This study reports zircon U-Pb and Hf isotopes and whole-rock elemental data for granodiorites from the East Kunlun orogen. The zircon U-Pb dating defines their crystallization age of 235 Ma. The rocks are characteriz...This study reports zircon U-Pb and Hf isotopes and whole-rock elemental data for granodiorites from the East Kunlun orogen. The zircon U-Pb dating defines their crystallization age of 235 Ma. The rocks are characterized by high-K calc-alkaline, magnesian and metaluminous with（K2O＋Na2O）=6.38 wt.%–7.01 wt.%, Mg#=42–50 [Mg#=100×molar Mg/（Mg＋Fe OT）], A/CNK=0.92–0.98, coupled with high εHf（t） values from-0.65 to-1.80. The rocks were derived from partial melting of a juvenile mafic crustal source within normal crust thickness. The juvenile lower crust was generated by mixing lithospheric mantle-derived melt（55%–60%） and supracrustal melt（40%–45%） during the seafloor subduction. Together with available data from the East Kunlun, it is proposed that the studied Middle Triassic granodiorites were formed in post-collisional extension setting, in which melting of the juvenile lower crust in response to the basaltic magma underplating resulted in the production of high-K granodioritic melts.展开更多
The Langdu high-K calc-alkaline intrusions are located in the Zhongdian area, which is the southern part of the Yidun island arc. These intrusive rocks consist mainly of monzonite porphyry, granodiorite, and diorite p...The Langdu high-K calc-alkaline intrusions are located in the Zhongdian area, which is the southern part of the Yidun island arc. These intrusive rocks consist mainly of monzonite porphyry, granodiorite, and diorite porphyry. The K20 content of majority of these rocks is greater than 3%, and, in the K20-SiO2 diagram, all the samples fall into the high-K calc-alkaline to shoshonitic fields. They are enriched in light rare earth elements （LREEs） and depleted in heavy rare earth elements （HREEs; LaN/YbN = 14.3-21.2）, and show slightly negative Eu anomalies （6Eu = 0.77-1.00）. These rocks have high K, Rb, Sr, and Ba contents; moderate to high enrichment of compatible elements （Cr = 36.7-79.9 ppm, Co = 9.6-16.4 ppm, and MgO = 2.2%-3.4%）; low Nb, Ta, and Ti contents, and characteristic of low high field strength elements（HFSEs） versus incompatible elements ratios （Nb/Th = 0.75, Nb/La = 0.34） and incompatible elements ratios （Nb/U = 3.0 and Ce/Pb = 5.1, Ba/Rb = 12.0）. These rocks exhibit restricted Sr and Nd isotopic compositions, with （87Sr/S6Sr）i values ranging from 0.7044 to 0.7069 and ENd（t） values from -2.8 to -2.2. The Sr-Nd isotope systematic and specific trace element ratios suggest that Langdu high-K calc-alkaline intrusive rocks derived from a metasomatized mantle source. The unique geochemical feature of intrusive rocks can be modeled successfully using different members of a slightly enriched mantle, a slab-derived fluid, and terrigenous sediments. It can be inferred that the degree of partial melting and the presence of specific components are temporally related to the tectonic evolution of the Zhongdian island arc. Formation of these rocks can be explained by the various degrees of melting within an ascending region of the slightly enriched mantle, triggered by the subduction of the Garz^--Litang ocean, and an interaction between the slab-derived fluid and the terrigenous sediments.展开更多
The calc-alkaline volcanic formations in the western part of the Kedougou-Kenieba inlier crop out in three complexes: the Foulde in the North and the areas of Mako and Baniomba in the South. These complexes which eith...The calc-alkaline volcanic formations in the western part of the Kedougou-Kenieba inlier crop out in three complexes: the Foulde in the North and the areas of Mako and Baniomba in the South. These complexes which either combine with the tholeiites or cut across the sedimentary formations are composed of thin veins and massive lava flows. They have many petrographic similarities and show chemical characteristics that resemble those of island-arc rocks. At the tectonic level, the D1 deformation phase preceding the formation of the basins and the transpressive tectonics including an oblique convergence may account for the structural evolution of the Mako volcanic belt. Its occurrence in different basins may be evidenced by the composition of some lithophilic components like the Sr, Ba, U, Rb and the composition of clinopyroxenes enriched in TiO2, FeO, Na2O in the Foulde calc-alkaline volcanic rocks that developed in a sedimentary environment.展开更多
