An advantageous porous architecture of electrodes is pivotal in significantly enhancing alkaline water electrolysis(AWE)efficiency by optimizing the mass transport mechanisms.This effect becomes even more pronounced w...An advantageous porous architecture of electrodes is pivotal in significantly enhancing alkaline water electrolysis(AWE)efficiency by optimizing the mass transport mechanisms.This effect becomes even more pronounced when aiming to achieve elevated current densities.Herein,we employed a rapid and scalable laser texturing process to craft novel multi-channel porous electrodes.Particularly,the obtained electrodes exhibit the lowest Tafel slope of 79 mV dec^(-1)(HER)and 49 mV dec^(-1)(OER).As anticipated,the alkaline electrolyzer(AEL)cell incorporating multi-channel porous electrodes(NP-LT30)exhibited a remarkable improvement in cell efficiency,with voltage drops(from 2.28 to 1.97 V)exceeding 300 mV under 1 A cm^(-1),compared to conventional perforated Ni plate electrodes.This enhancement mainly stemmed from the employed multi-channel porous structure,facilitating mass transport and bubble dynamics through an innovative convection mode,surpassing the traditional convection mode.Furthermore,the NP-LT30-based AEL cell demonstrated exceptional durability for 300 h under 1.0 A cm^(-2).This study underscores the capability of the novel multi-channel porous electrodes to expedite mass transport in practical AWE applications.展开更多
The transport and diffusion of substances in seawater are limited by the mixing motion of water bodies,while the main forms of mixing in offshore water bodies are advection and eddy diffusion.The eddy diffusion proces...The transport and diffusion of substances in seawater are limited by the mixing motion of water bodies,while the main forms of mixing in offshore water bodies are advection and eddy diffusion.The eddy diffusion process of water indicates the possible transport direction of dissolved substances.However,the complex environment in the coastal zone makes it difficult to quantitatively assess the water diffusion process.^(222)Rn is a useful tool to trace the diffusion process of water bodies.However,studies on the^(222)Rn distribution and its behavior in the Beibu Gulf are scarce.In this study,the activity distribution characteristics of^(222)Rn in surface seawater of the Guangxi shelf area of the Beibu Gulf were measured.Based on the one-dimensional,steady-state model,the vorticity diffusion coefficient of^(222)Rn in the horizontal direction was calculated as(0.42−2.13)×10^(8) m^(2)/d,and the offshore fluxes of^(222)Rn under the influence of water mixing were calculated as 2.00×10^(12) Bq/d.Correspondingly,the horizontal transport fluxes of silicate,phosphate,nitrite and nitrate were 6.28×10^(−3)mol/(m^(2)·d),0.10×10^(−3)mol/(m^(2)·d),0.20×10^(−3)mol/(m^(2)·d)and 4.15×10^(−3)mol/(m^(2)·d),respectively.These results indicate that the study of eddy current diffusion in offshore marine water facilitates a deeper understanding of the water mixing process and nutrient transport and migration.展开更多
The isotope composition in precipitation has been widely considered as a tracer of monsoon activity.Compared with the coastal region,the monsoon margin usually has limited precipitation with large fluctuation and is u...The isotope composition in precipitation has been widely considered as a tracer of monsoon activity.Compared with the coastal region,the monsoon margin usually has limited precipitation with large fluctuation and is usually sensitive to climate change.The water resource management in the monsoon margin should be better planned by understanding the composition of precipitation isotope and its influencing factors.In this study,the precipitation samples were collected at five sampling sites(Baiyin City,Kongtong District,Maqu County,Wudu District,and Yinchuan City)of the monsoon margin in the northwest of China in 2022 to analyze the characteristics of stable hydrogen(δD)and oxygen(δ18O)isotopes.We analyzed the impact of meteorological factors(temperature,precipitation,and relative humidity)on the composition of precipitation isotope at daily level by regression analysis,utilized the Hybrid Single-Particle Lagrangian Integrated Trajectory(HYSPLIT)-based backward trajectory model to simulate the air mass trajectory of precipitation events,and adopted the potential source contribution function(PSCF)and concentration weighted trajectory(CWT)to analyze the water vapor sources.The results showed that compared with the global meteoric water line(GMWL),the slope of the local meteoric water line(LMWL;δD=7.34δ^(18)O-1.16)was lower,indicating the existence of strong regional evaporation in the study area.Temperature significantly contributed toδ18O value,while relative humidity had a significant negative effect onδ18O value.Through the backward trajectory analysis,we found eight primary locations that were responsible for the water vapor sources of precipitation in the study area,of which moisture from the Indian Ocean to South China Sea(ITSC)and the western continental(CW)had the greatest influence on precipitation in the study area.The hydrogen and oxygen isotopes in precipitation are significantly influenced by the sources and transportation paths of air mass.In addition,the results of PSCF and CWT analysis showed that the water vapor source areas were primarily distributed in the south and northwest direction of the study area.展开更多
Local scour around pipelines crossing rivers or in marine environments is a significant concern.It can lead to failure of the pipelines resulting in environmental side effects and economic losses.This study developed ...Local scour around pipelines crossing rivers or in marine environments is a significant concern.It can lead to failure of the pipelines resulting in environmental side effects and economic losses.This study developed an experimental method to reduce local scour around pipelines with a steady flow of clear water by installing cylindrical and cubical sacrificial piles.Three sizes of sacrificial piles were examined in a linear arrangement.Sacrificial piles were installed on the upstream side of the pipeline at three distances.Maximum scour depth reduction rates below the pipeline were computed.The results showed that sacrificial piles could protect a pipeline from local scour.A portion of scoured sediment around the sacrificial piles was deposited beneath the pipeline.This sediment accumulation reduced the scour depth beneath the pipeline.Analysis of the experimental results demonstrated that the size of piles(d),the spacing between piles,and the distance between the pipe and piles(Xp)were the variables that reduced the maximum scour beneath the pipeline with a diameter of D.For the piles with d=0.40D and 0.64D,X_(p)=4OD was the optimal distance to install a group of piles,and cubical piles could mitigate scour more effectively than cylindrical piles under similar conditions.For the piles with d=D,the greatest reduction in scour depth was achieved at X_(p)=50D with any desired spacings between piles,and cylindrical piles in this dimension could protect the pipeline against scour more effectively than cubical piles.展开更多
