The important parameters that influence the mechanical property of the pavinglayer on an orthotropic steel bridge deck are the paving layer thickness and modulus of the asphaltconcrete surfacing. Three important indic...The important parameters that influence the mechanical property of the pavinglayer on an orthotropic steel bridge deck are the paving layer thickness and modulus of the asphaltconcrete surfacing. Three important indices that control the typical failures of the paving layerare the maximum tensile stress of paving layer, the maximum shear stress between the steel deck andthe paving layer, and the maximum deflection on the paving surface. In this paper, the analyticalmodel of paving systems on orthotropic steel bridge deck is established, and the finite elementmethod is adopted to study the stress and strain of paving system. With the variation of asphaltconcrete modulus in high or low temperature season, the influences of paving layer thickness onthree control indices are researched. The results provide a theoretical basis for the determinationof thickness of the paving layer on the steel bridge deck.展开更多
Effects of alloy elements on the microstructure and crack resistance of Fe-C-Cr weld surfacing layer were investigated. The results show that microstructures of the layer mainly consist of carbides and austenite matri...Effects of alloy elements on the microstructure and crack resistance of Fe-C-Cr weld surfacing layer were investigated. The results show that microstructures of the layer mainly consist of carbides and austenite matrix. Increasing C and Cr contents impair the crack resistance of the layer due to increased amount of brittle carbides. The addition of Ni, Nb or Mo improves the crack resistance of Fe-C-Cr weld surfacing layer by increasing the amount of austenite and forming fine NbC or M 7C 3 carbides in the layer. But, the excessive Nb (>2.50wt%) or Mo (>1.88wt%) impairs the crack resistance of the layer, which has relation with increased carbides or carbide coarsening and austenite matrix solid solution strengthening. The proper combination of C, Cr, Ni, Nb and Mo can further improve not only the crack resistance of Fe-C-Cr weld surfacing layer but also the erosion resistance as a result of fine NbC and M 7C 3 carbides distributing uniformly in austenite matrix. The optimal layer compositions are 3.05wt%C, 20.58wt%Cr, 1.75wt%Ni, 2.00wt%Nb and 1.88wt%Mo.展开更多
Effects of alloying elements on microstructure and erosion resistance of Fe-C-Cr weld surfacing layer have been studied. The experimental results show that increasing C and Cr content favors improving the erosion resi...Effects of alloying elements on microstructure and erosion resistance of Fe-C-Cr weld surfacing layer have been studied. The experimental results show that increasing C and Cr content favors improving the erosion resistance of the layer, and the excessive C and Cr result in decreasing the erosion resistance at 90 deg. erosion. That Mo, Nb or Ti improves the erosion resistance of Fe-C-Cr weld surfacing layer is mainly attributed to increasing the amount of M7C3 and forming fine NbC or TiC in austenite matrix, but the excessive Mo, Nb or Ti is unfavorable. The addition of Mo, Nb and Ti in proper combination possesses stronger effect on improving the erosion resistance and the erosion resistance (εA) of Fe-C-Cr weld surfacing layer with fine NbC, TiC and M7C3 distributing uniformly in austenite matrix obviously increases to 2.81 at 15 deg. erosion and 2.88 at 90 deg. erosion when the layer composition is 3.05C, 20.58Cr, 1.88Mo, 2.00Nb and 1.05Ti (in wt pct).展开更多
This study investigates the impact of the salinity barrier layer(BL)on the upper ocean response to Super Typhoon Mangkhut(2018)in the western North Pacific.After the passage of Mangkhut,a noticeable increase(~0.6 psu)...This study investigates the impact of the salinity barrier layer(BL)on the upper ocean response to Super Typhoon Mangkhut(2018)in the western North Pacific.After the passage of Mangkhut,a noticeable increase(~0.6 psu)in sea surface salinity and a weak decrease(<1℃)in sea surface temperature(SST)were observed on the right side of the typhoon track.Mangkhut-induced SST change can be divided into the three stages,corresponding to the variations in BL thickness and SST before,during,and after the passage of Mangkhut.During the pre-typhoon stage,SST slightly warmed due to the entrainment of BL warm water,which suppressed the cooling induced by surface heat fluxes and horizontal advection.During the forced stage,SST cooling was controlled by entrainment,and the preexisting BL reduced the total cooling by 0.89℃ d-1,thus significantly weakening the overall SST cooling induced by Mangkhut.During the relaxation stage,the SST cooling was primarily caused by the entrainment.Our results indicate that a preexisting BL can limit typhoon-induced SST cooling by suppressing the entrainment of cold thermocline water,which contributed to Mangkhut becoming the strongest typhoon in 2018.展开更多
In Na-ion batteries,O3-type layered oxide cathode materials encounter challenges such as particle cracking,oxygen loss,electrolyte side reactions,and multi-phase transitions during the charge/discharge process.This st...In Na-ion batteries,O3-type layered oxide cathode materials encounter challenges such as particle cracking,oxygen loss,electrolyte side reactions,and multi-phase transitions during the charge/discharge process.This study focuses on surface coating with NiTiO_(3) achieved via secondary heat treatment using a coating precursor and the surface material.Through in-situ x-ray diffraction(XRD)and differential electrochemical mass spectrometry(DEMS),along with crystal structure characterizations of post-cycling materials,it was determined that the NiTiO_(3) coating layer facilitates the formation of a stable lattice structure,effectively inhibiting lattice oxygen loss and reducing side reaction with the electrolyte.This enhancement in cycling stability was evidenced by a capacity retention of approximately 74%over 300 cycles at 1 C,marking a significant 30%improvement over the initial sample.Furthermore,notable advancements in rate performance were observed.Experimental results indicate that a stable and robust surface structure substantially enhances the overall stability of the bulk phase,presenting a novel approach for designing layered oxide cathodes with higher energy density.展开更多