Zircon U-Pb age,whole rock geochemical and zircon Hf isotopic data are presented for Late Paleozoic granodiorites from the Taerqi region,central Daxing'anling to constrain its petrogenesis and tectonic implication...Zircon U-Pb age,whole rock geochemical and zircon Hf isotopic data are presented for Late Paleozoic granodiorites from the Taerqi region,central Daxing'anling to constrain its petrogenesis and tectonic implication.LA-ICP-MS zircon U-Pb age data indicates that the Late Paleozoic granodiorites were emplaced with age of333.4 ± 2.2 Ma(Early Carboniferous).Geochemically,the granodiorite samples have Si O2= 60.54%-71.40%,Na2 O = 4.04%--4.66%,K2 O = 1.65%--4.27% and Mg O = 0.96%--3.53%,belonging to medium-K to high-K calc-alkaline I-type granites.They are slightly enriched in large ion lithophile elements(e.g.Rb,Th,U and K) and light rare earth elements,and depleted in high field strength elements(e.g.Nb,Ta and Ti),with εHf(t) values of 8.0--11.8 and Hf two-stage model ages of 586-829 Ma.All these geochemical features suggest that the primary magma was derived from partial melting of Neoproterozoic to Phanerozoic newly accreted lower crust.According to the geochemical data and regional geological investigations,the Early Carboniferous granodiorites formed in an island arc setting linked to the subduction of the Paleo-Asian Oceanic Plate beneath the Xing'an Terrane.This also implies that the Xing'an and Songliao terranes have not amalgamated before the Early Carboniferous.展开更多
Post-collision felsic rocks in Southeastern Yunnan province contain granodiorites. U-Pb zircon ages, geochemical data and Sr-Nd isotopic data for these rocks are reported in the present paper. Laser ablation inductive...Post-collision felsic rocks in Southeastern Yunnan province contain granodiorites. U-Pb zircon ages, geochemical data and Sr-Nd isotopic data for these rocks are reported in the present paper. Laser ablation inductively coupled plasma mass spectrometry U-Pb zircon analyses yielded consistent age 252.5 ± 1.0 Ma for one sample of the felsic rocks. The granodiorites were characterized by variational and high (87Sr/86Sr)i, ranging from 0.7223 to 0.7236 and very low εNd (t) values from –29.1 to –30.4. In addition, these rocks are characterized by slight Eu negative anomalies, Nb, Ta, Ti and Sr negative anomalies on primitive mantle normalization spider. Geochemical and isotopic characteristics suggest that these rocks were derived from an enriched crust source. The granodiorites resulted from the fractionation of potassium feldspar, plagioclase and ilmenite or rutile. However, the granodiorites were unaffected by visible crustal contamination during ascent. As a result, the granodiorites may have been formed due to partial melting of crust-derived sedimentary rocks beneath southeastern Yunnan province, southern China.展开更多
The high-K calc-alkaline granitoids in the northern part of the Mandara Hills are part of the wellexposed post-collisional plutons in northeastern Nigeria.The calc-alkaline rock association consists of quartz monzodio...The high-K calc-alkaline granitoids in the northern part of the Mandara Hills are part of the wellexposed post-collisional plutons in northeastern Nigeria.The calc-alkaline rock association consists of quartz monzodiorite,hornblende biotite granite,biotite granites and aplite which intruded the older basement consisting mainly of low-lying migmatitic gneisses and amphibolites during the Neoproterozoic Pan-African Orogeny.Petrological and geochemical studies have revealed the presence of hornblende,iron oxide,and metaluminous to slightly peraluminous characteristics in the granitoids which is typical of I-type granite.The granitoids are also depleted in some high field strength elements(e.g.Nb and Ta) as well as Ti.Plots of Mg#versus SiO2 indicate that the granite was derived from partial melting of crustal sources.Lithospheric delamination at the waning stage of the PanAfrican Orogeny possibly triggered upwelling of hot mafic magma from the mantle which underplated the lower crust.This,in turn,caused partial melting and magma generation at the lower to middle-crustal level.However,the peculiar geochemical characteristics of the quartz monzodiorite especially the enrichment in compatible elements such as MgO,Cr,and Ni,as well as LILE element(e.g.K,Ce,Cs,Ba,and Sr),signify that the rock formed from an enriched upper mantle source.The emplacement of high-K granites in the Madara Hill,therefore,marked an important episode of crustal reworking during the Neoproterozoic.However,further isotopic work is needed to confirm this model.展开更多
The Wulonggou area located in the Eastern Kunlun Orogen in NW China is characterized by extensive granitoid magmatism,ductile faulting and orogenic gold mineralization.The Huanglonggou granodiorite is cut by an orogen...The Wulonggou area located in the Eastern Kunlun Orogen in NW China is characterized by extensive granitoid magmatism,ductile faulting and orogenic gold mineralization.The Huanglonggou granodiorite is cut by an orogenic gold-bearing fault.This study investigated the major and trace-element compositions,zircon U-Pb dates and zircon Hf isotopic compositions of the Huanglonggou granodiorite.One Huanglonggou granodiorite sample yielded a weighted mean U-Pb zircon age of^221 Ma(Carnian).The Carnian granodiorite is metaluminous,with high alkalis contents of 6.37%--8.86%,high Al_2O_3contents of 15.41%--16.19%,high Sr contents of(426--475)×10^(-6),relatively high Sr/Y ratios,high(La/Yb)_Nvalues and low HREE,suggesting an adakite type high-Si O_2granite.The Huanglonggou granodiorite sample has zirconε_(Hf)(t)values ranging from-4.4 to+1.1.These Hf isotopic data suggest that the Carnian granodiorite was likely derived from the partial melting of subducted Paleo-Tethys oceanic slab.It is suggested that the Late Triassic granodiorite was emplaced during the northward subduction of Paleo-Tethys oceanic slab.Orogenic gold mineralization in the Wulonggou area formed after the emplacement of the Late Triassic intrusive rocks.展开更多
