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Optimization of the carrier tracking loop for GPS high dynamic receivers 被引量:6
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作者 李传军 杨树兴 《Journal of Beijing Institute of Technology》 EI CAS 2012年第2期164-171,共8页
A carrier tracking loop which can adjust the loop parameters adaptively is proposed for high dynamic application. Three modules, called the α-β-γT filter model, adaptive loop structure mod- el and adaptive loop ban... A carrier tracking loop which can adjust the loop parameters adaptively is proposed for high dynamic application. Three modules, called the α-β-γT filter model, adaptive loop structure mod- el and adaptive loop bandwidth model respectively, are added in the presented tracking loop com- pared with the traditional carrier tracking loop based on the second-order frequency lock loop (FLL) assisting third-order phase lock loop (PLL) loop filter. And the optimization methods for the track- ing bandwidth and the carrier loop order are analyzed. The real-time estimation methods of the dy- namic parameters, the velocity, acceleration and jerk along the line of sight (LOS) between the sat- ellite and the receiver' s antenna, and the measurement parameters are discussed based on the pres- ented α-β-γ filter algorithm. A method is introduced to improve the filter' s dynamic response to meet high dynamic application by self-adjusted α-β-γ filter coefficient used in the tracking loop. The performance of three cases with different carrier tracking loop is compared by simulation. 展开更多
关键词 OPTIMIZATION carrier tracking loop α-β-γ filter high dynamic receiver
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Application of Fe_2O_3/Al_2O_3 Composite Particles as Oxygen Carrier of Chemical Looping Combustion 被引量:11
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作者 Fang He Hua Wang Yongnian Dai 《Journal of Natural Gas Chemistry》 EI CAS CSCD 2007年第2期155-161,共7页
Chemical looping combustion (CLC) of carbonaceous compounds has been proposed, in the past decade, as an efficient method for CO2 capture without cost of extra energy penalties. The technique involves the use of a m... Chemical looping combustion (CLC) of carbonaceous compounds has been proposed, in the past decade, as an efficient method for CO2 capture without cost of extra energy penalties. The technique involves the use of a metal oxide as an oxygen carrier that transfers oxygen from combustion air to fuels. The combustion is carried out in a two-step process: in the fuel reactor, the fuel is oxidized by a metal oxide, and in the air reactor, the reduced metal is oxidized back to the original phase. The use of iron oxide as an oxygen carrier has been investigated in this article. Particles composed of 80 wt% Fe2O3, together with Al2O3 as binder, have been prepared by impregnation methods. X-ray diffraction (XRD) analysis reveals that Fe2O3 does not interact with the Al2O3 binder after multi-cycles. The reactivity of the oxygen carrier particles has been studied in twenty-cycle reduction-oxidation tests in a thermal gravimetrical analysis (TGA) reactor. The components in the outlet gas have been analyzed. It has been observed that about 85% of CH4 converted to CO2 and H2O during most of the reduction periods. The oxygen carrier has kept quite a high reactivity in the twenty-cycle reactions. In the first twenty reaction cycles, the reaction rates became slightly higher with the number of cyclic reactions increasing, which was confirmed by the scanning electron microscopy (SEM) test results. The SEM analysis revealed that the pore size inside the particle had been enlarged by the thermal stress during the reaction, which was favorable for diffusion of the gaseous reactants into the particles. The experimental results suggested that the Fe2O3/Al2O3 oxygen carrier was a promising candidate for a CLC system. 展开更多
关键词 chemical looping combustion iron oxide oxygen carrier CO2 capture
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Thermodynamic Analysis and Synthesis Gas Generation by Chemical-Looping Gasification of Biomass with Nature Hematite as Oxygen Carriers 被引量:2
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作者 Zhen Huang Fang He +5 位作者 Anqing Zheng Kun Zhao Sheng Chang Xinai Li Haibin Li Zengli Zhao 《Journal of Sustainable Bioenergy Systems》 2013年第1期33-39,共7页
