The exploration of novel multivariate heterostructures has emerged as a pivotal strategy for developing high-performance electromagnetic wave(EMW)absorption materials.However,the loss mechanism in traditional heterost...The exploration of novel multivariate heterostructures has emerged as a pivotal strategy for developing high-performance electromagnetic wave(EMW)absorption materials.However,the loss mechanism in traditional heterostructures is relatively simple,guided by empirical observations,and is not monotonous.In this work,we presented a novel semiconductor-semiconductor-metal heterostructure sys-tem,Mo-MXene/Mo-metal sulfides(metal=Sn,Fe,Mn,Co,Ni,Zn,and Cu),including semiconductor junctions and Mott-Schottky junctions.By skillfully combining these distinct functional components(Mo-MXene,MoS_(2),metal sulfides),we can engineer a multiple heterogeneous interface with superior absorption capabilities,broad effective absorption bandwidths,and ultrathin matching thickness.The successful establishment of semiconductor-semiconductor-metal heterostructures gives rise to a built-in electric field that intensifies electron transfer,as confirmed by density functional theory,which collaborates with multiple dielectric polarization mechanisms to substantially amplify EMW absorption.We detailed a successful synthesis of a series of Mo-MXene/Mo-metal sulfides featuring both semiconductor-semiconductor and semiconductor-metal interfaces.The achievements were most pronounced in Mo-MXene/Mo-Sn sulfide,which achieved remarkable reflection loss values of-70.6 dB at a matching thickness of only 1.885 mm.Radar cross-section calculations indicate that these MXene/Mo-metal sulfides have tremendous potential in practical military stealth technology.This work marks a departure from conventional component design limitations and presents a novel pathway for the creation of advanced MXene-based composites with potent EMW absorption capabilities.展开更多
Constructing a built-in electric field has emerged as a key strategy for enhancing charge separation and transfer,thereby improving photoelectrochemical performance.Recently,considerable efforts have been devoted to t...Constructing a built-in electric field has emerged as a key strategy for enhancing charge separation and transfer,thereby improving photoelectrochemical performance.Recently,considerable efforts have been devoted to this endeavor.This review systematically summarizes the impact of built-in electric fields on enhancing charge separation and transfer mechanisms,focusing on the modulation of built-in electric fields in terms of depth and orderliness.First,mechanisms and tuning strategies for built-in electric fields are explored.Then,the state-of-the-art works regarding built-in electric fields for modulating charge separation and transfer are summarized and categorized according to surface and interface depth.Finally,current strategies for constructing bulk built-in electric fields in photoelectrodes are explored,and insights into future developments for enhancing charge separation and transfer in high-performance photoelectrochemical applications are provided.展开更多
Lithium sulfur(Li-S)battery is a kind of burgeoning energy storage system with high energy density.However,the electrolyte-soluble intermediate lithium polysulfides(Li PSs)undergo notorious shuttle effect,which seriou...Lithium sulfur(Li-S)battery is a kind of burgeoning energy storage system with high energy density.However,the electrolyte-soluble intermediate lithium polysulfides(Li PSs)undergo notorious shuttle effect,which seriously hinders the commercialization of Li-S batteries.Herein,a unique VSe_(2)/V_(2)C heterostructure with local built-in electric field was rationally engineered from V_(2)C parent via a facile thermal selenization process.It exquisitely synergizes the strong affinity of V_(2)C with the effective electrocatalytic activity of VSe_(2).More importantly,the local built-in electric field at the heterointerface can sufficiently promote the electron/ion transport ability and eventually boost the conversion kinetics of sulfur species.The Li-S battery equipped with VSe_(2)/V_(2)C-CNTs-PP separator achieved an outstanding initial specific capacity of 1439.1 m A h g^(-1)with a high capacity retention of 73%after 100 cycles at0.1 C.More impressively,a wonderful capacity of 571.6 mA h g^(-1)was effectively maintained after 600cycles at 2 C with a capacity decay rate of 0.07%.Even under a sulfur loading of 4.8 mg cm^(-2),areal capacity still can be up to 5.6 m A h cm^(-2).In-situ Raman tests explicitly illustrate the effectiveness of VSe_(2)/V_(2)C-CNTs modifier in restricting Li PSs shuttle.Combined with density functional theory calculations,the underlying mechanism of VSe_(2)/V_(2)C heterostructure for remedying Li PSs shuttling and conversion kinetics was deciphered.The strategy of constructing VSe_(2)/V_(2)C heterocatalyst in this work proposes a universal protocol to design metal selenide-based separator modifier for Li-S battery.Besides,it opens an efficient avenue for the separator engineering of Li-S batteries.展开更多
