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Determination of Atomic Fractions of Isotopes Carbon-13 and Nitrogen-15 Directly in Glicine, L-Leucine, Isoleucine and Alanine
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作者 Levani Eliashvili Lamzira Parulava Vakhtang Betlemidze 《American Journal of Analytical Chemistry》 CAS 2023年第5期229-237,共9页
Using compounds modified by the isotopes carbon-13 and nitrogen-15 helps conduct research in various fields of science, such as medicine, pharmacology, pharmacokinetics, metabolism, agriculture, and others. In the cas... Using compounds modified by the isotopes carbon-13 and nitrogen-15 helps conduct research in various fields of science, such as medicine, pharmacology, pharmacokinetics, metabolism, agriculture, and others. In the case of the availability of reliable, express, and cheap methods, the area of their use will gradually expand. A determination of the atomic fraction of the isotopes carbon-13 and nitrogen-15 directly in glycine, leucine, isoleucine, and alanine is proposed;the modification concerns all centers or one or more identical carbon and nitrogen centers separately, as well as both isotopes at the same time. There are defined mass lines of the mass spectrum of each amino acid, through which the isotopic content of carbon and nitrogen is calculated. The processes that must be taken into account for the determination of the isotopic content are also established. Isotopic analysis of these compounds until now was carried out by transforming them into carbon oxide, dioxide, and molecular nitrogen, and determination of their content in individual centers was impossible. 展开更多
关键词 Mass Spectrometer Mass Spectrum Fragmentary Ion Ionization Mass-to-charge ratio Intensity of Ionic current carbon-13 Nitrogen-15 Atomic Fraction isotope-Modified
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Study the Changes in Soil Organic Carbon of Rice-Maize Cropping System in the Top Layer of Alluvisol Soil in Dan Phuong: A Study of C-13 Stable Isotope Composition (<i>&delta;</i><sup>13</sup>C) 被引量:1
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作者 Nguyen Thi Hong Thinh Vu Hoai +4 位作者 Ha Lan Anh Vo Thi Anh Truong Viet Chau Trinh Van Giap Tran Minh Tien 《Journal of Environmental Protection》 2019年第10期1361-1372,共12页
In this study, the experiments on field were conducted to examine the change in the content of soil organic carbon (SOC), its C-13 stable isotope composition (δ 13C) and some main physical, chemical parameters (soil ... In this study, the experiments on field were conducted to examine the change in the content of soil organic carbon (SOC), its C-13 stable isotope composition (δ 13C) and some main physical, chemical parameters (soil moisture, pH, soil density, content of humic, fulvic, total N, total P, total K) in alluvial soil of Dan Phuong region—Vietnam at a depth of 0 - 30 cm when we changed the regime from 2 maize -1 rice crop to 2 rice - 1 maize crop per 1 year. In addition to analyzing the main parameters in soil, C content and its δ 13C value in parts of rice and maize (root, stem and leaf) were also analyzed to assess the contribution of plant residues on soil organic carbon content after harvest. The experiment was carried out in 2016-2017 on the field with the traditional farming method of local farmers along with the tropical monsoon weather conditions of the North-Vietnam. The results showed that SOC had positive correlation with total N, total P parameters and negative correlation with δ 13C values of soil samples at two layers (0 - 15 cm and 15 - 30 cm). The average of total dry biomass (stem, stump + roots and leaf parts) per 1 rice and 1 maize crop was 10.64 Mg/ha and 9.09 Mg/ha, respectively. The average of δ 13C value of rice (C3 plant) was -29.78‰ and its value of maize (C4 plant) was -12.61‰. The new plant (rice) contributes to the total soil organic carbon content from 11.31% to 44.14% at the 0 - 15 cm layer and from 6.55% to 11.31% at the 15 - 30 cm layer in one-year experiment period. 展开更多
