Preface to Special Issue: CO_2 capture storage and utilization

Reducing the anthropogenic COemissions from fossil resource combustion and human activities has become one of the major challenges we are facing today.Beyond those practical applications for the utilization of CO,such as the synthesis of salicylic acid,methanol,urea,NaHCO-NaCOchemicals and recently developed polycarbonate synthesis,scientists are still seeking new materials and technologies for efficient capture,

Hcable for Time-Lapse Seismic Monitoring of Marine Carbon Capture and Storage

To ensure project safety and secure public support, an integrated and comprehensive monitoring program is needed within a carbon capture and storage(CCS) project. Monitoring can be done using many well-established techniques from various fields, and the seismic method proves to be the crucial one. This method is widely used to determine the CO_(2) distribution, image the plume development, and quantitatively estimate the concentration. Because both the CO_(2) distribution and the potential migration pathway can be spatially small scale, high resolution for seismic imaging is demanded. However, obtaining a high-resolution image of a subsurface structure in marine settings is difficult. Herein, we introduce the novel Hcable(Harrow-like cable system) technique, which may be applied to offshore CCS monitoring. This technique uses a highfrequency source(the dominant frequency>100 Hz) to generate seismic waves and a combination of a long cable and several short streamers to receive seismic waves. Ultrahigh-frequency seismic images are achieved through the processing of Hcable seismic data. Hcable is then applied in a case study to demonstrate its detailed characterization for small-scale structures. This work reveals that Hcable is a promising tool for timelapse seismic monitoring of oceanic CCS.

The European Carbon dioxide Capture and Storage Laboratory Infrastructure(ECCSEL)

The transition to a non-emitting energy mix for power generation will take decades. This transition will need to be sustainable, e.g.economically affordable. Fossil fuels which are abundant have an important role to play in this respect, provided that Carbon Capture and Storage(CCS) is progressively implemented. CCS is the only way to reduce emissions from energy intensive industries.Thus, the need for upgraded and new CCS research facilities is widely recognised among stakeholders across Europe, as emphasised by the Zero Emissions Platform(ZEP) [1] and the European Energy Research Alliance on CCS(EERA-CCS) [2].The European Carbon Dioxide Capture and Storage Laboratory Infrastructure, ECCSEL, provides funders, operators and researchers with significant benefits by offering access to world-class research facilities that, in many cases, are unlikely for a single nation to support in isolation.This implies creation of synergy and the avoidance of duplication as well as streamlining of funding for research facilities.ECCSEL offers open access to its advanced laboratories for talented scientists and visiting researchers to conduct cutting-edge research.In the planning of ECCSEL, gap analyses were performed and CCS technologies have been reviewed to underpin and envisage the future experimental setup; 1) Making use of readily available facilities, 2) Modifying existing facilities, and 3) Planning and building entirely new advanced facilities.The investments required for the first ten years(2015-2025) are expected to be in the range of €80-120 miilion. These investments show the current level of ambition, as proposed during the preparatory phase(2011-2014).Entering the implementation phase in 2015, 9 European countries signed Letter of Intent(LoI) to join a ECCSEL legal entity: France, United Kingdom, Netherlands, Italy, Spain, Poland, Greece, Norway and Switzerland(active observer). As the EU ERIC-regulation [3] would offer the most suitable legal framework for ECCSEL, the host country, Norway, will apply for establishing ERIC as the ECCSEL Research Infrastructure(RI)legal entity in 2017. Until the ECCSEL ERIC is approved by the European Commission(probably by summer 2017), an interim MoU agreement for the implementation phase of ECCSEL RI has been signed by 13 research institutions and universities representing the 9 countries. A consortium of these partners were granted 3 million EURO from Horizon 2020 to boost implementation of ECCSEL from September 2015 and two years onwards.?2016, Institute of Process Engineering, Chinese Academy of Sciences. Publishing services by Elsevier B.V. on behalf of KeAi Communications Co., Ltd. This is an open access article under the CC BY-NC-ND license(http://creativecommons.org/licenses/by-nc-nd/4.0/).