Constructing heterostructure is considered as an effective strategy to address the sluggish electronic and ionic kinetics of anode materials for sodium ion batteries(SIBs).However,realizing the orientated growth and u...Constructing heterostructure is considered as an effective strategy to address the sluggish electronic and ionic kinetics of anode materials for sodium ion batteries(SIBs).However,realizing the orientated growth and uniform distribution of the heterostructure is still a great challenge.Herein,the regulated novel CoSe_(2)/NiSe_(2)heterostructure confined in N-doped carbon nanofibers(CoSe_(2)/NiSe_(2)@N-C)are prepared by using Co/Ni-ZIF template,in which,the CoSe_(2)/NiSe_(2)heterostructures realize uniform distribution on a micro level.Benefiting from the unique heterostructure and N-doped carbon nanofibers,the CoSe_(2)/NiSe_(2)@N-C deliveries superior rate capability and durable cycle lifespan with a reversible capacity of 400.5 mA h g^(-1)after 5000 cycles at 2 A g^(-1).The Na-ion full battery with CoSe_(2)/NiSe_(2)@N-C anode and layered oxide cathode displays a remarkable energy density of 563 W h kg^(-1)with 241.1 W kg^(-1)at 0.1 A g^(-1).The theoretical calculations disclose that the periodic and directional built-in electric-field along with the heterointerfaces of CoSe_(2)/NiSe_(2)@N-C can accelerate electrochemical reaction kinetics.The in(ex)situ experimental measurements reveal the reversible conversion reaction and stable structure of CoSe_(2)/NiSe_(2)@N-C during Na+insertion/extraction.The study highlights the potential ability of precisely controlled heterostructure to stimulate the electrochemical performances of advanced anode for SIBs.展开更多
Developing efficient energy storage for sodium-ion batteries(SIBs)by creating high-performance heterojunctions and understanding their interfacial interaction at the atomic/molecular level holds promise but is also ch...Developing efficient energy storage for sodium-ion batteries(SIBs)by creating high-performance heterojunctions and understanding their interfacial interaction at the atomic/molecular level holds promise but is also challenging.Besides,sluggish reaction kinetics at low temperatures restrict the operation of SIBs in cold climates.Herein,cross-linking nanoarchitectonics of WS_(2)/Ti_(3)C_(2)T_(x) heterojunction,featuring built-in electric field(BIEF),have been developed,employing as a model to reveal the positive effect of heterojunction design and BIEF for modifying the reaction kinetics and electrochemical activity.Particularly,the theoretical analysis manifests the discrepancy in work functions leads to the electronic flow from the electron-rich Ti_(3)C_(2)T_(x) to layered WS_(2),spontaneously forming the BIEF and“ion reservoir”at the heterogeneous interface.Besides,the generation of cross-linking pathways further promotes the transportation of electrons/ions,which guarantees rapid diffusion kinetics and excellent structure coupling.Consequently,superior sodium storage performance is obtained for the WS_(2)/Ti_(3)C_(2)T_(x) heterojunction,with only 0.2%decay per cycle at 5.0 A g^(-1)(25℃)up to 1000 cycles and a high capacity of 293.5 mA h g^(-1)(0.1A g^(-1)after 100 cycles)even at-20℃.Importantly,the spontaneously formed BIEF,accompanied by“ion reservoir”,in heterojunction provides deep understandings of the correlation between structure fabricated and performance obtained.展开更多
Rapid technological development and population growth are responsible for a series of imminent environmental problems and an ineluctable energy crisis.The application of semiconductor nanomaterials in photocatalysis o...Rapid technological development and population growth are responsible for a series of imminent environmental problems and an ineluctable energy crisis.The application of semiconductor nanomaterials in photocatalysis or photoelectrocatalysis(PEC)for either the degradation of contaminants in the environment or the generation of hydrogen as clean fuel is an effective approach to alleviate these problems.However,the efficiency of such processes remains suboptimal for real applications.Reasonable construction of a built-in electric field is considered to efficiently enhance carrier separation and reduce carrier recombination to improve catalytic performance.In the past decade,as a new method to enhance the built-in electric field,the piezoelectric effect from piezoelectric materials has been extensively studied.In this review,we provide an overview of the properties of piezoelectric materials and the mechanisms of piezoelectricity and ferroelectricity for a built-in electric field.Then,piezoelectric and ferroelectric polarization regulated built-in electric fields that mediate catalysis are discussed.Furthermore,the applications of piezoelectric semiconductor materials are also highlighted,including degradation of pollutants,bacteria disinfection,water splitting for H2 generation,and organic synthesis.We conclude by discussing the challenges in the field and the exciting opportunities to further improve piezo-catalytic efficiency.展开更多
