采用温度相关比容平移项的比容平移Soave-Redlich-Kwong(VTSRK)方程计算新工质R1234yf和R1234ze(E)的热力学性质以及两种物质与CO_2的二元混合物性质,混合物计算采用van der Waals混合规则,二元交互作用系数由密度数据拟合得到。对纯净...采用温度相关比容平移项的比容平移Soave-Redlich-Kwong(VTSRK)方程计算新工质R1234yf和R1234ze(E)的热力学性质以及两种物质与CO_2的二元混合物性质,混合物计算采用van der Waals混合规则,二元交互作用系数由密度数据拟合得到。对纯净物计算与专用状态方程进行对比,VTSRK方程比SRK方程显著改善了液相密度表征效果。对混合物的密度计算结果与实验数据进行对比,对于R1234yf+CO_2二元混合体系方程与实验数据相对均方根偏差为1.17%,对于R1234ze(E)+CO_2二元混合体系相对均方根偏差为0.82%。结果显示,采用温度相关比容平移项的VTSRK方程应用于R1234yf和R1234ze(E)纯流体以及R1234yf+CO_2和R1234ze(E)+CO_2密度性质计算,可获得较高精度。展开更多
As one of the most important ways to reduce the greenhouse gas emission,carbon dioxide（CO2）enhanced gas recovery（CO2-EGR） is attractive since the gas recovery can be enhanced simultaneously with CO2sequestration.B...As one of the most important ways to reduce the greenhouse gas emission,carbon dioxide（CO2）enhanced gas recovery（CO2-EGR） is attractive since the gas recovery can be enhanced simultaneously with CO2sequestration.Based on the existing equation of state（EOS） module of TOUGH2 MP,extEOS7C is developed to calculate the phase partition of H2O-CO2-CH4-NaCl mixtures accurately with consideration of dissolved NaCI and brine properties at high pressure and temperature conditions.Verifications show that it can be applied up to the pressure of 100 MPa and temperature of 150℃.The module was implemented in the linked simulator TOUGH2MP-FLAC3 D for the coupled hydro-mechanical simulations.A simplified three-dimensional（3D）1/4 model（2.2 km×1 km×1 km） which consists of the whole reservoir,caprock and baserock was generated based on the geological conditions of a gas field in the North German Basin.The simulation results show that,under an injection rate of 200,000 t/yr and production rate of 200,000 sm3/d,CO2breakthrough occurred in the case with the initial reservoir pressure of 5 MPa but did not occur in the case of 42 MPa.Under low pressure conditions,the pressure driven horizontal transport is the dominant process;while under high pressure conditions,the density driven vertical flow is dominant.Under the considered conditions,the CO2-EGR caused only small pressure changes.The largest pore pressure increase（2 MPa） and uplift（7 mm） occurred at the caprock bottom induced by only CO2injection.The caprock had still the primary stress state and its integrity was not affected.The formation water salinity and temperature variations of ±20℃ had small influences on the CO2-EGR process.In order to slow down the breakthrough,it is suggested that CO2-EGR should be carried out before the reservoir pressure drops below the critical pressure of CO2.展开更多
In recent oil and gas exploration, the most reservoirs are low permeability with abundant reserves. Conventional mining of low permeability reservoir is commonly utilizing the hydraulic fracturing technology, whereas,...In recent oil and gas exploration, the most reservoirs are low permeability with abundant reserves. Conventional mining of low permeability reservoir is commonly utilizing the hydraulic fracturing technology, whereas, it encounters various technical issues, such as clay expansion and water lock damage. Using the fluid of supercritical carbon dioxide(S-CO_2) to exploit the low permeability oil and gas reservoirs is attracting more attention. The implementation of S-CO_2, without liquid phase, can help avoid the aforementioned problems. Nevertheless, the phase change of CO_2 during fracturing is complicate, and it is difficult to accurately predict the CO_2 phase transition. In this work, first, the physical properties of S-CO_2 were analyzed by the Span-Wagner model and Vesovic model. Next, S-CO_2 was applied to a typical oilfield, and an unsteady coupling model of heat transfer and pressure drop was developed. Then the staggered grid method and iteration procedures were used for numerical solutions, and the temperature and pressure distributions of wellbores were investigated. The results indicate that the temperature control of a wellbore is the key to the phase prediction of S-CO_2; CO_2 within the single-diameter pipeline below 2300 m can maintain the supercritical state, while CO_2 within the stepped pipeline can maintain the supercritical state at the depth of 2280 m. Moreover, compared with the single-diameter pipeline, the bottom pressure of the stepped pipeline is lower and the bottom temperature is higher. By analyzing the flow and heat transfer of S-CO_2 in the wellbores, the phase state of S-CO_2 was well predicted, which is helpful to improve the exploring performance of low permeability oil and gas reservoirs.展开更多