Thermodynamic parameters of chemical reactions in the system were carried out through thermodynamic analysis. According to the Gibbs free energy minimization principle of the system, equilibrium composition of the rea... Thermodynamic parameters of chemical reactions in the system were carried out through thermodynamic analysis. According to the Gibbs free energy minimization principle of the system, equilibrium composition of the reactions of chemical-looping gasification (CLG) of biomass with natural hematite (Fe2O3) as oxygen carrier were analyzed using commercial software of HSC Chemistry 5.1. The feasibility of the CLG of biomass with hematite was experimental verified in a lab-scale bubbling fluidized bed reactor using argon as fluidizing gas. It was indicated the experimental results were consistent with the theoretical analysis. The presence of oxygen carrier gave a significant effect on the biomass conversion and improved the synthesis gas yield obviously. It was observed that the gas content of CO and H2 was over 70% in CLG of biomass. The reduced hematite particles mainly existed in form of FeO. It was showed that the reduction of natural hematite with biomass proceeds in a stepwise manner from Fe2O3 →Fe3O4→ FeO. Reduction product of natural hematite can be restored the lattice oxygen by oxidation with air. 展开更多
关键词 THERMODYNAMICS Synthesis Gas Natural HEMATITE Oxygen carriers BIOMASS Chemical loopING GASIFICATION
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Effect of Gasifying Medium on the Coal Chemical Looping Gasification with CaSO_4 as Oxygen Carrier 被引量:2
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作者 刘永卓 贾伟华 +1 位作者 郭庆杰 Hojung Ryu 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2014年第Z1期1208-1214,共7页
The chemical looping gasification uses an oxygen carrier for solid fuel gasification by supplying insufficient lattice oxygen. The effect of gasifying medium on the coal chemical looping gasification with Ca SO4 as ox... The chemical looping gasification uses an oxygen carrier for solid fuel gasification by supplying insufficient lattice oxygen. The effect of gasifying medium on the coal chemical looping gasification with Ca SO4 as oxygen carrier is investigated in this paper. The thermodynamical analysis indicates that the addition of steam and CO2 into the system can reduce the reaction temperature, at which the concentration of syngas reaches its maximum value.Experimental result in thermogravimetric analyzer and a fixed-bed reactor shows that the mixture sample goes through three stages, drying stage, pyrolysis stage and chemical looping gasification stage, with the temperature for three different gaseous media. The peak fitting and isoconversional methods are used to determine the reaction mechanism of the complex reactions in the chemical looping gasification process. It demonstrates that the gasifying medium(steam or CO2) boosts the chemical looping process by reducing the activation energy in the overall reaction and gasification reactions of coal char. However, the mechanism using steam as the gasifying medium differs from that using CO2. With steam as the gasifying medium, parallel reactions occur in the beginning stage, followed by a limiting stage shifting from a kinetic to a diffusion regime. It is opposite to the reaction mechanism with CO2 as the gasifying medium. 展开更多
关键词 Chemical loopING GASIFICATION Ca SO4 oxygen carrier Reaction mechanism SYNGAS generation
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Copper-based oxygen carriers supported with alumina/lime for the chemical looping conversion of gaseous fuels
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作者 Syed K Haider María Erans +4 位作者 Felix Donat Lunbo Duan Stuart A Scott Vasilije Manovic Edward J Anthony 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2017年第5期891-901,共11页
Copper(Ⅱ) oxide in varying ratios was combined with either an alumina-based cement(Al300), or CaO derived from limestone as support material in a mechanical pelletiser. This production method was used to investig... Copper(Ⅱ) oxide in varying ratios was combined with either an alumina-based cement(Al300), or CaO derived from limestone as support material in a mechanical pelletiser. This production method was used to investigate its influence on possible mechanical and chemical improvements for oxygen carriers in chemical looping processes. These materials were tested in a lab-scale fluidised bed with CO or CH;as a reducing gas at 950 °C. As expected, the oxygen carriers containing a greater ratio of support material