A type of calcium coke was developed for use in the oxy-thermal process of calcium carbide production.The calcium coke was prepared by the co-pyrolysis of coking coal and calcium carbide slag, which is a solid waste g...A type of calcium coke was developed for use in the oxy-thermal process of calcium carbide production.The calcium coke was prepared by the co-pyrolysis of coking coal and calcium carbide slag, which is a solid waste generated from the chlor-alkali industry.The characteristics of the calcium cokes under different conditions were analyzed experimentally and theoretically.The results show that the thermal strength of calcium coke increased with the increase in the coking coal proportion, and the waterproof property of calcium coke also increased with increased carbonation time.The calcium coke can increase the contact area of calcium and carbon in the calcium carbide production process.Furthermore, the pore structure of the calcium coke can enhance the diffusion of gas inside the furnace, thus improving the efficiency of the oxy-thermal technology.展开更多
In this paper, lab scale production carried out of calcium carbonate in 400 mL open cylindrical beaker reactor following fuzzy logic approach is reported. 10 grams of Calcium hydroxide is mixed in 250 mL deionized wat...In this paper, lab scale production carried out of calcium carbonate in 400 mL open cylindrical beaker reactor following fuzzy logic approach is reported. 10 grams of Calcium hydroxide is mixed in 250 mL deionized water. Continuous jet supply of carbon dioxide is maintained at controlled flow rate. Reaction histories are noted for different reaction temperatures. Continuous constant magnetic stirring is applied to maintain homogeneity. The data obtained is fuzzified by constructing universe of discourse of temperature, reaction time, and amounts of reactants with reaction conversion. Rule based model is tabulated and results show that fuzzy logic approach is promising to set on data to plan and scale up the process. It is also found that a jump can not be made at this time with few studies of fuzzy logic applications to physiochemical processes unless otherwise amassing and storing up plentiful deduced explorations.展开更多
Composition, morphology, and structure of hydration products in hardened pastes of three kinds of blended cement(cement-silica fume, cement-quartz powder and cement-silica fume-quartz powder) hydrated under differen...Composition, morphology, and structure of hydration products in hardened pastes of three kinds of blended cement(cement-silica fume, cement-quartz powder and cement-silica fume-quartz powder) hydrated under different curing regimes(standard curing, 90 ℃ steam curing, 200 ℃ and 250 ℃ autoclave curing) were investigated by X-ray diffraction and field emission scanning electron microscope equipped with EDAX system. Results showed that the main hydration products in three kinds of hardened pastes under standard curing condition are all C-S-H gels, CH, and AFt. Under 90 ℃ steam curing condition, the main hydration products of cement-silica fume and cement-silica fume-quartz powder are C-S-H gels, whereas those of cement-quartz powder are C-S-H and CH. Under 200 or 250 ℃ autoclave curing condition, no obvious crystallized CH phase is found in hardened pastes of three kinds of blended cement, and C-S-H gels are transformed into one or more crystalline phases such as tobermorite, jennite, and xonotlite. The chemical composition and morphology of these crystalline phases depend on the composition of mixture and autoclave temperature.展开更多
In this work, CaO-NiO mixed oxide powders were evaluated as consecutive CO;chemisorbents and catalytic materials for hydrogen production thought the CH;reforming process. Between the NiO impregnated CaO and CaO-NiO me...In this work, CaO-NiO mixed oxide powders were evaluated as consecutive CO;chemisorbents and catalytic materials for hydrogen production thought the CH;reforming process. Between the NiO impregnated CaO and CaO-NiO mechanical composite, the first one presented better chemical behaviors during the CO;capture and CH;reforming processes, obtaining syngas(H;+ CO) as final product. Results showed that syngas was produced at two different temperature ranges, between 400 and 600 °C and at T > 800 °C, where the first temperature range corresponds to the CH;reforming process but the second temperature range was attributed to a different catalytic reaction process: CH;partial oxidation. These results were confirmed through different isothermal and cyclic experiments as well as by XRD analysis of the final catalytic products, where the nickel reduction was evidenced. Moreover, when a CO-O;flow was used during the carbonation process a triple process was achieved:(i) CO oxidation,(ii) CO;chemisorption and(iii) CH;reforming. Using this gas flow the hydrogen production was always higher than that obtained with CO;.展开更多