关键词 SOIL Organic carbon (SOc) c-13 Stable isotope MAIZE and RIcE crop SOIL Properties
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Differential response of radial growth and δ^(13)C in Qinghai spruce(Picea crassifolia) to climate change on the southern and northern slopes of the Qilian Mountains in Northwest China
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作者 Li Qin Huaming Shang +4 位作者 Weiping Liu Yuting Fan Kexiang Liu Tongwen Zhang Ruibo Zhang 《Journal of Forestry Research》 SCIE EI CAS CSCD 2024年第3期205-218,共14页
Tree radial growth can have significantly differ-ent responses to climate change depending on the environ-ment.To elucidate the effects of climate on radial growth and stable carbon isotope(δ^(13)C)fractionation of Q... Tree radial growth can have significantly differ-ent responses to climate change depending on the environ-ment.To elucidate the effects of climate on radial growth and stable carbon isotope(δ^(13)C)fractionation of Qing-hai spruce(Picea crassifolia),a widely distributed native conifer in northwestern China in different environments,we developed chronologies for tree-ring widths and δ^(13)C in trees on the southern and northern slopes of the Qilian Mountains,and analysed the relationship between these tree-ring variables and major climatic factors.Tree-ring widths were strongly influenced by climatic factors early in the growing season,and the radial growth in trees on the northern slopes was more sensitive to climate than in trees on the southern.Tree-ring δ^(13)C was more sensitive to climate than radial growth.δ^(13)C fractionation was mainly influenced by summer temperature and precipitation early in the growing season.Stomatal conductance more strongly limited stable carbon isotope fractionation in tree rings than photosynthetic rate did.The response between tree rings and climate in mountains gradually weakened as climate warmed.Changes in radial growth and stable carbon isotope fractionation of P.crassifolia in response to climate in the Qilian Mountains may be further complicated by continued climate change. 展开更多
关键词 Tree rings Qinghai spruce(Picea crassifolia Kom.) Stable carbon isotope(δ^(13)c) Qilian Mountains:climate change
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CAUBRATION METHOD IN ISOTOPIC CARBON ANALYSIS
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作者 张维成 李立武 《Nuclear Science and Techniques》 SCIE CAS CSCD 1993年第1期45-50,共6页
A very simple basic equation for the comparator technique is derived for the determination of 13C/12C ratio in biological samples by proton induced gamma- ray emission. On the basis of this treatments a new series of ... A very simple basic equation for the comparator technique is derived for the determination of 13C/12C ratio in biological samples by proton induced gamma- ray emission. On the basis of this treatments a new series of experiments has been made at a 2×1.7 tandem accelerator that proved conclusion about the method. 展开更多
关键词 PIGE 13c/12c ratio BIOLOGIcAL SAMPLES computer calculation isotope measurement STOPPING power
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Temporal and spatial variations of carbon isotope signature reveal substantial contribution of bracts and internode assimilates to grain filling of japonica rice