exhibited an enhanced crushing strength. Oxygen carriers comprised of a 1:3 ratio of support material to active CuO exhibited increased crushing strength by a minimum of 280% compared to pure CuO pellets.All oxygen carriers exhibited a high CO conversion yield and were fully reducible from CuO to Cu. For the initial redox cycle, Al300-supported oxygen carriers showed the highest fuel and oxygen carrier conversion. The general trend observed was a decline in conversion with an increasing number of redox cycles.In the case of CaO-supported oxygen carriers, all but one of the oxygen carriers suffered agglomeration.The agglomeration was more severe in carriers with higher ratios of CuO. Oxygen carrier Cu25Al75(75 wt% aluminate cement and 25 wt% CuO), which did not suffer from agglomeration, showed the highest attrition with a loss of approximately 8% of its initial mass over 25 redox cycles. The reducibility of the oxygen carriers was limited with CH;in comparison to CO. CH;conversion were 15%-25% and 50% for Cu25Ca75(25 wt% CuO and 75 wt% CaO) and Cu25Al75, respectively. Cu25Ca75 demonstrated improved conversion, whereas Cu25Al75 exhibited a trending decrease in conversion with increasing redox cycles. 展开更多
关键词 Chemical-looping Oxygen carrier COPPER Carbon capture
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Cycle performance of Cu-based oxygen carrier based on a chemical-looping combustion process 被引量:1
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作者 Xiaoming Zheng Lixin Che +1 位作者 Yanqiong Hao Qingquan Su 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2016年第1期101-109,共9页
The cycle life of oxygen carrier(OC) is crucial to the practical applications of chemical looping combustion(CLC). Cycle performance of Cu/SiO2 prepared with a mechanical mixing method was evaluated based on a CLC... The cycle life of oxygen carrier(OC) is crucial to the practical applications of chemical looping combustion(CLC). Cycle performance of Cu/SiO2 prepared with a mechanical mixing method was evaluated based on a CLC process characterized with an added methane steam reforming step. The Cu/SiO2 exhibited high redox reactivity in the initial cycles, while the performance degraded with cycle number. Through characterization of the degraded Cu/SiO2, the performance degradation was mainly caused by the secondary particles' fragmentation and the fine particles' local agglomeration, which worsened the distribution and diffusion of the reactive gases in the packed bed. A regeneration method of the degraded OC based on re-granulation has been proposed, and its mechanism has been illustrated. With this method, the performance of the degraded OC through 420 redox cycles was recovered to a level close to the initial one. 展开更多
关键词 Chemical-looping combustion Cu-based oxygen carrier Cycle life
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Experimental Study on Chemical Looping With Oxygen Uncoupling Using Copper Based Oxygen Carrier and Different Volatiles Contained Coal Chars 被引量:3
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作者 MEI Daofeng ZHAO Haibo MA Zhaojun FANG Yanfei ZHENG Chuguang 《中国电机工程学报》 EI CSCD 北大核心 2013年第11期I0003-I0003,5,共1页
采用溶胶一凝胶法制备CuO/CuAl204氧载体,研究了该氧载体在N2气氛下的释氧性能,发现氧载体774℃时开始释氧,且随着温度的升高氧气含量不断升高。随后,在流化床反应器中研究了挥发分含量不同的6种煤焦的化学链氧解耦燃烧(chemicall... 采用溶胶一凝胶法制备CuO/CuAl204氧载体,研究了该氧载体在N2气氛下的释氧性能,发现氧载体774℃时开始释氧,且随着温度的升高氧气含量不断升高。随后,在流化床反应器中研究了挥发分含量不同的6种煤焦的化学链氧解耦燃烧(chemicalloopingwithoxygenuncoupling,CLOU)特性,结果表明,挥发分含量的增加和温度的升高均会加速煤焦燃烧,煤焦中碳元素转化率达到95%所需要的时间随着挥发分含量及温度的升高不断减少,相应的碳的平均转化率也不断增加;然而,较高的挥发分含量和反应温度都会导致CO2捕集率的下降。对于挥发分含量低的高平煤焦和东欢坨煤焦,C02捕集率超过99%,而对于挥发分高的胜利褐煤焦,C02捕集率不足95%。 展开更多
关键词 氧载体 解偶联 循环使用 挥发物 化石燃料 煤焦 实验 化工
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Evaluation of multi-cycle performance of chemical looping dry reforming using CO_2 as an oxidant with Fe–Ni bimetallic oxides 被引量:6
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作者 Zhen Huang Huanqi Jiang +7 位作者 Fang He Dezhen Chen Guoqiang Wei Kun Zhao Anqing Zheng Yipeng Feng Zengli Zhao Haibin Li 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2016年第1期62-70,共9页