The rapid development of electric vehicles and portable energy storage systems demands improvements in the energy density and cost-effectiveness of lithium-ion batteries,a domain in which Lithium-rich layered cathode(...The rapid development of electric vehicles and portable energy storage systems demands improvements in the energy density and cost-effectiveness of lithium-ion batteries,a domain in which Lithium-rich layered cathode(LLO)materials inherently excel.However,these materials face practical challenges,such as low initial Coulombic efficiency,inferior cycle/rate performance,and voltage decline during cycling,which limit practical application.Our study introduces a surface multi-component integration strategy that incorporates oxygen vacancies into the pristine LLO material Li1.2Mn_(0.6)Ni_(0.2)O_(2).This process involves a brief citric acid treatment followed by calcination,aiming to explore rate-dependent degradation behavior.The induced surface oxygen vacancies can reduce surface oxygen partial pressure and diminish the generation of O_(2)and other highly reactive oxygen species on the surface,thereby facilitating the activation of Li ions trapped in tetrahedral sites while overcoming transport barriers.Additionally,the formation of a spinel-like phase with 3D Li+diffusion channels significantly improves Li^(+)diffusion kinetics and stabilizes the surface structure.The optimally modified sample boasts a discharge capacity of 299.5 mA h g^(-1)at a 0.1 C and 251.6 mA h g^(-1)at a 1 C during the initial activation cycle,with an impressive capacity of 222.1 mA h g^(-1)at a 5 C.Most notably,it retained nearly 70%of its capacity after 300 cycles at this elevated rate.This straightforward,effective,and highly viable modification strategy provides a crucial resolution for overcoming challenges associated with LLO materials,making them more suitable for practical application.展开更多
Using plasma build-up welding technology, Ni60, WC, Cr3C2, and TiC composite powders were clad on the surface of the substrate in a certain proportion according to the metallurgical bonding method to increase the bond...Using plasma build-up welding technology, Ni60, WC, Cr3C2, and TiC composite powders were clad on the surface of the substrate in a certain proportion according to the metallurgical bonding method to increase the bond strength between the coating and the substrate. Scanning electron microscopy and energy dispersive spectroscopy were used to observe the microstructure of the surfacing layer and the chemical composition of the sample. The hardness and wear resistance of the surfacing layer were tested and analyzed by the HV-1000 hardness tester and the impact wear device. The results showed that in the microstructure, fishbone, spider-web, and floral-like structures appeared in the surfacing layer. When the micro-hardness was tested, the depth of the indentation reflected the hardness of the surfacing layer. When analyzing wear resistance, the amount of wear increases with time.展开更多
The characteristic of the bond zone between Ni-based alloy light beam surfacing layer(SL)and base metal(BM)was investigated by scanning electron microscope,energy dispersive spectrometer and X-ray diffraction.The resu...The characteristic of the bond zone between Ni-based alloy light beam surfacing layer(SL)and base metal(BM)was investigated by scanning electron microscope,energy dispersive spectrometer and X-ray diffraction.The results show that the bond zone,which consists ofγ-Ni orγ-(Fe,Ni)planar crystal band close to SL andα-Fe bright band close to heat affected zone(HAZ),is actually the transition zone of composition and microstructure between SL and HAZ,and the metallurgical bond interface lies between theα-Fe bright band and HAZ.With the increase of light beam heat input from 2kJ/mm to 4kJ/mm,the width of the bond zone increases from 4μm to 15μm,and the morphology of bond interface changes from zigzag to straight.The formation of bond interface indicates the formation of reliable metallurgical bond between SL and BM.展开更多
Investigation has been made on the causes of hot cracking in the surfacing layer of Ni_3Al basealloy by analysing the solidification process of fusion pool and the distribution of thermal stresses. The re-sults show t...Investigation has been made on the causes of hot cracking in the surfacing layer of Ni_3Al basealloy by analysing the solidification process of fusion pool and the distribution of thermal stresses. The re-sults show that the cracking is directly related to both the occurrence of eutectic phase β' (NiAI) within theinterdendritic region and high thernial stresses in the surfacing layer ,and which are caused by selecting highwelding rate. When the process of electric arc weld is changed from straight line rnovement to that along’Z’pattern,the cracking in the surfacing layer of Ni_3Al base alloy is prevented owing to being reduced of boththe cooling rate of liquid in the fusion liool and the speed of the moving heat source. Lowering the outputpower of the electric arc welding could lead to the reducing of rnelting volume of the base material ,and lowerthe arnount of iron atoms dissolving in the fusion pool ,so that the trend of the eutectic reaction within the in-terdendritic region is reduced,and which is helpful to suppress the cracking in the surfacing layer of Ni_3Albase alloy.展开更多
Investigation has been made into the causes of cracking in the Surfacing welding layer of Ni3Al based alloy by analysing both the liqu id-to-solid transformation in the molten pool and the distribution of thermal stre...Investigation has been made into the causes of cracking in the Surfacing welding layer of Ni3Al based alloy by analysing both the liqu id-to-solid transformation in the molten pool and the distribution of thermal stress within the surfacing welding layer. The results show that cracking in the surfacing welding layer is directly related to the producing of eutectic phase β' (NiAl) in the interdendritic region and high thermal stress within the surfacing welding layer. When the process of electric arc surfacing welding is changed from along straight line to along' Z' pattern, cracking in the surfacing welding layer of Ni3Al based alloy is prevented due to being reduced of both the cooling rate of liquid in the molten pool and the moving speed of the heat source. Reducing the melting volume of the substrate material by lowering the output power of electric arc welding would make the content of iron atoms in the molten pool decrease. and this also can reduce the trend of the eutectic reaction in the interdendfitic region and is helpful to Suppress cracking in the surfacing welding layer.展开更多