Using the mass of time-varying length balance rope focused on the hoisting conveyance, the coupling longi- tudinal-transverse model of mine friction hoist was established by using of the Hamilton's principle. The mod...Using the mass of time-varying length balance rope focused on the hoisting conveyance, the coupling longi- tudinal-transverse model of mine friction hoist was established by using of the Hamilton's principle. The modified Galerkin's method was used to discretize partial differential Eqs. The mine hoisting system was used to the example to analysis the relation between the load, velocity and transverse vibration of rope. The in situ tests were illustrated to evaluate the proposed mathematical model. The results showed that the modeling method can well represent the transverse vibration of rope.展开更多
An electron transporting material of TFTTP (4-(5-hexylthiophene-2-yl)-2,6-bis(5-trifluoromethyl)thiophen-2-yl)pyridine) was investigated as a cathode buffer layer to enhance the power efficiency of organic sola...An electron transporting material of TFTTP (4-(5-hexylthiophene-2-yl)-2,6-bis(5-trifluoromethyl)thiophen-2-yl)pyridine) was investigated as a cathode buffer layer to enhance the power efficiency of organic solar cells (OSCs) based on subphthalocyanine and C60. The overall power conversion efficiency was increased by a factor of 1.31 by inserting the TFTTP interfacial layer between the active layer and metallic cathode. The inner mechanism responsible for the performance enhancement of OSCs was systematically studied with the simulation of dark diode behavior and optical field distribution inside the devices as well as the characterization of device photocurrent. The results showed that the TFTTP layer could significantly increase the built-in potential in the devices, leading to the enhanced dissociation of charge transfer excitons. In addition, by using TFTTP as the buffer layer, a better Ohmic contact at C60/metal interface was formed, facilitating more efficient free charge carrier collection.展开更多
A new method based on principal component analysis (PCA) and support vector machines (SVMs) is proposed for fault diagnosis of mine hoists. PCA is used to extract the principal features associated with the gearbox. Th...A new method based on principal component analysis (PCA) and support vector machines (SVMs) is proposed for fault diagnosis of mine hoists. PCA is used to extract the principal features associated with the gearbox. Then, with the irrelevant gearbox variables removed, the remaining gearbox, the hydraulic system and the wire rope parameters were used as input to a multi-class SVM. The SVM is first trained by using the one class-based multi-class optimization algorithm and it is then applied to fault identification. Comparison of various methods showed the PCA-SVM method successfully removed redundancy to solve the dimensionality curse. These results show that the algorithm using the RBF kernel function for the SVM had the best classification properties.展开更多
In order to discover the airflow pattern in mine shaft which outfitted with hoist equipment (HE), this paper set up the physical model and anatomized the piston-wind caused by hoist equipment, and researched the flo...In order to discover the airflow pattern in mine shaft which outfitted with hoist equipment (HE), this paper set up the physical model and anatomized the piston-wind caused by hoist equipment, and researched the flow field and velocity field around the hoist equipment during its moving process, and analyzed the airflow around single and couple hoist equipment as well as decisive range of piston effect and additional effect of hoist equipment to ventilation system. Research conclusion indicate that during hoist equipment movement, airflow pattern changes repeatedly because of the influence of pis-ton effect from hoist equipment, and the study of airflow stability in shaft is the foundation for the stability of ventilation in mine.展开更多
The frictional performance of gaskets is greatly affected by frictional heat in operational mine hoists. Based on frictional mechanism and heat transfer theory, the mathematical model of the temperature field of the P...The frictional performance of gaskets is greatly affected by frictional heat in operational mine hoists. Based on frictional mechanism and heat transfer theory, the mathematical model of the temperature field of the PVC gasket in an operational mine hoist was investigated, a numerical simulation using ANSYS is presented and the distribution of the temperature and heat flux were studied under basic assumptions. The results show that the temperature gradually decreases as the radius of the model increases and the isotherms are arcs of concentric semi-circle. The heat flux is of bilateral symmetry in the model and decreases radially. The theoretical values correspond with the measured values for a short time (τ≤ 100 s) when the steel wire rope slides.展开更多
Shell-feeding velocity is an important factor affecting naval gun shooting capacity. An agile shell-feeding system was designed to ensure quick implementation of the shell-feeding task. Based on composition of the agi...Shell-feeding velocity is an important factor affecting naval gun shooting capacity. An agile shell-feeding system was designed to ensure quick implementation of the shell-feeding task. Based on composition of the agile shell-feeding system, hoist technology was studied. Working principles were discussed and the hydraulic pressure system of the hoist was constructed. The hydraulic pressure cylinder and the accumulator were analyzed and calculated. Finally, PRO/E and ADAMS were used to simulate the hoist and its hydraulic system. It was found that this type of virtual prototype provides a good method to actualize a physical prototype.展开更多