Chemical looping dry reforming(CLDR) is an innovative technology for CO2 utilization using the chemical looping principle.The CLDR process consists of three stages,i.e.CH4 reduction,CO2 reforming,and air oxidation.S... Chemical looping dry reforming(CLDR) is an innovative technology for CO2 utilization using the chemical looping principle.The CLDR process consists of three stages,i.e.CH4 reduction,CO2 reforming,and air oxidation.Spinel nickel ferrite(NiFe2O4) was prepared and its multi-cycle performance as an oxygen carrier for CLDR was experimentally investigated.X-ray diffraction(XRD) and Laser Raman spectroscopy showed that a pure spinel crystalline phase(NiFe2O4) was obtained by a parallel flow co-precipitating method.NiFe2O4was reduced into Fe-Ni alloy and wustite(FexO) during the CH4 reduction process.Subsequent oxidation of the reduced oxygen carrier was performed with CO2 as an oxidant to form an intermediate state:a mixture of spinel Ni(1-x)Fe(2+x)O4,Fe(2+y)O4 and metallic Ni.And CO was generated in parallel during this stage.Approximate 185 mL of CO was generated for 1 g spinel NiFe2O4 in a single cycle.The intermediate oxygen carrier was fully oxidized in the air oxidation stage to form a mixture of Ni(1+x)Fe(2-x)O4 and Fe2O3.Although the original state of oxygen carrier(NiFe2O4) was not fully regenerated and agglomeration was observed,a good recyclability was shown in 10 successive redox cycles. 展开更多
关键词 Chemical looping Oxygen carrier Nickel ferrite CO2 utilization Multi-cycle performance
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A novel high precision Doppler frequency estimation method based on the third-order phase-locked loop 被引量:1
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作者 Tao Deng Mao-Li Ma +1 位作者 Qing-Hui Liu Ya-Jun Wu 《Research in Astronomy and Astrophysics》 SCIE CAS CSCD 2021年第9期83-90,共8页
In deep space exploration,many engineering and scientific requirements require the accuracy of the measured Doppler frequency to be as high as possible.In our paper,we analyze the possible frequency measurement points... In deep space exploration,many engineering and scientific requirements require the accuracy of the measured Doppler frequency to be as high as possible.In our paper,we analyze the possible frequency measurement points of the third-order phase-locked loop(PLL)and find a new Doppler measurement strategy.Based on this finding,a Doppler frequency measurement algorithm with significantly higher measurement accuracy is obtained.In the actual data processing,compared with the existing engineering software,the accuracy of frequency of 1 second integration is about 5.5 times higher when using the new algorithm.The improved algorithm is simple and easy to implement.This improvement can be easily combined with other improvement methods of PLL,so that the performance of PLL can be further improved. 展开更多
关键词 Doppler frequency measurement:deep space exploration:carrier tracking:phase locked loop:high precision
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Approach to blind estimation of the PN sequence in DS-SS signals with residual carrier 被引量:8
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作者 Tianqi Zhang Shaosheng Dai +2 位作者 Guoning Ma Wei Zhang Pu Miao 《Journal of Systems Engineering and Electronics》 SCIE EI CSCD 2010年第1期1-8,共8页
This paper presents an approach of singular value de- composition plus digital phase lock loop to solve the difficult problem of blind pseudo-noise (PN) sequence estimation in low signal to noise ratios (SNR) dire... This paper presents an approach of singular value de- composition plus digital phase lock loop to solve the difficult problem of blind pseudo-noise (PN) sequence estimation in low signal to noise ratios (SNR) direct sequence spread spectrum (DS-SS) signals with residual carrier. This approach needs some given parameters, such as the period and code rate of PN sequence. The received signal is firstly sampled and divided into non-overlapping signal vectors according to a temporal window, whose duration is two periods of PN sequence. An autocorrelation matrix is then computed and accumulated by those signal vectors one by one. The PN sequence with residual carrier can be estimated by the principal eigenvector of the autocorrelation matrix. Further more, a digital phase lock loop is used to process the estimated PN sequence, it estimates and tracks the residual carrier and removes the residual carrier in the end. Theory analysis and computer simulation results show that this approach can effectively realize the PN sequence blind estimation from the input DS-SS signals with residual carrier in lower SNR. 展开更多
关键词 direct sequence spread spectrum (DS-SS) signal pseudo-noise (PN) sequence blind estimation singular value de-composition digital phase lock loop residual carrier.
