ZnO films coated with reduced graphene oxide(RGO-ZnO) were prepared by a simple chemical approach. The graphene oxide(GO) films transferred onto ZnO films by spin coating were reduced to RGO films by two steps(ex...ZnO films coated with reduced graphene oxide(RGO-ZnO) were prepared by a simple chemical approach. The graphene oxide(GO) films transferred onto ZnO films by spin coating were reduced to RGO films by two steps(exposed to hydrazine vapor for 12 h and annealed at 600 °C). The crystal structures, electrical and photoluminescence properties of RGO-ZnO films on quartz substrates were systematically studied. The SEM images illustrated that RGO layers have successfully been coated on the ZnO films very tightly. The PL properties of RGO-ZnO were studied. PL spectra show two sharp peaks at 390 nm and a broad visible emission around 490 nm.The resistivity of RGO-ZnO films was measured by a Hall measurement system, RGO as nanofiller considerably decrease the resistivity of ZnO films. An electrode was fabricated, using RGO-ZnO films deposited on Si substrate as active materials, for super capacitor application. By comparison of different results, we conclude that the RGOZnO composite material couples possess the properties of super capacitor.展开更多
基金supported by the National Natural Science Foundation of China(Nos.61464005,51562015)the Natural Science Foundation of Jiangxi Province(Nos.20143ACB21004,20151BAB212008,20171BAB216015)+2 种基金the Jiangxi Province Foreign Cooperation Projects,China(No.20151BDH80031)the Leader Training Object Project of Major Disciplines Academic and Technical of Jiangxi Province(No.20123BCB22002)the Key Technology R&D Program of the Jiangxi Provine of Science and Technology(No.20171BBE50053)
文摘ZnO films coated with reduced graphene oxide(RGO-ZnO) were prepared by a simple chemical approach. The graphene oxide(GO) films transferred onto ZnO films by spin coating were reduced to RGO films by two steps(exposed to hydrazine vapor for 12 h and annealed at 600 °C). The crystal structures, electrical and photoluminescence properties of RGO-ZnO films on quartz substrates were systematically studied. The SEM images illustrated that RGO layers have successfully been coated on the ZnO films very tightly. The PL properties of RGO-ZnO were studied. PL spectra show two sharp peaks at 390 nm and a broad visible emission around 490 nm.The resistivity of RGO-ZnO films was measured by a Hall measurement system, RGO as nanofiller considerably decrease the resistivity of ZnO films. An electrode was fabricated, using RGO-ZnO films deposited on Si substrate as active materials, for super capacitor application. By comparison of different results, we conclude that the RGOZnO composite material couples possess the properties of super capacitor.