Double glow plasma surface metallurgy technique was used to fabricate a Fe?Al?Cr?Nb alloyed layer onto the surface of the 45 steel. The microstructures and composition of th?eA Fl?eCr?Nb alloyed layer were analyzed by...Double glow plasma surface metallurgy technique was used to fabricate a Fe?Al?Cr?Nb alloyed layer onto the surface of the 45 steel. The microstructures and composition of th?eA Fl?eCr?Nb alloyed layer were analyzed by scanning electronic microscopy, X-ray diffraction and energy dispersive spectroscopy. The results indicate thatthe 20 μm alloyed layer is homogeneous and compact. The alloyed elements exhibit a gradient distribution along the cross section. Microhardness and nanoindentation tests imply that the surface hardness of the alloyed layer reaches HV 580, which is almost 2.8 times that of the substrate. Compared with the substrate, the alloyed layer has a much smaller displacement and a larger elastic modulus. According to the friction and wear tests at room temperature, the? FeAl?Cr?Nb alloyed layer has lower friction coefficient and less wear mass, implying that the Fe?Al?Cr?Nb alloyed layer can effectively improve the surface hardness and wear resistance of the substrate.展开更多
The concentrations, accumulation and sources of 15 polycyclic aromatic hydrocarbons (PAHs) had been studied or evaluated in the surface layer sediments of Taizhou Bay, China. It showed that the concentrations of PAH...The concentrations, accumulation and sources of 15 polycyclic aromatic hydrocarbons (PAHs) had been studied or evaluated in the surface layer sediments of Taizhou Bay, China. It showed that the concentrations of PAHs ranged from 85.4 to 167.6 ng/g (averaged 138.62 ng/g), and the highest level was found in Jiao Jiang Dock. Percentages of 2-, 3-, 4-, 5- and 6-cyclic aromatic hydrocarbons were 7.8 %, 42.1%, 33.3 %, 9.6 % and 7.2 % respectively. The accumulation indices of PAHs ranged from 532.7 to 1068.9 (averaged 807.5), and the index of Phenanthrene was the highest (122.7), while that of Benzo (a) Pyrene was the lowest (2.7) among them. In Taizhou Bay, PAHs in surface layer sediments came mainly from coal burning, partly from direct pollution of petroleum hydrocarbons.展开更多
[Objective] This study aimed to investigation the effects of straw covering and different types of potassium fertilizer on salinity accumulation in surface layer of tobacco-planted paddy soil in southern China. [Metho...[Objective] This study aimed to investigation the effects of straw covering and different types of potassium fertilizer on salinity accumulation in surface layer of tobacco-planted paddy soil in southern China. [Method] Tobacco variety ‘Yunyan87’ was used as the experimental material to investigate the effects of salinity accumulation in surface layer of tobacco-planted paddy soil on the growth and development of flue-cured tobacco using different types of potassium fertilizer and mulching cultivation methods. [Result] The results showed that K+ , Ca2+ , SO42and NO3-were the major salt ions in topsoil at different growth stages of flue-cured tobacco, Na + and Mg2+ contents were also relatively high at vigorous growth stage, indicating that these salt ions were easily accumulated in surface layer of soil; to be specific, the absolute increase of salt ion concentration showed a decreasing order of K+ SO42- NO3-Ca2+ Mg2+ Na+ Cl-, while the relative increase of salt ion concentration showed a decreasing order of Ca2+ K+ Na+ NO3-SO42-Mg2+ Cl-. At 60 d posttransplanting, total salt content in topsoil reached the minimum of 359.1 mg/kg in Treatment 2, total salt content in topsoil reached the maximum of 536.1 mg/kg in Treatment 5 (CK), which was significantly higher than that in other treatments. At 90 d post-transplanting, no significant difference was observed in total salt content among various treatments. At harvesting period, total salt content in topsoil reached the maximum of 3 278.4 mg/kg in Treatment 1, which was significantly higher than that in other treatments. Topsoil pH showed no significant differences among various treatments at three different periods, ranging from 5.39 to 5.59. Straw covering could effectively reduce salt content in topsoil, accelerate vigorous growth of tobacco, shorten vigorous growth period and increase plant height, leaf number and lead area; at vigorous growth stage, root vitality and root volume of tobacco were improved, but the yield and output value were relatively low. Major agronomic traits and yield of tobacco showed no significant difference among various treatments. Output value of tobacco reached the maximum of 24 196.8 yuan/hm2 in Treatment 3, which was significantly higher than that in other treatments. [Conclusion] Appropriate types and proportions of potassium fertilizer and straw covering can effectively reduce the total salt content in tobacco-planted paddy soil and increase the effective supply amount of K+ , Ca2+ , SO42-and NO3-, thereby promoting and improving the root vitality of tobacco, which is conducive to the growth and development of tobacco and will eventually enhance the yield, quality and economic benefits of flue-cured tobacco.展开更多
