a rampart system is distributed in the study area.Ramparts are levee like structures formed from the fan material.They aim to mitigate flood hazard on residential areas,infrastructures,and agricultural lands of the study area.Results show that the rampart system can reduce the danger of floods,but it cannot be considered a long-term solution.Therefore,a comprehensive flood protection system distributed throughout the whole alluvial fan system is needed.Results also reveal that in regions where flood monitoring is challenging,SAR images can be used as a freely available data set to monitor and identify flooding hotspots.展开更多
文摘Ash-rich pyroclastic flows from the cataclysmic eruption of Mount Mazama (~7700 yr. B. P.), Cascade volcanic arc, Oregon, entered and blocked the narrow, bedrock-lined canyon of the Williamson River approximately 35 to 44 km from the source volcano. The blockage impounded a body of water which then released producing four stratigraphic units in the downstream debris fan. The four stratigraphic units are a boulder core comprised of locally sourced bedrock boulders and three sand-rich units including a fine-grained sand unit, a sandy pumice gravel (±basalt/hydrovolcanic tuff) unit, and a pumice pebble-bearing, crystal-rich sand unit. Hand-drilled auger holes up to ~1.6 m deep were used to obtain samples of the sand-rich units. Units were delimited using surface and down-hole observations, composition and texture, estimated density, statistical parameters of grain size, and vertical and lateral distribution of properties. Overtopping followed by rapid incision into the ash-rich pyroclastic flows progressively cleared the canyon, but a bedrock knickpoint near the head of the canyon limited the volume of debris available for transport to about 0.04 km<sup>3</sup> to 0.08 km<sup>3</sup>. Co-deposition of bedrock boulders and lithic-rich sand was followed by rapid deposition with minimal reworking of remobilized pyroclastics. Continued draining of the impounded lake sent hyperconcentrated flows onto the debris fan depositing pumice-rich gravels that graded upward to crystal-rich sands.
基金supported by the National Natural Science Foundation of China(No.22269010,52231007,12327804,T2321003,22088101)the Jiangxi Provincial Natural Science Foundation(No.20224BAB214021)+1 种基金the Major Research Program of Jingdezhen Ceramic Industry(No.2023ZDGG002)the Ministry of Science and Technology of China(973 Project No.2021YFA1200600).
文摘The exploration of novel multivariate heterostructures has emerged as a pivotal strategy for developing high-performance electromagnetic wave(EMW)absorption materials.However,the loss mechanism in traditional heterostructures is relatively simple,guided by empirical observations,and is not monotonous.In this work,we presented a novel semiconductor-semiconductor-metal heterostructure sys-tem,Mo-MXene/Mo-metal sulfides(metal=Sn,Fe,Mn,Co,Ni,Zn,and Cu),including semiconductor junctions and Mott-Schottky junctions.By skillfully combining these distinct functional components(Mo-MXene,MoS_(2),metal sulfides),we can engineer a multiple heterogeneous interface with superior absorption capabilities,broad effective absorption bandwidths,and ultrathin matching thickness.The successful establishment of semiconductor-semiconductor-metal heterostructures gives rise to a built-in electric field that intensifies electron transfer,as confirmed by density functional theory,which collaborates with multiple dielectric polarization mechanisms to substantially amplify EMW absorption.We detailed a successful synthesis of a series of Mo-MXene/Mo-metal sulfides featuring both semiconductor-semiconductor and semiconductor-metal interfaces.The achievements were most pronounced in Mo-MXene/Mo-Sn sulfide,which achieved remarkable reflection loss values of-70.6 dB at a matching thickness of only 1.885 mm.Radar cross-section calculations indicate that these MXene/Mo-metal sulfides have tremendous potential in practical military stealth technology.This work marks a departure from conventional component design limitations and presents a novel pathway for the creation of advanced MXene-based composites with potent EMW absorption capabilities.