Destruction of the North China Craton has caused extensive concern on its multiple potential mechanisms including thermal erosion,chemical erosion and delamination.It is widely accepted that thinning of the
1 Introduction Qilian Block is located in between the South China Craton and the North China Craton and the Tarim Craton(Fig.1a),which is one of the key area to study the tectonic evolution of China.The Phanerozoic te...1 Introduction Qilian Block is located in between the South China Craton and the North China Craton and the Tarim Craton(Fig.1a),which is one of the key area to study the tectonic evolution of China.The Phanerozoic tectonic framework展开更多
The characterization of the relationships between mineralization and hydrothermal alteration is an essential element in understanding gold deposits. In south-west Burkina Faso, the Napélépéra mineralisa...The characterization of the relationships between mineralization and hydrothermal alteration is an essential element in understanding gold deposits. In south-west Burkina Faso, the Napélépéra mineralisation, the mobility of chemical elements and alteration-mineralization relationships were studied by means of selected core drilling and geochemical analyses using ICP-MS (Inductively Coupled Plasma Mass Spectrometry) and ICP-AES (Inductively coupled plasma atomic emission spectroscopy). The mineralised granodiorite is grey porphyroid with quartz, plagioclase, biotite and amphibole. It is metaluminous and located in the tholeiitic series. The Na<sub>2</sub>O + CaO versus Fe<sub>2</sub>O<sub>3</sub> + MgO alteration diagram divides the samples according to alteration dominance. Chloritisation and carbonation are the main alterations. There is a relationship between gold mineralisation at Napélépéra and alteration, and the paragenesis of gold + pyrite ± carbonate ± silica ± sericite is the main characteristic. Carbonation is the result of fluid input in the shear corridor of the mineralised zone. The mass balance of comparative metals in the proximal and distal zones of the mineralisation shows the absence of metals, while As, Hg, Ag and Bi are strongly enriched from the distal zone to the mineralised zone. The oxides associated with the mineralisation are mainly NaO, SrO and CaO.展开更多
The early Mesozoic granodiorites (ca.165 Ma) in the northeastern Hunan Province (NEH) have SiO2=65.4-69.65%, K2O/Na2O=0.95-1.38 and K2O+Na2O>6%, A/CNK=0.96-1.13 and belong to metaluminous high-K calc-alkaline serie...The early Mesozoic granodiorites (ca.165 Ma) in the northeastern Hunan Province (NEH) have SiO2=65.4-69.65%, K2O/Na2O=0.95-1.38 and K2O+Na2O>6%, A/CNK=0.96-1.13 and belong to metaluminous high-K calc-alkaline series. They are characterized by LREE and LILEs enrichment, and HFSE depletion with slightly negative Eu anomalies (Eu/Eu*=0.62-0.90). The initial 87Sr/86Sr ratios are in range from 0.711458 to 0.717461, and εNd values vary from -9.4 to -12.3, distinct from those of the contemporaneous granodiorites mantle-derived from the Southeastern Hunan Province (SEH) (87Sr/86Sr(i)=0.707962～0.710396, εNd(t)=-6.98～-2.30). By contrast, such signatures are roughly similar to those of the neighboring other Mesozoic granitic plutons (Eu/Eu*=0.30-0.70; 87Sr/86Sr >0.710; εNd = -12 to -16) in South China Block (SCB), which have been interpreted as the remelting products of Precambrian basement. The Proterozoic lower-middle crust is an important contributor to the petrogenesis of these early Mesozoic granodiorites in the NEH. An intracontinental extension setting is present in the northeastern Hunan Province at that time due to the demand of enough thermal transfer.展开更多