This paper uses a Modified Soil-Plant-Atmosphere Scheme (MSPAS) to study the interaction between land surface and atmospheric boundary layer processes. The scheme is composed of two main parts: atmospheric boundary la...This paper uses a Modified Soil-Plant-Atmosphere Scheme (MSPAS) to study the interaction between land surface and atmospheric boundary layer processes. The scheme is composed of two main parts: atmospheric boundary layer processes and land surface processes. Compared with SiB and BATS, which are famous for their detailed parameterizations of physical variables, this simplified model is more convenient and saves much more computation time. Though simple, the feasibility of the model is well proved in this paper. The numerical simulation results from MSPAS show good agreement with reality. The scheme is used to obtain reasonable simulations for diurnal variations of heat balance, potential temperature of boundary layer, and wind field, and spatial distributions of temperature, specific humidity, vertical velocity, turbulence kinetic energy, and turbulence exchange coefficient over desert and oasis. In addition, MSPAS is used to simulate the interaction between desert and oasis at night, and again it obtains reasonable results. This indicates that MSPAS can be used to study the interaction between land surface processes and the atmospheric boundary layer over various underlying surfaces and can be extended for regional climate and numerical weather prediction study.展开更多
The Regional Atmospheric Modeling System (RAMS) and the computational fluid dynamics (CFD) codes known as FLUENT are combinatorially applied in a multi-scale numerical simulation of the urban surface layer (USL)...The Regional Atmospheric Modeling System (RAMS) and the computational fluid dynamics (CFD) codes known as FLUENT are combinatorially applied in a multi-scale numerical simulation of the urban surface layer (USL). RAMS and FLUENT are combined as a multi-scale numerical modeling system, in which the RAMS simulated data are delivered to the computational model for FLUENT simulation in an offline way. Numerical simulations are performed to present and preliminarily validate the capability of the multi-scale modeling system, and the results show that the modeling system can reasonably provide information on the meteorological elements in an urban area from the urban scale to the city-block scale, especially the details of the turbulent flows within the USL.展开更多
Based on specific geology and mining conditions of certain coal working face in China, a series of numerical models under different unconsolidated layers thickness were respectively established by employing FLAC3D. Th...Based on specific geology and mining conditions of certain coal working face in China, a series of numerical models under different unconsolidated layers thickness were respectively established by employing FLAC3D. The relationship between the unconsolidated layers thickness and surface movement laws was studied. Maximum surface subsidence, Maximum horizontal displacement and surface subsidence degree were obtained. Contours of surface subsidence/horizontal displacement and curves were drawn. Some laws of surface subsidence/horizontal displacement were analyzed. The role of the unconsolidated layers in surface subsidence was revealed. It is significant to predict surface subsidence of thick unconsolidated layers for coal mine and take effective measures to control surface subsidence.展开更多
The propagation of surface acoustic waves in layered piezoelectric structureswith initial stresses is investigated. The phase velocity equations are obtained for electricallyfree and shorted cases, respectively. Effec...The propagation of surface acoustic waves in layered piezoelectric structureswith initial stresses is investigated. The phase velocity equations are obtained for electricallyfree and shorted cases, respectively. Effects of the initial stresses on the phase velocity and theelectromechanical coupling coefficient for the fundamental mode of the layered piezoelectricstructures are discussed. Numerical results for the c-axis oriented film of LiNbO_3 on a sapphiresubstrate are given. It is found that the fractional change in phase velocity is a linear functionwith the initial stresses, and the electromechanical coupling factor increases with an increase ofthe absolute values of the compressive initial stresses. The results are useful for the design ofsurface acoustic wave devices.展开更多
In this paper,we proposal stream surface and stream layer.By using classical tensor calculus,we derive 3-D Navier-Stokes Equations(NSE)in the stream layer under semigeodesic coordinate system,Navier-Stokes equation on...In this paper,we proposal stream surface and stream layer.By using classical tensor calculus,we derive 3-D Navier-Stokes Equations(NSE)in the stream layer under semigeodesic coordinate system,Navier-Stokes equation on the stream surface and 2-D Navier-Stokes equations on a two dimensional manifold. After introducing stream function on the stream surface,a nonlinear initial-boundary value problem satisfies by stream function is obtained,existence and uniqueness of its solution are proven.Based this theory we proposal a new method called"dimension split method"to solve 3D NSE.展开更多
Size distribution of nano-carbides produced by duplex treatments of surface nanocrystallization(by surface severe plastic deformation) and plasma electrolytic carburizing on CP-Ti was investigated.Skewness and kurtosi...Size distribution of nano-carbides produced by duplex treatments of surface nanocrystallization(by surface severe plastic deformation) and plasma electrolytic carburizing on CP-Ti was investigated.Skewness and kurtosis of Gussian shape distribution curves were studied and the effect of time was determined.The usage of longer time is more suitable for achieving less size of complex nano-carbides.Surface roughness of treated samples was measured.It is observed that there is an optimum level for time on surface roughness increasing(difference between two measured data).展开更多
文摘The important parameters that influence the mechanical property of the pavinglayer on an orthotropic steel bridge deck are the paving layer thickness and modulus of the asphaltconcrete surfacing. Three important indices that control the typical failures of the paving layerare the maximum tensile stress of paving layer, the maximum shear stress between the steel deck andthe paving layer, and the maximum deflection on the paving surface. In this paper, the analyticalmodel of paving systems on orthotropic steel bridge deck is established, and the finite elementmethod is adopted to study the stress and strain of paving system. With the variation of asphaltconcrete modulus in high or low temperature season, the influences of paving layer thickness onthree control indices are researched. The results provide a theoretical basis for the determinationof thickness of the paving layer on the steel bridge deck.