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Research on Carrier Synchronization of QPSK Based on Simulink 被引量:1
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作者 Zhaoxu Zhang Zhigang Li Zheng Dou 《International Journal of Communications, Network and System Sciences》 2017年第8期227-235,共9页
As an important part of the communication system, synchronization technology is a communication system to run the correct protection, has been a hot topic in communication systems research. Four-phase phase shift keyi... As an important part of the communication system, synchronization technology is a communication system to run the correct protection, has been a hot topic in communication systems research. Four-phase phase shift keying (QPSK) circuit structure is relatively simple, and has a good band utilization, in the modern communication has a wide range of applications. Corresponding research on carrier synchronization for QPSK coherent demodulation is carried out. By comparing several carrier recovery loops, The quaternary loose tail loop is selected as carrier recovery loop. First of all, the core part of the digital phase-locked loop analysis and implementation, and finally through the tool Simulink to complete the realization of the system. 展开更多
关键词 carrier Synchronization QUATERNARY LOOSE TAIL loop SIMULINK Digital Communication
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A novel Doppler frequency measurement method based on the closed-loop signal correlation for deep space exploration
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作者 Tao Deng Mao-Li Ma +3 位作者 Qing-Bao He Qing-Hui Liu Ya-Jun Wu Xin Zheng 《Research in Astronomy and Astrophysics》 SCIE CAS CSCD 2021年第9期75-82,共8页
In deep space exploration,it is necessary to improve the accuracy of frequency measurement to meet the requirements of precise orbit determination and various scientific studies.A phase detector is one of the key modu... In deep space exploration,it is necessary to improve the accuracy of frequency measurement to meet the requirements of precise orbit determination and various scientific studies.A phase detector is one of the key modules that restricts the tracking performance of phase-locked loop(PLL).Based on the phase relationship between adjacent signals in the time domain,a novel phase detector is presented to replace the arctangent phase detector.The new PLL,which is a closed loop signal correlation algorithm,shows good performance in tracking signals with high precision and the tracking accuracy of frequency of1 second integration is close to Cramer-Rao lower bound(CRLB)when setting proper parameters.Actual data processing results further illustrate the excellent performance of the novel PLL. 展开更多