The present study aimed to assess calcium intake, dietary sources of this nutrient and its adequacy with respect to the dietary reference intake (DRI) in a representative sample of Spanish adults. In this study 418 ad...The present study aimed to assess calcium intake, dietary sources of this nutrient and its adequacy with respect to the dietary reference intake (DRI) in a representative sample of Spanish adults. In this study 418 adults (18 to 60 years) from 15 Spanish provinces were studied. Energy and nutrient intake was determined using a 24-hour recall questionnaire for two days. Adequacy of calcium intake was assessed using the established DRI for calcium. Anthropometric data (weight and height) were measured and the body mass index was calculated. Seventy eight percent of the participants in the study did not meet the DRI for calcium. Additionally, 33.7% of the participants did not meet the 67% of the DRI. The daily intake of calcium was 916.6 ± 288.1 mg/day, which represented the 81.3% of the DRI of calcium. Interestingly, subjects who had higher intake of calcium were taller. Additionally, it has been observed that individuals with normal body weight (BMI 2) had higher intakes of dairy products in comparison with overweight and obese individuals (BMI ≥ 25 kg/m2). The main food sources of calcium were dairy products (58.7% of calcium), cereals (13.6%) and vegetables (6.5%). Less than 1% (0.5%) of the calcium intake came from dietary supplements. It was observed that individuals who met the DRI for calcium had a significantly higher intake of dairy products (551.3 ± 240.4 g/day) than individuals who did not meet the DRI of calcium (305.0 ± 150.3 g/day). Calcium intake was inadequate in this sample of the adult Spanish population. Therefore, an increase in the consumption of dairy products, as well as cereals, vegetables and food items fortified with calcium seems to be necessary to achieve an adequate intake of calcium and to prevent diseases caused by calcium deficiency.展开更多
Dairy food consumption is important for children as it contributes to the intake of key nutrients, especially calcium. The aim of the present paper is to provide an overview of dairy products consumption for French ch...Dairy food consumption is important for children as it contributes to the intake of key nutrients, especially calcium. The aim of the present paper is to provide an overview of dairy products consumption for French children, according to age, sex and type of dairy products. Adequacy of dairy and calcium intakes in line with French national guidelines “3 portions of dairy products per day” were also evaluated. Data were extracted and analyzed from the CCAF—Comportementet Consommations Alimentairesen France-study. Seven-day questionnaires were administered to free-living individuals from autumn 2009 to summer 2010. Subjects were children (n = 1171) aged 3 - 17 years. Dairy products contributed substantially to the intake of calcium, phosphorus, potassium, zinc, vitamin B2 and vitamin B12. A general decrease in DP consumption has been observed since 2003. This is most notably due to a lower milk intake which is not compensated by increased cheese or fresh dairy products. Most of children (67%), and up to 73% of adolescents (15 - 17 y), did not reach the recommended “3 servings of dairy products per day”. Twenty percent of children from the age of 6 and nearly 2/3 of female adolescents did not reach their estimated average requirement for calcium. The overview of French dairy food consumption during childhood, of particular Public Health concern, emphasizes the need to encourage dairy consumption and particularly milk consumption at breakfast in order to maintain a nutrient adequacy in children and adolescents.展开更多