文摘采用温度相关比容平移项的比容平移Soave-Redlich-Kwong(VTSRK)方程计算新工质R1234yf和R1234ze(E)的热力学性质以及两种物质与CO_2的二元混合物性质,混合物计算采用van der Waals混合规则,二元交互作用系数由密度数据拟合得到。对纯净物计算与专用状态方程进行对比,VTSRK方程比SRK方程显著改善了液相密度表征效果。对混合物的密度计算结果与实验数据进行对比,对于R1234yf+CO_2二元混合体系方程与实验数据相对均方根偏差为1.17%,对于R1234ze(E)+CO_2二元混合体系相对均方根偏差为0.82%。结果显示,采用温度相关比容平移项的VTSRK方程应用于R1234yf和R1234ze(E)纯流体以及R1234yf+CO_2和R1234ze(E)+CO_2密度性质计算,可获得较高精度。
基金funded by the National Natural Science Foundation of China(Grant No.NSFC51374147)the German Society for Petroleum and Coal Science and Technology(Grant No.DGMK680-4)
文摘As one of the most important ways to reduce the greenhouse gas emission,carbon dioxide（CO2）enhanced gas recovery（CO2-EGR） is attractive since the gas recovery can be enhanced simultaneously with CO2sequestration.Based on the existing equation of state（EOS） module of TOUGH2 MP,extEOS7C is developed to calculate the phase partition of H2O-CO2-CH4-NaCl mixtures accurately with consideration of dissolved NaCI and brine properties at high pressure and temperature conditions.Verifications show that it can be applied up to the pressure of 100 MPa and temperature of 150℃.The module was implemented in the linked simulator TOUGH2MP-FLAC3 D for the coupled hydro-mechanical simulations.A simplified three-dimensional（3D）1/4 model（2.2 km×1 km×1 km） which consists of the whole reservoir,caprock and baserock was generated based on the geological conditions of a gas field in the North German Basin.The simulation results show that,under an injection rate of 200,000 t/yr and production rate of 200,000 sm3/d,CO2breakthrough occurred in the case with the initial reservoir pressure of 5 MPa but did not occur in the case of 42 MPa.Under low pressure conditions,the pressure driven horizontal transport is the dominant process;while under high pressure conditions,the density driven vertical flow is dominant.Under the considered conditions,the CO2-EGR caused only small pressure changes.The largest pore pressure increase（2 MPa） and uplift（7 mm） occurred at the caprock bottom induced by only CO2injection.The caprock had still the primary stress state and its integrity was not affected.The formation water salinity and temperature variations of ±20℃ had small influences on the CO2-EGR process.In order to slow down the breakthrough,it is suggested that CO2-EGR should be carried out before the reservoir pressure drops below the critical pressure of CO2.
基金financial support from the Project of the National Natural Science Foundation of China (No.51676208)the China Postdoctoral Science Foundation (No.2017M622308)the Fundamental Research Funds for the Central Universities (18CX07012A, 19CX05002A).
文摘In recent oil and gas exploration, the most reservoirs are low permeability with abundant reserves. Conventional mining of low permeability reservoir is commonly utilizing the hydraulic fracturing technology, whereas, it encounters various technical issues, such as clay expansion and water lock damage. Using the fluid of supercritical carbon dioxide(S-CO_2) to exploit the low permeability oil and gas reservoirs is attracting more attention. The implementation of S-CO_2, without liquid phase, can help avoid the aforementioned problems. Nevertheless, the phase change of CO_2 during fracturing is complicate, and it is difficult to accurately predict the CO_2 phase transition. In this work, first, the physical properties of S-CO_2 were analyzed by the Span-Wagner model and Vesovic model. Next, S-CO_2 was applied to a typical oilfield, and an unsteady coupling model of heat transfer and pressure drop was developed. Then the staggered grid method and iteration procedures were used for numerical solutions, and the temperature and pressure distributions of wellbores were investigated. The results indicate that the temperature control of a wellbore is the key to the phase prediction of S-CO_2; CO_2 within the single-diameter pipeline below 2300 m can maintain the supercritical state, while CO_2 within the stepped pipeline can maintain the supercritical state at the depth of 2280 m. Moreover, compared with the single-diameter pipeline, the bottom pressure of the stepped pipeline is lower and the bottom temperature is higher. By analyzing the flow and heat transfer of S-CO_2 in the wellbores, the phase state of S-CO_2 was well predicted, which is helpful to improve the exploring performance of low permeability oil and gas reservoirs.