关键词 Doppler measurement:Cramer-Rao lower bound carrier tracking:phase locked loop signal correlation
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准东煤分步和直接化学链燃烧特性
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作者 亚力昆江·吐尔逊 高志伟 +5 位作者 代正华 钟梅 靳立军 李建 刘洋 魏博 《洁净煤技术》 CAS CSCD 北大核心 2024年第6期16-26,共11页
化学链燃烧作为高效的低碳排放燃烧技术,在提高燃料利用率和减少CO_(2)排放方面显示出其独特优势。采用Fe_(2)O_(3)/Al_(2)O_(3)载氧体,利用两段式固定床反应器开展了准东煤直接和分步化学链燃烧试验,探究了载氧体反应前后理化特性。发... 化学链燃烧作为高效的低碳排放燃烧技术,在提高燃料利用率和减少CO_(2)排放方面显示出其独特优势。采用Fe_(2)O_(3)/Al_(2)O_(3)载氧体,利用两段式固定床反应器开展了准东煤直接和分步化学链燃烧试验,探究了载氧体反应前后理化特性。发现准东煤热解挥发分化学链燃烧碳转化率和CO_(2)选择性随温度和载氧体与煤质量比(OC/C)增加而升高。OC/C和温度升高提高半焦化学链燃烧碳转化率,但降低CO_(2)选择性。相比煤直接化学链燃烧,在相同条件,分步化学链燃烧CO_(2)选择性大幅提高、碳转化率有所降低。反应温度800℃,分步化学链燃烧CO_(2)选择性达89.51%,相比直接化学链燃烧提升了29.18%。反应温度950℃,分步化学链燃烧碳转化率在60.40%,比直接化学链燃烧降低6.78%。与半焦反应后载氧体还原程度高于与煤热解挥发分反应后载氧体,半焦与载氧体的反应是煤化学链燃烧的限制因素之一。本研究为实现准东煤低碳清洁燃烧提供重要理论依据和技术支撑。 展开更多
关键词 化学链燃烧 载氧体 煤热解挥发分 半焦 CO_(2)选择性
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中国化学链燃烧技术研发进展与展望
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作者 李振山 李维成 +5 位作者 刘海洋 段琦玮 王洋 李嘉晔 杨永嘉 蔡宁生 《中国电机工程学报》 EI CSCD 北大核心 2024年第18期7200-7220,I0010,共22页
化学链燃烧通过载氧体将空气中的氧传递给燃料、避免了高耗能的空分制氧,能够在较低能耗下实现CO_(2)的源头捕集,是最具潜力的固体燃料大规模碳减排技术之一。该文对中国化学链燃烧的研发进展进行系统的综述,介绍化学链燃烧技术在中国... 化学链燃烧通过载氧体将空气中的氧传递给燃料、避免了高耗能的空分制氧,能够在较低能耗下实现CO_(2)的源头捕集,是最具潜力的固体燃料大规模碳减排技术之一。该文对中国化学链燃烧的研发进展进行系统的综述,介绍化学链燃烧技术在中国的中试进展、工程示范部署及技术路线图,综述化学链燃烧在中国的基础研究现状,包括载氧体制备、载氧体氧化/还原反应动力学及模型、载氧体测试方法、双流化床等;并简要讨论化学链燃烧技术未来的发展趋势。 展开更多
关键词 碳捕集 化学链燃烧 载氧体 流化床 进展
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一种带自反馈的搬运车液压控制装置设计
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作者 郭婷 《工业仪表与自动化装置》 2024年第6期9-12,74,共5页
针对普通液压搬运车人工操作时受力无法控制且不能适应任意高度的问题,该文在传统液压搬运车的基础上进行了改造,设计加装了一套以信息采集、传输、处理、分析和反馈为闭环的自动控制装置。通过传感器收集载荷和位置等数据信息,再利用PI... 针对普通液压搬运车人工操作时受力无法控制且不能适应任意高度的问题,该文在传统液压搬运车的基础上进行了改造,设计加装了一套以信息采集、传输、处理、分析和反馈为闭环的自动控制装置。通过传感器收集载荷和位置等数据信息,再利用PID数字处理算法对信息加以分析,确认相关参数,从而实现了搬运车在自动控制下的平稳运行。同时,还根据载荷和高度位置的不同进行自适应调节反馈,使其在最短的时间内稳定地达到设计效果。实验测试分析结果表明,加装所提自动控制装置的搬运车相比于传统的人工操作方法,节省时间约40%,且该设计能够适用于多种复杂的搬运场景,具有良好的工程普适性。 展开更多
关键词 液压搬运车 闭环系统 自动控制系统 数字处理算法