Progress and prospect of carbon dioxide capture, utilization and storage in CNPC oilfields

The development history of carbon capture,utilization and storage for enhanced oil recovery(CCUS-EOR)in China is comprehensively reviewed,which consists of three stages:research and exploration,field test and industrial application.The breakthrough understanding of CO_(2) flooding mechanism and field practice in recent years and the corresponding supporting technical achievements of CCUS-EOR project are systematically described.The future development prospects are also pointed out.After nearly 60 years of exploration,the theory of CO_(2) flooding and storage suitable for continental sedimentary reservoirs in China has been innovatively developed.It is suggested that C7–C15 are also important components affecting miscibility of CO_(2) and crude oil.The mechanism of rapid recovery of formation energy by CO_(2) and significant improvement of block productivity and recovery factor has been verified in field tests.The CCUS-EOR reservoir engineering design technology for continental sedimentary reservoir is established.The technology of reservoir engineering parameter design and well spacing optimization has been developed,which focuses on maintaining miscibility to improve oil displacement efficiency and uniform displacement to improve sweep efficiency.The technology of CO_(2) capture,injection and production process,whole-system anticorrosion,storage monitoring and other whole-process supporting technologies have been initially formed.In order to realize the efficient utilization and permanent storage of CO_(2),it is necessary to take the oil reservoir in the oil-water transition zone into consideration,realize the large-scale CO_(2) flooding and storage in the area from single reservoir to the overall structural control system.The oil reservoir in the oil-water transition zone is developed by stable gravity flooding of injecting CO_(2) from structural highs.The research on the storage technology such as the conversion of residual oil and CO_(2) into methane needs to be carried out.

Secondary Silicates as a Barrier to Carbon Capture and Storage in Deccan Basalt

Investigating the immobilization of CO2,previous basalt-water-CO2 interaction studies revealed the formation of carbonates over a short period,but with the extensive formation of secondary silicates(SS).The mechanisms involved in these processes remain unresolved,so the present study was undertaken to understand secondary mineral formation mechanisms.XRPD and Rietveld refinement data for neo-formed minerals show a drastic decrease in the Ca-O bond length,with the calcite structure degenerating after 80 h(hours).However,SEM images and EDS data revealed that a longer interaction time resulted in the formation of chlorite and smectite,adjacent to basalt grains which prevent basaltwater-CO2 interaction to form carbonates,thus restricting carbonate formation.As a result of this,the CO2 mineralization rate is initially high(till 80 h),but it later reduces drastically.It is evident that,for such temperature-controlled transformations,low temperature is conducive to minimizing SS surface coating at the time of mineral carbonation.

The Joule–Thomson effect of (CO_(2)+H_(2)) binary system relevant to gas switching reforming with carbon capture and storage(CCS)

The Joule-Thomson effect is one of the important thermodynamic properties in the system relevant to gas switching reforming with carbon capture and storage(CCS). In this work, a set of apparatus was set up to determine the Joule-Thomson effect of binary mixtures(CO_(2)+ H_(2)). The accuracy of the apparatus was verified by comparing with the experimental data of carbon dioxide. The Joule-Thomson coefficients(μ_(JT)) for(CO_(2)+ H_(2)) binary mixtures with mole fractions of carbon dioxide(x_(CO_(2))= 0.1, 0.26, 0.5,0.86, 0.94) along six isotherms at various pressures were measured. Five equations of state EOSs(PR,SRK, PR, BWR and GERG-2008 equation) were used to calculate the μ_(JT)for both pure systems and binary systems, among which the GERG-2008 predicted best with a wide range of pressure and temperature.Moreover, the Joule-Thomson inversion curves(JTIC) were calculated with five equations of state. A comparison was made between experimental data and predicted data for the inversion curve of CO_(2). The investigated EOSs show a similar prediction of the low-temperature branch of the JTIC for both pure and binary systems, except for the BWRS equation of state. Among all the equations, SRK has the most similar result to GERG-2008 for predicting JTIC.

