The title compound, a novel Ag（Ⅰ） carboxyarylphosphonate [Ag（H2BCP）（4,4＇- bipy）]·2H2O （H3BCP = p-H2O3PCH2C6H4COOH, 4,4＇-bipy = 4,4＇-bipyridine）, was synthesized by a hydrothermal reaction and characte...The title compound, a novel Ag（Ⅰ） carboxyarylphosphonate [Ag（H2BCP）（4,4＇- bipy）]·2H2O （H3BCP = p-H2O3PCH2C6H4COOH, 4,4＇-bipy = 4,4＇-bipyridine）, was synthesized by a hydrothermal reaction and characterized by elemental analysis, IR spectra and single-crystal X-ray diffraction. It belongs to monoclinic system, space group P21/c with a = 5.7038（11）, b = 22.397（4）, c = 5.602（4） , β = 106.26（3）°, V = 1913.4（7） 3, Z = 4, C18H20N2O7PAg, Mr = 515.20, Dc = 1.788 g/cm3, μ = 1.182 mm–1, F（000） = 1040, the final R = 0.0404 and wR = 0.1216 for 4178 observed reflections with I 2σ（Ⅰ）. In the structure, the Ag（Ⅰ） cations are bridged by 4,4＇-bipy to give rise to 1D chains running along the b axis. These chains are linked further by the interactions of O （from BCP ligands） and Ag atoms to yield 2D layers. Hydrogen bonding interactions and weak π-π stacking interactions between 4,4＇-bipy rings assemble such adjacent layers to generate a 3D supramolecular architecture.展开更多
[Zn2（PCP）（phen）（H2O）F]n 1 and {[Zn3（MCP）2（phen）2（H2O）]·2.5H2O}n 2（PCP = p-O2C（C6H4）PO33-,MCP = m-O2C（C6H4）PO33- and phen = phenanthroline） were obtained by hydrothermal synthesis and characteriz...[Zn2（PCP）（phen）（H2O）F]n 1 and {[Zn3（MCP）2（phen）2（H2O）]·2.5H2O}n 2（PCP = p-O2C（C6H4）PO33-,MCP = m-O2C（C6H4）PO33- and phen = phenanthroline） were obtained by hydrothermal synthesis and characterized by X-ray single-crystal diffraction.Compound 1 crystallizes in the monoclinic P21/c space group with a = 7.908（2）,b = 20.254（3）,c = 13.477（2） ,β = 107.76（3）°,V = 2055.7（8） 3,Z = 4,C20H16FN2O6PZn2,Mr = 561.10,Dc = 1.813 g/cm3,μ = 2.463 mm-1,F（000） = 1128,the final R = 0.0340 and wR = 0.0794.Compound 2 crystallizes in the monoclinic P21/n space group with a = 15.629（3）,b = 18.141（4）,c = 17.723（7） ,β = 121.89（2）°,V = 4267（2） 3,Z = 4,C40H31N4O13.5P2Zn3,Mr = 1041.70,Dc = 1.620 g/cm3,μ = 1.818 mm-1,F（000） = 2108,the final R = 0.0669 and wR = 0.1775.In compound 1,the tetranuclear Zn4 units are linked together by μ4-PCP3- to build 2D（4,4） layers,which are further interconnected through the μ2-bridging fluorion into a 3D framework with 1D phen ligands-filled channels.As for the 3D supramolecular framework of 2,the novel hexanuclear Zn6 units with ＂chair＂ conformation are extended by the moieties of μ4-MCP3- ligand to a 2D（4,4） layer on the bc plane,which is viewed as the 2-folded layers in 1.In both compounds,the structures are stabilized by hydrogen bonding interactions and π-π stacking interactions between the phen rings.Additionally,FT-IR spectroscopy and the fluorescent properties are discussed.展开更多
基金supported by the National Natural Science Foundation of China (No. 20873021)the State Key Laboratory of Structural Chemistry and the Young Talent Programmed of Fujian Province (No. 2006F3072)
文摘The title compound, a novel Ag（Ⅰ） carboxyarylphosphonate [Ag（H2BCP）（4,4＇- bipy）]·2H2O （H3BCP = p-H2O3PCH2C6H4COOH, 4,4＇-bipy = 4,4＇-bipyridine）, was synthesized by a hydrothermal reaction and characterized by elemental analysis, IR spectra and single-crystal X-ray diffraction. It belongs to monoclinic system, space group P21/c with a = 5.7038（11）, b = 22.397（4）, c = 5.602（4） , β = 106.26（3）°, V = 1913.4（7） 3, Z = 4, C18H20N2O7PAg, Mr = 515.20, Dc = 1.788 g/cm3, μ = 1.182 mm–1, F（000） = 1040, the final R = 0.0404 and wR = 0.1216 for 4178 observed reflections with I 2σ（Ⅰ）. In the structure, the Ag（Ⅰ） cations are bridged by 4,4＇-bipy to give rise to 1D chains running along the b axis. These chains are linked further by the interactions of O （from BCP ligands） and Ag atoms to yield 2D layers. Hydrogen bonding interactions and weak π-π stacking interactions between 4,4＇-bipy rings assemble such adjacent layers to generate a 3D supramolecular architecture.
基金supported by the Fuzhou University Postdoctoral Sustentation Fund (No. 826641)the National Natural Science Foundation of China (No. 20771025)
文摘[Zn2（PCP）（phen）（H2O）F]n 1 and {[Zn3（MCP）2（phen）2（H2O）]·2.5H2O}n 2（PCP = p-O2C（C6H4）PO33-,MCP = m-O2C（C6H4）PO33- and phen = phenanthroline） were obtained by hydrothermal synthesis and characterized by X-ray single-crystal diffraction.Compound 1 crystallizes in the monoclinic P21/c space group with a = 7.908（2）,b = 20.254（3）,c = 13.477（2） ,β = 107.76（3）°,V = 2055.7（8） 3,Z = 4,C20H16FN2O6PZn2,Mr = 561.10,Dc = 1.813 g/cm3,μ = 2.463 mm-1,F（000） = 1128,the final R = 0.0340 and wR = 0.0794.Compound 2 crystallizes in the monoclinic P21/n space group with a = 15.629（3）,b = 18.141（4）,c = 17.723（7） ,β = 121.89（2）°,V = 4267（2） 3,Z = 4,C40H31N4O13.5P2Zn3,Mr = 1041.70,Dc = 1.620 g/cm3,μ = 1.818 mm-1,F（000） = 2108,the final R = 0.0669 and wR = 0.1775.In compound 1,the tetranuclear Zn4 units are linked together by μ4-PCP3- to build 2D（4,4） layers,which are further interconnected through the μ2-bridging fluorion into a 3D framework with 1D phen ligands-filled channels.As for the 3D supramolecular framework of 2,the novel hexanuclear Zn6 units with ＂chair＂ conformation are extended by the moieties of μ4-MCP3- ligand to a 2D（4,4） layer on the bc plane,which is viewed as the 2-folded layers in 1.In both compounds,the structures are stabilized by hydrogen bonding interactions and π-π stacking interactions between the phen rings.Additionally,FT-IR spectroscopy and the fluorescent properties are discussed.