文摘Effects of alloy elements on the microstructure and crack resistance of Fe-C-Cr weld surfacing layer were investigated. The results show that microstructures of the layer mainly consist of carbides and austenite matrix. Increasing C and Cr contents impair the crack resistance of the layer due to increased amount of brittle carbides. The addition of Ni, Nb or Mo improves the crack resistance of Fe-C-Cr weld surfacing layer by increasing the amount of austenite and forming fine NbC or M 7C 3 carbides in the layer. But, the excessive Nb (>2.50wt%) or Mo (>1.88wt%) impairs the crack resistance of the layer, which has relation with increased carbides or carbide coarsening and austenite matrix solid solution strengthening. The proper combination of C, Cr, Ni, Nb and Mo can further improve not only the crack resistance of Fe-C-Cr weld surfacing layer but also the erosion resistance as a result of fine NbC and M 7C 3 carbides distributing uniformly in austenite matrix. The optimal layer compositions are 3.05wt%C, 20.58wt%Cr, 1.75wt%Ni, 2.00wt%Nb and 1.88wt%Mo.
文摘Effects of alloying elements on microstructure and erosion resistance of Fe-C-Cr weld surfacing layer have been studied. The experimental results show that increasing C and Cr content favors improving the erosion resistance of the layer, and the excessive C and Cr result in decreasing the erosion resistance at 90 deg. erosion. That Mo, Nb or Ti improves the erosion resistance of Fe-C-Cr weld surfacing layer is mainly attributed to increasing the amount of M7C3 and forming fine NbC or TiC in austenite matrix, but the excessive Mo, Nb or Ti is unfavorable. The addition of Mo, Nb and Ti in proper combination possesses stronger effect on improving the erosion resistance and the erosion resistance (εA) of Fe-C-Cr weld surfacing layer with fine NbC, TiC and M7C3 distributing uniformly in austenite matrix obviously increases to 2.81 at 15 deg. erosion and 2.88 at 90 deg. erosion when the layer composition is 3.05C, 20.58Cr, 1.88Mo, 2.00Nb and 1.05Ti (in wt pct).
基金supported by the National Natural Science Foundation of China(Grant No.42176015)the National Natural Science Foundation of China(Grant No.41605070)+3 种基金the National Key Research and Development Program(Grant No.2021YFC3101500)the Hunan Provincial Natural Science Outstanding Youth Fund(Grant No.2023JJ10053)the Innovation Group Project of the Southern Marine Science and Engineering Guangdong Laboratory(Zhuhai)(Grant No.311022001)a project of the Southern Marine Science and Engineering Guangdong Laboratory(Zhuhai)(Grant No.SML2021SP207)。
文摘This study investigates the impact of the salinity barrier layer(BL)on the upper ocean response to Super Typhoon Mangkhut(2018)in the western North Pacific.After the passage of Mangkhut,a noticeable increase(~0.6 psu)in sea surface salinity and a weak decrease(<1℃)in sea surface temperature(SST)were observed on the right side of the typhoon track.Mangkhut-induced SST change can be divided into the three stages,corresponding to the variations in BL thickness and SST before,during,and after the passage of Mangkhut.During the pre-typhoon stage,SST slightly warmed due to the entrainment of BL warm water,which suppressed the cooling induced by surface heat fluxes and horizontal advection.During the forced stage,SST cooling was controlled by entrainment,and the preexisting BL reduced the total cooling by 0.89℃ d-1,thus significantly weakening the overall SST cooling induced by Mangkhut.During the relaxation stage,the SST cooling was primarily caused by the entrainment.Our results indicate that a preexisting BL can limit typhoon-induced SST cooling by suppressing the entrainment of cold thermocline water,which contributed to Mangkhut becoming the strongest typhoon in 2018.