The properties of salinity in the South China Sea(SCS),a significant marginal sea connecting the Pacific and Indian Oceans,are greatly influenced by the transport of fresh water flux between the two oceans.However,the...The properties of salinity in the South China Sea(SCS),a significant marginal sea connecting the Pacific and Indian Oceans,are greatly influenced by the transport of fresh water flux between the two oceans.However,the long-term changes in the intermediate water in the SCS have not been thoroughly studied due to limited data,particularly in relation to its thermodynamic variations.This study utilized reanalysis data products to identify a 60-year trend of freshening in the intermediate waters of the northern South China Sea(NSCS),accompanied by an expansion of low-salinity water.The study also constructed salinity budget terms,including advection and entrainment processes,and conducted an analysis of the salinity budget to understand the impacts of external and internal dynamic processes on the freshening trend of the intermediate water in the NSCS.The analysis revealed that the freshening in the northwest Pacific Ocean and the intensification of intrusion through the Luzon Strait at intermediate levels are the primary drivers of the salinity changes in the NSCS.Additionally,a weakened trend in the intensity of vertical entrainment also contributes to the freshening in the NSCS.This study offers new insights into the understanding of regional deep sea changes in response to variations in both thermodynamics and oceanic dynamic processes.展开更多
The climatological characteristics and interdecadal variability of the water vapor transport and budget over the Yellow River-Huaihe River valleys (YH1) and the Yangtze River-Huaihe River valleys (YH2) of East Chi...The climatological characteristics and interdecadal variability of the water vapor transport and budget over the Yellow River-Huaihe River valleys (YH1) and the Yangtze River-Huaihe River valleys (YH2) of East China were investigated in this study,using the NCEP/NCAR monthly mean reanalysis datasets from 1979 to 2009.Changes in the water vapor transport pattern occurred during the late 1990s over YH1 (YH2) that corresponded with the recent interdecadal changes in the eastern China summer precipitation pattern.The net moisture influx in the YH1 increased and the net moisture influx in the YH2 decreased during 2000-2009 in comparison to 1979-1999.Detailed features in the moisture flux and transport changes across the four boundaries were explored.The altered water vapor transport over the two domains can be principally attributed to the additive effects of the changes in the confluent southwesterly moisture flow by the Indian summer monsoon and East Asian summer monsoon (related with the eastward recession of the western Pacific subtropical high).The altered water vapor transport over YH1 was also partly caused by the weakened midlatitude westerlies.展开更多
Based on ECMWF monthly mean data from January 1980 to December 1989,characterishcs of the three-dimensional structure of the mean water vapor transport over Monsoon Asia are described,and the more forportant features ...Based on ECMWF monthly mean data from January 1980 to December 1989,characterishcs of the three-dimensional structure of the mean water vapor transport over Monsoon Asia are described,and the more forportant features of the different regional water vapor transport in the indian Monsoon region and the East AsianMonsoon region are analyzed.It is found that there is a moist tongue extending from the equator POleWard to the Asian Monsoon region.The three-dimensional distributions of the mean water vapor transport fields over the entire globe renect clearly the asymmetry of the Asian Monsoon system,and the existence of a counterrHadley monsoon circulation.The moisture conver-gened(divergence) area in Asia coincides with the connuellt(diffiuent) zone of the monsoon cjrculahon.Furthermore,the moist featllres of the tWo sub-regions of the Asian Monsoon area are different both in their magnitudes and in their seasonal variations.展开更多
Four trawl-resistant bottom mounts, with acoustic Doppler current profilers(ADCPs) embedded, were deployed in the Karimata Strait from November 2008 to June 2015 as part of the South China Sea-Indonesian Seas Transpor...Four trawl-resistant bottom mounts, with acoustic Doppler current profilers(ADCPs) embedded, were deployed in the Karimata Strait from November 2008 to June 2015 as part of the South China Sea-Indonesian Seas Transport/Exchange and Impact on Seasonal Fish Migration(SITE) Program, to estimate the volume and property transport between the South China Sea and Indonesian seas via the strait. The observed current data reveal that the volume transport through the Karimata Strait exhibits significant seasonal variation. The winteraveraged(from December to February) transport is –1.99 Sv(1 Sv=1×10~6 m^3/s), while in the boreal summer(from June to August), the average transport is 0.69 Sv. Moreover, the average transport from January 2009 to December2014 is –0.74 Sv(the positive/negative value indicates northward/southward transport). May and September are the transition period. In May, the currents in the Karimata Strait turn northward, consistent with the local monsoon. In September, the southeasterly trade wind is still present over the strait, driving surface water northward, whereas the bottom flow reverses direction, possibly because of the pressure gradient across the strait from north to south.展开更多
The summer mean water vapor transport (WVT) and cross-equatorial flow (CEF) over the Asian- Australian monsoon region simulated by 22 coupled atmospheric-oceanic general circulation models (AOGCMs) from the Worl...The summer mean water vapor transport (WVT) and cross-equatorial flow (CEF) over the Asian- Australian monsoon region simulated by 22 coupled atmospheric-oceanic general circulation models (AOGCMs) from the World Climate Research Programme's Coupled Model Intercomparison Project Phase 5 (CMIP5) were evaluated. Based on climatology of the twentieth-century simulations, most of models have a reason- ably realistic representation of summer monsoon WVT characterized by southeast water vapor conveyor belt over the South Indian Ocean and southwest belt from the Arabian Sea to the East Asian. The correlation coefficients between NCEP reanalysis and simulations of BCC-CSMI-1, BNU-ESM, CanESM2, FGOALS-s2, MIROC4h and MPI-ESM-LR are up to 0.8. The simulated CEF depicted by the meridional wind along the equator includes the Somali jet and eastern CEF in low atmosphere and the reverse circulation in upper atmosphere, which were generally consistent with NCEP reanalysis. Multi-model ensemble means (MME) can reproduce more reasonable climatological features in spatial distribution both of WVT and CEF. Ten models with more reasonable WVT simulations were selected for future projection studies, including BCC- CSMI-1, BNU-ESM, CanESM2, CCSM4, FGOALS-s2, FIO-ESM, GFDL-ESM2G, MRIOCS, MPI-ESM-LR and NorESM-1M. Analysis based on the future projection experiments in RCP (Representative Concentra- tion Pathway) 2.6, RCP4.5, RCP6 and RCP8.5 show that the global warming forced by different RCP scenarios will results in enhanced WVT over the Indian area and the west Pacific and weaken WVT in the low latitudes of tropical Indian Ocean.展开更多