A method for producing size- and shape-con-trolled calcium alginate beads with immobilized proteins was developed. Unlike previous cal-cium alginate bead production methods, pro-tein-immobilized alginate beads with un...A method for producing size- and shape-con-trolled calcium alginate beads with immobilized proteins was developed. Unlike previous cal-cium alginate bead production methods, pro-tein-immobilized alginate beads with uniform shape and sizes less then 20 micrometers in diameter could successfully be produced by using sonic vibration. BSA and FITC-conjugated anti-BSA antibodies were used to confirm pro-tein immobilization in the alginate beads. Pro-tein diffusion from the beads could be reduced to less than 10% by cross-linking the proteins to the alginate with 1-ethyl-3-(3-dimethylamino-propyl)carbodiimide (EDC) and N-hydroxysul-fosuccinimide (NHSS). The calcium alginate beads could also be arranged freely on a slide glass by using a femtosecond laser.展开更多
The compressive strength,hydration products and microstructure of concrete with calcium-enriched fly ash(CEFA) at different temperature were investigated.The result indicates that the hydration products age of 7 d at-...The compressive strength,hydration products and microstructure of concrete with calcium-enriched fly ash(CEFA) at different temperature were investigated.The result indicates that the hydration products age of 7 d at-15 ℃ are mainly ettringite and C-S-H,and fly ash particles remain original state.Standard curing was adapted after 7 d curing at-15 ℃.At the age of 35 d,C-S-H was found on the surface of fly ash particles.The hydration product of CEFA is mainly C-S-H gel,which can densify the microstructure of concrete.展开更多
目的探究骨折患者初期血钙、血磷、钙磷乘积水平变化并分析其与骨折部位的相关性。方法选取2021年1月~2023年11月四川省骨科医院收治的骨折患者1049例作为研究对象,按骨折部位粗分为两组:上半身部位骨折(n=478)和下半身部位骨折(n=571)...目的探究骨折患者初期血钙、血磷、钙磷乘积水平变化并分析其与骨折部位的相关性。方法选取2021年1月~2023年11月四川省骨科医院收治的骨折患者1049例作为研究对象,按骨折部位粗分为两组:上半身部位骨折(n=478)和下半身部位骨折(n=571);细分十组:椎体骨折(n=108)、锁骨骨折(n=109)、上肢骨折(n=106)、手部骨折(n=104)、股骨颈骨折(n=103)、股骨粗隆间骨折(n=106)、髌骨骨折(n=101)、下肢骨折(n=103)、足部骨折(n=105)和其他骨折(n=104)。另选取同期健康体检人群110例作为对照组。全部患者于急诊当日和入院后24~48h两次抽取静脉血测定血钙、血磷,并计算钙磷乘积,比较三者水平变化并分析其与骨折部位的相关性。结果与对照组比较,骨折患者急诊当日和入院后24~48h,血钙(2.27±0.12 mmol/L,2.19±0.12 mmol/L vs2.35±0.10mmol/L)、血磷(1.00±0.20mmol/L,1.08±0.19mmol/L vs 1.15±0.15mmol/L)、钙磷乘积(28.10±6.00mg/dl,29.30±5.85mg/dl vs 33.41±4.87mg/dl)均降低,差异具有统计学意义(t=6.804,12.501;7.475,3.722;8.964,7.115,均P<0.01)。上、下半身骨折相比,急诊当日血钙、血磷和钙磷乘积下半身骨折低于上半身骨折(t=4.129,5.931,6.660,均P<0.01);入院后24~48h则仅钙、钙磷乘积下半身骨折低于上半身骨折(t=6.432,1.990,均P<0.05),差异具有统计学意义。沿时间轴比较,入院后24~48h与急诊当日相比,上、下半身骨折均表现出血钙降低而血磷升高(t=12.779,-5.730;16.919,-14.358),钙磷乘积则仅下半身骨折较急诊当日升高(t=-8.860),差异具有统计学意义(均P<0.01)。不同部位骨折患者入院后24~48h与急诊当日相比,除椎体骨折外,其余九组血钙均降低(t=6.233~11.349);除上肢骨折、手部骨折外,其余八组血磷升高(t=-7.770~-3.327);椎体骨折、股骨颈骨折、股骨粗隆间骨折、下肢骨折、足部骨折、其他骨折钙磷乘积升高(t=-5.819~-2.927),差异具有统计学意义(均P<0.01)。结论骨折患者急诊当日血钙、血磷和钙磷乘积均降低,24~48h后多数患者血钙持续降低,血磷和钙磷乘积逐渐回升,其水平变化程度与骨折部位有关。展开更多
基金financially supported by the Natural Science Foundation of China (Nos.U1610101 and 21776288)the Green Process Manufacturing Innovation Research Institute, Chinese Academy of Sciences (No.IAGM-2019-A09)the funding support from Vinnova (Dn: 2018-05293)。
文摘A type of calcium coke was developed for use in the oxy-thermal process of calcium carbide production.The calcium coke was prepared by the co-pyrolysis of coking coal and calcium carbide slag, which is a solid waste generated from the chlor-alkali industry.The characteristics of the calcium cokes under different conditions were analyzed experimentally and theoretically.The results show that the thermal strength of calcium coke increased with the increase in the coking coal proportion, and the waterproof property of calcium coke also increased with increased carbonation time.The calcium coke can increase the contact area of calcium and carbon in the calcium carbide production process.Furthermore, the pore structure of the calcium coke can enhance the diffusion of gas inside the furnace, thus improving the efficiency of the oxy-thermal technology.
文摘In this paper, lab scale production carried out of calcium carbonate in 400 mL open cylindrical beaker reactor following fuzzy logic approach is reported. 10 grams of Calcium hydroxide is mixed in 250 mL deionized water. Continuous jet supply of carbon dioxide is maintained at controlled flow rate. Reaction histories are noted for different reaction temperatures. Continuous constant magnetic stirring is applied to maintain homogeneity. The data obtained is fuzzified by constructing universe of discourse of temperature, reaction time, and amounts of reactants with reaction conversion. Rule based model is tabulated and results show that fuzzy logic approach is promising to set on data to plan and scale up the process. It is also found that a jump can not be made at this time with few studies of fuzzy logic applications to physiochemical processes unless otherwise amassing and storing up plentiful deduced explorations.
