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Rheological properties of a multiscale granular system during mixing of cemented paste backfill:A review 被引量:3
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作者 Cuiping Li Xue Li Zhu’en Ruan 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2023年第8期1444-1454,共11页
The technology of cemented paste backfill(CPB)is an effective method for green mining.In CPB,mixing is a vital process aiming to prepare a paste that meets the non-stratification,non-segregation,and non-bleeding requi... The technology of cemented paste backfill(CPB)is an effective method for green mining.In CPB,mixing is a vital process aiming to prepare a paste that meets the non-stratification,non-segregation,and non-bleeding requirements.As a multiscale granular system,homogenization is one of the challenges in the paste-mixing process.Due to the high shearing,high concentration,and multiscale characteristics,paste exhibits complex rheological properties in the mixing process.An overview of the mesomechanics and structural evolution is presented in this review.The effects of various influencing factors on the paste's rheological properties were investigated,and the rheological models of the paste were outlined from the macroscopic and mesoscopic levels.The results show that the mechanical effects and structural evolution are the fundamental factors affecting the rheological properties of the paste.Existing problems and future development trends are presented to change the practice where the CPB process comes first and the theory lags. 展开更多
关键词 cemented paste backfill RHEOLOGY mixing process MESOMECHANICS structural evolution
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Using cemented paste backfill to tackle the phosphogypsum stockpile in China:A down-to-earth technology with new vitalities in pollutant retention and CO_(2) abatement 被引量:3
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作者 Yikai Liu Yunmin Wang Qiusong Chen 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2024年第7期1480-1499,共20页
Phosphogypsum(PG),a hard-to-dissipate by-product of the phosphorus fertilizer production industry,places strain on the biogeochemical cycles and ecosystem functions of storage sites.This pervasive problem is already w... Phosphogypsum(PG),a hard-to-dissipate by-product of the phosphorus fertilizer production industry,places strain on the biogeochemical cycles and ecosystem functions of storage sites.This pervasive problem is already widespread worldwide and requires careful stewardship.In this study,we review the presence of potentially toxic elements(PTEs)in PG and describe their associations with soil properties,anthropogenic activities,and surrounding organisms.Then,we review different ex-/in-situ solutions for promoting the sustainable management of PG,with an emphasis on in-situ cemented paste backfill,which offers a cost-effective and highly scalable opportunity to advance the value-added recovery of PG.However,concerns related to the PTEs'retention capacity and long-term effectiveness limit the implementation of this strategy.Furthermore,given that the large-scale demand for ordinary Portland cement from this conventional option has resulted in significant CO_(2) emissions,the technology has recently undergone additional scrutiny to meet the climate mitigation ambition of the Paris Agreement and China's Carbon Neutrality Economy.Therefore,we discuss the ways by which we can integrate innovative strategies,including supplementary cementitious materials,alternative binder solutions,CO_(2) mineralization,CO_(2) curing,and optimization of the supply chain for the profitability and sustainability of PG remediation.However,to maximize the co-benefits in environmental,social,and economic,future research must bridge the gap between the feasibility of expanding these advanced pathways and the multidisciplinary needs. 展开更多
关键词 cemented paste backfill PHOSPHOGYPSUM carbon dioxide mitigation potentially toxic elements solidification and stabilization
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Estimating shear strength of high-level pillars supported with cemented backfilling using the HoekeBrown strength criterion 被引量:3
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作者 Kaizong Xia Congxin Chen +3 位作者 Xiumin Liu Yue Wang Xuanting Liu Jiahao Yuan 《Journal of Rock Mechanics and Geotechnical Engineering》 SCIE CSCD 2024年第2期454-469,共16页
Deep metal mines are often mined using the high-level pillars with subsequent cementation backfilling(HLSCB)mining method.At the design stage,it is therefore important to have a reasonable method for determining the s... Deep metal mines are often mined using the high-level pillars with subsequent cementation backfilling(HLSCB)mining method.At the design stage,it is therefore important to have a reasonable method for determining the shear strength of the high-level pillars(i.e.cohesion and internal friction angle)when they are supported by cemented backfilling.In this study,a formula was derived for the upper limit of the confining pressure σ3max on a high-level pillar supported by cemented backfilling in a deep metal mine.A new method of estimating the shear strength of such pillars was then proposed