基金financially supported by the Industrial Technology Innovation Program of IMAST(No.2023JSYD 01003)the National Natural Science Foundation of China(Nos.52104292 and U2341209)。
文摘Constructing a built-in electric field has emerged as a key strategy for enhancing charge separation and transfer,thereby improving photoelectrochemical performance.Recently,considerable efforts have been devoted to this endeavor.This review systematically summarizes the impact of built-in electric fields on enhancing charge separation and transfer mechanisms,focusing on the modulation of built-in electric fields in terms of depth and orderliness.First,mechanisms and tuning strategies for built-in electric fields are explored.Then,the state-of-the-art works regarding built-in electric fields for modulating charge separation and transfer are summarized and categorized according to surface and interface depth.Finally,current strategies for constructing bulk built-in electric fields in photoelectrodes are explored,and insights into future developments for enhancing charge separation and transfer in high-performance photoelectrochemical applications are provided.
基金The National Natural Science Foundation of China under contract No.42372154。
文摘Deepwater oil and gas exploration is the key to sustainable breakthroughs in petroleum exploration worldwide.The Central Canyon gas field has confirmed the Lingshui Sag is a hydrocarbon-generating sag,and the deepwater reservoirs in the Lingshui Sag still have more fabulous oil and gas exploration potential.Based on drilling data and three-dimensional(3D)seismic data,this paper uses seismic facies analysis,seismic attribute analysis,and coherence slice analysis to identify the types of submarine fans(lobe-shaped and band-shaped submarine fans)that developed in the Lingshui Sag during the Middle Miocene,clarify the source-to-sink system of the submarine fans and discuss the genesis mechanism of the submarine fans.The results show that:(1)the deepwater source-to-sink system of the Lingshui Sag in the Middle Miocene mainly consisted of a“delta(sediment supply)-submarine canyon(sediment transport channel)-submarine fan(deepwater sediment sink)”association;(2)the main factor controlling the formation of the submarine fans developed in the Lingshui Sag was on the relative sea level decline;and(3)the bottom current reworked the lobe-shaped submarine fan that developed in the northern Lingshui Sag and formed the band-shaped submarine fan with a greater sand thickness.This paper aims to provide practical geological knowledge for subsequent petroleum exploration and development in the deepwater area of the Qiongdongnan Basin through a detailed analysis of the Middle Miocene submarine fan sedimentary system developed in the Lingshui Sag.
基金supported by the National Natural Science Foundation of China(No.52072099)the Joint Guidance Project of the Natural Science Foundation of Heilongjiang Province,China(No.LH2022E093)the Team Program of the Natural Science Foundation of Heilongjiang Province,China(No.TD2021E005)。
文摘Lithium sulfur(Li-S)battery is a kind of burgeoning energy storage system with high energy density.However,the electrolyte-soluble intermediate lithium polysulfides(Li PSs)undergo notorious shuttle effect,which seriously hinders the commercialization of Li-S batteries.Herein,a unique VSe_(2)/V_(2)C heterostructure with local built-in electric field was rationally engineered from V_(2)C parent via a facile thermal selenization process.It exquisitely synergizes the strong affinity of V_(2)C with the effective electrocatalytic activity of VSe_(2).More importantly,the local built-in electric field at the heterointerface can sufficiently promote the electron/ion transport ability and eventually boost the conversion kinetics of sulfur species.The Li-S battery equipped with VSe_(2)/V_(2)C-CNTs-PP separator achieved an outstanding initial specific capacity of 1439.1 m A h g^(-1)with a high capacity retention of 73%after 100 cycles at0.1 C.More impressively,a wonderful capacity of 571.6 mA h g^(-1)was effectively maintained after 600cycles at 2 C with a capacity decay rate of 0.07%.Even under a sulfur loading of 4.8 mg cm^(-2),areal capacity still can be up to 5.6 m A h cm^(-2).In-situ Raman tests explicitly illustrate the effectiveness of VSe_(2)/V_(2)C-CNTs modifier in restricting Li PSs shuttle.Combined with density functional theory calculations,the underlying mechanism of VSe_(2)/V_(2)C heterostructure for remedying Li PSs shuttling and conversion kinetics was deciphered.The strategy of constructing VSe_(2)/V_(2)C heterocatalyst in this work proposes a universal protocol to design metal selenide-based separator modifier for Li-S battery.Besides,it opens an efficient avenue for the separator engineering of Li-S batteries.