The cyclotron mass of magnetopolarons in wurtzite InxGa1-xN/GaN quantum well is studied in the presence of an external magnetic field by using the Larsen perturbation method. The effects of the built-in electric field...The cyclotron mass of magnetopolarons in wurtzite InxGa1-xN/GaN quantum well is studied in the presence of an external magnetic field by using the Larsen perturbation method. The effects of the built-in electric field and different phonon modes including interface, confined and half-space phonon modes are considered in our calculation. The results for a zinc-blende quantum well are also given for comparison. It is found that the main contribution to the transition energy comes from half-space and interface phonon modes when the well width is very small while the confined modes play a more important role in a wider well due to the location of the electron wave function. As the well width increases, the cyclotron mass of magnetopolarons first increases to a maximum and then decreases either with or without the built-in electric field in the wurtzite structure and the built-in electric field slightly reduces the cyclotron mass. The variation of cyclotron mass in a zinc-blende structure is similar to that in a wurtzite structure. With the increase of external magnetic field, the cyclotron mass of polarons almost linearly increases. The cyclotron frequency of magnetopolarons is also discussed.展开更多
This research investigated the outputting circulation current inhibition characteristic which are controlled by the instantaneous feedback voltage in inverter parallel driving of the mine hoist. We established a trans...This research investigated the outputting circulation current inhibition characteristic which are controlled by the instantaneous feedback voltage in inverter parallel driving of the mine hoist. We established a transfer function of the parallel inverters controlled by the close-loop adjustment of instantaneous voltage feedback. The influence of the parameters of the close-loop feedback circuit to the inhibition effects to the outputting circulation current is observed. After analyzing the circulating current inhibition characteristics, the proportion integration (PI) controller is introduced into the close-loop adjustment by instantaneous voltage feedback. The characteristics equation is gained to determine the PI parameters by drawing the Bode plots. The inhibition effects of the proposed controller are examined by the established simulation model of parallel inverter system. The harmonic distortion rate at the outputting voltage frequency value of 4, 10, 20, 41 and 50 Hz, are all lower than 2.32 % by the instantaneous outputting voltage feedback.展开更多
Serious accidents of mine hoists caused by high-speed sliding between friction lining and wire rope are often seen in coal mines.In order to solve this problem,we analyzed the contact characteristics between friction ...Serious accidents of mine hoists caused by high-speed sliding between friction lining and wire rope are often seen in coal mines.In order to solve this problem,we analyzed the contact characteristics between friction lining and wire rope.Then we carried out a dynamic mechanical analysis(DMA) to explain the change in mechanical properties of the friction lining as function of temperature and load frequency and found that temperature has a stronger effect on the mechanical properties than the frequency.We used multiple regression analysis to obtain the thermoviscoelastic constitutive relations of the friction lining.As well we derived the analytic solution for the thermoviscoelastic contact radius and pressure by combining the theory of viscoelastic contact mechanics with thermoviscoelastic constitutive relations.展开更多
Based on fault diagnosis and fault tolerant technologies, the mine-hoist active fault-tolerant control system (MAFCS) is presented with corresponding strategies,, which includes the fault diagnosis module (FDM), the d...Based on fault diagnosis and fault tolerant technologies, the mine-hoist active fault-tolerant control system (MAFCS) is presented with corresponding strategies,, which includes the fault diagnosis module (FDM), the dynamic library (DL) and the fault-tolerant control module (FCM). When a fault is judged from some sensor by FDM, FCM reconfigure the state of MAFCS by calling the parameters from all sub libraries in DL, in order to ensure the reliabil- ity and safety of mine hoist. The simulating result shows that, MAFCS is of certain intelligence, which can adopt the corresponding control strategies according to different fault modes, even when there are quite difference between the real data and the prior fault modes.展开更多
基金supported by the National Natural Science Foundation of China(No.22269010,52231007,12327804,T2321003,22088101)the Jiangxi Provincial Natural Science Foundation(No.20224BAB214021)+1 种基金the Major Research Program of Jingdezhen Ceramic Industry(No.2023ZDGG002)the Ministry of Science and Technology of China(973 Project No.2021YFA1200600).