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作者 Mengjiao Jiang Hongfa Xu +4 位作者 Nianfu Yang Ganghua Li Yanfeng Ding Matthew J.Paul Zhenghui Liu 《The Crop Journal》 SCIE CSCD 2021年第2期271-281,共11页
Carbon isotope composition(δ^(13)C)of a plant organ is an inherent signature reflecting its physiological property,and thus is used as an integrative index in crop breeding.It is also a non-intrusive method for quant... Carbon isotope composition(δ^(13)C)of a plant organ is an inherent signature reflecting its physiological property,and thus is used as an integrative index in crop breeding.It is also a non-intrusive method for quantifying the relative contribution of different source organs to grain filling in cereals.Using the samples collected from two-year field and pot experiments with two nitrogen(N)fertilization treatments,we investigated the temporal and spatial variations of δ^(13)C in source organs of leaf,sheath,internode,and bracts,and in sink organ grain.Constitutive nature of δ^(13)C was uncovered,with an order of leaf(−27.84‰)<grain(−27.82‰)<sheath(−27.24‰)<bracts(−26.81‰)<internode(−25.67‰).For different positions of individual organs within the plant,δ^(13)C of the leaf and sheath presented a diminishing trend from the top(flag leaf and its sheath)to the bottom(the last leaf in reverse order and its sheath).No obvious pattern was found for the internode.For temporal variations, δ^(13)C of the leaf and sheath had a peak(the most negative)at 10 days after anthesis(DAA),whereas that of the bracts showed a marked increase at the time point of anthesis,implying a transformation from sink to source organ.By comparing the δ^(13)C in its natural abundance in the water-soluble fractions of the sheath,internode,and bracts with the δ^(13)C in mature grains,the relative contribution of these organs to grain filling was assessed.With reference to the leaf,the internode accounted for as high as 32.64%and 42.56%at 10 DAA and 20 DAA,respectively.Meanwhile,bracts presented a larger contribution than the internode,with superior bracts being higher than inferior bracts.In addition,N topdressing reduced the contribution of the internode and bracts.Our findings clearly proved the actual significance of non-foliar organs of the internode and bracts for rice yield formation,thus extending our basic knowledge of source and sink relations. 展开更多
关键词 japonica rice carbon isotope composition(δ^(13)c) Temporal and spatial variations Source and sink relation Grain yield formation
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Power-law patterns in the Phanerozoic sedimentary records of carbon, oxygen, sulfur,and strontium isotopes
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作者 Haitao Shang 《Journal of Palaeogeography》 SCIE CSCD 2024年第1期116-126,共11页
Power-law patterns appear in a variety of natural systems on the modern Earth;nevertheless,whether such behaviors appeared in the deep-time environment has rarely been studied. Isotopic records in sedimentary rocks, w... Power-law patterns appear in a variety of natural systems on the modern Earth;nevertheless,whether such behaviors appeared in the deep-time environment has rarely been studied. Isotopic records in sedimentary rocks, which are widely used to reconstruct the geological/geochemical conditions in paleoenvironments and the evolutionary trajectories of biogeochemical cycles, offer an opportunity to investigate power laws in ancient geological systems. In this study, I focus on the Phanerozoic sedimentary records of carbon, oxygen, sulfur, and strontium isotopes, which have well documented and