文摘树是连通的无圈图,研究树的拉普拉斯矩阵具有重要的图论和实际意义.设G是一个有n个点和m个边的图,A(G)和D(G)分别是图G的邻接矩阵和对角度矩阵,那么G的拉普拉斯矩阵定义为L(G)=D(G)-A(G).LI矩阵定义为LI(G)=L(G)-(2m/n)I_(n),其中I_(n)是单位矩阵.图的LI矩阵的Ky Fan k-范数代表了拉普拉斯特征值和拉普拉斯特征值平均值之间距离的有序和.研究了双星图的LI矩阵的Ky Fan k-范数,证明了双星图的LI矩阵的Ky Fan k-范数满足文献[6]中提出的猜想.
基金financially supported by the Natural Science Foundation of Shandong Province(ZR2021QB055,ZR2023MB017,ZR2022JQ10)the National Natural Science Foundation of China(21901146,220781792,22274083)。
文摘Constructing heterostructure is considered as an effective strategy to address the sluggish electronic and ionic kinetics of anode materials for sodium ion batteries(SIBs).However,realizing the orientated growth and uniform distribution of the heterostructure is still a great challenge.Herein,the regulated novel CoSe_(2)/NiSe_(2)heterostructure confined in N-doped carbon nanofibers(CoSe_(2)/NiSe_(2)@N-C)are prepared by using Co/Ni-ZIF template,in which,the CoSe_(2)/NiSe_(2)heterostructures realize uniform distribution on a micro level.Benefiting from the unique heterostructure and N-doped carbon nanofibers,the CoSe_(2)/NiSe_(2)@N-C deliveries superior rate capability and durable cycle lifespan with a reversible capacity of 400.5 mA h g^(-1)after 5000 cycles at 2 A g^(-1).The Na-ion full battery with CoSe_(2)/NiSe_(2)@N-C anode and layered oxide cathode displays a remarkable energy density of 563 W h kg^(-1)with 241.1 W kg^(-1)at 0.1 A g^(-1).The theoretical calculations disclose that the periodic and directional built-in electric-field along with the heterointerfaces of CoSe_(2)/NiSe_(2)@N-C can accelerate electrochemical reaction kinetics.The in(ex)situ experimental measurements reveal the reversible conversion reaction and stable structure of CoSe_(2)/NiSe_(2)@N-C during Na+insertion/extraction.The study highlights the potential ability of precisely controlled heterostructure to stimulate the electrochemical performances of advanced anode for SIBs.
基金the Key Project of the Natural Science Foundation of Ningxia Hui Autonomous Region,China(2022AAC02020)the Major Strategic Research Project of the Chinese Academy of Engineering and Local Cooperation(2021NXZD8)the Key Research and Development Plan Project of Ningxia Hui Autonomous Region,China(2022004129003).We are grateful to the editors and anonymous reviewers for their insightful comments and suggestions in improving this manuscript.
文摘It is of great significance to study the effects of desert plants on soil enzyme activities and soil organic carbon(SOC)for maintaining the stability of the desert ecosystem.In this study,we studied the responses of soil enzyme activities and SOC fractions(particulate organic carbon(POC)and mineral-associated organic carbon(MAOC))to five typical desert plant communities(Convolvulus tragacanthoides,Ephedra rhytidosperma,Stipa breviflora,Stipa tianschanica var.gobica,and Salsola laricifolia communities)in the proluvial fan in the eastern foothills of the Helan Mountain in Ningxia Hui Autonomous Region,China.We recorded the plant community information mainly including the plant coverage and herb and shrub species,and obtained the aboveground biomass and plant species diversity through sample surveys in late July 2023.Soil samples were also collected at depths of 0–10 cm(topsoil)and 10–20 cm(subsoil)to determine the soil physicochemical properties and enzyme activities.The results showed that the plant coverage and aboveground biomass of S.laricifolia community were significantly higher than those of C.tragacanthoides,S.breviflora,and S.tianschanica var.gobica communities(P<0.05).Soil enzyme activities varied among different plant communities.In the topsoil,the enzyme activities of alkaline phosphatase(ALP)andβ-1,4-glucosidas(βG)were significantly higher in E.rhytidosperma and S.tianschanica var.gobica communities than in other plant communities(P<0.05).The topsoil had higher POC and MAOC contents than the subsoil.Specifically,the content of POC in the topsoil was 18.17%–42.73%higher than that in the subsoil.The structural equation model(SEM)indicated that plant species diversity,soil pH,and soil water content(SWC)were the main factors influencing POC and MAOC.The soil pH inhibited the formation of POC and promoted the formation of MAOC.Conversely,SWC stimulated POC production and hindered MAOC formation.Our study aimed to gain insight into the effects of desert plant communities on soil enzyme activities and SOC fractions,as well as the drivers of SOC fractions in the proluvial fan in the eastern foothills of the Helan Mountain and other desert ecosystems.