In sub-tropical coastal waters around Hong Kong, algal blooms and red tides are usually first sighted in the Mirs Bay, in the eastern waters of Hong Kong. A calibrated three-dimensional hydrodynamic model for the Pear...In sub-tropical coastal waters around Hong Kong, algal blooms and red tides are usually first sighted in the Mirs Bay, in the eastern waters of Hong Kong. A calibrated three-dimensional hydrodynamic model for the Pearl River Estuary (Delft3D) has been applied to the study of the physical hydrography of Hong Kong waters and its relationship with algal bloom transport patterns in the dry and wet seasons. The general 3D hydrodynamic circulation and salinity structure in the partially-mixed estuary are presented. Extensive numerical surface drogue tracking experiments are performed for algal blooms that are initiated in the Mirs Bay under different seasonal, wind and tidal conditions. The probability of bloom impact on the Victoria Harbour and nearby urban coastal waters is estimated. The computations show that: i) In the wet season (May - August), algal blooms initiated in the Mirs Bay will move in a clockwise direction out of the bay, and be transported away from Hong Kong due to SW monsoon winds which drive the SW to NE coastal current; ii) In the dry season (November- April), algal blooms initiated in the northeast Mirs Bay will move in an anti-clockwise direction and be carried away into southern waters due to the NE to SW coastal current driven by the NE monsoon winds; the bloom typically flows past the east edge of the Victoria Harbeur and nearby waters. Finally, the role of hydrodynamic transport in an important episodic event -- the spring 1998 massive red tide -- is quantitatively examined. It is shown that the strong NE to E wind during late March to early April, coupled with the diurnal tide at the beginning of April, significantly increased the probability of bloom transport into the Port Shelter and East Lamma Channel, resulting in the massive fish kill. The results provide a basis for risk assessment of harmful algal bloom (HAB) impact on urban coastal waters around the Victoria Habour.展开更多
Since 2002, an artificial water and sediment regulation(AWSR) has been carried out, which largely reduced water and sediment discharged from the Yellow River into the Bohai Sea. Although the sediment transport in the ...Since 2002, an artificial water and sediment regulation(AWSR) has been carried out, which largely reduced water and sediment discharged from the Yellow River into the Bohai Sea. Although the sediment transport in the Yellow River Mouth(YRM) has been observed and modeled intensively since AWSR, but preferentially for the non-storm conditions. In this study, a three-dimensional current-wave-sediment coupled model, DHI-MIKE numerical model, was used to examine the seasonal suspended-sediment transport in the YRM after the AWSR. Results show that the seasonal distribution of suspended-sediments in the YRM is dominated by wind and wave rather than river input. The major transport pathway of suspended-sediments is from the western Laizhou Bay to the Bohai Strait during the winter monsoon, especially in storm events. In addition, about 66% of the river sediments deposit within 30 km of the YRM, which is smaller than previous estimations. It suggests that the YRM has been eroded in recent decades.展开更多
Underwater transportation of bubbles and gases has essential applications in manipulating and using gas,but achieving this function at the microscopic level remains a significant challenge.Here,we report a strategy to...Underwater transportation of bubbles and gases has essential applications in manipulating and using gas,but achieving this function at the microscopic level remains a significant challenge.Here,we report a strategy to self-transport gas in water along a laser-induced open superhydrophobic microchannel with a width less than 100μm.The femtosecond laser can directly write superhydrophobic and underwater superaerophilic microgrooves on the polytetrafluoroethylene(PTFE)surfaces.In water,the single laser-induced microgroove and water medium generate a hollow microchannel.When the microchannel connects two superhydrophobic regions in water,the gas spontaneously travels from the small region to the large area along this hollow microchannel.Gas self-transportation can be extended to laser-drilled microholes through a thin PTFE sheet,which can even achieve anti-buoyancy unidirectional penetration.The gas can overcome the bubble’s buoyance and spontaneously travel downward.The Laplace pressure difference drives the processes of spontaneous gas transportation and unidirectional bubble passage.We believe the property of gas self-transportation in the femtosecond laser-structured open superhydrophobic and underwater superaerophilic microgrooves/microholes has significant potential applications related to manipulating underwater gas.展开更多
In this paper, the hydraulic characteristics of the fracture-karst aquifer and the distribution patterns of petrochemical contaminants are studied. Then, a numerical model using the mixed Eulerian-Lagrangian approach ...In this paper, the hydraulic characteristics of the fracture-karst aquifer and the distribution patterns of petrochemical contaminants are studied. Then, a numerical model using the mixed Eulerian-Lagrangian approach is constructed to predict the distribution and transport of petrochemical compounds in groundwater. The results of numerical modelling and sensitivity analysis show that it may be a workable way for aquifer remediation to combine contamination sources control and capture zone establishment.展开更多
The water dissociation mechanism on a bipolar membrane under the electrical field was investigated and characterized in terms of ionic transport and limiting current density. It is considered that the depletion layer ...The water dissociation mechanism on a bipolar membrane under the electrical field was investigated and characterized in terms of ionic transport and limiting current density. It is considered that the depletion layer exists at the junction of a bipolar membrane, which is coincided with the viewpoint of the most literatures, but we also consider that the thickness and conductivity of this layer is not only related with the increase of the applied voltage but also with the limiting current density. Below the limiting current density, the thickness of the depletion layer keeps a constant and the conductivity decreases with the increase of the applied voltage; while above the limiting current density, the depletion thickness will increase with the increase of the applied voltage and the conductivity keeps a very low constant. Based on the data reported in the literatures and independent determinations, the limiting current density was calculated and the experimental curves Ⅰ-Ⅴ in the two directions were com展开更多