In this study,we report for thefirst time an Early Palaeozoic basement diorite from the drilled well Nirona-A in the Banni Half-Graben of the Kutch basin,western India.The 40Ar–39Ar dates provided a plateau age of 441...In this study,we report for thefirst time an Early Palaeozoic basement diorite from the drilled well Nirona-A in the Banni Half-Graben of the Kutch basin,western India.The 40Ar–39Ar dates provided a plateau age of 441.84±2.66 Ma and another pseudo plateau of 441.28±5.82 to 388.08±16.65 Ma for the basement diorite.These ages constrain the basement formation age to the Late Ordovician-Early Silurian period.The obtained basement ages are correlatable with the later part of Cambro-Ordovician alkaline magmatism that has been reported from the Huqf area in Central Oman,whereas their lithological and petrographic correlativity with base-ment diorites occurring in the Dinsi Body of Nagar Parkar igneous complex in Pakistan can also be envisaged.The geochemical studies characterized the diorite with enrich-ment of LILE(Rb,Ba,and K)and LREE(La,Ce,Nd),strong depletion of HFSE(Nb,Sr,P,and Ti),along with weakly negative Eu anomalies.The geochemical signatures indicate their petrogenetic affiliation with mantle-derived magmas,as well as their tectonic setting to be arc-related,having post-collisional continental-arc type affinity.The*440 Ma basement of Kutch,therefore,appears to rep-resent the later thermal event associated with the reworked Neoproterozoic subduction-related suite from Greater India’s northwest edge,which has implications for Gond-wana assembly in the northwest Indian subcontinent.展开更多
The Yangla copper deposit, located in western Yunnan Province, China, is a typical giant, newly started mining copper deposit with an estimated Cu reserves of about 1,200,000 tons. The deposit is spatially and tempora...The Yangla copper deposit, located in western Yunnan Province, China, is a typical giant, newly started mining copper deposit with an estimated Cu reserves of about 1,200,000 tons. The deposit is spatially and temporally associated with the Linong granodiorite, which is rich in SiO2 （SIO2=58.25 wt%-69.84 wt%） and alkalis （Na20＋K20=5.98 wt%-8.34 wt%）, indicating an association with shoshonitic series to high-K calc-alkaline series granites, and shows low contents of TiO2 （0.35 wt%- 0.48 wt%）, MgO （1.51 wt%-1.72 wt%）, and A1203 （13.38 wt%-19.75 wt%）. The 34S values of sulfides of the main ore stage from copper ores vary range from -4.2%o to -0.9%o, indicating a much greater contribution from the mantle to the ore-forming fluids. The 34S values of the late ore stage is -9.8%0, indicating enrichment of biogenic sulfur which may derive from the crustal hydrothermal fluid. The 208pb/204pb, 207pb/204pb and 206pb/204pb of sulfides of the main ore stage from copper ores range within 38.66-38.73, 15.71-15.74 and 18.35-19.04, respectively, implying that the Pb was derived from the mantle, with the crustal component, probably representing mixtures of mantle lead and crustal lead. Sulfide of the late ore stage in their Pb isotopic composition, 208pb/204pb= 38.69, 207pb/204pb=15.70, 206Pb/204pb=18.35, implying that the Pb was derived from the crust. The Linong granodiorite is syn- collisional, produced by partial melting of thickened lower crust, which was triggered by the westward subduction of the Jinshajiang Oceanic plate. During a transition in geodynamic setting from collision- related compression to extension, gently dipping ductile shear zones （related to subduction） were transformed to brittle shear zones, consisting of a series of thrust faults in the Jinshajiang tectonic belt. The tensional thrust faults would have been a favorable environment for ore-forming fluids. The ascending magma provided a channel for the ore-forming fluid from the mantle wedge. After the magma arrived at the base of the early-stage Linong granodiorite, the platy granodiorite at the base of the body would have shielded the late-stage magma from the fluid. The magma would have cooled slowly, and some of the ore-forming fluid in the magma would have entered the gently dipping thrust faults near the Linong granodiorite, resulting in mineralization.展开更多
The Qushi’ang granodiorite（QSG） is located at the central east of the ophiolitic melange belt in the East Kunlun Orogenic Belt（EKOB） in the northern margin of the Qinghai-Tibetan Plateau. LA-MC-ICP-MS zircon U–P...The Qushi’ang granodiorite（QSG） is located at the central east of the ophiolitic melange belt in the East Kunlun Orogenic Belt（EKOB） in the northern margin of the Qinghai-Tibetan Plateau. LA-MC-ICP-MS zircon U–Pb dating suggests that the granodiorite and mafic microgranular enclaves（MMEs） crystallized 246.61±0.62 and 245.45±0.9 Ma ago, respectively. Granodiorite, porphyritic diorite, and MMEs are metaluminous and medium-K calk-alkaline series, with island-arc magma features, such as LILE enrichment and HFSE depletion. The porphyritic diorite has high Cr（13.50 ppm to 59.01 ppm）, Ni（228.53 ppm to 261.29 ppm）, and Mg~#（46–54）. Granodiorite and porphyritic diorite have similar mineral compositions and evolved major and trace elements contents, particularly Cr and Ni, both of which are significantly higher than that in granites of the same period. The crystallization age of MMEs is close to that of granodiorite, and their major and trace elements contents are in-between porphyritic diorite and granodiorite. The results suggest that the original mafic magma, which was the product of mantle melting by subduction process, intruded into the lower crust（Kuhai Rock Group）, resulting in the formation of granodiorite. Countinous intrusion of mafic magma into the unconsolidated granodiorite formed MMEs and porphyritic diorite. The granodiorite reformed by late-stage strike-slip faulting tectonic event indicates that the strike-slip fault of Middle Kunlun and the collision of the Bayanhar block with East Kunlun were later than 246 Ma. Therefore, the formation of the QSG not only indicates the critical period of evolution of East Kunlun but also represents the tectonic transition from oceanic crust subduction to slab breaking.展开更多
