Evolution of cavity size and energy conversion due to droplet impact on a water surface

The deformation characteristics of the cavity due to droplet impact on a water surface are experimentally investigated.Dimensional analysis shows that the characteristic values of time,depth,and horizontal diameter can be taken as 10^(-3)times the ratio of surface tension to the product of viscosity coefficient and gravitational acceleration,the maximum depth,and the maximum horizontal diameter,respectively.The evolutions of the dimensionless cavity sizes for different values of Weber number(We)coincide for 220<We<686.A partial-sphere model of cavity is established based on experimental observations.Energy models are then derived,and the energy conversions are calculated to identify the relationship between these conversions and cavity deformation.It is found that the kinetic energy model established under the hypothesis proposed by Leng is no longer applicable when the dimensionless time t^(*)<3.5,owing to deviations from the geometric model.

Au-Ag alloy nanoparticles with tunable cavity for plasmon-enhanced photocatalytic H2 evolution

Au-Ag alloy nanoparticles with different cavity sizes have great potential for improving photocatalytic performance due to their tunable plasmon effect.In this study,galvanic replacement was combined with co-reduction with the reaction kinetics processes regulated to rapidly synthesize Au-Ag hollow alloy nanoparticles with tunable cavity sizes.The position of the localized surface plasmon resonance(LSPR)peak could be effectively adjusted between 490 nm and 713 nm by decreasing the cavity size of the Au-Ag hollow nanoparticles from 35 nm to 20 nm.The plasmon-enhanced photocatalytic H2 evolution of alloy nanoparticles with different cavity sizes was investigated.Compared with pure P25(TiO2),intact and thin-shelled Au-Ag hollow nanoparticles(HNPs)-supported photocatalyst exhibited an increase in the photocatalytic H2 evolution rate from 0.48μmol h^−1 to 4μmol h^−1 under full-spectrum irradiation.This improved photocatalytic performance was likely due to the plasmon-induced electromagnetic field effect,which caused strong photogenerated charge separation,rather than the generation of hot electrons.

Damage evolution and fragmentation behavior of pyramid cut blasting under uniaxial compression

Pyramid cut blasting is an essential form of inclined hole cut blasting,but the in-situ stress effect of pyramid cut blasting is rarely studied.Based on the research background of pyramid cut blasting in a deep rock mass,the size,volume,and fragment size distribution of the blasting cavity before and after uniaxial compression were analysed by a model test.Otherwise,the damage and effective stress of the pyramid cut blasting were analysed with LS-DYNA numerical simulation.The results show that the damage and fragmentation of pyramid cut blasting are not only affected by blasting stress wave and blasting gas,but also affected by uniaxial compression.Under the influence of uniaxial compression,the blasting stress wave and blasting gas are more likely to damage the rock mass parallel to the uniaxial compression direction near the connecting line of blasting hole,and make the volume of cavity larger and the fragment rate lower.Additionally,uniaxial compression has a prominent influence during the middle and late stages of blasting.

RELATIONSHIP OF FIRST STEP HEIGHT,STEP SLOPE AND CAVITY IN X-SHAPED FLARING GATE PIERS

The energy dissipation of X-shaped flaring gate piers ahead of a stepped spillway was adopted in the Suofengying Hydroplant. Under the circumstance that the first step is higher than others, at the step surface an aerated cavity occured behind piers. The interaction of the weir head, the elevation difference between crest and chamber outlet, the first step height, the slopes of weir end and step, and the size of cavity, was investigated, the expression was derived to characterize their relationship, and the corresponding curves were plotted. The comparison of the calculated and simulated results with the measured data was performed. When the slopes of step and weir end are equivalent, the relative height difference between the first and second steps becomes the main factor influencing the aerated cavity. These findings may be useful in practical applications.

Controlled fabrication and microwave absorbing mechanism of hollow Fe3O4@C microspheres

Uniform core-shell SiO2@Fe_3O_4@C microspheres were prepared by a one-step hydrothermal method with SiO_2 microspheres as the template, and the hollow Fe_3O_4@C(HFC) microspheres were achieved via etching SiO_2 template. By changing the sizes of SiO_2 microspheres, a series of HFC microspheres with variable cavity sizes were obtained to study the relationship between cavity size and microwave absorbing(MA) performance for the first time. The morphology and structure of samples were characterized in detail. The results showed that the MA performance of HFC sample depended on its cavity size. In particular, the hollow structure was good for improving MA performance and could make MA move to the high-frequency region. More importantly, as the cavity size increases, the resonance frequency of HFC-i(i=1,2, 3, 4) samples moved to a low frequency, and the optimal matching thickness of HFC-i samples was increasing. Among all HFC-i samples, HFC-3 showed the most excellent MA performance,which could be mainly explained by the quarter-wavelength matching model, intrinsical magnetic and dielectric loss. Furthermore,the MA performance of HFC mixture blended by the equal mass fraction of HFC-2, HFC-3 and HFC-4 was the comprehensive results of three HFC-i samples. All the above suggested that the cavity size in HFC sample had a great influence on the MA performance.