extraordinarily comprehensive datasets. I perform statistical analyses on these datasets and show that the variations in the sedimentary records of the four isotopes exhibit power-law behaviors. The exponents of these power laws range between 2.2 and 2.9;this narrow interval indicates that the variations in carbon, oxygen, sulfur, and strontium isotopes likely belong to the same universality class, suggesting that these systematic power-law patterns are governed by universal, scale-free mechanisms. I then derive a general form for these power laws from a minimalistic model based on basic physical principles and geosystem-specific assumptions, which provides an interpretation for the power-law patterns from the perspective of thermodynamics. The fundamental mechanisms regulating such patterns might have been ubiquitous in paleoenvironments, implying that similar power-law behaviors may exist in the sedimentary records of other isotopes. 展开更多
关键词 Power laws Phanerozoic sedimentary records carbon isotope(δ~(13)c) Oxygen isotope(δ~(18)O) Sulfur isotope(δ~(34)S) Strontium isotope(~(87)Sr/~(86)Sr)
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DETERMINING CARBON-13 ENRICHMENT USING LOW ENERGY PROTONS
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作者 张维成 晁致远 彭秀茹 《Nuclear Science and Techniques》 SCIE CAS CSCD 1995年第2期71-74,共4页
DETERMININGCARBON-13ENRICHMENTUSINGLOWENERGYPROTONSZhangWeicheng(张维成);ChaoZhiyuan(晁致远)andPengXiuru(彭秀茹)(Inst... DETERMININGCARBON-13ENRICHMENTUSINGLOWENERGYPROTONSZhangWeicheng(张维成);ChaoZhiyuan(晁致远)andPengXiuru(彭秀茹)(InstituteofModernPhys... 展开更多
关键词 低能质子 确定13c浓度 伽马探测
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稻秆木素侧链^(13)C同位素示踪及固体^(13)CNMR分析 被引量:24
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作者 顾瑞军 谢益民 +2 位作者 曾绍琼 伍红 安田征市 《高等学校化学学报》 SCIE EI CAS CSCD 北大核心 2002年第6期1073-1076,共4页
在水稻 (Oryza sativa L.)生长过程中 ,向其茎秆部节间的空腔分别注入在侧链α,β,γ位带有 1 3C标记的松柏醇葡萄糖甙 ,得到 1 3C标记的稻秆木素 ,用高分辨率固体核磁 1 3C NMR对其组织进行分析 ,发现外源性的松柏醇葡萄糖甙并不影响... 在水稻 (Oryza sativa L.)生长过程中 ,向其茎秆部节间的空腔分别注入在侧链α,β,γ位带有 1 3C标记的松柏醇葡萄糖甙 ,得到 1 3C标记的稻秆木素 ,用高分辨率固体核磁 1 3C NMR对其组织进行分析 ,发现外源性的松柏醇葡萄糖甙并不影响水稻中木素的正常合成 .证明了 β-O-4,β-β,β-5和 β-1结构是稻秆原本木素中的主要结构 ,另外还有少量的松柏醇和阿魏酸类结构 ,并证实木素在 展开更多
关键词 稻秆 木素 同位素示踪 13 核磁共振 分离 造纸工业 制浆
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河西走廊中部沙漠植物δ^(13)C值的特点及其对水分利用效率的指示 被引量:35
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作者 苏培玺 陈怀顺 李启森 《冰川冻土》 CSCD 北大核心 2003年第5期597-602,共6页
通过分析河西走廊中部沙漠中几种木本植物叶片或同化枝的稳定碳同位素比率(δ13C)和碳同位素辨别力(Δ),以其作为水分利用效率(WUE)的指示,研究了本区沙漠植物叶片或同化枝δ13C值的季节变化特点,以及不同生境和不同水分状况下δ13C值... 通过分析河西走廊中部沙漠中几种木本植物叶片或同化枝的稳定碳同位素比率(δ13C)和碳同位素辨别力(Δ),以其作为水分利用效率(WUE)的指示,研究了本区沙漠植物叶片或同化枝δ13C值的季节变化特点,以及不同生境和不同水分状况下δ13C值的差异,并比较研究了绿洲防护林树种及绿洲作物.结果表明:梭梭和沙拐枣同化枝的δ13C值分别为-14 31‰和-14 82‰,Δ值在5‰~6‰之间;柠条、泡泡刺、花棒和红沙叶片的δ13C值分别为-25 75‰、-25 79‰、-26 38‰和-28 05‰,Δ值在16‰~20‰之间.几种沙漠植物长期水分利用效率大小的顺序为:梭梭≈沙拐枣>柠条≈泡泡刺≈花棒>红沙. 展开更多
关键词 河西走廊 沙漠植物 稳定碳同位素比率 稳定碳同位素辨别力 水分利用效率
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有机溶剂稀释与气相色谱-燃烧-同位素质谱(GC-C-IRMS)联用测定食醋中乙酸的δ^(13)C 被引量:11
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作者 钟其顶 王道兵 +2 位作者 孟镇 熊正河 王敏 《质谱学报》 EI CAS CSCD 北大核心 2014年第4期372-377,共6页
食醋中乙酸的碳-13比值(δ13 C)与食醋原料有密切关联,通过测定乙酸中δ13 C可对食醋原料进行溯源。本工作建立了有机溶剂稀释法与气相色谱-燃烧-稳定同位素比值质谱(GC-C-IRMS)联用法测定食醋中乙酸的δ13 C。在乙酸浓度为2%~99.9%的... 食醋中乙酸的碳-13比值(δ13 C)与食醋原料有密切关联,通过测定乙酸中δ13 C可对食醋原料进行溯源。本工作建立了有机溶剂稀释法与气相色谱-燃烧-稳定同位素比值质谱(GC-C-IRMS)联用法测定食醋中乙酸的δ13 C。在乙酸浓度为2%~99.9%的模拟样品测试中获得了稳定的检测结果;同一样品中乙酸的δ13 C重复测定16次的标准偏差小于0.15‰;参与欧盟同位素实验室间能力测试时,该方法的测定结果与其中5个国际实验室测定平均值差异为0.17‰。该方法的精密度和稳定性好、准确性高、操作简便快速,适合在食醋真实性技术中应用和推广。 展开更多
关键词 食醋 乙酸 气相色谱-燃烧-稳定同位素比值质谱(Gc-c-IRMS) 碳-13 稳定同位素比值
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小麦不同进化材料叶与非叶器官C4光合酶活性及δ^(13)C值差异 被引量:4