基金financially supported by the China Geological Survey(Nos.12120115069701,12120113095700 and 1212011220391)the National Natural Science Foundation of China(No.41272079)+2 种基金the China Postdoctoral Science Foundation-China(No.2015M582529)the State Key Laborato-ry of Continental Tectonics and Dynamics(No.K201508)the Special Financial Support Program of Central Government for Local Universities(No.80000-14Z019)
文摘This study reports zircon U-Pb and Hf isotopes and whole-rock elemental data for granodiorites from the East Kunlun orogen. The zircon U-Pb dating defines their crystallization age of 235 Ma. The rocks are characterized by high-K calc-alkaline, magnesian and metaluminous with（K2O＋Na2O）=6.38 wt.%–7.01 wt.%, Mg#=42–50 [Mg#=100×molar Mg/（Mg＋Fe OT）], A/CNK=0.92–0.98, coupled with high εHf（t） values from-0.65 to-1.80. The rocks were derived from partial melting of a juvenile mafic crustal source within normal crust thickness. The juvenile lower crust was generated by mixing lithospheric mantle-derived melt（55%–60%） and supracrustal melt（40%–45%） during the seafloor subduction. Together with available data from the East Kunlun, it is proposed that the studied Middle Triassic granodiorites were formed in post-collisional extension setting, in which melting of the juvenile lower crust in response to the basaltic magma underplating resulted in the production of high-K granodioritic melts.
基金supported by the National Science Foundation of China (NSFC) project(41203039)the innovation team of ore-forming dynamics and prediction of concealed deposits, KMUST(2008)
文摘The Langdu high-K calc-alkaline intrusions are located in the Zhongdian area, which is the southern part of the Yidun island arc. These intrusive rocks consist mainly of monzonite porphyry, granodiorite, and diorite porphyry. The K20 content of majority of these rocks is greater than 3%, and, in the K20-SiO2 diagram, all the samples fall into the high-K calc-alkaline to shoshonitic fields. They are enriched in light rare earth elements （LREEs） and depleted in heavy rare earth elements （HREEs; LaN/YbN = 14.3-21.2）, and show slightly negative Eu anomalies （6Eu = 0.77-1.00）. These rocks have high K, Rb, Sr, and Ba contents; moderate to high enrichment of compatible elements （Cr = 36.7-79.9 ppm, Co = 9.6-16.4 ppm, and MgO = 2.2%-3.4%）; low Nb, Ta, and Ti contents, and characteristic of low high field strength elements（HFSEs） versus incompatible elements ratios （Nb/Th = 0.75, Nb/La = 0.34） and incompatible elements ratios （Nb/U = 3.0 and Ce/Pb = 5.1, Ba/Rb = 12.0）. These rocks exhibit restricted Sr and Nd isotopic compositions, with （87Sr/S6Sr）i values ranging from 0.7044 to 0.7069 and ENd（t） values from -2.8 to -2.2. The Sr-Nd isotope systematic and specific trace element ratios suggest that Langdu high-K calc-alkaline intrusive rocks derived from a metasomatized mantle source. The unique geochemical feature of intrusive rocks can be modeled successfully using different members of a slightly enriched mantle, a slab-derived fluid, and terrigenous sediments. It can be inferred that the degree of partial melting and the presence of specific components are temporally related to the tectonic evolution of the Zhongdian island arc. Formation of these rocks can be explained by the various degrees of melting within an ascending region of the slightly enriched mantle, triggered by the subduction of the Garz^--Litang ocean, and an interaction between the slab-derived fluid and the terrigenous sediments.
文摘The calc-alkaline volcanic formations in the western part of the Kedougou-Kenieba inlier crop out in three complexes: the Foulde in the North and the areas of Mako and Baniomba in the South. These complexes which either combine with the tholeiites or cut across the sedimentary formations are composed of thin veins and massive lava flows. They have many petrographic similarities and show chemical characteristics that resemble those of island-arc rocks. At the tectonic level, the D1 deformation phase preceding the formation of the basins and the transpressive tectonics including an oblique convergence may account for the structural evolution of the Mako volcanic belt. Its occurrence in different basins may be evidenced by the composition of some lithophilic components like the Sr, Ba, U, Rb and the composition of clinopyroxenes enriched in TiO2, FeO, Na2O in the Foulde calc-alkaline volcanic rocks that developed in a sedimentary environment.
