CF3I gas mixtures have attracted considerable attention as potential environmentally-friendly alternatives to SF6 gas,owing to their excellent insulating performance.This paper attempts to study the CF3I ternary gas m...CF3I gas mixtures have attracted considerable attention as potential environmentally-friendly alternatives to SF6 gas,owing to their excellent insulating performance.This paper attempts to study the CF3I ternary gas mixtures with c-C4F8 and buffer gases N2 and CO2 by considering dielectric strength from electron transport parameters based on the Boltzmann method and synergistic effect analysis,compared with SF6 gas mixtures.The results confirm that the critical electric field strength of CF3I/c-C4F8/70%CO2 is greater than that of 30%SF6/70%CO2 when the CF3I content is greater than 17%.Moreover,a higher content of c-C4F8 decreases the sensitivity of gas mixtures to an electric field,and this phenomenon is more obvious in CF3I/c-C4F8/CO2 gas mixtures.The synergistic effects for CF3I/c-C4F8/70%N2 were most obvious when the c-C4F8 content was approximately 20%,and for CF3I/c-C4F8/70%CO2 when the c-C4F8 content was approximately 10%.On the basis of this research,CF3I/c-C4F8/70%N2 shows better insulation performance when the c-C4F8 content is in the15%–20%range.For CF3I/c-C4F8/70%CO2,when the c-C4F8 content is in the 10%–15%range,the gas mixtures have excellent performance.Hence,these gas systems might be used as alternative gas mixtures to SF6 in high-voltage equipment.展开更多
SF_6因具有良好的绝缘效果而被广泛地应用于电力系统中。但同时,SF_6也是一种温室气体,随着环境问题日益恶化,人们迫切需要找到替代SF_6的绝缘气体。为此,通过实验研究了环境友好气体c-C_4F_8及c-C_4F_8/N_2混合气体替代SF_6的可行性。...SF_6因具有良好的绝缘效果而被广泛地应用于电力系统中。但同时,SF_6也是一种温室气体,随着环境问题日益恶化,人们迫切需要找到替代SF_6的绝缘气体。为此,通过实验研究了环境友好气体c-C_4F_8及c-C_4F_8/N_2混合气体替代SF_6的可行性。通过调节电极间隙(1~6 mm)和气压(150~350 k Pa),测量了气体在不同条件下的击穿电压及击穿电流波形,得到了气体的绝缘特性并与SF_6气体进行了对比分析。实验结果表明:纯净的c-C_4F_8气体的绝缘强度约为SF_6的1.3倍,体积比为1:1的c-C_4F_8/N_2混合气体的绝缘强度约为与SF_6的0.9倍。通过计算,c-C_4F_8/N_2混合气体的液化温度可以达到电力系统使用要求。考虑到c-C_4F_8气体对于环境的影响较小,使用c-C_4F_8/N_2混合气体作为替代SF_6的绝缘气体,有着良好的应用前景。展开更多
This paper has researched the insulation characteristics of 10% c-C4F8/N2/CO2 mixtures under lightning impulse voltage by experiment. It is shown that the positive and negative lightning impulse breakdown voltages of ...This paper has researched the insulation characteristics of 10% c-C4F8/N2/CO2 mixtures under lightning impulse voltage by experiment. It is shown that the positive and negative lightning impulse breakdown voltages of 10%c-C4F8/N2/CO2 gas mixtures rise linearly as the electrode gap distance and gas pressure increase and under the same conditions, the positive lightning impulse breakdown voltage of the gas mixtures is always higher than the negative lightning impulse breakdown voltage. As the gas mixtures have a little higher liquefied temperature than SF6 and the comprehensive GWP is about 5% of SF6, and the positive and negative lightning impulse breakdown voltages can both reach 60% of SF6, 10%c-C4F8/N2/CO2 gas mixtures can be applied as insulation gas in electrical equipment such as C-GIS, GIT, GIL and so on.展开更多
An improved Monte Carlo method was used to simulate the motion of electrons in c-C_4F_8 and SF_6 gas mixtures for pulsed townsend discharge. The electron swarm parameters such as effective ionization coefficient, [AK...An improved Monte Carlo method was used to simulate the motion of electrons in c-C_4F_8 and SF_6 gas mixtures for pulsed townsend discharge. The electron swarm parameters such as effective ionization coefficient, [AKα-] and drift velocity over the E/N range from 280～700 Td(1Td=10-21 V·m2) were calculated by employing a set of cross sections available in literature. From the variation cure of [AKα-] with SF_6 partial pressure p, the limiting field (E/N)_lim of gas mixture at different gas content was determined. It is found that the limiting field of c-C_4F_8 and SF_6 gas mixture is higher than that of pure SF_6 at any SF_6 mixture ratio. Simulation results show excellent agreement with experiment data available in previous literature.展开更多