Carbon capture and storage,geomechanics and induced seismic activity

Injection of large volumes of carbon dioxide(CO) for the purposes of greenhouse-gas emissions reduction has the potential to induce earthquakes.Operators of proposed projects must therefore take steps to reduce the risks posed by this induced seismicity.In this paper,we examine the causes of injection-induced seismicity(IIS),and how it should be monitored and modelled,and thereby mitigated.Many US case studies are found where fluids are injected into layers that are in close proximity to crystalline basement rocks.We investigate this issue further by comparing injection and seismicity in two areas where oilfield wastewater is injected in significant volumes:Oklahoma,where fluids are injected into a basal layer,and Saskatchewan,where fluids are injected into a much shallower layer.We suggest that the different induced seismicity responses in these two areas are at least in part due to these different injection depths.We go on to outline two different approaches for modelling IIS:a statistics based approach and a physical,numerical modelling based approach.Both modelling types have advantages and disadvantages,but share a need to be calibrated with good quality seismic monitoring data if they are to be used with any degree of reliability.We therefore encourage the use of seismic monitoring networks at all future carbon capture and storage(CCS) sites.

Conversion Carbon Capture and Storage Factors in Temperate Human Controlled Wetland

This paper provides guidance for the quantification and reporting of blue carbon removals in the temperate coastal ecosystems,“Italian valli da pesca”or H.C.W.(Human Controlled Wetland,Lat.45°Lon.12°),where some pools as seagrasses,and salt marshes,are highly efficient at capturing and storing carbon dioxide(CO_(2))from the atmosphere.Halophyte salt marsh plants were found to have a%C on Dry Weight(D.W.)of 32.26±3.91(mean±standard deviation),macrophytes 33.65±7.99,seagrasses 29.23±2.23,tamarisk 48.42±2.80,while the first 5 centimetres of wetland mud,on average,had a%C of 8.56±0.94.Like the ISO(International Organization for Standardization)14064 guideline to quantify the GHG(Greenhouse Gas)emission,we have studied the different conversion factors to be used as a practical tool for measurement the CO_(2)sink activity.These factors are essential to calculate the overall carbon reduction in a project located in temperate wetland using a method as the ISO 14064.2,UNI-BNeutral,VCS VERRA or other that will come.

Assessing the Viability of Gandhar Field in India’s Cambay Basin for CO_(2) Storage

Our research is centered on the Gandhar oil field, which was discovered in 1983, where daily oil production has declined significantly over the years. The primary objective was to evaluate the feasibility of carbon dioxide(CO_(2)) storage through its injection into the siliciclastic reservoirs of Ankleshwar Formation. We aimed to obtain high-resolution acoustic impedance data to estimate porosity employing model-based poststack seismic inversion. We conducted an analysis of the density and effective porosity in the target zone through geostatistical techniques and probabilistic neural networks. Simultaneously, the work also involved geomechanical analysis through the computation of pore pressure and fracture gradient using well-log data, geological information, and drilling events in the Gandhar field. Our investigation unveiled spatial variations in effective porosity within the Hazad Member of the Ankleshwar Formation, with an effective porosity exceeding 25% observed in several areas, which indicates the presence of well-connected pore spaces conducive to efficient CO_(2) migration. Geomechanical analysis showed that the vertical stress(Sv) ranged from 55 MPa to 57 MPa in Telwa and from 63.7 MPa to 67.7 MPa in Hazad Member. The pore pressure profile displayed variations along the stratigraphic sequence, with the shale zone, particularly in the Kanwa Formation, attaining the maximum pressure gradient(approximately 36 MPa). However, consistently low pore pressure values(30-34 MPa) considerably below the fracture gradient curves were observed in Hazad Member due to depletion. The results from our analysis provide valuable insights into shaping future field development strategies and exploration of the feasibility of CO_(2) sequestration in Gandhar Field.

Criteria for Selecting Carbon Subsurface and Ocean Storage Site in Developing Countries: A Review