基金supported by the China Geological Survey (Grants 201301009018)
文摘Zircon U-Pb age,whole rock geochemical and zircon Hf isotopic data are presented for Late Paleozoic granodiorites from the Taerqi region,central Daxing'anling to constrain its petrogenesis and tectonic implication.LA-ICP-MS zircon U-Pb age data indicates that the Late Paleozoic granodiorites were emplaced with age of333.4 ± 2.2 Ma(Early Carboniferous).Geochemically,the granodiorite samples have Si O2= 60.54%-71.40%,Na2 O = 4.04%--4.66%,K2 O = 1.65%--4.27% and Mg O = 0.96%--3.53%,belonging to medium-K to high-K calc-alkaline I-type granites.They are slightly enriched in large ion lithophile elements(e.g.Rb,Th,U and K) and light rare earth elements,and depleted in high field strength elements(e.g.Nb,Ta and Ti),with εHf(t) values of 8.0--11.8 and Hf two-stage model ages of 586-829 Ma.All these geochemical features suggest that the primary magma was derived from partial melting of Neoproterozoic to Phanerozoic newly accreted lower crust.According to the geochemical data and regional geological investigations,the Early Carboniferous granodiorites formed in an island arc setting linked to the subduction of the Paleo-Asian Oceanic Plate beneath the Xing'an Terrane.This also implies that the Xing'an and Songliao terranes have not amalgamated before the Early Carboniferous.
文摘Post-collision felsic rocks in Southeastern Yunnan province contain granodiorites. U-Pb zircon ages, geochemical data and Sr-Nd isotopic data for these rocks are reported in the present paper. Laser ablation inductively coupled plasma mass spectrometry U-Pb zircon analyses yielded consistent age 252.5 ± 1.0 Ma for one sample of the felsic rocks. The granodiorites were characterized by variational and high (87Sr/86Sr)i, ranging from 0.7223 to 0.7236 and very low εNd (t) values from –29.1 to –30.4. In addition, these rocks are characterized by slight Eu negative anomalies, Nb, Ta, Ti and Sr negative anomalies on primitive mantle normalization spider. Geochemical and isotopic characteristics suggest that these rocks were derived from an enriched crust source. The granodiorites resulted from the fractionation of potassium feldspar, plagioclase and ilmenite or rutile. However, the granodiorites were unaffected by visible crustal contamination during ascent. As a result, the granodiorites may have been formed due to partial melting of crust-derived sedimentary rocks beneath southeastern Yunnan province, southern China.
文摘The high-K calc-alkaline granitoids in the northern part of the Mandara Hills are part of the wellexposed post-collisional plutons in northeastern Nigeria.The calc-alkaline rock association consists of quartz monzodiorite,hornblende biotite granite,biotite granites and aplite which intruded the older basement consisting mainly of low-lying migmatitic gneisses and amphibolites during the Neoproterozoic Pan-African Orogeny.Petrological and geochemical studies have revealed the presence of hornblende,iron oxide,and metaluminous to slightly peraluminous characteristics in the granitoids which is typical of I-type granite.The granitoids are also depleted in some high field strength elements(e.g.Nb and Ta) as well as Ti.Plots of Mg#versus SiO2 indicate that the granite was derived from partial melting of crustal sources.Lithospheric delamination at the waning stage of the PanAfrican Orogeny possibly triggered upwelling of hot mafic magma from the mantle which underplated the lower crust.This,in turn,caused partial melting and magma generation at the lower to middle-crustal level.However,the peculiar geochemical characteristics of the quartz monzodiorite especially the enrichment in compatible elements such as MgO,Cr,and Ni,as well as LILE element(e.g.K,Ce,Cs,Ba,and Sr),signify that the rock formed from an enriched upper mantle source.The emplacement of high-K granites in the Madara Hill,therefore,marked an important episode of crustal reworking during the Neoproterozoic.However,further isotopic work is needed to confirm this model.
基金Supported by Project of National Natural Science Foundation of China(No.41572056)
文摘The Wulonggou area located in the Eastern Kunlun Orogen in NW China is characterized by extensive granitoid magmatism,ductile faulting and orogenic gold mineralization.The Huanglonggou granodiorite is cut by an orogenic gold-bearing fault.This study investigated the major and trace-element compositions,zircon U-Pb dates and zircon Hf isotopic compositions of the Huanglonggou granodiorite.One Huanglonggou granodiorite sample yielded a weighted mean U-Pb zircon age of^221 Ma(Carnian).The Carnian granodiorite is metaluminous,with high alkalis contents of 6.37%--8.86%,high Al_2O_3contents of 15.41%--16.19%,high Sr contents of(426--475)×10^(-6),relatively high Sr/Y ratios,high(La/Yb)_Nvalues and low HREE,suggesting an adakite type high-Si O_2granite.The Huanglonggou granodiorite sample has zirconε_(Hf)(t)values ranging from-4.4 to+1.1.These Hf isotopic data suggest that the Carnian granodiorite was likely derived from the partial melting of subducted Paleo-Tethys oceanic slab.It is suggested that the Late Triassic granodiorite was emplaced during the northward subduction of Paleo-Tethys oceanic slab.Orogenic gold mineralization in the Wulonggou area formed after the emplacement of the Late Triassic intrusive rocks.