based on the Hoek eBrown failure criterion.Our analysis indicates that the horizontal stress σhh acting on the cemented backfill pillar can be simplified by expressing it as a constant value.A reasonable and effective value for σ3max can then be determined.The value of s3max predicted using the proposed method is generally less than 3 MPa.Within this range,the shear strength of the high-level pillar is accurately calculated using the equivalent MohreCoulomb theory.The proposed method can effectively avoid the calculation of inaccurate shear strength values for the high-level pillars when the original HoekeBrown criterion is used in the presence of large confining pressures,i.e.the situation in which the cohesion value is too large and the friction angle is too small can effectively be avoided.The proposed method is applied to a deep metal mine in China that is being excavated using the HLSCB method.The shear strength parameters of the high-level pillars obtained using the proposed method were input in the numerical simulations.The numerical results show that the recommended level heights and sizes of the high-level pillars and rooms in the mine are rational. 展开更多
关键词 Deep metal mines High-level pillars HoekeBrown strength criterion cemented backfilling Confining pressure Shear strength
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Rheological and physicomechanical properties of rod milling sand-based cemented paste backfill modified by sulfonated naphthalene formaldehyde condensate
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作者 Qinli Zhang Hao Wu +3 位作者 Yan Feng Daolin Wang Huaibin Su Xiaoshuang Li 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2023年第2期225-235,共11页
Rod milling sand(RMS)—a coarse sand aggregate—was recycled for cemented paste backfill(CPB)for the underground mined area at the Jinchuan nickel deposit,named rod milling sand-based cemented paste backfill(RCPB).The... Rod milling sand(RMS)—a coarse sand aggregate—was recycled for cemented paste backfill(CPB)for the underground mined area at the Jinchuan nickel deposit,named rod milling sand-based cemented paste backfill(RCPB).The adverse effects of coarse particles on the transportation of CPB slurry through pipelines to underground stopes resulting in weakening of the stability of the backfill system are well known.Therefore,sulfonated naphthalene formaldehyde(SNF)condensate was used for the performance improvement of RCPB.The synergistic effect of solid content(SC),lime-to-sand ratio,and SNF dosage on the rheological and physicomechanical properties,including slump,yield stress,bleeding rate,uniaxial compressive strength(UCS),as well as mechanism analysis of RCPB,have been explored.The results indicate that the effect of SNF on RCPB performance is related to the SNF dosage,lime-to-sand ratio,and SC.The slump of fresh RCPB with 0.1wt%-0.5wt%SNF increased by 2.6%-26.2%,whereas the yield stress reduced by 4.1%-50.3%,indicating better workability and improved cohesiveness of the mix.The bleeding rate of fresh RCPB decreased first and then rose with the increase of SNF dosage,and the peak decrease was 67.67%.UCS of RCPB first increased and then decreased with the increase of SNF dosage.At the optimal SNF addition ratio of 0.3wt%,the UCS of RCPB curing for 7,14 and,28 d ages increased by 31.5%,28.4%,and 29.5%,respectively.The beneficial effects of SNF in enhancing the early UCS of RCPB have been corroborated.However,the later UCS increases at a slower rate.The research findings may guide the design and preparation of RCPB with adequate performance for practical applications. 展开更多
关键词 rod milling sand sulfonated naphthalene formaldehyde condensate cemented paste backfill rheological properties physicomechanical properties
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Development and application of novel high‐efficiency composite ultrafine cement grouts for roadway in fractured surrounding rocks 被引量:1
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作者 Maolin Tian Shaojie Chen +1 位作者 Lijun Han Hongtian Xiao 《Deep Underground Science and Engineering》 2024年第1期53-69,共17页
The fractured surrounding rocks of roadways pose major challenges to safe mining.Grouting has often been used to reinforce the surrounding rocks to mitigate the safety risks associated with fractured rocks.The aim of ... The fractured surrounding rocks of roadways pose major challenges to safe mining.Grouting has often been used to reinforce the surrounding rocks to mitigate the safety risks associated with fractured rocks.The aim of this study is to develop highly efficient composite ultrafine cement(CUC)grouts to reinforce the roadway in fractured surrounding rocks.The materials used are ultrafine cement(UC),ultrafine fly ash(UF),ultrafine slag(US),and additives(superplasticizer[SUP],aluminate ultrafine expansion agent[AUA],gypsum,and retarder).The fluidity,bleeding,shrinkage,setting time,chemical composition,microstructure,degree of hydration,and mechanical property of grouting materials were evaluated in this study.Also,a suitable and effective CUC grout mixture was used to reinforce the roadway in the fractured surrounding rock.The results have shown that the addition of UF and US reduces the plastic viscosity