Important first phases in the process of implementing CO2 subsurface and ocean storage projects include selecting of best possible location(s) for CO2 storage, and site selection evaluation. Sites must fulfill a number of criteria that boil down to the following basics: they must be able to accept the desired volume of CO2 at the rate at which it is supplied from the CO2 source(s);they must as well be safe and reliable;and must comply with regulatory and other societal requirements. They also must have at least public acceptance and be based on sound financial analysis. Site geology;hydrogeological, pressure, and geothermal regimes;land features;location, climate, access, etc. can all be refined from these basic criteria. In addition to aiding in site selection, site characterization is essential for other purposes, such as foreseeing the fate and impacts of the injected CO2, and informing subsequent phases of site development, including design, permitting, operation, monitoring, and eventual abandonment. According to data from the IEA, in 2022, emissions from Africa and Asias emerging markets and developing economies, excluding Chinas, increased by 4.2%, which is equivalent to 206 million tonnes of CO2 and were higher than those from developed economies. Coal-fired power generation was responsible for more than half of the rise in emissions that were recorded in the region. The difficulty of achieving sustainable socio-economic progress in the developing countries is entwined with the work of reducing CO2 emissions, which is a demanding project for the economy. Organisations from developing countries, such as Bangladesh, Cameroon, India, and Nigeria, have formed partnerships with organisations in other countries for lessons learned and investment within the climate change arena. The basaltic rocks, coal seams, depleted oil and gas reservoirs, soils, deep saline aquifers, and sedimentary basins that developing countries (Bangladesh, Cameroon, India, and Nigeria etc.) possess all contribute to the individual countrys significant geological sequestration potential. There are limited or no carbon capture and storage or clean development mechanism projects running in these countries at this time. The site selection and characterization procedure are not complete without an estimate of the storage capacity of a storage location. Estimating storage capacity relies on volumetric estimates because a site must accept the planned volume of CO2 during the active injection period. As more and more applications make use of site characterization, so too does the body of written material on the topic. As the science of CO2 storage develops, regulatory requirements are implemented, field experience grows, and the economics of CO2 capture and storage improve, so too will site selection and characterisation change.

Carbon Capture Technologies in OAPEC Member Countries and the Circular Carbon Economy: A Roadmap to Zero Emissions by 2050

Several Organization of Arab Petroleum Exporting Countries (OAPEC) member states (OMSs) have updated their nationally determined contributions (NDCs) with the aim of achieving zero carbon emissions by 2050. Carbon neutrality requires shifting from a linear carbon economy (LCE) to a circular carbon economy (CCE). Carbon capture and storage (CCS) technologies, including reduction, recycle, reuse, removal, and storage technologies, represent an important strategy for achieving such a shift. Herein, we investigate the effects of CCS technology adoption in six OMSs—namely the Kingdom of Saudi Arabia (KSA), Qatar, the United Arab Emirates (UAE), Kuwait, Algeria, and Iraq—by examining their Circular Carbon Economy Index (CCEI) scores, which reflect compliance with CCE-transition policies. Total CCEI, current performance CCEI dimension, and future enabler CCEI dimensions scores were compared among the aforementioned six OMSs and relative to Norway, which was used as a global-high CCEI reference standard. Specifically, CCEI general scope and CCEI oil scope dimension scores were compared. The KSA, Qatar, the UAE, and Kuwait had higher CCEI scores than Algeria and Iraq, reflecting their greater adoption of CCE-transition policies and greater emission-reducing modernization investments. The current performance CCEI scores of Algeria and Iraq appear to be buttressed to some extent by their greater natural carbon sink resources. Based on the findings, we recommend specific actions for OMSs to enhance their CCE transitions and mitigate the negative impacts associated with the associated investments, including: taking rapid practical steps to eliminate carbon oil industry emissions;detailed CCS planning by national oil companies;international cooperation and coordination;and increased investment in domestic CCS utilization infrastructure.

Life-cycle Assessment of Carbon Dioxide Capture for Enhanced Oil Recovery

The development and deployment of Carbon dioxide Capture and Storage （CCS） technology is a cornerstone of the Norwegian government＇s climate strategy. A number of projects are currently evaluated/planned along the Norwegian West Coast, one at Tjeldbergodden. COe from this project will be utilized in part for enhanced oil recovery in the Halten oil field, in the Norwegian Sea. We study a potential design of such a system. A combined cycle power plant with a gross power output of 832 MW is combined with CO2 capture plant based on a post-combustion capture using amines as a solvent. The captured CO2 is used for enhanced oil recovery （EOR）. We employ a hybrid life-cycle assessment （LCA） method to assess the environmental impacts of the system. The study focuses on the modifications and operations of the platform during EOR. We allocate the impacts connected to the capture of CO2 to electricity production, and the impacts connected to the transport and storage of CO2 to the oil produced. Our study shows a substantial reduction of the greenhouse gas emissions from power production by 80% to 75 g·（kW·h）^-1. It also indicates a reduction of the emissions associated with oil production per unit oil produced, mostly due to the increased oil production. Reductions are especially significant if the additional power demand due to EOR leads to power supply from the land.