基金Project supported by the National Key R&D Program of China (Grant No.2022YFB2402500)the National Natural Science Foundation of China (Grant Nos.52122214,92372116,and 52394174)+2 种基金Youth Innovation Promotion Association of the Chinese Academy of Sciences (Grant No.2020006)Jiangsu Province Carbon Peak and Neutrality Innovation Program (Industry tackling on prospect and key technology BE2022002-5)Guangxi Power Grid Project (Grant No.GXKJXM20210260)。
文摘In Na-ion batteries,O3-type layered oxide cathode materials encounter challenges such as particle cracking,oxygen loss,electrolyte side reactions,and multi-phase transitions during the charge/discharge process.This study focuses on surface coating with NiTiO_(3) achieved via secondary heat treatment using a coating precursor and the surface material.Through in-situ x-ray diffraction(XRD)and differential electrochemical mass spectrometry(DEMS),along with crystal structure characterizations of post-cycling materials,it was determined that the NiTiO_(3) coating layer facilitates the formation of a stable lattice structure,effectively inhibiting lattice oxygen loss and reducing side reaction with the electrolyte.This enhancement in cycling stability was evidenced by a capacity retention of approximately 74%over 300 cycles at 1 C,marking a significant 30%improvement over the initial sample.Furthermore,notable advancements in rate performance were observed.Experimental results indicate that a stable and robust surface structure substantially enhances the overall stability of the bulk phase,presenting a novel approach for designing layered oxide cathodes with higher energy density.
基金supported by the National Key R&D Program of China(2021YFB2401800)the National Natural Science Foundation of China(21875022,22179008)+4 种基金the Yibin‘Jie Bang Gua Shuai’(2022JB004)the support from the Beijing Nova Program(20230484241)the support from the Postdoctoral Fellowship Program of CPSF(GZB20230931)the support from the 4B7B beam line of Beijing Synchrotron Radiation Facility(2021-BEPC-PT-005924,2021-BEPC-PT-005967)BL08U1A beam line of Shanghai Synchrotron Radiation Facility(2021-SSRF-PT-017710)。
文摘The rapid development of electric vehicles and portable energy storage systems demands improvements in the energy density and cost-effectiveness of lithium-ion batteries,a domain in which Lithium-rich layered cathode(LLO)materials inherently excel.However,these materials face practical challenges,such as low initial Coulombic efficiency,inferior cycle/rate performance,and voltage decline during cycling,which limit practical application.Our study introduces a surface multi-component integration strategy that incorporates oxygen vacancies into the pristine LLO material Li1.2Mn_(0.6)Ni_(0.2)O_(2).This process involves a brief citric acid treatment followed by calcination,aiming to explore rate-dependent degradation behavior.The induced surface oxygen vacancies can reduce surface oxygen partial pressure and diminish the generation of O_(2)and other highly reactive oxygen species on the surface,thereby facilitating the activation of Li ions trapped in tetrahedral sites while overcoming transport barriers.Additionally,the formation of a spinel-like phase with 3D Li+diffusion channels significantly improves Li^(+)diffusion kinetics and stabilizes the surface structure.The optimally modified sample boasts a discharge capacity of 299.5 mA h g^(-1)at a 0.1 C and 251.6 mA h g^(-1)at a 1 C during the initial activation cycle,with an impressive capacity of 222.1 mA h g^(-1)at a 5 C.Most notably,it retained nearly 70%of its capacity after 300 cycles at this elevated rate.This straightforward,effective,and highly viable modification strategy provides a crucial resolution for overcoming challenges associated with LLO materials,making them more suitable for practical application.
基金Funded by the Scientific Research Foundation of Shandong University of Science and Technology for Recruited Talents(No.2014RCJJ041)the National Natural Science Foundation of China(51774199)
文摘Using plasma build-up welding technology, Ni60, WC, Cr3C2, and TiC composite powders were clad on the surface of the substrate in a certain proportion according to the metallurgical bonding method to increase the bond strength between the coating and the substrate. Scanning electron microscopy and energy dispersive spectroscopy were used to observe the microstructure of the surfacing layer and the chemical composition of the sample. The hardness and wear resistance of the surfacing layer were tested and analyzed by the HV-1000 hardness tester and the impact wear device. The results showed that in the microstructure, fishbone, spider-web, and floral-like structures appeared in the surfacing layer. When the micro-hardness was tested, the depth of the indentation reflected the hardness of the surfacing layer. When analyzing wear resistance, the amount of wear increases with time.
基金Item Sponsored by National Natural Science Foundation of China(59905017)
文摘The characteristic of the bond zone between Ni-based alloy light beam surfacing layer(SL)and base metal(BM)was investigated by scanning electron microscope,energy dispersive spectrometer and X-ray diffraction.The results show that the bond zone,which consists ofγ-Ni orγ-(Fe,Ni)planar crystal band close to SL andα-Fe bright band close to heat affected zone(HAZ),is actually the transition zone of composition and microstructure between SL and HAZ,and the metallurgical bond interface lies between theα-Fe bright band and HAZ.With the increase of light beam heat input from 2kJ/mm to 4kJ/mm,the width of the bond zone increases from 4μm to 15μm,and the morphology of bond interface changes from zigzag to straight.The formation of bond interface indicates the formation of reliable metallurgical bond between SL and BM.
基金supported by the foundation of '863' high technology in China
文摘Investigation has been made on the causes of hot cracking in the surfacing layer of Ni_3Al basealloy by analysing the solidification process of fusion pool and the distribution of thermal stresses. The re-sults show that the cracking is directly related to both the occurrence of eutectic phase β' (NiAI) within theinterdendritic region and high thernial stresses in the surfacing layer ,and which are caused by selecting highwelding rate. When the process of electric arc weld is changed from straight line rnovement to that along’Z’pattern,the cracking in the surfacing layer of Ni_3Al base alloy is prevented owing to being reduced of boththe cooling rate of liquid in the fusion liool and the speed of the moving heat source. Lowering the outputpower of the electric arc welding could lead to the reducing of rnelting volume of the base material ,and lowerthe arnount of iron atoms dissolving in the fusion pool ,so that the trend of the eutectic reaction within the in-terdendritic region is reduced,and which is helpful to suppress the cracking in the surfacing layer of Ni_3Albase alloy.