文摘The exploration of novel multivariate heterostructures has emerged as a pivotal strategy for developing high-performance electromagnetic wave(EMW)absorption materials.However,the loss mechanism in traditional heterostructures is relatively simple,guided by empirical observations,and is not monotonous.In this work,we presented a novel semiconductor-semiconductor-metal heterostructure sys-tem,Mo-MXene/Mo-metal sulfides(metal=Sn,Fe,Mn,Co,Ni,Zn,and Cu),including semiconductor junctions and Mott-Schottky junctions.By skillfully combining these distinct functional components(Mo-MXene,MoS_(2),metal sulfides),we can engineer a multiple heterogeneous interface with superior absorption capabilities,broad effective absorption bandwidths,and ultrathin matching thickness.The successful establishment of semiconductor-semiconductor-metal heterostructures gives rise to a built-in electric field that intensifies electron transfer,as confirmed by density functional theory,which collaborates with multiple dielectric polarization mechanisms to substantially amplify EMW absorption.We detailed a successful synthesis of a series of Mo-MXene/Mo-metal sulfides featuring both semiconductor-semiconductor and semiconductor-metal interfaces.The achievements were most pronounced in Mo-MXene/Mo-Sn sulfide,which achieved remarkable reflection loss values of-70.6 dB at a matching thickness of only 1.885 mm.Radar cross-section calculations indicate that these MXene/Mo-metal sulfides have tremendous potential in practical military stealth technology.This work marks a departure from conventional component design limitations and presents a novel pathway for the creation of advanced MXene-based composites with potent EMW absorption capabilities.
基金financially supported by the Industrial Technology Innovation Program of IMAST(No.2023JSYD 01003)the National Natural Science Foundation of China(Nos.52104292 and U2341209)。
文摘Constructing a built-in electric field has emerged as a key strategy for enhancing charge separation and transfer,thereby improving photoelectrochemical performance.Recently,considerable efforts have been devoted to this endeavor.This review systematically summarizes the impact of built-in electric fields on enhancing charge separation and transfer mechanisms,focusing on the modulation of built-in electric fields in terms of depth and orderliness.First,mechanisms and tuning strategies for built-in electric fields are explored.Then,the state-of-the-art works regarding built-in electric fields for modulating charge separation and transfer are summarized and categorized according to surface and interface depth.Finally,current strategies for constructing bulk built-in electric fields in photoelectrodes are explored,and insights into future developments for enhancing charge separation and transfer in high-performance photoelectrochemical applications are provided.
基金supported by the National Natural Science Foundation of China(No.52072099)the Joint Guidance Project of the Natural Science Foundation of Heilongjiang Province,China(No.LH2022E093)the Team Program of the Natural Science Foundation of Heilongjiang Province,China(No.TD2021E005)。
文摘Lithium sulfur(Li-S)battery is a kind of burgeoning energy storage system with high energy density.However,the electrolyte-soluble intermediate lithium polysulfides(Li PSs)undergo notorious shuttle effect,which seriously hinders the commercialization of Li-S batteries.Herein,a unique VSe_(2)/V_(2)C heterostructure with local built-in electric field was rationally engineered from V_(2)C parent via a facile thermal selenization process.It exquisitely synergizes the strong affinity of V_(2)C with the effective electrocatalytic activity of VSe_(2).More importantly,the local built-in electric field at the heterointerface can sufficiently promote the electron/ion transport ability and eventually boost the conversion kinetics of sulfur species.The Li-S battery equipped with VSe_(2)/V_(2)C-CNTs-PP separator achieved an outstanding initial specific capacity of 1439.1 m A h g^(-1)with a high capacity retention of 73%after 100 cycles at0.1 C.More impressively,a wonderful capacity of 571.6 mA h g^(-1)was effectively maintained after 600cycles at 2 C with a capacity decay rate of 0.07%.Even under a sulfur loading of 4.8 mg cm^(-2),areal capacity still can be up to 5.6 m A h cm^(-2).In-situ Raman tests explicitly illustrate the effectiveness of VSe_(2)/V_(2)C-CNTs modifier in restricting Li PSs shuttle.Combined with density functional theory calculations,the underlying mechanism of VSe_(2)/V_(2)C heterostructure for remedying Li PSs shuttling and conversion kinetics was deciphered.The strategy of constructing VSe_(2)/V_(2)C heterocatalyst in this work proposes a universal protocol to design metal selenide-based separator modifier for Li-S battery.Besides,it opens an efficient avenue for the separator engineering of Li-S batteries.