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作者 魏爱丽 杨茂 +2 位作者 黄琴 张英华 王志敏 《麦类作物学报》 CAS CSCD 北大核心 2021年第2期183-190,共8页
为明确小麦进化过程中C_(4)代谢酶活性的变化趋势,以二倍体小麦种(野生一粒小麦、栽培一粒小麦、拟斯卑尔脱山羊草、粗山羊草)、四倍体小麦种(野生二粒小麦、栽培二粒小麦、阿拉拉特、提莫菲维小麦)及六倍体小麦种(斯卑尔脱小麦、普通小... 为明确小麦进化过程中C_(4)代谢酶活性的变化趋势,以二倍体小麦种(野生一粒小麦、栽培一粒小麦、拟斯卑尔脱山羊草、粗山羊草)、四倍体小麦种(野生二粒小麦、栽培二粒小麦、阿拉拉特、提莫菲维小麦)及六倍体小麦种(斯卑尔脱小麦、普通小麦)为试验材料,对不同染色体倍数小麦种不同绿色器官光合碳同化酶(PEPC、RuBPC、NADP-MDH、NADP-ME、NAD-ME)活性及稳定碳同位素(δ^(13)C)值进行了比较分析。结果表明,在同一种内,非叶器官(叶鞘、穗下节间、芒、护颖、外颖)RuBPC活性显著低于旗叶,除六倍体小麦品种外,其余小麦材料的PEPC及其他C_(4)途径酶活性均高于叶片。在小麦进化过程中,随着染色体倍数的增加,旗叶片的C_(3)和C_(4)同化酶活性均上升,且PEPC/RuBPC活性比值显著增加;非叶器官的RuBPC活性增加,但PEP羧化酶及其他C_(4)途径酶活性下降,PEPC/RuBPC活性比值显著降低。旗叶和穗器官的δ^(13)C值均在C3途径范围内,穗器官的δ^(13)C值高于叶片;随染色体倍数的增加,旗叶δ^(13)C值增高,而穗器官的δ^(13)C值下降。综合来看,小麦非叶器官具有较强的C_(4)光合酶活性,在进化过程中,其C4酶活性趋向减弱,而旗叶的C_(4)酶活性则趋向增加。 展开更多
关键词 小麦 非叶器官 进化 PEP羧化酶 稳定碳同位素(δ^(13)c)
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^(13)C脉冲标记法研究非正常凋落物对土壤有机碳的激发效应 被引量:5
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作者 张天霖 蔡章林 +3 位作者 赵厚本 吴仲民 周光益 邱治军 《生态环境学报》 CSCD 北大核心 2021年第9期1797-1804,共8页
冰暴、台风等极端气候事件严重干扰了森林生态系统,导致大量落叶、断枝、断干等非正常凋落物产生,将对土壤碳库产生激发效应,然而目前对这种现象的研究仍十分匮乏。以马尾松(Pinus massoniana)、黧蒴锥(Castanopsis fissa)、浙江润楠(Ma... 冰暴、台风等极端气候事件严重干扰了森林生态系统,导致大量落叶、断枝、断干等非正常凋落物产生,将对土壤碳库产生激发效应,然而目前对这种现象的研究仍十分匮乏。以马尾松(Pinus massoniana)、黧蒴锥(Castanopsis fissa)、浙江润楠(Machilus chekiangensis)3种南亚热带常见树种为研究对象,利用^(13)C标记植株并采集其新鲜叶片添加至土壤表面,进行了为期110 d的室内培养实验,培养中分别测量了CO_(2)排放量、^(13)C丰度值以及培养前后土壤碳库的变化。结果表明,不同树种的非正常凋落物的碳排放模式相似,均表现为前期快速升高,之后波动下降,后期稳定在较低水平。其中91.39%—94.04%的碳排放过程发生在前中期(0—45 d)。110 d的培养过程中,非正常凋落物分解产生的碳有67.86%—95.31%以C–CO_(2)的形式排放到大气当中。非正常凋落物输入对土壤有机碳的激发效应主要分为3个阶段。培养前期(0—7 d)3种非正常凋落物输入均引起了土壤碳强烈的负激发效应且在短期内达到峰值,峰值分别为−50.05、−117.72、−124.08;培养中期(7—35 d)负激发效应强度逐步下降,表现为先快速下降后速率转慢;培养后期(35—110 d)碳激发效应较为平稳,不同树种之间有所差异,黧蒴锥、浙江润楠的碳激发效应逐渐转为正向,而马尾松维持负激发效应并缓慢下降至消失。经过110 d的培养,马尾松、黧蒴锥的0—5 cm层土壤有机碳显著高于对照组(P<0.05),黧蒴锥的0—5、5—10 cm层土壤的^(13)C同位素值显著高于对照组(P<0.05)。各处理组与对照组之间全氮、有效氮差异均不显著(P>0.05)。非正常凋落物输入在短期内对表层土壤有机碳含量影响显著而对深层土壤没有影响,其分解产生的碳大部分以C–CO_(2)的形式排放到大气当中。 展开更多
关键词 南亚热带森林生态系统 新鲜植物叶片 ^(13)c同位素 激发效应 分解过程 土壤碳库
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基于^(87)Sr/^(86)Sr和δ^(13)C对进口大麦进行产地溯源 被引量:4
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作者 马明 冯睿 +6 位作者 李锦花 张吉红 刘永丰 施滔 曹国洲 陈先锋 殷居易 《食品安全质量检测学报》 CAS 北大核心 2021年第19期7857-7862,共6页
目的建立基于^(87)Sr/^(86)Sr和δ^(13)C稳定同位素比质谱法(stable isotope ratio mass spectrometry,IRMS)的进口大麦产地溯源技术。方法样品干燥粉碎后,经硝酸消解,锶特效树脂净化后利用热电离质谱法(thermal ionization mass spectr... 目的建立基于^(87)Sr/^(86)Sr和δ^(13)C稳定同位素比质谱法(stable isotope ratio mass spectrometry,IRMS)的进口大麦产地溯源技术。方法样品干燥粉碎后,经硝酸消解,锶特效树脂净化后利用热电离质谱法(thermal ionization mass spectrometry,TIMS)分析检测^(87)Sr/^(86);样品用锡囊包裹后,利用元素分析-稳定同位素比质谱法分析检测δ^(13)C;利用SPSS 25.0软件对进口大麦的^(87)Sr/^(86)Sr和δ^(13)C进行正态性验证、方差分析、事后多重比较分析和判别分析。结果不同进口国大麦中的^(87)Sr/^(86)Sr和δ^(13)C具有显著性差异,经判别分析,进口自澳大利亚、法国和美国的大麦可以达到100%正确判别率,整体正确判别率达到86.2%,若将美国和加拿大进口的大麦归类为北美洲进口大麦,则可实现进口自北美、法国和澳大利亚大麦的100%正确判别率。结论利用^(87)Sr/^(86)Sr和δ^(13)C可以对不同进口国大麦进行产地溯源分析。 展开更多
关键词 ^(87)Sr/^(86) δ^(13)c 进口大麦 产地溯源 稳定同位素比质谱法
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具有动态稀释功能的EA-IRMS联机系统在δ^(13)C和δ^(15)N测定中的应用 被引量:4
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作者 孟宪菁 杨斌 +4 位作者 李安 贾晓艺 朱湘 马潇 尹松 《质谱学报》 EI CAS CSCD 北大核心 2018年第6期746-753,共8页
自然界的样品中C、N元素含量或C/N变化极大,以往的元素分析-稳定同位素比值质谱仪(EAIRMS)大多采用固定比例稀释样品气,不仅需要预先了解样品中元素含量及C/N等信息,还需要精确控制取样量。为了提高样品分析效率,本实验初步建立了具有... 自然界的样品中C、N元素含量或C/N变化极大,以往的元素分析-稳定同位素比值质谱仪(EAIRMS)大多采用固定比例稀释样品气,不仅需要预先了解样品中元素含量及C/N等信息,还需要精确控制取样量。为了提高样品分析效率,本实验初步建立了具有动态稀释功能的EA-IRMS联机系统,快速分析有机碳、总氮稳定同位素比值(δ^(13) C和δ^(15) N)。结果表明,该联机系统与传统的固定比例稀释方法的δ^(13) C和δ^(15) N测定结果一致性较好(p>0.05)。对于C/N差异较大或难以精确称重的9种样品,该联机系统的δ^(13) C和δ^(15) N测定结果具有良好的重复性。通过动态稀释,δ^(13) C和δ^(15) N的测定精度分别为0.07‰~0.32‰和0.05‰~0.27‰。该联机系统在不同时间(间隔45天)的测定结果再现性良好(p>0.05),δ^(13) C和δ^(15) N的测定偏差分别小于0.2‰和0.3‰。结合动态稀释功能的EA-IRMS,无需精确控制样品质量,省时、省力,具有一定的应用前景。 展开更多