The swarm parametes for c-C4F8/CF4 mixtures, including the density-normalized effective ionization coeffcient, drift velocity and mean energy were calculated using Monte-Carlo method with the null collision technique....The swarm parametes for c-C4F8/CF4 mixtures, including the density-normalized effective ionization coeffcient, drift velocity and mean energy were calculated using Monte-Carlo method with the null collision technique. The overall density-reduced electric field strength could be varied between 150 and 500 Td, while the c-C4F8 content in gas mixtures is varied in the range of 0-100%. The value of the density-normalized effective ionization coeffcient shows a strong dependence on the c-C4F8 content, becoming more electronegative as the content of c-C4F8 is increased. The drift velocity of c-C4F8/CF4 mixtures is more affected by CF4. The calculated limiting field strength for c-C4F8/CF4 mixtures is higher than that of SF6/CF4.展开更多
In c-C4F8 and c-C4F8/CO2 mixtures, the swarm parameters including ionization coeffcient, attachment coeffcient and effective ionization coeffcient were obtained at the ratio of the electric field strength to the gas d...In c-C4F8 and c-C4F8/CO2 mixtures, the swarm parameters including ionization coeffcient, attachment coeffcient and effective ionization coeffcient were obtained at the ratio of the electric field strength to the gas density between 150-550 Td by the steady-state Townsend (SST) method. Static breakdown voltages at each ratio were also measured at the SST condition. The limiting field strengths were obtained by two methods: computing the density-normalized effective ionization coeffcient as a function of the overall density-reduced electric field strength; and measuring static breakdown voltages as a function of the product of gas density and electrode separation. Good agreement was obtained by these two methods, which ensures the correctness of the former method. The limiting field strengths of c-C4F8 and c-C4F8/CO2 mixtures were compared with those of pure SF6, SF6/CO2 mixtures and pure c-C4F8. It is found that buffer gas CO2 does not reduce the limiting field strengths of c-C4F8 greatly, the limiting field strengths of c-C4F8/CO2 mixtures are higher than those of SF6/CO2 mixtures or even pure SF6, and so c-C4F8/CO2 mixtures are suggested to be possible substitutes for SF6.展开更多
基金supported by National Natural Science Foundation of China(No.51337006)。
文摘CF3I gas mixtures have attracted considerable attention as potential environmentally-friendly alternatives to SF6 gas,owing to their excellent insulating performance.This paper attempts to study the CF3I ternary gas mixtures with c-C4F8 and buffer gases N2 and CO2 by considering dielectric strength from electron transport parameters based on the Boltzmann method and synergistic effect analysis,compared with SF6 gas mixtures.The results confirm that the critical electric field strength of CF3I/c-C4F8/70%CO2 is greater than that of 30%SF6/70%CO2 when the CF3I content is greater than 17%.Moreover,a higher content of c-C4F8 decreases the sensitivity of gas mixtures to an electric field,and this phenomenon is more obvious in CF3I/c-C4F8/CO2 gas mixtures.The synergistic effects for CF3I/c-C4F8/70%N2 were most obvious when the c-C4F8 content was approximately 20%,and for CF3I/c-C4F8/70%CO2 when the c-C4F8 content was approximately 10%.On the basis of this research,CF3I/c-C4F8/70%N2 shows better insulation performance when the c-C4F8 content is in the15%–20%range.For CF3I/c-C4F8/70%CO2,when the c-C4F8 content is in the 10%–15%range,the gas mixtures have excellent performance.Hence,these gas systems might be used as alternative gas mixtures to SF6 in high-voltage equipment.