Understanding the transport resistance of water molecules in polyamide(PA)reverse osmosis(RO)membranes at the molecular level is of great importance in guiding the design,preparation,and applications of these membrane...Understanding the transport resistance of water molecules in polyamide(PA)reverse osmosis(RO)membranes at the molecular level is of great importance in guiding the design,preparation,and applications of these membranes.In this work,we use molecular simulation to calculate the total transport resistance by dividing it into two contributions:the interior part and the interfacial part.The interior resistance is dependent on the thickness of the PA layer,while the interfacial resistance is not.Simulation based on the 5 nm PA layer reveals that interfacial resistance is the dominating contribution(>62%)to the total resistance.However,for real-world RO membranes with a 200 nm PA layer,interfacial resistance plays a minor role,with a contribution below 10%.This implies that there is a risk of inaccuracy when using the typical method to estimate the transport resistance of RO membranes,as this method involves simply multiplying the total transport resistance of the simulated value based on a membrane with a 5 nm PA layer.Furthermore,both the interfacial resistance and the interior resistance are dependent on the chemistry of the PA layer.Our simulation reveals that decreasing the number of residual carboxyl groups in the PA layer leads to decreased interior resistance;therefore,the water permeability can be improved at no cost of ion rejection,which is in excellent agreement with the experimental results.展开更多
Hydrological and LADCP data from four experiments at sea (Semane 1999, 2000/1 2000/3, 2001) are used to describe the structure and circulation of Mediterranean Water in the Gulf of Cadiz. These data were gathered on m...Hydrological and LADCP data from four experiments at sea (Semane 1999, 2000/1 2000/3, 2001) are used to describe the structure and circulation of Mediterranean Water in the Gulf of Cadiz. These data were gathered on meridional sections along 8?20′W and 6?15′W and between these longitudes on a zonal section along 35?50′N. The mesoscale and the submesoscale structures (Mediterranean Water Undercurrents, meddies, cyclones) observed along these sections are characterized in terms of thermohaline properties and of velocity. The transports of mass and salt in each class of density (North Atlantic Central Water, Mediterranean Water, North Atlantic Deep Water) are computed with an inverse model. The model indicates a general eastward flux in the Central Water layer, and a westward flux in the Mediterranean Water layer, but there is also a horizontal recirculation and entrainment in these two layers, as well as strong transports associated with the meddy and cyclone found during Semane 1999.展开更多
The transport cross-section based on inflow transport approximation can significantly improve the accuracy of light water reactor(LWR)analysis,especially for the treatment of the anisotropic scattering effect.The prev...The transport cross-section based on inflow transport approximation can significantly improve the accuracy of light water reactor(LWR)analysis,especially for the treatment of the anisotropic scattering effect.The previous inflow transport approximation is based on the moderator cross-section and normalized fission source,which is approximated using transport theory.Although the accuracy of reactivity is increased,the P0 flux moment has a large error in the Monte Carlo code.In this study,an improved inflow transport approximation was introduced with homogenization techniques,applying the homogenized cross-section and accurate fission source.The numerical results indicated that the improved inflow transport approximation can increase the P0 flux moment accuracy and maintain the reactivity calculation precision with the previous inflow transport approximation in typical LWR cases.In addition to this investigation,the improved inflow transport approximation is related to the temperature factors.The improved inflow transport approximation is flexible and accurate in the treatment of the anisotropic scattering effect,which can be directly used in the temperature-dependent nuclear data library.展开更多
Directional fluid transport is of significan</span><span style="font-family:Verdana;">ce</span><span style="font-family:Verdana;"> to many physical processes in nature. How ...Directional fluid transport is of significan</span><span style="font-family:Verdana;">ce</span><span style="font-family:Verdana;"> to many physical processes in nature. How to manipulate this process by man-made material is still a key challenge to scientists. In this study, Janus fabric was constructed by electrospinning a layer of polyvinylidene fluoride (PVDF) nanofibers on woven cotton or gauze. The chemical composition, morphology and surface wettability of two sides of Janus fabric were characterized by infrared spectroscopy, scanning electron microscope (SEM) and contact angle measurement. By controlling the PVDF electrospinning time, the maximum hydrostatic pressure of Janus fabric with different PVDF thickness was measured. It was found that PVDF/gauze is more favorable for unidirectional water transportation, and the moisture also can transfer from hydrophobic side to hydrophilic side. With the advantages of facile preparation, low-cost and one-way water/moisture transportation, the Janus fabric prepared in this study can be applied for water separation, humidity transfer and water collection from the air.展开更多
基金financial support from the National Key R&D Program(2023YFE0108000)the Academy of Sciences Project of Guangdong Province(2019GDASYL-0102007,2021GDASYL-20210103063)+1 种基金GDAS’Project of Science and Technology Development(2022GDASZH-2022010203-003)financial support from the China Scholarship Council(202108210128)。
文摘An advantageous porous architecture of electrodes is pivotal in significantly enhancing alkaline water electrolysis(AWE)efficiency by optimizing the mass transport mechanisms.This effect becomes even more pronounced when aiming to achieve elevated current densities.Herein,we employed a rapid and scalable laser texturing process to craft novel multi-channel porous electrodes.Particularly,the obtained electrodes exhibit the lowest Tafel slope of 79 mV dec^(-1)(HER)and 49 mV dec^(-1)(OER).As anticipated,the alkaline electrolyzer(AEL)cell incorporating multi-channel porous electrodes(NP-LT30)exhibited a remarkable improvement in cell efficiency,with voltage drops(from 2.28 to 1.97 V)exceeding 300 mV under 1 A cm^(-1),compared to conventional perforated Ni plate electrodes.This enhancement mainly stemmed from the employed multi-channel porous structure,facilitating mass transport and bubble dynamics through an innovative convection mode,surpassing the traditional convection mode.Furthermore,the NP-LT30-based AEL cell demonstrated exceptional durability for 300 h under 1.0 A cm^(-2).This study underscores the capability of the novel multi-channel porous electrodes to expedite mass transport in practical AWE applications.
