After analysing the disadvantages of the traditional residue hydrotreating-catalytic cracking combination process, RIPP has proposed a bi-directional combination technology integrating residue hydrotreating with catal...After analysing the disadvantages of the traditional residue hydrotreating-catalytic cracking combination process, RIPP has proposed a bi-directional combination technology integrating residue hydrotreating with catalytic cracking called RICP which does not further recycles the FCC heavy cycle oil (HCO) inside the FCC unit and delivers HCO to the residue hydrotreating unit as a diluting oil for the residue that is concurrently subjected to hydrotreating prior to being used as the FCC feed oil. The RICP technology can stimulate residue hydrotreating reactions through utilization of HCO along with an in- creased yield of FCC light distillate, resulting in enhanced petroleum utilization and economic benefits of the refinery.展开更多
Residue deep hydrotreating(RDHT)process was developed by the Research Institute of Petroleum Processing(RIPP)to provide high quality feedstock for deep catalytic cracking(DCC)process.In this research work,the effects ...Residue deep hydrotreating(RDHT)process was developed by the Research Institute of Petroleum Processing(RIPP)to provide high quality feedstock for deep catalytic cracking(DCC)process.In this research work,the effects of RDHT process and reaction severity on heteroatom removal,hydrogen content increase,hydrocarbon composition improvement,and DCC product yields were studied.It was showed that the RDHT process can effectively reduce heteroatoms,increase hydrogen content and improve the hydrocarbon compositions,which can contribute to an increase of light olefins yield in DCC unit.展开更多
The paper presents the results of investigation of changes in the composition of hydrocarbons and sulfur-containing compounds of an atmospheric residue in the course of cracking in the presence of a tungsten carbide-n...The paper presents the results of investigation of changes in the composition of hydrocarbons and sulfur-containing compounds of an atmospheric residue in the course of cracking in the presence of a tungsten carbide-nickel-chromium(WC/Ni-Cr)catalytic additive and without it.The cracking is carried out in an autoclave at 500℃for 30 min.The addition of the WC/Ni-Cr additive promotes the deepening of reactions of destruction not only of resins and asphaltenes,but also high molecular weight naphthene-aromatic compounds of the atmospheric residue.It is shown that the content of low molecular weight C9-C17 n-alkanes and C9-C10 alkylbenzenes rose sharply in the products of cracking with addition of WC/Ni-Cr in comparison with those produced without the additive.Alkyl-and naphthene-substituted aromatic hydrocarbons of benzene,naphthalene,phenanthrene series,polyarenes,benzo-and dibenzothiophenes are identified.展开更多
文摘After analysing the disadvantages of the traditional residue hydrotreating-catalytic cracking combination process, RIPP has proposed a bi-directional combination technology integrating residue hydrotreating with catalytic cracking called RICP which does not further recycles the FCC heavy cycle oil (HCO) inside the FCC unit and delivers HCO to the residue hydrotreating unit as a diluting oil for the residue that is concurrently subjected to hydrotreating prior to being used as the FCC feed oil. The RICP technology can stimulate residue hydrotreating reactions through utilization of HCO along with an in- creased yield of FCC light distillate, resulting in enhanced petroleum utilization and economic benefits of the refinery.
基金This work was supported by the Science and Technology Project of Sinopec(118015-1).
文摘Residue deep hydrotreating(RDHT)process was developed by the Research Institute of Petroleum Processing(RIPP)to provide high quality feedstock for deep catalytic cracking(DCC)process.In this research work,the effects of RDHT process and reaction severity on heteroatom removal,hydrogen content increase,hydrocarbon composition improvement,and DCC product yields were studied.It was showed that the RDHT process can effectively reduce heteroatoms,increase hydrogen content and improve the hydrocarbon compositions,which can contribute to an increase of light olefins yield in DCC unit.
文摘The paper presents the results of investigation of changes in the composition of hydrocarbons and sulfur-containing compounds of an atmospheric residue in the course of cracking in the presence of a tungsten carbide-nickel-chromium(WC/Ni-Cr)catalytic additive and without it.The cracking is carried out in an autoclave at 500℃for 30 min.The addition of the WC/Ni-Cr additive promotes the deepening of reactions of destruction not only of resins and asphaltenes,but also high molecular weight naphthene-aromatic compounds of the atmospheric residue.It is shown that the content of low molecular weight C9-C17 n-alkanes and C9-C10 alkylbenzenes rose sharply in the products of cracking with addition of WC/Ni-Cr in comparison with those produced without the additive.Alkyl-and naphthene-substituted aromatic hydrocarbons of benzene,naphthalene,phenanthrene series,polyarenes,benzo-and dibenzothiophenes are identified.