文摘Destruction of the North China Craton has caused extensive concern on its multiple potential mechanisms including thermal erosion,chemical erosion and delamination.It is widely accepted that thinning of the
基金supported by the China Geological Survey (1212011086065, 12120113033004, 121201010000150014-40)
文摘1 Introduction Qilian Block is located in between the South China Craton and the North China Craton and the Tarim Craton(Fig.1a),which is one of the key area to study the tectonic evolution of China.The Phanerozoic tectonic framework
文摘The characterization of the relationships between mineralization and hydrothermal alteration is an essential element in understanding gold deposits. In south-west Burkina Faso, the Napélépéra mineralisation, the mobility of chemical elements and alteration-mineralization relationships were studied by means of selected core drilling and geochemical analyses using ICP-MS (Inductively Coupled Plasma Mass Spectrometry) and ICP-AES (Inductively coupled plasma atomic emission spectroscopy). The mineralised granodiorite is grey porphyroid with quartz, plagioclase, biotite and amphibole. It is metaluminous and located in the tholeiitic series. The Na<sub>2</sub>O + CaO versus Fe<sub>2</sub>O<sub>3</sub> + MgO alteration diagram divides the samples according to alteration dominance. Chloritisation and carbonation are the main alterations. There is a relationship between gold mineralisation at Napélépéra and alteration, and the paragenesis of gold + pyrite ± carbonate ± silica ± sericite is the main characteristic. Carbonation is the result of fluid input in the shear corridor of the mineralised zone. The mass balance of comparative metals in the proximal and distal zones of the mineralisation shows the absence of metals, while As, Hg, Ag and Bi are strongly enriched from the distal zone to the mineralised zone. The oxides associated with the mineralisation are mainly NaO, SrO and CaO.
基金This project was jointly supported by China National Natural Science Foundation(Grant No.40334039)CAS Knowledge Innovation Project(Grant No.KZCX1-102)CAS Key Laboratory ofIsotope Geochronology and Geochemistry(Grant No.GIGCX-03-01)
文摘The early Mesozoic granodiorites (ca.165 Ma) in the northeastern Hunan Province (NEH) have SiO2=65.4-69.65%, K2O/Na2O=0.95-1.38 and K2O+Na2O>6%, A/CNK=0.96-1.13 and belong to metaluminous high-K calc-alkaline series. They are characterized by LREE and LILEs enrichment, and HFSE depletion with slightly negative Eu anomalies (Eu/Eu*=0.62-0.90). The initial 87Sr/86Sr ratios are in range from 0.711458 to 0.717461, and εNd values vary from -9.4 to -12.3, distinct from those of the contemporaneous granodiorites mantle-derived from the Southeastern Hunan Province (SEH) (87Sr/86Sr(i)=0.707962～0.710396, εNd(t)=-6.98～-2.30). By contrast, such signatures are roughly similar to those of the neighboring other Mesozoic granitic plutons (Eu/Eu*=0.30-0.70; 87Sr/86Sr >0.710; εNd = -12 to -16) in South China Block (SCB), which have been interpreted as the remelting products of Precambrian basement. The Proterozoic lower-middle crust is an important contributor to the petrogenesis of these early Mesozoic granodiorites in the NEH. An intracontinental extension setting is present in the northeastern Hunan Province at that time due to the demand of enough thermal transfer.
文摘In this study,we report for thefirst time an Early Palaeozoic basement diorite from the drilled well Nirona-A in the Banni Half-Graben of the Kutch basin,western India.The 40Ar–39Ar dates provided a plateau age of 441.84±2.66 Ma and another pseudo plateau of 441.28±5.82 to 388.08±16.65 Ma for the basement diorite.These ages constrain the basement formation age to the Late Ordovician-Early Silurian period.The obtained basement ages are correlatable with the later part of Cambro-Ordovician alkaline magmatism that has been reported from the Huqf area in Central Oman,whereas their lithological and petrographic correlativity with base-ment diorites occurring in the Dinsi Body of Nagar Parkar igneous complex in Pakistan can also be envisaged.The geochemical studies characterized the diorite with enrich-ment of LILE(Rb,Ba,and K)and LREE(La,Ce,Nd),strong depletion of HFSE(Nb,Sr,P,and Ti),along with weakly negative Eu anomalies.The geochemical signatures indicate their petrogenetic affiliation with mantle-derived magmas,as well as their tectonic setting to be arc-related,having post-collisional continental-arc type affinity.The*440 Ma basement of Kutch,therefore,appears to rep-resent the later thermal event associated with the reworked Neoproterozoic subduction-related suite from Greater India’s northwest edge,which has implications for Gond-wana assembly in the northwest Indian subcontinent.