基金This work was jointly supported by the National Natural Science Foundation of China projects[grant numbers 42305178 and U2344224]the National Key Scientific and Technological Infrastructure project“Earth System Numerical Simulation Facility”(EarthLab).
基金The Scientific Research Foundation of the Third Institute of Oceanography,Ministry of Natural Resources under contract Nos 2023007 and 2020017the Natural Science Foundation of Fujian Province under contract No.2020J05010+1 种基金the Foundation of Xiamen Institute of Marine Development under contract No.KFY202204the Asian Cooperation Fund Project-Study on Typical Bay Ecological Protection and Management Demonstration.
文摘The transport and diffusion of substances in seawater are limited by the mixing motion of water bodies,while the main forms of mixing in offshore water bodies are advection and eddy diffusion.The eddy diffusion process of water indicates the possible transport direction of dissolved substances.However,the complex environment in the coastal zone makes it difficult to quantitatively assess the water diffusion process.^(222)Rn is a useful tool to trace the diffusion process of water bodies.However,studies on the^(222)Rn distribution and its behavior in the Beibu Gulf are scarce.In this study,the activity distribution characteristics of^(222)Rn in surface seawater of the Guangxi shelf area of the Beibu Gulf were measured.Based on the one-dimensional,steady-state model,the vorticity diffusion coefficient of^(222)Rn in the horizontal direction was calculated as(0.42−2.13)×10^(8) m^(2)/d,and the offshore fluxes of^(222)Rn under the influence of water mixing were calculated as 2.00×10^(12) Bq/d.Correspondingly,the horizontal transport fluxes of silicate,phosphate,nitrite and nitrate were 6.28×10^(−3)mol/(m^(2)·d),0.10×10^(−3)mol/(m^(2)·d),0.20×10^(−3)mol/(m^(2)·d)and 4.15×10^(−3)mol/(m^(2)·d),respectively.These results indicate that the study of eddy current diffusion in offshore marine water facilitates a deeper understanding of the water mixing process and nutrient transport and migration.
基金supported by the National Natural Science Foundation of China(42161007)the Scientific Research Program for Higher Education Institutions of Gansu Province(2021B-081)the Natural Science Foundation of Gansu Province(22JR5RA074).
文摘The isotope composition in precipitation has been widely considered as a tracer of monsoon activity.Compared with the coastal region,the monsoon margin usually has limited precipitation with large fluctuation and is usually sensitive to climate change.The water resource management in the monsoon margin should be better planned by understanding the composition of precipitation isotope and its influencing factors.In this study,the precipitation samples were collected at five sampling sites(Baiyin City,Kongtong District,Maqu County,Wudu District,and Yinchuan City)of the monsoon margin in the northwest of China in 2022 to analyze the characteristics of stable hydrogen(δD)and oxygen(δ18O)isotopes.We analyzed the impact of meteorological factors(temperature,precipitation,and relative humidity)on the composition of precipitation isotope at daily level by regression analysis,utilized the Hybrid Single-Particle Lagrangian Integrated Trajectory(HYSPLIT)-based backward trajectory model to simulate the air mass trajectory of precipitation events,and adopted the potential source contribution function(PSCF)and concentration weighted trajectory(CWT)to analyze the water vapor sources.The results showed that compared with the global meteoric water line(GMWL),the slope of the local meteoric water line(LMWL;δD=7.34δ^(18)O-1.16)was lower,indicating the existence of strong regional evaporation in the study area.Temperature significantly contributed toδ18O value,while relative humidity had a significant negative effect onδ18O value.Through the backward trajectory analysis,we found eight primary locations that were responsible for the water vapor sources of precipitation in the study area,of which moisture from the Indian Ocean to South China Sea(ITSC)and the western continental(CW)had the greatest influence on precipitation in the study area.The hydrogen and oxygen isotopes in precipitation are significantly influenced by the sources and transportation paths of air mass.In addition,the results of PSCF and CWT analysis showed that the water vapor source areas were primarily distributed in the south and northwest direction of the study area.
文摘Local scour around pipelines crossing rivers or in marine environments is a significant concern.It can lead to failure of the pipelines resulting in environmental side effects and economic losses.This study developed an experimental method to reduce local scour around pipelines with a steady flow of clear water by installing cylindrical and cubical sacrificial piles.Three sizes of sacrificial piles were examined in a linear arrangement.Sacrificial piles were installed on the upstream side of the pipeline at three distances.Maximum scour depth reduction rates below the pipeline were computed.The results showed that sacrificial piles could protect a pipeline from local scour.A portion of scoured sediment around the sacrificial piles was deposited beneath the pipeline.This sediment accumulation reduced the scour depth beneath the pipeline.Analysis of the experimental results demonstrated that the size of piles(d),the spacing between piles,and the distance between the pipe and piles(Xp)were the variables that reduced the maximum scour beneath the pipeline with a diameter of D.For the piles with d=0.40D and 0.64D,X_(p)=4OD was the optimal distance to install a group of piles,and cubical piles could mitigate scour more effectively than cylindrical piles under similar conditions.For the piles with d=D,the greatest reduction in scour depth was achieved at X_(p)=50D with any desired spacings between piles,and cylindrical piles in this dimension could protect the pipeline against scour more effectively than cubical piles.