基金supported by the faculty startup funds from the Yangzhou Universitythe Natural Science Foundation of Jiangsu Province(BK20210821)+1 种基金the National Natural Science Foundation of China(22102141)the Lvyangjinfeng Talent Program of Yangzhou。
文摘Developing efficient energy storage for sodium-ion batteries(SIBs)by creating high-performance heterojunctions and understanding their interfacial interaction at the atomic/molecular level holds promise but is also challenging.Besides,sluggish reaction kinetics at low temperatures restrict the operation of SIBs in cold climates.Herein,cross-linking nanoarchitectonics of WS_(2)/Ti_(3)C_(2)T_(x) heterojunction,featuring built-in electric field(BIEF),have been developed,employing as a model to reveal the positive effect of heterojunction design and BIEF for modifying the reaction kinetics and electrochemical activity.Particularly,the theoretical analysis manifests the discrepancy in work functions leads to the electronic flow from the electron-rich Ti_(3)C_(2)T_(x) to layered WS_(2),spontaneously forming the BIEF and“ion reservoir”at the heterogeneous interface.Besides,the generation of cross-linking pathways further promotes the transportation of electrons/ions,which guarantees rapid diffusion kinetics and excellent structure coupling.Consequently,superior sodium storage performance is obtained for the WS_(2)/Ti_(3)C_(2)T_(x) heterojunction,with only 0.2%decay per cycle at 5.0 A g^(-1)(25℃)up to 1000 cycles and a high capacity of 293.5 mA h g^(-1)(0.1A g^(-1)after 100 cycles)even at-20℃.Importantly,the spontaneously formed BIEF,accompanied by“ion reservoir”,in heterojunction provides deep understandings of the correlation between structure fabricated and performance obtained.
文摘As energy efficiency and indoor comfort increasingly become key standards in modern residential and office environments,research on intelligent fan speed control systems has become particularly important.This study aims to develop a temperature-feedback-based fan speed optimization strategy to achieve higher energy efficiency and user comfort.Firstly,by analyzing existing fan speed control technologies,their main limitations are identified,such as the inability to achieve smooth speed transitions.To address this issue,a BP-PID speed control algorithm is designed,which dynamically adjusts fan speed based on indoor temperature changes.Experimental validation demonstrates that the designed system can achieve smooth speed transitions compared to traditional fan systems while maintaining stable indoor temperatures.Furthermore,the real-time responsiveness of the system is crucial for enhancing user comfort.Our research not only demonstrates the feasibility of temperature-based fan speed optimization strategies in both theory and practice but also provides valuable insights for energy management in future smart home environments.Ultimately,this research outcome will facilitate the development of smart home systems and have a positive impact on environmental sustainability.
基金financial support from the National Natural Science Foundation of China (NSFC,21875155,22032004)the support of the National Key Research and Development Program of China (2021YFA1201502)the support of the Nanqiang Young Top-notch Talent Fellowship in Xiamen University。
文摘The practical application of lithium-sulfur(Li-S)batteries is greatly hindered by soluble polysulfides shuttling and sluggish sulfur redox kinetics.Rational design of multifunctional hybrid materials with superior electronic conductivity and high electrocatalytic activity,e.g.,heterostructures,is a promising strategy to solve the above obstacles.Herein,a binary metal sulfide MnS-MoS_(2) heterojunction electrocatalyst is first designed for the construction of high-sulfur-loaded and durable Li-S batteries.The MnS-MoS_(2) p-n heterojunction shows a unique structure of MoS_(2) nanosheets decorated with ample MnS nanodots,which contributes to the formation of a strong built-in electric field at the two-phase interface.The MnS-MoS_(2) hybrid host shows strong soluble polysulfide affinity,enhanced electronic conductivity,and exceptional catalytic effect on sulfur reduction.Benefiting from the synergistic effect,the as-derived S/MnS-MoS_(2) cathode delivers a superb rate capability(643 m A h g^(-1)at 6 C)and a durable cyclability(0.048%decay per cycle over 1000 cycles).More impressively,an areal capacity of 9.9 m A h cm^(-2)can be achieved even under an extremely high sulfur loading of 14.7 mg cm^(-2)and a low electrolyte to sulfur ratio of 2.9μL mg^(-1).This work provides an in-depth understanding of the interfacial catalytic effect of binary metal compound heterojunctions on sulfur reaction kinetics.
