The defects from electron transport layer,perovskite layer and their interface would result in carrier nonradiative recombination losses.Poor buried interfacial contact is detrimental to charge extraction and device s...The defects from electron transport layer,perovskite layer and their interface would result in carrier nonradiative recombination losses.Poor buried interfacial contact is detrimental to charge extraction and device stability.Here,we report a bottom-up holistic carrier management strategy induced synergistically by multiple chemical bonds to minimize bulk and interfacial energy losses for high-performance perovskite photovoltaics.4-trifluoromethyl-benzamidine hydrochloride(TBHCl)containing–CF_(3),amidine cation and Cl^(-)is in advance incorporated into SnO_(2)colloid solution to realize bottom-up modification.The synergistic effect of multiple functional groups and multiple-bond-induced chemical interaction are revealed theoretically and experimentally.F and Cl^(-)can passivate oxygen vacancy and/or undercoordinated Sn^(4+)defects by coordinating with Sn^(4+).The F can suppress cation migration and modulate crystallization via hydrogen bond with FA^(+),and can passivate lead defects by coordinating with Pb^(2+).The–NH_(2)–C=NH^(+)_(2)and Cl^(-)can passivate cation and anion vacancy defects through ionic bonds with perovskites,respectively.Through TBHCl modification,the suppression of agglomeration of SnO_(2)nanoparticles,bulk and interfacial defect passivation,and release of tensile strains of perovskite films are demonstrated,which resulted in a PCE enhancement from 21.28%to 23.40%and improved stability.With post-treatment,the efficiency is further improved to 23.63%.展开更多
EAST (experimental advanced superconducting tokamak) fast control power supply is a high-capacity single-phase AC/DC/AC inverter power supply, which traces the displacement signal of plasma, and excites coils in a v...EAST (experimental advanced superconducting tokamak) fast control power supply is a high-capacity single-phase AC/DC/AC inverter power supply, which traces the displacement signal of plasma, and excites coils in a vacuum vessel to produce a magnetic field that realizes plasma stabilization. To meet the requirements of a large current and fast response, the multi- ple structure of the carrier phase-shift three-level inverter is presented, which realizes parallelled multi-inverters, raises the equivalent switching frequency of the inverters and improves the per- formance of output waves. In this work the design scheme is analyzed, and the output harmonic characteristic of parallel inverters is studied. The simulation and experimental results confirm that the scheme and control strategy is valid. The power supply system can supply a large current, and has a perfect performance on harmonic features as well as the ability of a fast response.展开更多
An efficient trust-aware secure routing and network strategy-based data collection scheme is presented in this paper to enhance the performance and security of wireless sensor networks during data collection.The metho...An efficient trust-aware secure routing and network strategy-based data collection scheme is presented in this paper to enhance the performance and security of wireless sensor networks during data collection.The method first discovers the routes between the data sensors and the sink node.Several factors are considered for each sensor node along the route,including energy,number of neighbours,previous transmissions,and energy depletion ratio.Considering all these variables,the Sink Reachable Support Measure and the Secure Communication Support Measure,the method evaluates two distinct measures.The method calculates the data carrier support value using these two metrics.A single route is chosen to collect data based on the value of data carrier support.It has contributed to the design of Secure Communication Support(SCS)Estimation.This has been measured according to the strategy of each hop of the route.The suggested method improves the security and efficacy of data collection in wireless sensor networks.The second stage uses the two-fish approach to build a trust model for secure data transfer.A sim-ulation exercise was conducted to evaluate the effectiveness of the suggested framework.Metrics,including PDR,end-to-end latency,and average residual energy,were assessed for the proposed model.The efficiency of the suggested route design serves as evidence for the average residual energy for the proposed framework.展开更多