基金National Natural Science Foundation of China(92158204,42076019)Innovation Group Project of the Southern Marine Science and Engineering Guangdong Laboratory(Zhuhai)(31020004)Open Project of the State Key Laboratory of Tropical Oceanography(LTOZZ2001)。
文摘The properties of salinity in the South China Sea(SCS),a significant marginal sea connecting the Pacific and Indian Oceans,are greatly influenced by the transport of fresh water flux between the two oceans.However,the long-term changes in the intermediate water in the SCS have not been thoroughly studied due to limited data,particularly in relation to its thermodynamic variations.This study utilized reanalysis data products to identify a 60-year trend of freshening in the intermediate waters of the northern South China Sea(NSCS),accompanied by an expansion of low-salinity water.The study also constructed salinity budget terms,including advection and entrainment processes,and conducted an analysis of the salinity budget to understand the impacts of external and internal dynamic processes on the freshening trend of the intermediate water in the NSCS.The analysis revealed that the freshening in the northwest Pacific Ocean and the intensification of intrusion through the Luzon Strait at intermediate levels are the primary drivers of the salinity changes in the NSCS.Additionally,a weakened trend in the intensity of vertical entrainment also contributes to the freshening in the NSCS.This study offers new insights into the understanding of regional deep sea changes in response to variations in both thermodynamics and oceanic dynamic processes.
基金supported by the Major State Basic Research Development Program of China (973 Program) under Grant Nos. 2009CB421406 and 2010CB950304Chinese Academy of Sciences under Grant No. KZCX2-YW-Q1-02the National Natural Science Foundation of China under Grant Nos. 40875048 and 40821092
文摘The climatological characteristics and interdecadal variability of the water vapor transport and budget over the Yellow River-Huaihe River valleys (YH1) and the Yangtze River-Huaihe River valleys (YH2) of East China were investigated in this study,using the NCEP/NCAR monthly mean reanalysis datasets from 1979 to 2009.Changes in the water vapor transport pattern occurred during the late 1990s over YH1 (YH2) that corresponded with the recent interdecadal changes in the eastern China summer precipitation pattern.The net moisture influx in the YH1 increased and the net moisture influx in the YH2 decreased during 2000-2009 in comparison to 1979-1999.Detailed features in the moisture flux and transport changes across the four boundaries were explored.The altered water vapor transport over the two domains can be principally attributed to the additive effects of the changes in the confluent southwesterly moisture flow by the Indian summer monsoon and East Asian summer monsoon (related with the eastward recession of the western Pacific subtropical high).The altered water vapor transport over YH1 was also partly caused by the weakened midlatitude westerlies.
文摘Based on ECMWF monthly mean data from January 1980 to December 1989,characterishcs of the three-dimensional structure of the mean water vapor transport over Monsoon Asia are described,and the more forportant features of the different regional water vapor transport in the indian Monsoon region and the East AsianMonsoon region are analyzed.It is found that there is a moist tongue extending from the equator POleWard to the Asian Monsoon region.The three-dimensional distributions of the mean water vapor transport fields over the entire globe renect clearly the asymmetry of the Asian Monsoon system,and the existence of a counterrHadley monsoon circulation.The moisture conver-gened(divergence) area in Asia coincides with the connuellt(diffiuent) zone of the monsoon cjrculahon.Furthermore,the moist featllres of the tWo sub-regions of the Asian Monsoon area are different both in their magnitudes and in their seasonal variations.
基金The National Key Research and Development Program of China under contract No.2016YFC1402604the Scientific and Technological Innovation Project financially supported by Qingdao National Laboratory for Marine Science and Technology under contract No.2015ASKJ01+4 种基金the SOA Program on Global Change and Air-Sea Interactions under contract Nos GASI-IPOVAI-03,GASI-IPOVAI-02 and GASI-IPOVAI-01-02the National Natural Science Foundation of China under contract Nos 40476025,41876027and 41506036the China-Indonesia Maritime Cooperation Fund under contract No.U1406405the National Science Foundation of the United States under contract No.OCE-07-25935the Office of Naval Research of United States under contract No.N00014-08-01-0618
文摘Four trawl-resistant bottom mounts, with acoustic Doppler current profilers(ADCPs) embedded, were deployed in the Karimata Strait from November 2008 to June 2015 as part of the South China Sea-Indonesian Seas Transport/Exchange and Impact on Seasonal Fish Migration(SITE) Program, to estimate the volume and property transport between the South China Sea and Indonesian seas via the strait. The observed current data reveal that the volume transport through the Karimata Strait exhibits significant seasonal variation. The winteraveraged(from December to February) transport is –1.99 Sv(1 Sv=1×10~6 m^3/s), while in the boreal summer(from June to August), the average transport is 0.69 Sv. Moreover, the average transport from January 2009 to December2014 is –0.74 Sv(the positive/negative value indicates northward/southward transport). May and September are the transition period. In May, the currents in the Karimata Strait turn northward, consistent with the local monsoon. In September, the southeasterly trade wind is still present over the strait, driving surface water northward, whereas the bottom flow reverses direction, possibly because of the pressure gradient across the strait from north to south.