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Switchable PLL Frequency Synthesizer andHot Carrier Effects
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作者 Yang Liu Ashok Srivastava Yao Xu 《Circuits and Systems》 2011年第1期45-52,共8页
In this paper, a new strategy of switchable CMOS phase-locked loop frequency synthesizer is proposed to increase its tuning range. The switchable PLL which integrates two phase-locked loops with different tuning frequ... In this paper, a new strategy of switchable CMOS phase-locked loop frequency synthesizer is proposed to increase its tuning range. The switchable PLL which integrates two phase-locked loops with different tuning frequencies are designed and fabricated in 0.5 μm n-well CMOS process. Cadence/Spectre simulations show that the frequency range of the switchable phased-locked loop is between 320 MHz to 1.15 GHz. The experimental results show that the RMS jitter of the phase-locked loop changes from 26 ps to 123 ps as output frequency varies. For 700 MHz carrier frequency, the phase noise of the phase-locked loop reaches as low as ?81 dBc/Hz at 10 kHz offset frequency and ?104 dBc/Hz at 1 MHz offset frequency. A device degradation model due to hot carrier effects has been used to analyze the jitter and phase noise performance in an open loop voltage-controlled oscillator. The oscillation frequency of the voltage-controlled oscillator decreases by approximately 100 to 200 MHz versus the bias voltage and the RMS jitter increases by 40 ps under different phase-locked loop output frequencies after 4 hours of stress time. 展开更多
关键词 CMOS Phase-Locked loop Voltage-Controlled OSCILLATOR HOT carrier Effects JITTER Phase Noise
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准东煤半焦赤铁矿载氧体化学链燃烧及碱(土)金属迁移特性 被引量:1
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作者 刘银河 王儒儒 +3 位作者 关昱 林啸龙 王博 王园园 《煤炭学报》 EI CAS CSCD 北大核心 2024年第2期1148-1160,共13页
准东煤在常规燃烧利用过程中出现严重的积灰结渣和CO_(2)排放等问题,极大地限制了其低碳清洁高效利用。采用中低温热解低阶煤生产半焦、焦油和热解气是煤炭分质分级利用的龙头技术,准东高碱煤热解半焦气化活性高,采用化学链燃烧方式有... 准东煤在常规燃烧利用过程中出现严重的积灰结渣和CO_(2)排放等问题,极大地限制了其低碳清洁高效利用。采用中低温热解低阶煤生产半焦、焦油和热解气是煤炭分质分级利用的龙头技术,准东高碱煤热解半焦气化活性高,采用化学链燃烧方式有利于实现其低碳清洁高效转化。以CO_(2)为气化介质,赤铁矿石为载氧体,在固定床上开展准东煤半焦原位气化化学链燃烧特性研究,并探究了准东煤半焦中碱(土)金属(AAEMs)的迁移转化规律。研究表明,赤铁矿载氧体能够显著提高固定床反应器出口烟气中CO_(2)体积分数,然而随着载氧体与半焦质量比(mOC/mC)不断增加,CO_(2)体积分数先急剧增加而后趋于不变,最佳的mOC/mC为50:1,而700℃热解制取的准东煤半焦经酸洗脱灰处理后固定床反应器出口相应烟气中CO_(2)的选择性降低了8.95%,这表明准东煤半焦中具有催化活性的AAEMs显著影响其化学链燃烧性能。赤铁矿载氧体对准东煤半焦表面AAEMs的分布也有显著影响,与未加入时相比,Na、K元素在半焦表面呈现较为明显的团簇富集,Ca、Mg元素在空间分布上呈更为明显的依赖关系。采用原位气化化学链燃烧方式后准东煤半焦中的AAEMs向赤铁矿载氧体中发生迁移与转化,并生成霞石(NaAlSiO_(4))、钾长石(KAlSi_(3)O_(8))、钙铝黄长石(Ca_(2)Al_(2)SiO_(7))、镁橄榄石(Mg_(2)SiO_(4))等高熔点矿物质,有效抑制了准东煤半焦中AAEMs向气相的挥发。 展开更多