关键词 元素分析-稳定同位素比值质谱(EA-IRMS) δ13c δ15N 元素含量 碳氮比 固定比例稀释 动态稀释
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气相色谱-燃烧-稳定同位素比值质谱测定葡萄酒中甘油δ^(13)C的可行性探讨 被引量:1
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作者 王道兵 钟其顶 +1 位作者 李国辉 岳红卫 《酿酒科技》 2018年第3期17-23,共7页
气相色谱-燃烧-稳定同位素比值质谱技术(GC-C-IRMS)在单体化合物的稳定同位素组成分析中具有重要应用,探讨了应用该技术测定葡萄酒中甘油碳同位素比值的可行性并优化了分析条件。研究结果表明,该方法的分析精度可优于0.3‰,然而样品的... 气相色谱-燃烧-稳定同位素比值质谱技术(GC-C-IRMS)在单体化合物的稳定同位素组成分析中具有重要应用,探讨了应用该技术测定葡萄酒中甘油碳同位素比值的可行性并优化了分析条件。研究结果表明,该方法的分析精度可优于0.3‰,然而样品的理化特性,如乙醇含量和甘油含量均会影响结果的准确性。应用"相同处理"原则配制标准品可用于样品数据校正,但是由于不同葡萄酒中乙醇和甘油含量差异较大,使得标准品的配制过程很复杂。因此,我们认为GC-C-IRMS不适于葡萄酒中甘油碳同位素分析。 展开更多
关键词 葡萄酒 甘油 碳同位素组成 气相色谱-燃烧-稳定同位素比值质谱
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Belowground Carbon and Nitrogen on a Thinned and Un-Thinned Seasonally Dry Tropical Forest
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作者 Deodato do Nascimento Aquino Eunice Maia de Andrade +2 位作者 Andréa Dardes de Almeida Castanho Lécio Resende Pereira Júnior Helba Araújo de Queiroz Palácio 《American Journal of Plant Sciences》 2017年第9期2083-2100,共18页
The aim of this study was to quantify the dynamics of herbaceous biomass and fine root productivity, and their relationship to stocks of carbon and nitrogen, in the Vertisols of two adjacent watersheds of a seasonally... The aim of this study was to quantify the dynamics of herbaceous biomass and fine root productivity, and their relationship to stocks of carbon and nitrogen, in the Vertisols of two adjacent watersheds of a seasonally dry tropical forest (SDTF) under two different types of ground cover. The two watersheds are located in the county of Iguatu in the State of Ceará, Brazil. The control watershed of 2.1 ha, has been under regeneration for 35 years (RC35), while the second watershed (1.1 ha) was subjected to thinning for a period of 5 years (TC5). The sampled variables were herbaceous shoot biomass, fine roots, gravimetric moisture, the isotope δ13C (‰), total soil carbon (TSC) and total nitrogen (TN) in the 0 - 20, 20 - 40 and 40 - 60 cm layers, between April 2013 and March 2014. To quantify herbaceous shoot biomass, samples were taken monthly. For TSC and TN, the campaigns were held every two months. The data underwent analysis of means and were compared by t-test (p < 0.05). Under TC5, there was an increase in the stocks of TSC and TN of 151 and 137% respectively in the 40 - 60 cm layer, in relation to RC35. The implementation of thinning in a SDFT is seen as a management alternative to be considered in sustainability programs in the semi-arid region, contributing to maximising the production of herbaceous forage for feeding large and small ruminants, and for bee pasture, in addition to increasing the stock of carbon in the soil of SDFT and reducing global warming. 展开更多
关键词 carbon SEQUESTratioN DRY FORESTS isotope δ13c HERBAcEOUS Plants
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Sedimentary record of climate change in a high latitude fjord—Kongsfjord
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作者 Hang Wu Binbin Deng +5 位作者 Jinlong Wang Sheng Zeng Juan Du Peng Yu Qianqian Bi Jinzhou Du 《Acta Oceanologica Sinica》 SCIE CAS CSCD 2023年第1期91-102,共12页