Investigation of the role of Ca(OH)2 in the catalytic Alkaline Thermal Treatment of cellulose to produce H2 with integrated carbon capture

The Alkaline Thermal Treatment(ATT)of biomass is one of the few biomass conversion processes that has a potential for BECCS(bio-energy with carbon capture and storage).Combining in-situ carbon capture withcreates a carbon-neutral process that has the potential to be carbon-negative.This study has shown that the conversion of cellulose tosuppressedcan be achieved through the reforming of gaseous intermediates in a fixed bed of 10%Ni/ZrO2.Reforming occurs at low temperatures≤773 K,which could allow for improved sustainability.

Nanocomposite sodalite/ceramic membrane for pre-combustion CO2 capture： synthesis and morphological characterization

Carbon capture and storage （CCS） is amongst the possible options to reduce CO2 emission. In the application of CCS, CO2 capture techniques such as adsorption and membrane system have been proposed due to less energy requirement and environmental benign than the absorption process. However, membrane system has drawbacks such as poor membrane reproducibility, scale-up difficulty and high cost of the membrane supports. In this study synthesis and characterization of nanocomposite sodalite （HS）/ceramic membrane via ＂pore-plugging＂ hydrothermal synthesis （PPH） protocol for pre- combustion CO2 capture is reported. The morphology and crystallinity of the as-prepared membranes were checked with scanning electron microscopy and X-ray diffraction. Surface chemistry of the membrane was examined with Fourier Transform Infrared spectroscopy. In nanocomposite architecture membranes, zeolite crystals are embedded within the pores of the supports instead of forming thin-film layers of the zeolite crystals on the surface of the supports. Compared to the conventional in situ direct hydrothermal synthesis, membranes obtained from PPH possess higher mechanical strength and thermal stability. In addition, defect control with nanocomposite architecture membranes is possible because the zeolite crystals are embedded within the pores of the support, thereby limiting the maximum defect size to the pore size of the support. Furthermore, the nanocomposite architecture nature of the membranes safeguards the membrane from shocks or abrasion that could promote formation of defects. The aforementioned advantages of the nanocomposite architecture membranes could be beneficial in developing high performance and cost-effective membrane materials for pre-combustion CO2 capture.

A review of in situ carbon mineralization in basalt

Global warming has greatly threatened the human living environment and carbon capture and storage(CCS)technology is recognized as a promising way to reduce carbon emissions.Mineral storage is considered a reliable option for long-term carbon storage.Basalt rich in alkaline earth elements facilitates rapid and permanent CO_(2) fixation as carbonates.However,the complex CO_(2)-fluid-basalt interaction poses challenges for assessing carbon storage potential.Under different reaction conditions,the carbonation products and carbonation rates vary.Carbon mineralization reactions also induce petrophysical and mechanical responses,which have potential risks for the long-term injectivity and the carbon storage safety in basalt reservoirs.In this paper,recent advances in carbon mineralization storage in basalt based on laboratory research are comprehensively reviewed.The assessment methods for carbon storage potential are introduced and the carbon trapping mechanisms are investigated with the identification of the controlling factors.Changes in pore structure,permeability and mechanical properties in both static reactions and reactive percolation experiments are also discussed.This study could provide insight into challenges as well as perspectives for future research.

A review of interaction mechanisms and microscopic simulation methods for CO_(2)-water-rock system

This work systematically reviews the complex mechanisms of CO_(2)-water-rock interactions,microscopic simulations of reactive transport(dissolution,precipitation and precipitate migration)in porous media,and microscopic simulations of CO_(2)-water-rock system.The work points out the key issues in current research and provides suggestions for future research.After injection of CO_(2) into underground reservoirs,not only conventional pressure-driven flow and mass transfer processes occur,but also special physicochemical phenomena like dissolution,precipitation,and precipitate migration.The coupling of these processes causes complex changes in permeability and porosity parameters of the porous media.Pore-scale microscopic flow simulations can provide detailed information within the three-dimensional pore and throat space and explicitly observe changes in the fluid-solid interfaces of porous media during reactions.At present,the research has limitations in the decoupling of complex mechanisms,characterization of differential multi-mineral reactions,precipitation generation mechanisms and characterization(crystal nucleation and mineral detachment),simulation methods for precipitation-fluid interaction,and coupling mechanisms of multiple physicochemical processes.In future studies,it is essential to innovate experimental methods to decouple“dissolution-precipitation-precipitate migration”processes,improve the accuracy of experimental testing of minerals geochemical reaction-related parameters,build reliable characterization of various precipitation types,establish precipitation-fluid interaction simulation methods,coordinate the boundary conditions of different physicochemical processes,and,finally,achieve coupled flow simulation of“dissolution-precipitation-precipitate migration”within CO_(2)-water-rock systems.