基金supported by the National Basic Research Program of China (2009CB421003,2009CB421005)by the 111 Project (Grant No. B07011)
文摘The Yangla copper deposit, located in western Yunnan Province, China, is a typical giant, newly started mining copper deposit with an estimated Cu reserves of about 1,200,000 tons. The deposit is spatially and temporally associated with the Linong granodiorite, which is rich in SiO2 （SIO2=58.25 wt%-69.84 wt%） and alkalis （Na20＋K20=5.98 wt%-8.34 wt%）, indicating an association with shoshonitic series to high-K calc-alkaline series granites, and shows low contents of TiO2 （0.35 wt%- 0.48 wt%）, MgO （1.51 wt%-1.72 wt%）, and A1203 （13.38 wt%-19.75 wt%）. The 34S values of sulfides of the main ore stage from copper ores vary range from -4.2%o to -0.9%o, indicating a much greater contribution from the mantle to the ore-forming fluids. The 34S values of the late ore stage is -9.8%0, indicating enrichment of biogenic sulfur which may derive from the crustal hydrothermal fluid. The 208pb/204pb, 207pb/204pb and 206pb/204pb of sulfides of the main ore stage from copper ores range within 38.66-38.73, 15.71-15.74 and 18.35-19.04, respectively, implying that the Pb was derived from the mantle, with the crustal component, probably representing mixtures of mantle lead and crustal lead. Sulfide of the late ore stage in their Pb isotopic composition, 208pb/204pb= 38.69, 207pb/204pb=15.70, 206Pb/204pb=18.35, implying that the Pb was derived from the crust. The Linong granodiorite is syn- collisional, produced by partial melting of thickened lower crust, which was triggered by the westward subduction of the Jinshajiang Oceanic plate. During a transition in geodynamic setting from collision- related compression to extension, gently dipping ductile shear zones （related to subduction） were transformed to brittle shear zones, consisting of a series of thrust faults in the Jinshajiang tectonic belt. The tensional thrust faults would have been a favorable environment for ore-forming fluids. The ascending magma provided a channel for the ore-forming fluid from the mantle wedge. After the magma arrived at the base of the early-stage Linong granodiorite, the platy granodiorite at the base of the body would have shielded the late-stage magma from the fluid. The magma would have cooled slowly, and some of the ore-forming fluid in the magma would have entered the gently dipping thrust faults near the Linong granodiorite, resulting in mineralization.
基金jointly supported by the National Science Foundation of China (Grant No.,41472191,41502191,41172186,40972136)the Special Fund for Basic Scientific Research of Central Colleages,Chang'an University (Grant Nos.310827161002,310827161006)the Commonweal Geological Survey,the Aluminum Corporation of China and the Land-Resources Department of Qinghai Province (Grant No.,200801)
文摘The Qushi’ang granodiorite（QSG） is located at the central east of the ophiolitic melange belt in the East Kunlun Orogenic Belt（EKOB） in the northern margin of the Qinghai-Tibetan Plateau. LA-MC-ICP-MS zircon U–Pb dating suggests that the granodiorite and mafic microgranular enclaves（MMEs） crystallized 246.61±0.62 and 245.45±0.9 Ma ago, respectively. Granodiorite, porphyritic diorite, and MMEs are metaluminous and medium-K calk-alkaline series, with island-arc magma features, such as LILE enrichment and HFSE depletion. The porphyritic diorite has high Cr（13.50 ppm to 59.01 ppm）, Ni（228.53 ppm to 261.29 ppm）, and Mg~#（46–54）. Granodiorite and porphyritic diorite have similar mineral compositions and evolved major and trace elements contents, particularly Cr and Ni, both of which are significantly higher than that in granites of the same period. The crystallization age of MMEs is close to that of granodiorite, and their major and trace elements contents are in-between porphyritic diorite and granodiorite. The results suggest that the original mafic magma, which was the product of mantle melting by subduction process, intruded into the lower crust（Kuhai Rock Group）, resulting in the formation of granodiorite. Countinous intrusion of mafic magma into the unconsolidated granodiorite formed MMEs and porphyritic diorite. The granodiorite reformed by late-stage strike-slip faulting tectonic event indicates that the strike-slip fault of Middle Kunlun and the collision of the Bayanhar block with East Kunlun were later than 246 Ma. Therefore, the formation of the QSG not only indicates the critical period of evolution of East Kunlun but also represents the tectonic transition from oceanic crust subduction to slab breaking.