文摘Investigation has been made into the causes of cracking in the Surfacing welding layer of Ni3Al based alloy by analysing both the liqu id-to-solid transformation in the molten pool and the distribution of thermal stress within the surfacing welding layer. The results show that cracking in the surfacing welding layer is directly related to the producing of eutectic phase β' (NiAl) in the interdendritic region and high thermal stress within the surfacing welding layer. When the process of electric arc surfacing welding is changed from along straight line to along' Z' pattern, cracking in the surfacing welding layer of Ni3Al based alloy is prevented due to being reduced of both the cooling rate of liquid in the molten pool and the moving speed of the heat source. Reducing the melting volume of the substrate material by lowering the output power of electric arc welding would make the content of iron atoms in the molten pool decrease. and this also can reduce the trend of the eutectic reaction in the interdendfitic region and is helpful to Suppress cracking in the surfacing welding layer.
基金Project(51371097)supported by the National Natural Science Foundation of ChinaProject supported by the Priority Academic Program Development of Jiangsu Higher Education Institutions,China
文摘Double glow plasma surface metallurgy technique was used to fabricate a Fe?Al?Cr?Nb alloyed layer onto the surface of the 45 steel. The microstructures and composition of th?eA Fl?eCr?Nb alloyed layer were analyzed by scanning electronic microscopy, X-ray diffraction and energy dispersive spectroscopy. The results indicate thatthe 20 μm alloyed layer is homogeneous and compact. The alloyed elements exhibit a gradient distribution along the cross section. Microhardness and nanoindentation tests imply that the surface hardness of the alloyed layer reaches HV 580, which is almost 2.8 times that of the substrate. Compared with the substrate, the alloyed layer has a much smaller displacement and a larger elastic modulus. According to the friction and wear tests at room temperature, the? FeAl?Cr?Nb alloyed layer has lower friction coefficient and less wear mass, implying that the Fe?Al?Cr?Nb alloyed layer can effectively improve the surface hardness and wear resistance of the substrate.
文摘The concentrations, accumulation and sources of 15 polycyclic aromatic hydrocarbons (PAHs) had been studied or evaluated in the surface layer sediments of Taizhou Bay, China. It showed that the concentrations of PAHs ranged from 85.4 to 167.6 ng/g (averaged 138.62 ng/g), and the highest level was found in Jiao Jiang Dock. Percentages of 2-, 3-, 4-, 5- and 6-cyclic aromatic hydrocarbons were 7.8 %, 42.1%, 33.3 %, 9.6 % and 7.2 % respectively. The accumulation indices of PAHs ranged from 532.7 to 1068.9 (averaged 807.5), and the index of Phenanthrene was the highest (122.7), while that of Benzo (a) Pyrene was the lowest (2.7) among them. In Taizhou Bay, PAHs in surface layer sediments came mainly from coal burning, partly from direct pollution of petroleum hydrocarbons.
基金Supported by Project of Guangdong Zhongyan Industry Limited Liability Company[YYG15JO-QK(2011)-004]~~
文摘[Objective] This study aimed to investigation the effects of straw covering and different types of potassium fertilizer on salinity accumulation in surface layer of tobacco-planted paddy soil in southern China. [Method] Tobacco variety ‘Yunyan87’ was used as the experimental material to investigate the effects of salinity accumulation in surface layer of tobacco-planted paddy soil on the growth and development of flue-cured tobacco using different types of potassium fertilizer and mulching cultivation methods. [Result] The results showed that K+ , Ca2+ , SO42and NO3-were the major salt ions in topsoil at different growth stages of flue-cured tobacco, Na + and Mg2+ contents were also relatively high at vigorous growth stage, indicating that these salt ions were easily accumulated in surface layer of soil; to be specific, the absolute increase of salt ion concentration showed a decreasing order of K+ SO42- NO3-Ca2+ Mg2+ Na+ Cl-, while the relative increase of salt ion concentration showed a decreasing order of Ca2+ K+ Na+ NO3-SO42-Mg2+ Cl-. At 60 d posttransplanting, total salt content in topsoil reached the minimum of 359.1 mg/kg in Treatment 2, total salt content in topsoil reached the maximum of 536.1 mg/kg in Treatment 5 (CK), which was significantly higher than that in other treatments. At 90 d post-transplanting, no significant difference was observed in total salt content among various treatments. At harvesting period, total salt content in topsoil reached the maximum of 3 278.4 mg/kg in Treatment 1, which was significantly higher than that in other treatments. Topsoil pH showed no significant differences among various treatments at three different periods, ranging from 5.39 to 5.59. Straw covering could effectively reduce salt content in topsoil, accelerate vigorous growth of tobacco, shorten vigorous growth period and increase plant height, leaf number and lead area; at vigorous growth stage, root vitality and root volume of tobacco were improved, but the yield and output value were relatively low. Major agronomic traits and yield of tobacco showed no significant difference among various treatments. Output value of tobacco reached the maximum of 24 196.8 yuan/hm2 in Treatment 3, which was significantly higher than that in other treatments. [Conclusion] Appropriate types and proportions of potassium fertilizer and straw covering can effectively reduce the total salt content in tobacco-planted paddy soil and increase the effective supply amount of K+ , Ca2+ , SO42-and NO3-, thereby promoting and improving the root vitality of tobacco, which is conducive to the growth and development of tobacco and will eventually enhance the yield, quality and economic benefits of flue-cured tobacco.