基金supported by the National Basic Research Program of China(973 Program)under Grant 2010CB950500 and 2010CB950304the Scientific Research Foundation of the First Institute of Oceanography,State Oceanic Administration(Grant No.GY02-2001G26)the National Natural Science Foundation of China under Grant No.41206026
文摘The summer mean water vapor transport (WVT) and cross-equatorial flow (CEF) over the Asian- Australian monsoon region simulated by 22 coupled atmospheric-oceanic general circulation models (AOGCMs) from the World Climate Research Programme's Coupled Model Intercomparison Project Phase 5 (CMIP5) were evaluated. Based on climatology of the twentieth-century simulations, most of models have a reason- ably realistic representation of summer monsoon WVT characterized by southeast water vapor conveyor belt over the South Indian Ocean and southwest belt from the Arabian Sea to the East Asian. The correlation coefficients between NCEP reanalysis and simulations of BCC-CSMI-1, BNU-ESM, CanESM2, FGOALS-s2, MIROC4h and MPI-ESM-LR are up to 0.8. The simulated CEF depicted by the meridional wind along the equator includes the Somali jet and eastern CEF in low atmosphere and the reverse circulation in upper atmosphere, which were generally consistent with NCEP reanalysis. Multi-model ensemble means (MME) can reproduce more reasonable climatological features in spatial distribution both of WVT and CEF. Ten models with more reasonable WVT simulations were selected for future projection studies, including BCC- CSMI-1, BNU-ESM, CanESM2, CCSM4, FGOALS-s2, FIO-ESM, GFDL-ESM2G, MRIOCS, MPI-ESM-LR and NorESM-1M. Analysis based on the future projection experiments in RCP (Representative Concentra- tion Pathway) 2.6, RCP4.5, RCP6 and RCP8.5 show that the global warming forced by different RCP scenarios will results in enhanced WVT over the Indian area and the west Pacific and weaken WVT in the low latitudes of tropical Indian Ocean.
基金This study was supported by a Hong Kong Research Grants Council Group Research Project (RGC//HKU1/02C) ,and partially by a grantfromthe University Grants Committee of the Hong Kong Special Administrative Region,China(Project No. AoE/P-04/04 and P-04/02) tothe Area of Excellencein Marine Environment Research andInnovativeTechnology (MERIT)
文摘In sub-tropical coastal waters around Hong Kong, algal blooms and red tides are usually first sighted in the Mirs Bay, in the eastern waters of Hong Kong. A calibrated three-dimensional hydrodynamic model for the Pearl River Estuary (Delft3D) has been applied to the study of the physical hydrography of Hong Kong waters and its relationship with algal bloom transport patterns in the dry and wet seasons. The general 3D hydrodynamic circulation and salinity structure in the partially-mixed estuary are presented. Extensive numerical surface drogue tracking experiments are performed for algal blooms that are initiated in the Mirs Bay under different seasonal, wind and tidal conditions. The probability of bloom impact on the Victoria Harbour and nearby urban coastal waters is estimated. The computations show that: i) In the wet season (May - August), algal blooms initiated in the Mirs Bay will move in a clockwise direction out of the bay, and be transported away from Hong Kong due to SW monsoon winds which drive the SW to NE coastal current; ii) In the dry season (November- April), algal blooms initiated in the northeast Mirs Bay will move in an anti-clockwise direction and be carried away into southern waters due to the NE to SW coastal current driven by the NE monsoon winds; the bloom typically flows past the east edge of the Victoria Harbeur and nearby waters. Finally, the role of hydrodynamic transport in an important episodic event -- the spring 1998 massive red tide -- is quantitatively examined. It is shown that the strong NE to E wind during late March to early April, coupled with the diurnal tide at the beginning of April, significantly increased the probability of bloom transport into the Port Shelter and East Lamma Channel, resulting in the massive fish kill. The results provide a basis for risk assessment of harmful algal bloom (HAB) impact on urban coastal waters around the Victoria Habour.
基金supported by the National Natural Science Foundation of China (Nos. 41476030, U1706215, and 41406081)the Project of Taishan Scholar
文摘Since 2002, an artificial water and sediment regulation(AWSR) has been carried out, which largely reduced water and sediment discharged from the Yellow River into the Bohai Sea. Although the sediment transport in the Yellow River Mouth(YRM) has been observed and modeled intensively since AWSR, but preferentially for the non-storm conditions. In this study, a three-dimensional current-wave-sediment coupled model, DHI-MIKE numerical model, was used to examine the seasonal suspended-sediment transport in the YRM after the AWSR. Results show that the seasonal distribution of suspended-sediments in the YRM is dominated by wind and wave rather than river input. The major transport pathway of suspended-sediments is from the western Laizhou Bay to the Bohai Strait during the winter monsoon, especially in storm events. In addition, about 66% of the river sediments deposit within 30 km of the YRM, which is smaller than previous estimations. It suggests that the YRM has been eroded in recent decades.
基金the National Science Foundation of China under the Grant Nos.61875158 and 61805192the National Key Research and Development Program of China under the Grant No.2017YFB1104700+1 种基金the International Joint Research Laboratory for Micro/Nano Manufacturing and Measurement Technologiesthe Fundamental Research Funds for the Central Universities。
文摘Underwater transportation of bubbles and gases has essential applications in manipulating and using gas,but achieving this function at the microscopic level remains a significant challenge.Here,we report a strategy to self-transport gas in water along a laser-induced open superhydrophobic microchannel with a width less than 100μm.The femtosecond laser can directly write superhydrophobic and underwater superaerophilic microgrooves on the polytetrafluoroethylene(PTFE)surfaces.In water,the single laser-induced microgroove and water medium generate a hollow microchannel.When the microchannel connects two superhydrophobic regions in water,the gas spontaneously travels from the small region to the large area along this hollow microchannel.Gas self-transportation can be extended to laser-drilled microholes through a thin PTFE sheet,which can even achieve anti-buoyancy unidirectional penetration.The gas can overcome the bubble’s buoyance and spontaneously travel downward.The Laplace pressure difference drives the processes of spontaneous gas transportation and unidirectional bubble passage.We believe the property of gas self-transportation in the femtosecond laser-structured open superhydrophobic and underwater superaerophilic microgrooves/microholes has significant potential applications related to manipulating underwater gas.