The sedimentary record of climate change in the Arctic region is useful for understanding global warming.Kongsfjord is located in the subpolar region of the Arctic and is a suitable site for studying climate change.Gl... The sedimentary record of climate change in the Arctic region is useful for understanding global warming.Kongsfjord is located in the subpolar region of the Arctic and is a suitable site for studying climate change.Glacier retreat is occurring in this region due to climate change,leading to an increase in meltwater outflow with a high debris content.In August 2017,we collected a sediment Core Z3 from the central fjord near the Yellow River Station.Then,we used the widely used chronology method of 210Pb,^(137)Cs,and other parameters to reflect the climate change record in the sedimentary environment of Kongsfjord.The results showed that after the mid-late 1990s,the mass accumulation rate of this core increased from 0.10 g/(cm^(2)·a)to 0.34 g/(cm^(2)·a),while the flux of^(210)Pb_(ex)increased from 125 Bq/(m^(2)·a)to 316 Bq/(m^(2)·a).The higher sedimentary inventory of^(210)Pb_(ex)in Kongsfjord compared to global fallout might have been caused by sediment focusing,boundary scavenging,and riverine input.Similarities between the inventory of^(137)Cs and global fallout indicated that terrestrial particulate matter was the main source of^(137)Cs in fjord sediments.The sedimentation rate increased after 1997,possibly due to the increased influx of glacial meltwater containing debris.In addition,the^(137)Cs activity,percentage of organic carbon(OC),and OC/total nitrogen concentration ratio showed increasing trends toward the top of the core since 1997,corresponding to a decrease in the mass balance of glaciers in the region.The results ofδ^(13)C,δ^(15)N and OC/TN concentration ratio showed both terrestrial and marine sources contributed to the organic matter in Core Z3.The relative contribution of terrestrial organic matter which was calculated by a two-endmember model showed an increased trend since mid-1990s.All these data indicate that global climate change has a significant impact on Arctic glaciers. 展开更多
关键词 Kongsfjord RADIONUcLIDE organic carbon/total nitrogen(Oc/TN)concentration ratio δ^(13)c δ^(15)N sediment record climate change
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Carbon isotope ratios of C_(4) plants in loess areas of North China 被引量:16
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作者 WANG Guoan1,2,3, HAN Jiamao 2, ZHOU Liping3, XIONG Xiaogang4, TAN Ming2, WU Zhenhai5 & PENG Jun6 1. Department of Plant Nutrition, China Agricultural University, Beijing 100094, China 2. Institute of Geology and Geophysics, Chinese Academy of Sciences, Beijing 100029, China +3 位作者 3. College of Environmental Sciences, MOE Laboratory for Earth Surface Processes, Peking University, Beijing 100871, China 4. Institute of Botany, Chinese Academy of Sciences, Beijing 100093, China 5. Northwest Sci-Tech University of Agriculture and Forestry, Yangling 712100, China 6. Network Center, China Agricultural University, Beijing 100094, China 《Science China Earth Sciences》 SCIE EI CAS 2006年第1期97-102,共6页
Carbon isotope ratios (δ 13C) of 89 C4 plant samples were determined from the loess area in North China. δ 13C values vary between –10.5‰ and –14.6‰ with a mean of –12.6‰. Along a pre-cipitation gradient from ... Carbon isotope ratios (δ 13C) of 89 C4 plant samples were determined from the loess area in North China. δ 13C values vary between –10.5‰ and –14.6‰ with a mean of –12.6‰. Along a pre-cipitation gradient from the semi-moist area to the semiarid area, then to the arid area, the δ 13C val-ues of C4 plants show a slight decreasing trend. The δ 13C values of C4 plants in the dry season are found lower than those in the wet season. These trends are opposite to those observed for C3 spe-cies. 展开更多
关键词 c4 plants carbon isotope ratios LOESS area.