关键词 准东煤半焦 赤铁矿载氧体 碱(土)金属 化学链燃烧 分质分级利用
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钾修饰铁锆氧载体制备及煤化学链燃烧中钾元素赋存形态探究
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作者 魏国兴 刘涛 +1 位作者 宋方林 焦发存 《应用化工》 CAS CSCD 北大核心 2024年第10期2338-2344,共7页
考察了制备条件对载氧体性能的影响,并通过HSC Chemistry考察了温度与还原度(R_(ox))对钾元素赋存形态的影响。结果表明,最佳制备条件为:ZrO_(2)的添加量为30%,K_(2)CO_(3)的添加量为5%,载氧体的煅烧温度为800℃。煤过量或较高时钾元素... 考察了制备条件对载氧体性能的影响,并通过HSC Chemistry考察了温度与还原度(R_(ox))对钾元素赋存形态的影响。结果表明,最佳制备条件为:ZrO_(2)的添加量为30%,K_(2)CO_(3)的添加量为5%,载氧体的煅烧温度为800℃。煤过量或较高时钾元素的赋存形态主要为气态钾单质K(g)。而在系统中载氧体含量足量或过量时,在高温时钾元素的主要赋存形态转变为了KFeO_(2)。并且只有在反应温度较低且载氧体还原程度较深时,钾元素才能保持以K_(2)CO_(3)的原形式存在。 展开更多
关键词 载氧体 化学链燃烧 HSC Chemistry模拟 钾赋存形态
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基于锁频环辅助锁相环的载波跟踪方法研究 被引量:1
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作者 王宇琦 张佩华 《现代导航》 2024年第2期97-101,共5页
载波跟踪的目的是尽力使复制的载波信号与接收到的信号保持一致,从而能够很好地剥离卫星信号中的载波。因此,载波跟踪环路的跟踪精度很大程度决定了最后的定位测量精度。考虑到卫星等载体的高动态性带来的多普勒频移,跟踪环路需要同时... 载波跟踪的目的是尽力使复制的载波信号与接收到的信号保持一致,从而能够很好地剥离卫星信号中的载波。因此,载波跟踪环路的跟踪精度很大程度决定了最后的定位测量精度。考虑到卫星等载体的高动态性带来的多普勒频移,跟踪环路需要同时具有较好跟踪精度和动态性能。因此,环路需要同时利用锁频环对信号具有较好的动态适应性和锁相环对信号具有较好的跟踪精度的特点。首先分析了锁频环和锁相环的原理,基于此采用了基于阈值调整的二阶锁频环辅助三阶锁相环的方法,最后利用Matlab对该算法进行仿真。结果表明跟踪环路能够较快地对信号进行跟踪的同时也具有较好的跟踪精度。 展开更多
关键词 载波环路 锁相环 锁频环
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化学链重整过程中LaFeO_(3)载氧体的CH_(4)部分氧化反应机理研究 被引量:1
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作者 王娜娜 冯于川 +1 位作者 郭欣 马素霞 《燃料化学学报(中英文)》 EI CAS CSCD 北大核心 2024年第4期586-594,共9页
本研究基于密度泛函理论(DFT)计算揭示了化学链重整过程中LaFeO_(3)载氧体的CH_(4)部分氧化反应机理,通过系统研究CH_(4)吸附活化、H_(2)和CO形成以及氧扩散等基元反应步骤,构建了CH_(4)部分氧化反应网络。研究发现,CH_(4)发生逐步脱氢... 本研究基于密度泛函理论(DFT)计算揭示了化学链重整过程中LaFeO_(3)载氧体的CH_(4)部分氧化反应机理,通过系统研究CH_(4)吸附活化、H_(2)和CO形成以及氧扩散等基元反应步骤,构建了CH_(4)部分氧化反应网络。研究发现,CH_(4)发生逐步脱氢反应形成H原子,其中,CH3脱氢反应所需要克服的能垒(1.50 eV)最高,是CH_(4)逐步脱氢反应的限速步骤。载氧体表面H_(2)形成有两种路径,其中,H原子从O顶位迁移到Fe顶位,然后与另外O顶位的H原子成键形成H_(2)分子是主要途径。由于其相对较低的能垒(1.27 eV),CO的形成过程较易发生。氧扩散需要克服1.35 eV的能垒,表明氧扩散过程需要在高温下进行且扩散速率较低。通过比较各基元反应能垒,发现H_(2)形成是LaFeO_(3)载氧体CH_(4)部分氧化反应动力学的限速步骤,而H迁移是限制H_(2)形成的关键,加快H迁移是增强LaFeO_(3)载氧体性能的主要途径。基于DFT计算研究系列A/B位点掺杂LaFeO_(3)载氧体的H迁移过程,有望实现潜在A/B位点有效掺杂剂的快速筛选,指导高性能LaFeO_(3)载氧体的设计开发。 展开更多
关键词 化学链重整 LaFeO_(3)载氧体 CH_(4)部分氧化 反应机理 密度泛函理论
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