基金This research project was supported by the National Natural Science Foundation of China(grants 49772162 and 40002022)the Doctoral Foundation of China(grant 1999028421).
文摘In this paper, the hydraulic characteristics of the fracture-karst aquifer and the distribution patterns of petrochemical contaminants are studied. Then, a numerical model using the mixed Eulerian-Lagrangian approach is constructed to predict the distribution and transport of petrochemical compounds in groundwater. The results of numerical modelling and sensitivity analysis show that it may be a workable way for aquifer remediation to combine contamination sources control and capture zone establishment.
基金National Natural Science Foundation of China(29976040),Natural Science Foundation of AnhuiProvince(99045431),Foundation of Environments and Resources of USTC and Youth Foundation of USTC.
文摘The water dissociation mechanism on a bipolar membrane under the electrical field was investigated and characterized in terms of ionic transport and limiting current density. It is considered that the depletion layer exists at the junction of a bipolar membrane, which is coincided with the viewpoint of the most literatures, but we also consider that the thickness and conductivity of this layer is not only related with the increase of the applied voltage but also with the limiting current density. Below the limiting current density, the thickness of the depletion layer keeps a constant and the conductivity decreases with the increase of the applied voltage; while above the limiting current density, the depletion thickness will increase with the increase of the applied voltage and the conductivity keeps a very low constant. Based on the data reported in the literatures and independent determinations, the limiting current density was calculated and the experimental curves Ⅰ-Ⅴ in the two directions were com
基金Financial support from the National Key Research and Development Program of China(2017YFC0403902)the National Basic Research Program of China(2015CB655301)+5 种基金the National Natural Science Foundation of China(21825803)the Jiangsu Natural Science Foundations(BK20190085 and BK20150063)the Program of Excellent Innovation Teams of Jiangsu Higher Education Institutionsthe Project of Priority Academic Program Development of Jiangsu Higher Education Institutions is gratefully acknowledgedWe are also grateful to the High Performance Computing Center of Nanjing Tech Universitythe National Supercomputing Center in Wuxi for supporting us with computational resources.
文摘Understanding the transport resistance of water molecules in polyamide(PA)reverse osmosis(RO)membranes at the molecular level is of great importance in guiding the design,preparation,and applications of these membranes.In this work,we use molecular simulation to calculate the total transport resistance by dividing it into two contributions:the interior part and the interfacial part.The interior resistance is dependent on the thickness of the PA layer,while the interfacial resistance is not.Simulation based on the 5 nm PA layer reveals that interfacial resistance is the dominating contribution(>62%)to the total resistance.However,for real-world RO membranes with a 200 nm PA layer,interfacial resistance plays a minor role,with a contribution below 10%.This implies that there is a risk of inaccuracy when using the typical method to estimate the transport resistance of RO membranes,as this method involves simply multiplying the total transport resistance of the simulated value based on a membrane with a 5 nm PA layer.Furthermore,both the interfacial resistance and the interior resistance are dependent on the chemistry of the PA layer.Our simulation reveals that decreasing the number of residual carboxyl groups in the PA layer leads to decreased interior resistance;therefore,the water permeability can be improved at no cost of ion rejection,which is in excellent agreement with the experimental results.
文摘Hydrological and LADCP data from four experiments at sea (Semane 1999, 2000/1 2000/3, 2001) are used to describe the structure and circulation of Mediterranean Water in the Gulf of Cadiz. These data were gathered on meridional sections along 8?20′W and 6?15′W and between these longitudes on a zonal section along 35?50′N. The mesoscale and the submesoscale structures (Mediterranean Water Undercurrents, meddies, cyclones) observed along these sections are characterized in terms of thermohaline properties and of velocity. The transports of mass and salt in each class of density (North Atlantic Central Water, Mediterranean Water, North Atlantic Deep Water) are computed with an inverse model. The model indicates a general eastward flux in the Central Water layer, and a westward flux in the Mediterranean Water layer, but there is also a horizontal recirculation and entrainment in these two layers, as well as strong transports associated with the meddy and cyclone found during Semane 1999.
基金supported by the National Key R&D Program of China(No.2017YFC0307800-05).
文摘The transport cross-section based on inflow transport approximation can significantly improve the accuracy of light water reactor(LWR)analysis,especially for the treatment of the anisotropic scattering effect.The previous inflow transport approximation is based on the moderator cross-section and normalized fission source,which is approximated using transport theory.Although the accuracy of reactivity is increased,the P0 flux moment has a large error in the Monte Carlo code.In this study,an improved inflow transport approximation was introduced with homogenization techniques,applying the homogenized cross-section and accurate fission source.The numerical results indicated that the improved inflow transport approximation can increase the P0 flux moment accuracy and maintain the reactivity calculation precision with the previous inflow transport approximation in typical LWR cases.In addition to this investigation,the improved inflow transport approximation is related to the temperature factors.The improved inflow transport approximation is flexible and accurate in the treatment of the anisotropic scattering effect,which can be directly used in the temperature-dependent nuclear data library.
文摘Directional fluid transport is of significan</span><span style="font-family:Verdana;">ce</span><span style="font-family:Verdana;"> to many physical processes in nature. How to manipulate this process by man-made material is still a key challenge to scientists. In this study, Janus fabric was constructed by electrospinning a layer of polyvinylidene fluoride (PVDF) nanofibers on woven cotton or gauze. The chemical composition, morphology and surface wettability of two sides of Janus fabric were characterized by infrared spectroscopy, scanning electron microscope (SEM) and contact angle measurement. By controlling the PVDF electrospinning time, the maximum hydrostatic pressure of Janus fabric with different PVDF thickness was measured. It was found that PVDF/gauze is more favorable for unidirectional water transportation, and the moisture also can transfer from hydrophobic side to hydrophilic side. With the advantages of facile preparation, low-cost and one-way water/moisture transportation, the Janus fabric prepared in this study can be applied for water separation, humidity transfer and water collection from the air.