In order to solve the lack of relevant evaluation research on the accuracy of HMP155A humidity sensor calibration results in the past, this paper designs the corresponding experimental scheme, and obtains the correspo...In order to solve the lack of relevant evaluation research on the accuracy of HMP155A humidity sensor calibration results in the past, this paper designs the corresponding experimental scheme, and obtains the corresponding calibration results according to the experimental scheme;Then the measurement uncertainty of the indication error in the calibration results is evaluated by GUM, and the corresponding extended uncertainty </span><i><span style="font-family:Verdana;">U</span></i><sub><span style="font-family:Verdana;">95</span></sub><span style="font-family:Verdana;"> is obtained. Finally, according to the requirements of JJF1094-2016 characteristic evaluation of measuring instruments, combined with the calibration results and the actual situation of </span><i><span style="font-family:Verdana;">U</span></i><sub><span style="font-family:Verdana;">95</span></sub><span style="font-family:Verdana;">, the conformity of the indication error of calibration is determined. The result is that each calibration point of the sensor meets the requirements of conformity determination and is within the qualified range. This research effectively makes up for the blank of the previous research on the conformity determination of the indication error of the calibration results and has strong theoretical and practical significance.展开更多
The colorimetric enantiodiscrimination between mandelic acid and L-proline-Cu（II） is exploited to develop enantioselective indicator displacement assays. The sensitivity of the assay could be tuned by using a colori...The colorimetric enantiodiscrimination between mandelic acid and L-proline-Cu（II） is exploited to develop enantioselective indicator displacement assays. The sensitivity of the assay could be tuned by using a colorimetric indicator. The chromophoric ligand, pyrocatechol violet, effectively competes with the mandelic acid guest for open coordination sites on L-proline-Cu（II）. The △A could be increased to 0.12 by changing the ratio of（＋）- and（-）-mandelic acid concentrations that were found to be optimal from the displacement experiments. The resultant enantiomer excess versus △A relationship is linear. From the calibration curves, the absorbance values of the unknowns may be calculated for the enantiomeric excess value and the colorimetric enantiodiscrimination of mandelic acid can thus be obtained.展开更多
文摘In order to solve the lack of relevant evaluation research on the accuracy of HMP155A humidity sensor calibration results in the past, this paper designs the corresponding experimental scheme, and obtains the corresponding calibration results according to the experimental scheme;Then the measurement uncertainty of the indication error in the calibration results is evaluated by GUM, and the corresponding extended uncertainty </span><i><span style="font-family:Verdana;">U</span></i><sub><span style="font-family:Verdana;">95</span></sub><span style="font-family:Verdana;"> is obtained. Finally, according to the requirements of JJF1094-2016 characteristic evaluation of measuring instruments, combined with the calibration results and the actual situation of </span><i><span style="font-family:Verdana;">U</span></i><sub><span style="font-family:Verdana;">95</span></sub><span style="font-family:Verdana;">, the conformity of the indication error of calibration is determined. The result is that each calibration point of the sensor meets the requirements of conformity determination and is within the qualified range. This research effectively makes up for the blank of the previous research on the conformity determination of the indication error of the calibration results and has strong theoretical and practical significance.
基金supported by the National Natural Science Foundation of China(No.21165022)
文摘The colorimetric enantiodiscrimination between mandelic acid and L-proline-Cu（II） is exploited to develop enantioselective indicator displacement assays. The sensitivity of the assay could be tuned by using a colorimetric indicator. The chromophoric ligand, pyrocatechol violet, effectively competes with the mandelic acid guest for open coordination sites on L-proline-Cu（II）. The △A could be increased to 0.12 by changing the ratio of（＋）- and（-）-mandelic acid concentrations that were found to be optimal from the displacement experiments. The resultant enantiomer excess versus △A relationship is linear. From the calibration curves, the absorbance values of the unknowns may be calculated for the enantiomeric excess value and the colorimetric enantiodiscrimination of mandelic acid can thus be obtained.