The full-bridge converters usually use transformer leakage inductance and parallel resonant capacitors to achieve smooth current commutation and soft switching functions,which can easily cause problems such as energy ...The full-bridge converters usually use transformer leakage inductance and parallel resonant capacitors to achieve smooth current commutation and soft switching functions,which can easily cause problems such as energy leakage and significant duty cycle loss.This paper designs a novel full-bridge zero-current(FB-ZCS)converter with series resonant capacitors and proposes a frequency and phase-shift synthesis modulation(FPSSM)control strategy based on this topology.Compared with the traditional parallel resonant capacitor circuit,the passive components used are significantly reduced,the structure is simple,and there is only a slight energy loss.By controlling the charging time of the capacitor,it can be achieved without additional switches or auxiliary circuits.The automatic control of capacitor energy based on input current addresses the low efficiency of the traditional control strategies.This paper introduces its principle in detail and verifies it through simulation.Finally,an experimental prototype was built further to demonstrate the feasibility of the theory through experiments.The module can be applied to a photovoltaic DC collection system using input parallel output series(IPOS)cascade to provide a new topology for large-scale,long-distance DC transmission.展开更多
Carrier Ethernet(CE) is gradually stepping away from standardization and testing to deployment and application in live networks.Although great improvement has been made in the reliability of various CE technologies,th...Carrier Ethernet(CE) is gradually stepping away from standardization and testing to deployment and application in live networks.Although great improvement has been made in the reliability of various CE technologies,there is need for improvement in their Quality of Service(QoS),Operation,Administration and Maintenance(OAM),especially the multi-vendor interoperability.The deployment of CE should be service-oriented,and the factors,such as maturity of related technologies and standards,deployment costs,and the complexity of network reconstruction as well as the interoperability with other vendors,should be taken into full consideration to flexibly select appropriate networking technology for different application scenarios according to technical features.展开更多
The carrier synchronization algorithm of the autonomous radio for deep space is studied.When the signal modulation is unknown,this paper improves the existing universal carrier synchronization loop for multiple modula...The carrier synchronization algorithm of the autonomous radio for deep space is studied.When the signal modulation is unknown,this paper improves the existing universal carrier synchronization loop for multiple modulations,expands the frequency tracking range of the loop,proposes a Tong detection-based M-ary Phase Shift Keying(M-PSK)signal locking detection algorithm to rapidly and effectively determine whether the current phase discrimination mode matches the modulation mode,so as to independently choose whether to switch the phase discrimination mode.Through theoretical analysis and comparison,it is described that the total detection probability of the algorithm proposed in this paper is significantly higher than the probability of single lock detection.Simulation results show that the algorithm has high detection probabiUty and low computational complexity at a low signal to noise ratio.展开更多