基金supported by the National Natural Science Foundation of China (Grant No.40275004)the State Key Laboratory of Atmosphere Physics and Chemistry,and the City University of Hong Kong(Grant No.8780046)the City University of Hong Kong Strategic Research(Grant No.7001038)
文摘This paper uses a Modified Soil-Plant-Atmosphere Scheme (MSPAS) to study the interaction between land surface and atmospheric boundary layer processes. The scheme is composed of two main parts: atmospheric boundary layer processes and land surface processes. Compared with SiB and BATS, which are famous for their detailed parameterizations of physical variables, this simplified model is more convenient and saves much more computation time. Though simple, the feasibility of the model is well proved in this paper. The numerical simulation results from MSPAS show good agreement with reality. The scheme is used to obtain reasonable simulations for diurnal variations of heat balance, potential temperature of boundary layer, and wind field, and spatial distributions of temperature, specific humidity, vertical velocity, turbulence kinetic energy, and turbulence exchange coefficient over desert and oasis. In addition, MSPAS is used to simulate the interaction between desert and oasis at night, and again it obtains reasonable results. This indicates that MSPAS can be used to study the interaction between land surface processes and the atmospheric boundary layer over various underlying surfaces and can be extended for regional climate and numerical weather prediction study.
基金This study was supported by the National Natural Science Foundation of China (Grant Nos. 40233030, 40405004, 40405014).
文摘The Regional Atmospheric Modeling System (RAMS) and the computational fluid dynamics (CFD) codes known as FLUENT are combinatorially applied in a multi-scale numerical simulation of the urban surface layer (USL). RAMS and FLUENT are combined as a multi-scale numerical modeling system, in which the RAMS simulated data are delivered to the computational model for FLUENT simulation in an offline way. Numerical simulations are performed to present and preliminarily validate the capability of the multi-scale modeling system, and the results show that the modeling system can reasonably provide information on the meteorological elements in an urban area from the urban scale to the city-block scale, especially the details of the turbulent flows within the USL.
基金Project(2007BAK28B03)supported by the National Eleventh-Five Year Research Program of ChinaProject(2010YD05)supported by the Fundamental Research Funds for the Central UniversitiesProject(200911036)supported by the Ministry of Land and Resources Research Special
文摘Based on specific geology and mining conditions of certain coal working face in China, a series of numerical models under different unconsolidated layers thickness were respectively established by employing FLAC3D. The relationship between the unconsolidated layers thickness and surface movement laws was studied. Maximum surface subsidence, Maximum horizontal displacement and surface subsidence degree were obtained. Contours of surface subsidence/horizontal displacement and curves were drawn. Some laws of surface subsidence/horizontal displacement were analyzed. The role of the unconsolidated layers in surface subsidence was revealed. It is significant to predict surface subsidence of thick unconsolidated layers for coal mine and take effective measures to control surface subsidence.
基金Project supported by the National Natural Science Foundation of China(Nos.10132010 and 10072033)
文摘The propagation of surface acoustic waves in layered piezoelectric structureswith initial stresses is investigated. The phase velocity equations are obtained for electricallyfree and shorted cases, respectively. Effects of the initial stresses on the phase velocity and theelectromechanical coupling coefficient for the fundamental mode of the layered piezoelectricstructures are discussed. Numerical results for the c-axis oriented film of LiNbO_3 on a sapphiresubstrate are given. It is found that the fractional change in phase velocity is a linear functionwith the initial stresses, and the electromechanical coupling factor increases with an increase ofthe absolute values of the compressive initial stresses. The results are useful for the design ofsurface acoustic wave devices.
文摘In this paper,we proposal stream surface and stream layer.By using classical tensor calculus,we derive 3-D Navier-Stokes Equations(NSE)in the stream layer under semigeodesic coordinate system,Navier-Stokes equation on the stream surface and 2-D Navier-Stokes equations on a two dimensional manifold. After introducing stream function on the stream surface,a nonlinear initial-boundary value problem satisfies by stream function is obtained,existence and uniqueness of its solution are proven.Based this theory we proposal a new method called"dimension split method"to solve 3D NSE.
基金Partial work of this project funded by National Elite Foundation of Iran and Iranian Nanotechnology Initiative is appreciated.
文摘Size distribution of nano-carbides produced by duplex treatments of surface nanocrystallization(by surface severe plastic deformation) and plasma electrolytic carburizing on CP-Ti was investigated.Skewness and kurtosis of Gussian shape distribution curves were studied and the effect of time was determined.The usage of longer time is more suitable for achieving less size of complex nano-carbides.Surface roughness of treated samples was measured.It is observed that there is an optimum level for time on surface roughness increasing(difference between two measured data).