基金financed by the grants from The National Social Science Fund of China,Late Stage Funding (No. 21FZWB005)。
文摘Zhao Rukuo's Zhu Fan Zhi in the Southern Song dynasty was the first book in the history of China to systematically describe the “Maritime Silk Road”, recording the geography, products, customs, trade, etc. of more than 50 foreign countries and regions. The book included a large amount of medical literature, introducing medical customs and the production of drugs in various places, as well as the efficacy of some medicine. These materials are of unique value for understanding the medicine trade in the Song dynasty, and even the medical culture along the “Maritime Road of Aromatic Medicine”.
基金supported by the National R&D Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Science and ICT (2018M3D1A1058793 and 2021R1A3B1068920)supported by the Creative Materials Discovery Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Science and ICT (2018M3D1A1058744)the Yonsei Signature Research Cluster Program of 2021 (2021-22-0002)。
文摘To overcome the serious technological issues affecting lithium-sulfur(Li-S) batteries,such as sluggish sulfur redox kinetics and the detrimental shuttle effect,heterostructure engineering has been investigated as a strategy to effectively capture soluble lithium polysulfide intermediates and promote their conversion reaction by integrating highly polar metal oxides with catalytically active metals sulfides.However,to fully exploit the outstanding properties of heterostructure-based composites,their detailed structure and interfacial contacts should be designed rationally.Herein,optimally arranged TiO_(2)and MoS_(2)-based heterostructures(TiO_(2)@MoS_(2)) are fabricated on carbon cloth as a multifunctional interlayer to efficiently trap polysulfide intermediates and accelerate their redox kinetics.Owing to the synergistic effects between TiO_(2)and MoS_(2)and the uniform heterointerface distribution that induces the ideally oriented built-in electric field,Li-S batteries with TiO_(2)@MoS_(2)interlayers exhibit high rate capability(601 mA h g^(-1)at 5 C),good cycling stability(capacity-fade rate of 0.067% per cycle over 500 cycles at2 C),and satisfactory areal capacity(5.2 mA h cm^(-2)) under an increased sulfur loading of 5.2 mg cm^(-2).Moreover,by comparing with a MoS_(2)@TiO_(2)interlayer composed of reversely arranged heterostructures,the effect of the built-in electric field’s direction on the electrocatalytic reactions of polysulfide intermediates is thoroughly investigated for the first time.The superior electrocatalytic activities of the rationally arranged TiO_(2)@MoS_(2)interlayer demonstrate the importance of optimizing the built-in electric field of heterostructures for producing high-performance Li-S batteries.
文摘This study focuses on a single-stage axial flow fan, investigating the effect of three kinds of wave leading edge stator blades on its noise reduction. The DDES method and the duct acoustic analogy theory based on the penetrable data surface were used for noise prediction. The results showed that the three kinds of wave leading edge blades were effective in reducing the rotor-stator interaction tonal noise and also have a certain inhibitory effect on broadband noise. The A10W15 stator blade can effectively reduce broadband noise in the frequency range of 2200 - 4200 Hz. When the amplitude is increased to 20, the noise reduction effect is further enhanced. However, when the amplitude is increased to 30, the broadband noise reduction effect is no longer significant. Further research shows that the wave leading edge stator blades can significantly change the pressure fluctuation distribution on the leading edge and suction surface, which control the modal energy distribution. Finally, this paper analyzed multiple factors affecting the broadband noise reduction, such as the noise source cut-off and cut-on effect and correlation. The purpose of this paper is to explore the laws of the influence of wave leading edge blades on the duct noise of real fan, and to reveal its noise control mechanism. .