Three dispersion compensation schemes of an optical label switching transmission system were investigated, which employs 40 Gbit/s return zero differential phase-shift keying(RZ-DPSK) payload labeled with 2.5 Gbit/s...Three dispersion compensation schemes of an optical label switching transmission system were investigated, which employs 40 Gbit/s return zero differential phase-shift keying(RZ-DPSK) payload labeled with 2.5 Gbit/s on-off keying(OOK) signal based on the optical carrier suppression and separation(OCSS) techniq ue, In the system, proposed are the receiver sensi ti vity oS payload and label, achieving -- 32. 4 dBm and --38.5 dBm, respectively. Using the optimal dispersion compensation scheme, after transmitted over 160 km and 320 km SMF respectively, the label can be recovered without power penalty, while the payload can be recovered with less than 2 dB and 5 dB penalty, respectively.展开更多
背景:医用水凝胶是具有三维结构网络的新型功能高分子材料,具有出色的生物相容性,目前已在组织工程领域、药物载体领域有广泛研究,但基于组织工程探究医用水凝胶与中医药结合治疗疾病的研究还处于初期探索阶段。因此,通过对医用水凝胶...背景:医用水凝胶是具有三维结构网络的新型功能高分子材料,具有出色的生物相容性,目前已在组织工程领域、药物载体领域有广泛研究,但基于组织工程探究医用水凝胶与中医药结合治疗疾病的研究还处于初期探索阶段。因此,通过对医用水凝胶机制作用的剖析,整合医用水凝胶与中医药在研究中联合应用的文章,进而更好地为科研工作者提供思路,对中医药与医用水凝胶联合应用具有重要意义。目的:基于组织工程研究探讨中医药联合医用水凝胶治疗疾病的策略及意义。方法:利用PubMed和中国知网数据库,检索有关中医药联合医用水凝胶在组织工程中应用的文献,检索时间为2010年1月至2022年11月,英文检索词为“hydrogel,traditional Chinese medicine,drug carrier,tissue engineering”,中文检索词为“医用水凝胶、中医药、药物载体、组织工程”。根据纳入与排除标准对所有文章进行初筛后,最终纳入61篇文章进行综述。结果与结论:①中医药联合医用水凝胶的应用虽然在关节内、组织器官内、软组织伤口和组织工程等方面有所涉及,但除了中医药结合水凝胶敷料在临床应用治疗软组织损伤外,其他方面尚处于基础实验阶段。②中医药联合医用水凝胶的发展有着巨大潜力和发展前景,但对于性能要求较高的凝胶在制造方面存在一定难度,理化性质精确掌握难度较大。③目前综合来看可注射水凝胶凭借着简便易用的特点,其在与中医药联合使用可延伸范围较广,可用于关节、器官和组织工程相关疾病的治疗;智能水凝胶有较高的灵敏度和可逆转化性也可满足特殊环境下的使用;将两者结合的中医药使用过程中还需要明确中药成分的作用机制。④中医药联合医用水凝胶治疗疾病的策略应着手于中医药对器官、组织、细胞的治疗作用联合适当种类的医用水凝胶进行匹配,可弥补传统中医给药方式和频繁给药的不足,在组织工程方面可以用水凝胶负载中药干预后的干细胞,或者同时负载中药和干细胞用于相关疾病的治疗。⑤在中医药联合医用水凝胶应用的未来研究中,还需要考虑:应当确保医用水凝胶生物性能可以量化,以不同材料不同制造工艺把握水凝胶特性,制造出所需要的符合应用条件的医用水凝胶;在中医药方面需要对已知中药单体、中药复方提取物的治疗效果和应用机制全面了解剖析,在更明了的机制下实现中医药与医用水凝胶更多更完美的结合;借助医学科技创新能力的不断提高,医用水凝胶可以创新性地结合中医药其他传统治疗方法比如针灸、推拿和拔罐等方式进行多角度运用。展开更多
基金financially supported by the Support Plan for Overseas Students to Return to China for Entrepreneurship and Innovation(cx2020003)the Fundamental Research Funds for the Central Universities(2020CDJ-LHZZ-074)the Natural Science Foundation of Chongqing(cstc2020jcyj-msxm X0629)。
文摘The defects from electron transport layer,perovskite layer and their interface would result in carrier nonradiative recombination losses.Poor buried interfacial contact is detrimental to charge extraction and device stability.Here,we report a bottom-up holistic carrier management strategy induced synergistically by multiple chemical bonds to minimize bulk and interfacial energy losses for high-performance perovskite photovoltaics.4-trifluoromethyl-benzamidine hydrochloride(TBHCl)containing–CF_(3),amidine cation and Cl^(-)is in advance incorporated into SnO_(2)colloid solution to realize bottom-up modification.The synergistic effect of multiple functional groups and multiple-bond-induced chemical interaction are revealed theoretically and experimentally.F and Cl^(-)can passivate oxygen vacancy and/or undercoordinated Sn^(4+)defects by coordinating with Sn^(4+).The F can suppress cation migration and modulate crystallization via hydrogen bond with FA^(+),and can passivate lead defects by coordinating with Pb^(2+).The–NH_(2)–C=NH^(+)_(2)and Cl^(-)can passivate cation and anion vacancy defects through ionic bonds with perovskites,respectively.Through TBHCl modification,the suppression of agglomeration of SnO_(2)nanoparticles,bulk and interfacial defect passivation,and release of tensile strains of perovskite films are demonstrated,which resulted in a PCE enhancement from 21.28%to 23.40%and improved stability.With post-treatment,the efficiency is further improved to 23.63%.