基金financially supported by the Natural Science Foundation of Shandong Province(ZR2021QB055,ZR2023MB017,ZR2022JQ10)the National Natural Science Foundation of China(21901146,220781792,22274083)。
文摘Constructing heterostructure is considered as an effective strategy to address the sluggish electronic and ionic kinetics of anode materials for sodium ion batteries(SIBs).However,realizing the orientated growth and uniform distribution of the heterostructure is still a great challenge.Herein,the regulated novel CoSe_(2)/NiSe_(2)heterostructure confined in N-doped carbon nanofibers(CoSe_(2)/NiSe_(2)@N-C)are prepared by using Co/Ni-ZIF template,in which,the CoSe_(2)/NiSe_(2)heterostructures realize uniform distribution on a micro level.Benefiting from the unique heterostructure and N-doped carbon nanofibers,the CoSe_(2)/NiSe_(2)@N-C deliveries superior rate capability and durable cycle lifespan with a reversible capacity of 400.5 mA h g^(-1)after 5000 cycles at 2 A g^(-1).The Na-ion full battery with CoSe_(2)/NiSe_(2)@N-C anode and layered oxide cathode displays a remarkable energy density of 563 W h kg^(-1)with 241.1 W kg^(-1)at 0.1 A g^(-1).The theoretical calculations disclose that the periodic and directional built-in electric-field along with the heterointerfaces of CoSe_(2)/NiSe_(2)@N-C can accelerate electrochemical reaction kinetics.The in(ex)situ experimental measurements reveal the reversible conversion reaction and stable structure of CoSe_(2)/NiSe_(2)@N-C during Na+insertion/extraction.The study highlights the potential ability of precisely controlled heterostructure to stimulate the electrochemical performances of advanced anode for SIBs.
基金supported by the faculty startup funds from the Yangzhou Universitythe Natural Science Foundation of Jiangsu Province(BK20210821)+1 种基金the National Natural Science Foundation of China(22102141)the Lvyangjinfeng Talent Program of Yangzhou。
文摘Developing efficient energy storage for sodium-ion batteries(SIBs)by creating high-performance heterojunctions and understanding their interfacial interaction at the atomic/molecular level holds promise but is also challenging.Besides,sluggish reaction kinetics at low temperatures restrict the operation of SIBs in cold climates.Herein,cross-linking nanoarchitectonics of WS_(2)/Ti_(3)C_(2)T_(x) heterojunction,featuring built-in electric field(BIEF),have been developed,employing as a model to reveal the positive effect of heterojunction design and BIEF for modifying the reaction kinetics and electrochemical activity.Particularly,the theoretical analysis manifests the discrepancy in work functions leads to the electronic flow from the electron-rich Ti_(3)C_(2)T_(x) to layered WS_(2),spontaneously forming the BIEF and“ion reservoir”at the heterogeneous interface.Besides,the generation of cross-linking pathways further promotes the transportation of electrons/ions,which guarantees rapid diffusion kinetics and excellent structure coupling.Consequently,superior sodium storage performance is obtained for the WS_(2)/Ti_(3)C_(2)T_(x) heterojunction,with only 0.2%decay per cycle at 5.0 A g^(-1)(25℃)up to 1000 cycles and a high capacity of 293.5 mA h g^(-1)(0.1A g^(-1)after 100 cycles)even at-20℃.Importantly,the spontaneously formed BIEF,accompanied by“ion reservoir”,in heterojunction provides deep understandings of the correlation between structure fabricated and performance obtained.
