Copper(Cu)is considered to be the most effective catalyst for electrochemical conversion of carbon dioxide(CO_(2))into value-added hydrocarbons,but its stability still faces considerable challenge.Here,we report the p...Copper(Cu)is considered to be the most effective catalyst for electrochemical conversion of carbon dioxide(CO_(2))into value-added hydrocarbons,but its stability still faces considerable challenge.Here,we report the poisoning effect of carbon deposition during CO_(2)reduction on the active sites of Cu electrodea critical deactivation factor that is often overlooked.We find that,*C,an intermediate toward methane formation,could desorb on the electrode surface to form carbon species.We reveal a strong correlation between the formation of methane and the carbon deposition,and the reaction conditions favoring methane production result in more carbon deposition.The deposited carbon blocks the active sites and consequently causes rapid deterioration of the catalytic performance.We further demonstrate that the carbon deposition can be mitigated by increasing the roughness of the electrode and increasing the pH of the electrolyte.This work offers a new guidance for designing more stable catalysts for CO_(2)reduction.展开更多
新疆塔木—卡兰古铅锌铜成矿带位于西昆仑与塔里木盆地的结合带 ,是近年来新发现的一个大型矿带。通过对含矿岩系的岩石化学、成矿元素、硫同位素、稀土元素的研究 ,并结合流体包裹体成分及H、O同位素的综合研究分析 ,认为该成矿带可分...新疆塔木—卡兰古铅锌铜成矿带位于西昆仑与塔里木盆地的结合带 ,是近年来新发现的一个大型矿带。通过对含矿岩系的岩石化学、成矿元素、硫同位素、稀土元素的研究 ,并结合流体包裹体成分及H、O同位素的综合研究分析 ,认为该成矿带可分为两种矿床类型 ,即砂砾岩型铅铜 (钴 )矿和碳酸盐岩型铅锌矿。二者为同一热卤水成矿系统的不同成矿阶段的产物 ,两类矿床可互为找矿标志。下部砂砾岩型矿床的成矿元素组合为Cu Co Pb Ag As(Ni Zn Cd) ,硫同位素组成表明富集轻硫 ,海底热液活动不强烈 ;上部碳酸盐岩型矿床的成矿元素组合为Pb Zn Cd As Ag Ba ,硫同位素分布具塔式结构 ,显示具海水还原硫和深源硫的混合来源 ,有强烈的海底热液活动。提出该成矿带的找矿目标应以上部碳酸盐岩型铅锌矿为主 ,同时应当注意下部砂砾岩型铅铜矿及其含铜砂页岩中钴的综合评价和工业利用。展开更多
基金supported by the National Basic Research Program of China(Grant 2018YFA0702001)the National Natural Science Foundation of China(Grants 22225901,21975237 and 51702312)+5 种基金the Fundamental Research Funds for the Central Universities(Grant WK2340000101)the USTC Research Funds of the Double First-Class Initiative(Grant YD2340002007 and YD9990002017)the Open Funds of the State Key Laboratory of Rare Earth Resource Utilization(Grant RERU2022007)the China Postdoctoral Science Foundation(Grants 2023M733371,2022M723032,and 2023T160617)the Natural Science Foundation Youth Project of Anhui Province(2308085QB37)the China National Postdoctoral Program for Innovative Talents(BX2023341).
文摘Copper(Cu)is considered to be the most effective catalyst for electrochemical conversion of carbon dioxide(CO_(2))into value-added hydrocarbons,but its stability still faces considerable challenge.Here,we report the poisoning effect of carbon deposition during CO_(2)reduction on the active sites of Cu electrodea critical deactivation factor that is often overlooked.We find that,*C,an intermediate toward methane formation,could desorb on the electrode surface to form carbon species.We reveal a strong correlation between the formation of methane and the carbon deposition,and the reaction conditions favoring methane production result in more carbon deposition.The deposited carbon blocks the active sites and consequently causes rapid deterioration of the catalytic performance.We further demonstrate that the carbon deposition can be mitigated by increasing the roughness of the electrode and increasing the pH of the electrolyte.This work offers a new guidance for designing more stable catalysts for CO_(2)reduction.
文摘新疆塔木—卡兰古铅锌铜成矿带位于西昆仑与塔里木盆地的结合带 ,是近年来新发现的一个大型矿带。通过对含矿岩系的岩石化学、成矿元素、硫同位素、稀土元素的研究 ,并结合流体包裹体成分及H、O同位素的综合研究分析 ,认为该成矿带可分为两种矿床类型 ,即砂砾岩型铅铜 (钴 )矿和碳酸盐岩型铅锌矿。二者为同一热卤水成矿系统的不同成矿阶段的产物 ,两类矿床可互为找矿标志。下部砂砾岩型矿床的成矿元素组合为Cu Co Pb Ag As(Ni Zn Cd) ,硫同位素组成表明富集轻硫 ,海底热液活动不强烈 ;上部碳酸盐岩型矿床的成矿元素组合为Pb Zn Cd As Ag Ba ,硫同位素分布具塔式结构 ,显示具海水还原硫和深源硫的混合来源 ,有强烈的海底热液活动。提出该成矿带的找矿目标应以上部碳酸盐岩型铅锌矿为主 ,同时应当注意下部砂砾岩型铅铜矿及其含铜砂页岩中钴的综合评价和工业利用。