基金supported by Key Project of National Ninth Five-Year Research Program of China[(1998)1303]
文摘EAST (experimental advanced superconducting tokamak) fast control power supply is a high-capacity single-phase AC/DC/AC inverter power supply, which traces the displacement signal of plasma, and excites coils in a vacuum vessel to produce a magnetic field that realizes plasma stabilization. To meet the requirements of a large current and fast response, the multi- ple structure of the carrier phase-shift three-level inverter is presented, which realizes parallelled multi-inverters, raises the equivalent switching frequency of the inverters and improves the per- formance of output waves. In this work the design scheme is analyzed, and the output harmonic characteristic of parallel inverters is studied. The simulation and experimental results confirm that the scheme and control strategy is valid. The power supply system can supply a large current, and has a perfect performance on harmonic features as well as the ability of a fast response.
文摘An efficient trust-aware secure routing and network strategy-based data collection scheme is presented in this paper to enhance the performance and security of wireless sensor networks during data collection.The method first discovers the routes between the data sensors and the sink node.Several factors are considered for each sensor node along the route,including energy,number of neighbours,previous transmissions,and energy depletion ratio.Considering all these variables,the Sink Reachable Support Measure and the Secure Communication Support Measure,the method evaluates two distinct measures.The method calculates the data carrier support value using these two metrics.A single route is chosen to collect data based on the value of data carrier support.It has contributed to the design of Secure Communication Support(SCS)Estimation.This has been measured according to the strategy of each hop of the route.The suggested method improves the security and efficacy of data collection in wireless sensor networks.The second stage uses the two-fish approach to build a trust model for secure data transfer.A sim-ulation exercise was conducted to evaluate the effectiveness of the suggested framework.Metrics,including PDR,end-to-end latency,and average residual energy,were assessed for the proposed model.The efficiency of the suggested route design serves as evidence for the average residual energy for the proposed framework.
基金This work was supported by the Key R&D Program of Tianjin(No.20YFYSGX00060).
文摘The full-bridge converters usually use transformer leakage inductance and parallel resonant capacitors to achieve smooth current commutation and soft switching functions,which can easily cause problems such as energy leakage and significant duty cycle loss.This paper designs a novel full-bridge zero-current(FB-ZCS)converter with series resonant capacitors and proposes a frequency and phase-shift synthesis modulation(FPSSM)control strategy based on this topology.Compared with the traditional parallel resonant capacitor circuit,the passive components used are significantly reduced,the structure is simple,and there is only a slight energy loss.By controlling the charging time of the capacitor,it can be achieved without additional switches or auxiliary circuits.The automatic control of capacitor energy based on input current addresses the low efficiency of the traditional control strategies.This paper introduces its principle in detail and verifies it through simulation.Finally,an experimental prototype was built further to demonstrate the feasibility of the theory through experiments.The module can be applied to a photovoltaic DC collection system using input parallel output series(IPOS)cascade to provide a new topology for large-scale,long-distance DC transmission.
文摘Carrier Ethernet(CE) is gradually stepping away from standardization and testing to deployment and application in live networks.Although great improvement has been made in the reliability of various CE technologies,there is need for improvement in their Quality of Service(QoS),Operation,Administration and Maintenance(OAM),especially the multi-vendor interoperability.The deployment of CE should be service-oriented,and the factors,such as maturity of related technologies and standards,deployment costs,and the complexity of network reconstruction as well as the interoperability with other vendors,should be taken into full consideration to flexibly select appropriate networking technology for different application scenarios according to technical features.
基金Supported by Program for New Century Excellent Talents in University(NCET-12-0030)National Natural Science Foundation of China(91438116)
文摘The carrier synchronization algorithm of the autonomous radio for deep space is studied.When the signal modulation is unknown,this paper improves the existing universal carrier synchronization loop for multiple modulations,expands the frequency tracking range of the loop,proposes a Tong detection-based M-ary Phase Shift Keying(M-PSK)signal locking detection algorithm to rapidly and effectively determine whether the current phase discrimination mode matches the modulation mode,so as to independently choose whether to switch the phase discrimination mode.Through theoretical analysis and comparison,it is described that the total detection probability of the algorithm proposed in this paper is significantly higher than the probability of single lock detection.Simulation results show that the algorithm has high detection probabiUty and low computational complexity at a low signal to noise ratio.