基金Funded by the National Natural Science Foundation of China(Nos.51272193,51372183,51072150)Program for New Century Excellent Talents in University(No.NCET-10-0660)the National Key Research Projects(No.2016YFB0303501)
文摘Composition, morphology, and structure of hydration products in hardened pastes of three kinds of blended cement(cement-silica fume, cement-quartz powder and cement-silica fume-quartz powder) hydrated under different curing regimes(standard curing, 90 ℃ steam curing, 200 ℃ and 250 ℃ autoclave curing) were investigated by X-ray diffraction and field emission scanning electron microscope equipped with EDAX system. Results showed that the main hydration products in three kinds of hardened pastes under standard curing condition are all C-S-H gels, CH, and AFt. Under 90 ℃ steam curing condition, the main hydration products of cement-silica fume and cement-silica fume-quartz powder are C-S-H gels, whereas those of cement-quartz powder are C-S-H and CH. Under 200 or 250 ℃ autoclave curing condition, no obvious crystallized CH phase is found in hardened pastes of three kinds of blended cement, and C-S-H gels are transformed into one or more crystalline phases such as tobermorite, jennite, and xonotlite. The chemical composition and morphology of these crystalline phases depend on the composition of mixture and autoclave temperature.
基金financially supported by the projects PAPIITUNAM(IN-101916)CONACyTDGAPA-UNAM for financial support
文摘In this work, CaO-NiO mixed oxide powders were evaluated as consecutive CO;chemisorbents and catalytic materials for hydrogen production thought the CH;reforming process. Between the NiO impregnated CaO and CaO-NiO mechanical composite, the first one presented better chemical behaviors during the CO;capture and CH;reforming processes, obtaining syngas(H;+ CO) as final product. Results showed that syngas was produced at two different temperature ranges, between 400 and 600 °C and at T > 800 °C, where the first temperature range corresponds to the CH;reforming process but the second temperature range was attributed to a different catalytic reaction process: CH;partial oxidation. These results were confirmed through different isothermal and cyclic experiments as well as by XRD analysis of the final catalytic products, where the nickel reduction was evidenced. Moreover, when a CO-O;flow was used during the carbonation process a triple process was achieved:(i) CO oxidation,(ii) CO;chemisorption and(iii) CH;reforming. Using this gas flow the hydrogen production was always higher than that obtained with CO;.
文摘The present study aimed to assess calcium intake, dietary sources of this nutrient and its adequacy with respect to the dietary reference intake (DRI) in a representative sample of Spanish adults. In this study 418 adults (18 to 60 years) from 15 Spanish provinces were studied. Energy and nutrient intake was determined using a 24-hour recall questionnaire for two days. Adequacy of calcium intake was assessed using the established DRI for calcium. Anthropometric data (weight and height) were measured and the body mass index was calculated. Seventy eight percent of the participants in the study did not meet the DRI for calcium. Additionally, 33.7% of the participants did not meet the 67% of the DRI. The daily intake of calcium was 916.6 ± 288.1 mg/day, which represented the 81.3% of the DRI of calcium. Interestingly, subjects who had higher intake of calcium were taller. Additionally, it has been observed that individuals with normal body weight (BMI 2) had higher intakes of dairy products in comparison with overweight and obese individuals (BMI ≥ 25 kg/m2). The main food sources of calcium were dairy products (58.7% of calcium), cereals (13.6%) and vegetables (6.5%). Less than 1% (0.5%) of the calcium intake came from dietary supplements. It was observed that individuals who met the DRI for calcium had a significantly higher intake of dairy products (551.3 ± 240.4 g/day) than individuals who did not meet the DRI of calcium (305.0 ± 150.3 g/day). Calcium intake was inadequate in this sample of the adult Spanish population. Therefore, an increase in the consumption of dairy products, as well as cereals, vegetables and food items fortified with calcium seems to be necessary to achieve an adequate intake of calcium and to prevent diseases caused by calcium deficiency.