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Variations in carbon isotope ratios of C_3 plants and distribution of C_4 plants along an altitudinal transect on the eastern slope of Mount Gongga 被引量:17
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作者 LI JiaZhu1, WANG GuoAn2, LIU XianZhao1, HAN JiaMao3, LIU Min4 & LIU XiaoJuan2 1 College of Geography and Planning, Ludong University, Yantai 264025, China 2 Key Laboratory of Plant-Soil Interactions, Ministry of Education, College of Resources and Environmental Sciences, China Agri- cultural University, Beijing 100193, China +1 位作者 3 Institute of Geology and Geophysics, Chinese Academy of Sciences, Beijing 100029, China 4 College of Environmental Sciences, MOE Laboratory for Earth Surface Processes, Peking University, Beijing 100871, China 《Science China Earth Sciences》 SCIE EI CAS 2009年第11期1714-1723,共10页
Variations in carbon isotopic ratios (δ 13C) of C3 plants and distribution of C4 plants were investigated along an altitudinal transect on the eastern slope of Mount Gongga, and the environmental effects on them were... Variations in carbon isotopic ratios (δ 13C) of C3 plants and distribution of C4 plants were investigated along an altitudinal transect on the eastern slope of Mount Gongga, and the environmental effects on them were discussed. It is shown that plants with C4 photosynthetic pathway mainly occur at altitudes below 2100 m a.s.l., suggesting that the low summer temperature is responsible for the distributional pattern. In addition, δ 13C of C3 plants increases with elevation at the region above 2000 m a.s.l. with the characteristics of humid climate, and the increase rate in δ 13C for C3 plants is about 1.3‰ per kilometer. Temperature determines the altitudinal trend of δ 13C. 展开更多
关键词 MOUNT Gongga carbon isotopIc ratios c3/c4 PLANTS c4 DISTRIBUTION ALTITUDE
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影响C_4草本植物C/N比值变化的因素与土壤有机C积累的关系 被引量:10
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作者 朴河春 朱建明 +1 位作者 余登利 冉景丞 《第四纪研究》 CAS CSCD 北大核心 2004年第6期621-629,共9页
文章对采自贵州从低海拔的东部到高海拔的西部且大致平行的石灰岩和砂岩两地带均生长的3种C4草本植物,即巴茅(Miscanthus floridulus)、白茅(Imperata cylindrica)和类芦(Neyraudia reynaudiana),以及相对应的土壤表层样品,进行了营养... 文章对采自贵州从低海拔的东部到高海拔的西部且大致平行的石灰岩和砂岩两地带均生长的3种C4草本植物,即巴茅(Miscanthus floridulus)、白茅(Imperata cylindrica)和类芦(Neyraudia reynaudiana),以及相对应的土壤表层样品,进行了营养元素和C同位素组成分析;研究营养元素含量随着海拔的不同而出现的变化趋势,以及这些元素之间的相互协变作用,尤其是Ca和N之间的相互协变作用对植物的N含量、C/N比值和δ13C值的影响,以了解植物的C/N比值(指示植物残留物质量的一种标志)与土壤有机C积累的关系。研究结果表明,植物的N含量和δ13C值具有随海拔的上升而显著增大趋势,而植物的C/N比值在砂岩地区虽有减小的趋势,在石灰岩地带则没有。对所研究的C4草本植物来说,在土壤pH值为5.8的中性条件下显示出Ca的最大吸收,因此,Ca与其他营养元素之间的协变模式在两种土壤类型中表现出相反的倾向,并存在土壤交换性Ca的边界浓度:当土壤可交换性Ca的含量为2.24 mg/g,相应土壤的pH值在5.8以下时,随着土壤可交换性Ca浓度的增大,植物的N含量上升,而植物的C/N比值会显著降低;当Ca在边界浓度以上时,随着土壤可交换性Ca浓度的增大,植物的N含量下降,而植物的C/N比值有增加的趋势。由此可见。 展开更多
关键词 c4草类植物 营养元素相互作用 土壤可交换性ca含量 c同位素 c/N比值 海拔 土壤有机c的积累
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