基金National Natural Science Foundation of China(60677004)National High Technology"863"Research and Development Program of China(2007AA01Z260)+4 种基金Key Project of Chinese Ministry of Education(107011)Key Laboratory of Broadband Optical Fiber Transmission and Communication Networks(Ministry of Education)Teaching and Scientific Research Foundation for the Returned Overseas Chinese Scholars(State Education Ministry)the Corporative Building Project of Beijing Educational Committee(XK100130737)Program for New Century Excellent Talents in University of China( NECT-07-0111)
文摘Three dispersion compensation schemes of an optical label switching transmission system were investigated, which employs 40 Gbit/s return zero differential phase-shift keying(RZ-DPSK) payload labeled with 2.5 Gbit/s on-off keying(OOK) signal based on the optical carrier suppression and separation(OCSS) techniq ue, In the system, proposed are the receiver sensi ti vity oS payload and label, achieving -- 32. 4 dBm and --38.5 dBm, respectively. Using the optimal dispersion compensation scheme, after transmitted over 160 km and 320 km SMF respectively, the label can be recovered without power penalty, while the payload can be recovered with less than 2 dB and 5 dB penalty, respectively.
文摘背景:医用水凝胶是具有三维结构网络的新型功能高分子材料,具有出色的生物相容性,目前已在组织工程领域、药物载体领域有广泛研究,但基于组织工程探究医用水凝胶与中医药结合治疗疾病的研究还处于初期探索阶段。因此,通过对医用水凝胶机制作用的剖析,整合医用水凝胶与中医药在研究中联合应用的文章,进而更好地为科研工作者提供思路,对中医药与医用水凝胶联合应用具有重要意义。目的:基于组织工程研究探讨中医药联合医用水凝胶治疗疾病的策略及意义。方法:利用PubMed和中国知网数据库,检索有关中医药联合医用水凝胶在组织工程中应用的文献,检索时间为2010年1月至2022年11月,英文检索词为“hydrogel,traditional Chinese medicine,drug carrier,tissue engineering”,中文检索词为“医用水凝胶、中医药、药物载体、组织工程”。根据纳入与排除标准对所有文章进行初筛后,最终纳入61篇文章进行综述。结果与结论:①中医药联合医用水凝胶的应用虽然在关节内、组织器官内、软组织伤口和组织工程等方面有所涉及,但除了中医药结合水凝胶敷料在临床应用治疗软组织损伤外,其他方面尚处于基础实验阶段。②中医药联合医用水凝胶的发展有着巨大潜力和发展前景,但对于性能要求较高的凝胶在制造方面存在一定难度,理化性质精确掌握难度较大。③目前综合来看可注射水凝胶凭借着简便易用的特点,其在与中医药联合使用可延伸范围较广,可用于关节、器官和组织工程相关疾病的治疗;智能水凝胶有较高的灵敏度和可逆转化性也可满足特殊环境下的使用;将两者结合的中医药使用过程中还需要明确中药成分的作用机制。④中医药联合医用水凝胶治疗疾病的策略应着手于中医药对器官、组织、细胞的治疗作用联合适当种类的医用水凝胶进行匹配,可弥补传统中医给药方式和频繁给药的不足,在组织工程方面可以用水凝胶负载中药干预后的干细胞,或者同时负载中药和干细胞用于相关疾病的治疗。⑤在中医药联合医用水凝胶应用的未来研究中,还需要考虑:应当确保医用水凝胶生物性能可以量化,以不同材料不同制造工艺把握水凝胶特性,制造出所需要的符合应用条件的医用水凝胶;在中医药方面需要对已知中药单体、中药复方提取物的治疗效果和应用机制全面了解剖析,在更明了的机制下实现中医药与医用水凝胶更多更完美的结合;借助医学科技创新能力的不断提高,医用水凝胶可以创新性地结合中医药其他传统治疗方法比如针灸、推拿和拔罐等方式进行多角度运用。