Enhancing carbon neutrality:A perspective on the role of Microbially Induced Carbonate Precipitation(MICP)

Microbially Induced Carbonate Precipitation(MICP)presents a promising avenue for sustainable carbon management,offering a rapid alternative to natural carbonate formation.This paper explores the potential of MICP,particularly through ureolysis,in carbon storage and greenhouse gas mitigation.Urease-producing bacteria play a key role by converting CO2 into calcium carbonate(CaCO3).These microbes thrive in various environments,from soils to construction sites,making MICP a versatile tool for Carbon Capture and Storage(CCS).This process not only results in the formation of solid carbonates but also effectively sequesters CO2,positioning MICP as a transformative approach for climate change mitigation.The article highlights MICP’s capacity to harness microbial activities for environmental benefits,emphasizing its importance in reducing atmospheric CO2 levels and contributing to a more sustainable future.

Geophysical monitoring technology for CO_2 sequestration

Geophysical techniques play key roles in the measuring, monitoring, and verifying the safety of CO2 sequestration and in identifying the efficiency of CO2-enhanced oil recovery. Although geophysical monitoring techniques for CO2 sequestration have grown out of conventional oil and gas geophysical exploration techniques, it takes a long time to conduct geophysical monitoring, and there are many barriers and challenges. In this paper, with the initial objective of performing CO2 sequestration, we studied the geophysical tasks associated with evaluating geological storage sites and monitoring CO2 sequestration. Based on our review of the scope of geophysical monitoring techniques and our experience in domestic and international carbon capture and sequestration projects, we analyzed the inherent difficulties and our experiences in geophysical monitoring techniques, especially, with respect to 4D seismic acquisition, processing, and interpretation.

Carbon peak and carbon neutrality in China:Goals,implementation path and prospects

Climate change is a common problem in human society.The Chinese government promises to peak carbon dioxide emissions by 2030 and strives to achieve carbon neutralization by 2060.The proposal of the goal of carbon peak and carbon neutralization has led China into the era of climate economy and set off a green change with both opportunities and challenges.On the basis of expounding the objectives and specific connotation of China’s carbon peak and carbon neutralization,this paper systematically discusses the main implementation path and the prospect of China’s carbon peak and carbon neutralization.China’s path to realizing carbon neutralization includes four directions:(1)in terms of carbon dioxide emission control:energy transformation path,energy conservation,and emission reduction path;(2)for increasing carbon sink:carbon capture,utilization,and storage path,ecological governance,and land greening path;(3)in key technology development:zero-carbon utilization,coal new energy coupling,carbon capture utilization and storage(CCUS),energy storage technology and other key technology paths required to achieve carbon peak and carbon neutralization;(4)from the angle of policy development:Formulate legal guarantees for the government to promote the carbon trading market;Formulate carbon emission standards for enterprises and increase publicity and education for individuals and society.Based on practicing the goal and path of carbon peak and carbon neutralization,China will vigorously develop low carbon and circular economy and promote green and high-quality economic development;speed up to enter the era of fossil resources and promoting energy transformation;accelerate the integrated innovation of green and low-carbon technologies and promote carbon neutrality.

Clean Coal Technologies in China： Current Status and Future Perspectives

Coal is the dominant primary energy source in China and the major source of greenhouse gases and air pollutants. To facilitate the use of coal in an environmentally satisfactory and economically viable way, clean coal technologies （CCTs） are necessary. This paper presents a review of recent research and development of four kinds of CCTs： coal power generation; coal conversion; pollution control; and carbon capture, utilization, and storage. It also outlines future perspectives on directions for technology re search and development （R＆D）. This review shows that China has made remarkable progress in the R＆D of CCTs, and that a number of CCTs have now entered into the commercialization stage.