基金supported by the Youth Innovation Promotion Association of the Chinese Academy of Sciences(2015023)National Natural Science Foundation of China(81471784,51802115)+3 种基金Natural Science Foundation of Beijing(2172058)Natural Science Foundation of Shandong Province(ZR2018BEM010,ZR2019YQ21)Major Program of Shandong Province Natural Science Foundation(ZR2018ZC0843)Scientific and Technology Project of University of Jinan(XKY1923)~~
文摘Rapid technological development and population growth are responsible for a series of imminent environmental problems and an ineluctable energy crisis.The application of semiconductor nanomaterials in photocatalysis or photoelectrocatalysis(PEC)for either the degradation of contaminants in the environment or the generation of hydrogen as clean fuel is an effective approach to alleviate these problems.However,the efficiency of such processes remains suboptimal for real applications.Reasonable construction of a built-in electric field is considered to efficiently enhance carrier separation and reduce carrier recombination to improve catalytic performance.In the past decade,as a new method to enhance the built-in electric field,the piezoelectric effect from piezoelectric materials has been extensively studied.In this review,we provide an overview of the properties of piezoelectric materials and the mechanisms of piezoelectricity and ferroelectricity for a built-in electric field.Then,piezoelectric and ferroelectric polarization regulated built-in electric fields that mediate catalysis are discussed.Furthermore,the applications of piezoelectric semiconductor materials are also highlighted,including degradation of pollutants,bacteria disinfection,water splitting for H2 generation,and organic synthesis.We conclude by discussing the challenges in the field and the exciting opportunities to further improve piezo-catalytic efficiency.
文摘Using the mass of time-varying length balance rope focused on the hoisting conveyance, the coupling longi- tudinal-transverse model of mine friction hoist was established by using of the Hamilton's principle. The modified Galerkin's method was used to discretize partial differential Eqs. The mine hoisting system was used to the example to analysis the relation between the load, velocity and transverse vibration of rope. The in situ tests were illustrated to evaluate the proposed mathematical model. The results showed that the modeling method can well represent the transverse vibration of rope.
文摘An electron transporting material of TFTTP (4-(5-hexylthiophene-2-yl)-2,6-bis(5-trifluoromethyl)thiophen-2-yl)pyridine) was investigated as a cathode buffer layer to enhance the power efficiency of organic solar cells (OSCs) based on subphthalocyanine and C60. The overall power conversion efficiency was increased by a factor of 1.31 by inserting the TFTTP interfacial layer between the active layer and metallic cathode. The inner mechanism responsible for the performance enhancement of OSCs was systematically studied with the simulation of dark diode behavior and optical field distribution inside the devices as well as the characterization of device photocurrent. The results showed that the TFTTP layer could significantly increase the built-in potential in the devices, leading to the enhanced dissociation of charge transfer excitons. In addition, by using TFTTP as the buffer layer, a better Ohmic contact at C60/metal interface was formed, facilitating more efficient free charge carrier collection.
基金Project 06KJD470182 supported by the Jiangsu Educational Natural Science Foundation of china
文摘A new method based on principal component analysis (PCA) and support vector machines (SVMs) is proposed for fault diagnosis of mine hoists. PCA is used to extract the principal features associated with the gearbox. Then, with the irrelevant gearbox variables removed, the remaining gearbox, the hydraulic system and the wire rope parameters were used as input to a multi-class SVM. The SVM is first trained by using the one class-based multi-class optimization algorithm and it is then applied to fault identification. Comparison of various methods showed the PCA-SVM method successfully removed redundancy to solve the dimensionality curse. These results show that the algorithm using the RBF kernel function for the SVM had the best classification properties.
基金Supported by Natural Science Foundation of China (50474062) and State Administration of Coal Mine Safety of China (04-233)
文摘In order to discover the airflow pattern in mine shaft which outfitted with hoist equipment (HE), this paper set up the physical model and anatomized the piston-wind caused by hoist equipment, and researched the flow field and velocity field around the hoist equipment during its moving process, and analyzed the airflow around single and couple hoist equipment as well as decisive range of piston effect and additional effect of hoist equipment to ventilation system. Research conclusion indicate that during hoist equipment movement, airflow pattern changes repeatedly because of the influence of pis-ton effect from hoist equipment, and the study of airflow stability in shaft is the foundation for the stability of ventilation in mine.
基金Projects 50225519 supported by the National Outstanding Youth Science Foundation of China0E4458 by the Youth Science Foundation of China Univer-sity of Mining and Technology
文摘The frictional performance of gaskets is greatly affected by frictional heat in operational mine hoists. Based on frictional mechanism and heat transfer theory, the mathematical model of the temperature field of the PVC gasket in an operational mine hoist was investigated, a numerical simulation using ANSYS is presented and the distribution of the temperature and heat flux were studied under basic assumptions. The results show that the temperature gradually decreases as the radius of the model increases and the isotherms are arcs of concentric semi-circle. The heat flux is of bilateral symmetry in the model and decreases radially. The theoretical values correspond with the measured values for a short time (τ≤ 100 s) when the steel wire rope slides.