文摘SF_6因具有良好的绝缘效果而被广泛地应用于电力系统中。但同时,SF_6也是一种温室气体,随着环境问题日益恶化,人们迫切需要找到替代SF_6的绝缘气体。为此,通过实验研究了环境友好气体c-C_4F_8及c-C_4F_8/N_2混合气体替代SF_6的可行性。通过调节电极间隙(1~6 mm)和气压(150~350 k Pa),测量了气体在不同条件下的击穿电压及击穿电流波形,得到了气体的绝缘特性并与SF_6气体进行了对比分析。实验结果表明:纯净的c-C_4F_8气体的绝缘强度约为SF_6的1.3倍,体积比为1:1的c-C_4F_8/N_2混合气体的绝缘强度约为与SF_6的0.9倍。通过计算,c-C_4F_8/N_2混合气体的液化温度可以达到电力系统使用要求。考虑到c-C_4F_8气体对于环境的影响较小,使用c-C_4F_8/N_2混合气体作为替代SF_6的绝缘气体,有着良好的应用前景。
基金supported by National Natural Science Foundation of China (No. 51337006)
文摘This paper has researched the insulation characteristics of 10% c-C4F8/N2/CO2 mixtures under lightning impulse voltage by experiment. It is shown that the positive and negative lightning impulse breakdown voltages of 10%c-C4F8/N2/CO2 gas mixtures rise linearly as the electrode gap distance and gas pressure increase and under the same conditions, the positive lightning impulse breakdown voltage of the gas mixtures is always higher than the negative lightning impulse breakdown voltage. As the gas mixtures have a little higher liquefied temperature than SF6 and the comprehensive GWP is about 5% of SF6, and the positive and negative lightning impulse breakdown voltages can both reach 60% of SF6, 10%c-C4F8/N2/CO2 gas mixtures can be applied as insulation gas in electrical equipment such as C-GIS, GIT, GIL and so on.
文摘An improved Monte Carlo method was used to simulate the motion of electrons in c-C_4F_8 and SF_6 gas mixtures for pulsed townsend discharge. The electron swarm parameters such as effective ionization coefficient, [AKα-] and drift velocity over the E/N range from 280～700 Td(1Td=10-21 V·m2) were calculated by employing a set of cross sections available in literature. From the variation cure of [AKα-] with SF_6 partial pressure p, the limiting field (E/N)_lim of gas mixture at different gas content was determined. It is found that the limiting field of c-C_4F_8 and SF_6 gas mixture is higher than that of pure SF_6 at any SF_6 mixture ratio. Simulation results show excellent agreement with experiment data available in previous literature.
基金the National Natural Science Foundation of China (No. 50777041)
文摘The swarm parametes for c-C4F8/CF4 mixtures, including the density-normalized effective ionization coeffcient, drift velocity and mean energy were calculated using Monte-Carlo method with the null collision technique. The overall density-reduced electric field strength could be varied between 150 and 500 Td, while the c-C4F8 content in gas mixtures is varied in the range of 0-100%. The value of the density-normalized effective ionization coeffcient shows a strong dependence on the c-C4F8 content, becoming more electronegative as the content of c-C4F8 is increased. The drift velocity of c-C4F8/CF4 mixtures is more affected by CF4. The calculated limiting field strength for c-C4F8/CF4 mixtures is higher than that of SF6/CF4.
基金the National Natural Science Foundation of China (No. 50777041)
文摘In c-C4F8 and c-C4F8/CO2 mixtures, the swarm parameters including ionization coeffcient, attachment coeffcient and effective ionization coeffcient were obtained at the ratio of the electric field strength to the gas density between 150-550 Td by the steady-state Townsend (SST) method. Static breakdown voltages at each ratio were also measured at the SST condition. The limiting field strengths were obtained by two methods: computing the density-normalized effective ionization coeffcient as a function of the overall density-reduced electric field strength; and measuring static breakdown voltages as a function of the product of gas density and electrode separation. Good agreement was obtained by these two methods, which ensures the correctness of the former method. The limiting field strengths of c-C4F8 and c-C4F8/CO2 mixtures were compared with those of pure SF6, SF6/CO2 mixtures and pure c-C4F8. It is found that buffer gas CO2 does not reduce the limiting field strengths of c-C4F8 greatly, the limiting field strengths of c-C4F8/CO2 mixtures are higher than those of SF6/CO2 mixtures or even pure SF6, and so c-C4F8/CO2 mixtures are suggested to be possible substitutes for SF6.