文摘Dairy food consumption is important for children as it contributes to the intake of key nutrients, especially calcium. The aim of the present paper is to provide an overview of dairy products consumption for French children, according to age, sex and type of dairy products. Adequacy of dairy and calcium intakes in line with French national guidelines “3 portions of dairy products per day” were also evaluated. Data were extracted and analyzed from the CCAF—Comportementet Consommations Alimentairesen France-study. Seven-day questionnaires were administered to free-living individuals from autumn 2009 to summer 2010. Subjects were children (n = 1171) aged 3 - 17 years. Dairy products contributed substantially to the intake of calcium, phosphorus, potassium, zinc, vitamin B2 and vitamin B12. A general decrease in DP consumption has been observed since 2003. This is most notably due to a lower milk intake which is not compensated by increased cheese or fresh dairy products. Most of children (67%), and up to 73% of adolescents (15 - 17 y), did not reach the recommended “3 servings of dairy products per day”. Twenty percent of children from the age of 6 and nearly 2/3 of female adolescents did not reach their estimated average requirement for calcium. The overview of French dairy food consumption during childhood, of particular Public Health concern, emphasizes the need to encourage dairy consumption and particularly milk consumption at breakfast in order to maintain a nutrient adequacy in children and adolescents.
文摘A method for producing size- and shape-con-trolled calcium alginate beads with immobilized proteins was developed. Unlike previous cal-cium alginate bead production methods, pro-tein-immobilized alginate beads with uniform shape and sizes less then 20 micrometers in diameter could successfully be produced by using sonic vibration. BSA and FITC-conjugated anti-BSA antibodies were used to confirm pro-tein immobilization in the alginate beads. Pro-tein diffusion from the beads could be reduced to less than 10% by cross-linking the proteins to the alginate with 1-ethyl-3-(3-dimethylamino-propyl)carbodiimide (EDC) and N-hydroxysul-fosuccinimide (NHSS). The calcium alginate beads could also be arranged freely on a slide glass by using a femtosecond laser.
文摘The compressive strength,hydration products and microstructure of concrete with calcium-enriched fly ash(CEFA) at different temperature were investigated.The result indicates that the hydration products age of 7 d at-15 ℃ are mainly ettringite and C-S-H,and fly ash particles remain original state.Standard curing was adapted after 7 d curing at-15 ℃.At the age of 35 d,C-S-H was found on the surface of fly ash particles.The hydration product of CEFA is mainly C-S-H gel,which can densify the microstructure of concrete.
文摘目的探究骨折患者初期血钙、血磷、钙磷乘积水平变化并分析其与骨折部位的相关性。方法选取2021年1月~2023年11月四川省骨科医院收治的骨折患者1049例作为研究对象,按骨折部位粗分为两组:上半身部位骨折(n=478)和下半身部位骨折(n=571);细分十组:椎体骨折(n=108)、锁骨骨折(n=109)、上肢骨折(n=106)、手部骨折(n=104)、股骨颈骨折(n=103)、股骨粗隆间骨折(n=106)、髌骨骨折(n=101)、下肢骨折(n=103)、足部骨折(n=105)和其他骨折(n=104)。另选取同期健康体检人群110例作为对照组。全部患者于急诊当日和入院后24~48h两次抽取静脉血测定血钙、血磷,并计算钙磷乘积,比较三者水平变化并分析其与骨折部位的相关性。结果与对照组比较,骨折患者急诊当日和入院后24~48h,血钙(2.27±0.12 mmol/L,2.19±0.12 mmol/L vs2.35±0.10mmol/L)、血磷(1.00±0.20mmol/L,1.08±0.19mmol/L vs 1.15±0.15mmol/L)、钙磷乘积(28.10±6.00mg/dl,29.30±5.85mg/dl vs 33.41±4.87mg/dl)均降低,差异具有统计学意义(t=6.804,12.501;7.475,3.722;8.964,7.115,均P<0.01)。上、下半身骨折相比,急诊当日血钙、血磷和钙磷乘积下半身骨折低于上半身骨折(t=4.129,5.931,6.660,均P<0.01);入院后24~48h则仅钙、钙磷乘积下半身骨折低于上半身骨折(t=6.432,1.990,均P<0.05),差异具有统计学意义。沿时间轴比较,入院后24~48h与急诊当日相比,上、下半身骨折均表现出血钙降低而血磷升高(t=12.779,-5.730;16.919,-14.358),钙磷乘积则仅下半身骨折较急诊当日升高(t=-8.860),差异具有统计学意义(均P<0.01)。不同部位骨折患者入院后24~48h与急诊当日相比,除椎体骨折外,其余九组血钙均降低(t=6.233~11.349);除上肢骨折、手部骨折外,其余八组血磷升高(t=-7.770~-3.327);椎体骨折、股骨颈骨折、股骨粗隆间骨折、下肢骨折、足部骨折、其他骨折钙磷乘积升高(t=-5.819~-2.927),差异具有统计学意义(均P<0.01)。结论骨折患者急诊当日血钙、血磷和钙磷乘积均降低,24~48h后多数患者血钙持续降低,血磷和钙磷乘积逐渐回升,其水平变化程度与骨折部位有关。