文摘Shell-feeding velocity is an important factor affecting naval gun shooting capacity. An agile shell-feeding system was designed to ensure quick implementation of the shell-feeding task. Based on composition of the agile shell-feeding system, hoist technology was studied. Working principles were discussed and the hydraulic pressure system of the hoist was constructed. The hydraulic pressure cylinder and the accumulator were analyzed and calculated. Finally, PRO/E and ADAMS were used to simulate the hoist and its hydraulic system. It was found that this type of virtual prototype provides a good method to actualize a physical prototype.
基金Project supported by the National Natural Science Foundation of China (Grant No. 10964007)the Natural Science Foundation of Inner Mongolia,China (Grant No. 2009MS0110)
文摘The cyclotron mass of magnetopolarons in wurtzite InxGa1-xN/GaN quantum well is studied in the presence of an external magnetic field by using the Larsen perturbation method. The effects of the built-in electric field and different phonon modes including interface, confined and half-space phonon modes are considered in our calculation. The results for a zinc-blende quantum well are also given for comparison. It is found that the main contribution to the transition energy comes from half-space and interface phonon modes when the well width is very small while the confined modes play a more important role in a wider well due to the location of the electron wave function. As the well width increases, the cyclotron mass of magnetopolarons first increases to a maximum and then decreases either with or without the built-in electric field in the wurtzite structure and the built-in electric field slightly reduces the cyclotron mass. The variation of cyclotron mass in a zinc-blende structure is similar to that in a wurtzite structure. With the increase of external magnetic field, the cyclotron mass of polarons almost linearly increases. The cyclotron frequency of magnetopolarons is also discussed.
文摘This research investigated the outputting circulation current inhibition characteristic which are controlled by the instantaneous feedback voltage in inverter parallel driving of the mine hoist. We established a transfer function of the parallel inverters controlled by the close-loop adjustment of instantaneous voltage feedback. The influence of the parameters of the close-loop feedback circuit to the inhibition effects to the outputting circulation current is observed. After analyzing the circulating current inhibition characteristics, the proportion integration (PI) controller is introduced into the close-loop adjustment by instantaneous voltage feedback. The characteristics equation is gained to determine the PI parameters by drawing the Bode plots. The inhibition effects of the proposed controller are examined by the established simulation model of parallel inverter system. The harmonic distortion rate at the outputting voltage frequency value of 4, 10, 20, 41 and 50 Hz, are all lower than 2.32 % by the instantaneous outputting voltage feedback.
基金Projects 50875253 supported by the National Natural Science Foundation of China20060290505 by the Research Fund for the Doctoral Program of Higher Education of China+2 种基金107054 by the Key Project of Ministry of Education of ChinaBK2008127 by the Natural Science Foundation of Jiangsu ProvinceCX08B_042Z by the Scientific Innovation Program for Postgraduates in Colleges and Universities of Jiangsu Province
文摘Serious accidents of mine hoists caused by high-speed sliding between friction lining and wire rope are often seen in coal mines.In order to solve this problem,we analyzed the contact characteristics between friction lining and wire rope.Then we carried out a dynamic mechanical analysis(DMA) to explain the change in mechanical properties of the friction lining as function of temperature and load frequency and found that temperature has a stronger effect on the mechanical properties than the frequency.We used multiple regression analysis to obtain the thermoviscoelastic constitutive relations of the friction lining.As well we derived the analytic solution for the thermoviscoelastic contact radius and pressure by combining the theory of viscoelastic contact mechanics with thermoviscoelastic constitutive relations.
文摘Based on fault diagnosis and fault tolerant technologies, the mine-hoist active fault-tolerant control system (MAFCS) is presented with corresponding strategies,, which includes the fault diagnosis module (FDM), the dynamic library (DL) and the fault-tolerant control module (FCM). When a fault is judged from some sensor by FDM, FCM reconfigure the state of MAFCS by calling the parameters from all sub libraries in DL, in order to ensure the reliabil- ity and safety of mine hoist. The simulating result shows that, MAFCS is of certain intelligence, which can adopt the corresponding control strategies according to different fault modes, even when there are quite difference between the real data and the prior fault modes.