基金The National Natural Science Foundation of China under contract Nos 42076066,92055203 and U20A20100。
文摘There are many large-scale Cenozoic sedimentary basins with plentiful river deltas,deep-water fans and carbonate platforms in the southern South China Sea.The Crocker Fan was deposited as a typical submarine fan during the late Eocene–early Miocene,and stretches extensively across the entire Sarawak–Sabah of the northern Borneo area.However,systematic analyses are still lacking regarding its sediment composition and potential source suppliers.No consensus has been reached yet on the provenance evolution and sedimentary infilling processes,which seriously impeded the oil-and-gas exploration undertakings.By combining with sedimentaryfacies identification,heavy mineral assemblages,elemental geochemistry and detrital zircon U-Pb dating,this paper aims to generalize an integrated analysis on the potential provenance terranes and restore source-to-sink pathways of the Crocker Fan.In general,the Crocker Fan was initially formed over the Cretaceous–lower/middle Eocene Rajang Group by an angular Rajang unconformity.The continual southward subduction of the protoSouth China Sea resulted in magmatic activities and subsequent regional deformation and thrusting along the Lupar Line in the northern Borneo.The lowermost Crocker sequence is featured by a thick conglomerate layer sourced from in-situ or adjacent paleo-uplifts.From the late Eocene to the early Miocene,the Crocker Fan was constantly delivered with voluminous detritus from the Malay Peninsula of the western Sundaland.The Zengmu Basin was widely deposited with delta plain and neritic facies sediments,while the Brunei-Sabah Basin,to the farther east,was ubiquitously characterized by turbiditic sequences.The Crocker Fan successions are overall thick layers of modest-grained sandstones,which formed high-quality reservoirs in the southern South China Sea region.
文摘In this study, we tried to improve the performance by giving a pre-swirling flow to the radial inflow that occurred in the semi-opened axial fan. In addition, the flow fields of rotor outlet were clarified experimentally, and the effect of pre-swirling flow was considered. The experiment was carried out using a performance test wind tunnel with a square cross section of 880 mm. Three types of casings were prepared, in which the blade tip protruded 0%, 20%, and 40% of the meridional chord length. They were called R25, R15, and R05, respectively, in the casing bellmouth model code. Guide blades for generating a pre-swirling flow were installed on the vertical wall surface of the casing. In addition, a vertical wall was installed 60% upstream of the meridional chord length as an obstacle to prevent axial inflow. The velocity fields of the rotor outlet were measured using a hot-wire anemometer. From the results, the pre-swirling flow did not significantly affect the fan performance. When there was no obstacles wall upstream, there was a partial increase in efficiency, but the difference was not so large. When there was an obstacle wall upstream, the efficiency increased overall in the case of R15, but in the case of R05, the efficiency increased only in the low flow rate region, and conversely decreased in the high flow rate region. By observing the blade outlet flow fields when the performance was improved, it was confirmed that the influence of the tip leakage vortex was weakened.
文摘Among the common hazards related to alluvial fans,flooding is one of the most important.Nonetheless,in populated alluvial fans,not only the natural processes are effective in floods,but the artificial structures and modifications can change the behavior of flooding and its potential risks.This study aims to indicate the flood-prone landforms in a set of populated alluvial fans in an arid region and investigate the role of anthropogenic activities in controlling/exacerbating flooding in alluvial fans.To achieve this goal,15 Ground Range Detected in High resolution(GRDH)SAR Sentinel-1 images,covering a total of 24 alluvial fans,were acquired.Pre-processing and post-processing steps were applied to all images to identify flood-prone sections of the studied alluvial fans.The results showed that feeder channels,spreading sites,and wide interfluves are the most flood-prone landforms of alluvial fans.In terms of anthropogenic modifications to mitigate flooding,a rampart system is distributed in the study area.Ramparts are levee like structures formed from the fan material.They aim to mitigate flood hazard on residential areas,infrastructures,and agricultural lands of the study area.Results show that the rampart system can reduce the danger of floods,but it cannot be considered a long-term solution.Therefore,a comprehensive flood protection system distributed throughout the whole alluvial fan system is needed.Results also reveal that in regions where flood monitoring is challenging,SAR images can be used as a freely available data set to monitor and identify flooding hotspots.