of CUC,and the best fluidity can be obtained by adding 40%UF and 10%US.Since UC and UF particles are small,the pozzolanic effect of UF promotes the hydration reaction,which is conductive to the stability of CUC grouts.In addition,fine particles of UC,UF,and US can effectively fill the pores,while the volumetric expansion of AUA and gypsum decreases the pores and thus affects the microstructure of the solidified grout.The compressive test results have shown that the addition of specific amounts of UF and US can ameliorate the mechanical properties of CUC grouts.Finally,the CUC22‐8 grout was used to reinforce the No.20322 belt roadway.The results of numerical simulation and field monitoring have indicated that grouting can efficaciously reinforce the surrounding rock of the roadway.In this research,high‐performance CUC grouts were developed for surrounding rock reinforcement of underground engineering by utilizing UC and some additives. 展开更多
关键词 broken surrounding rock composite ultrafine cement(CUC)grouts grouting material grouting performance grouting reinforcement
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基于改进CNN-BiLSTM模型和地磁监测数据的多时间长度GIC预测
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作者 蓝东亮 陈延云 +4 位作者 吴影 赵淼 王亮 吴伟丽 黄冲 《空间科学学报》 CAS CSCD 北大核心 2024年第3期488-499,共12页
太阳风暴在电力系统网络中驱动产生的GIC会影响电力设备和系统的安全运行,严重时还会引发大面积停电事件.预测电网GIC水平能够为电力系统保护措施提供重要参考,然而对这方面的研究仍显不足.为了解决该问题,将卷积神经网络(CNN)与双向长... 太阳风暴在电力系统网络中驱动产生的GIC会影响电力设备和系统的安全运行,严重时还会引发大面积停电事件.预测电网GIC水平能够为电力系统保护措施提供重要参考,然而对这方面的研究仍显不足.为了解决该问题,将卷积神经网络(CNN)与双向长短时记忆(BiLSTM)以及注意力机制相结合,利用空间天气的相关监测信息,提出了大规模电网GIC多时间长度的预测方法.本文在分析太阳风暴驱动产生电网地磁感应电流(Geomagnetically Induced Current, GIC)基础上,构建了GIC预测模型;提出了基于多头注意力机制的CNN-BiLSTM改进模型,对GIC进行预测,并给出了预测流程.采用CNN捕获地磁扰动局部信息,根据BiLSTM综合地磁暴扰动信息的全局特征,综合利用多头注意力机制评估对GIC关键作用的地磁信息片段,实现电网GIC的预测.利用2004年11月8日00:00 LT-20:00 LT巨型磁暴期间DED地磁台站和QGZH地磁台监测数据,应用所提方法对岭澳500 kV变电站GIC进行回归预测.经过训练后, GIC预测相对误差均在12%以内,精度高于其他模型的预测结果. 展开更多
关键词 太阳风暴 gic预测 卷积神经网络 地磁数据
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Research on casing deformation prevention technology based on cementing slurry system optimization
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作者 Yan Yan Meng Cai +3 位作者 Wen-Hai Ma Xiao-Chuan Zhang Li-Hong Han Yong-Hong Liu 《Petroleum Science》 SCIE EI CAS CSCD 2024年第2期1231-1240,共10页
The casing deformation prevention technology based on the optimization of cement slurry is proposed to reduce the casing deformation of shale oil and gas wells during hydraulic fracturing. In this paper, the fracture ... The casing deformation prevention technology based on the optimization of cement slurry is proposed to reduce the casing deformation of shale oil and gas wells during hydraulic fracturing. In this paper, the fracture mechanism of hollow particles in cement sheath was firstly analyzed by discrete element method, and the effect of hollow particles in cement on casing deformation was investigated by laboratory experiment method. Finally, field test was carried out to verify the improvement effect of the casing deformation based on cement slurry modification. The results show that the formation displacement can be absorbed effectively by hollow particles inside the cement transferring the excessive deformation away from casing. The particles in the uncemented state provide deformation space during formation slipping. The casing with diameter of 139.7 mm could be passed through by bridge plug with the diameter of 99 mm when the mass ratio of particle/cement reaches 1:4. According to the field test feedback, the method based on optimization of cement slurry can effectively reduce the risk of casing deformation, and the recommended range of hollow microbeads content in the cement slurry is between 15% and 25%. 展开更多
关键词 cement slurry Hollow ceramsite Casing deformation Formation slip Field test
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Particle aggregation and breakage kinetics in cemented paste backfill
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作者 Liuhua Yang Hengwei Jia +4 位作者 Aixiang Wu Huazhe Jiao Xinming Chen Yunpeng Kou Mengmeng Dong 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2024年第9期1965-1974,共10页
The macroscopic flow behavior and rheological properties of cemented paste backfill(CPB)are highly impacted by the inherent structure of the paste matrix.In this study,the effects of shear-induced forces and proportio... The macroscopic flow behavior and rheological properties of cemented paste backfill(CPB)are highly impacted by the inherent structure of the paste matrix.In this study,the effects of shear-induced forces and proportioning parameters on the microstructure of fresh CPB were studied.The size evolution and distribution of floc/agglomerate/particles of paste were monitored by focused beam reflection measuring(FBRM)technique,and the influencing factors of aggregation and breakage kinetics of CPB were discussed.The results indicate that influenced by both internal and external factors,the paste kinetics evolution covers the dynamic phase and the stable phase.Increasing the mass content or the cement-tailings ratio can accelerate aggregation kinetics,which is advantageous for the rise of average floc size.Besides,the admixture and high shear can improve breaking kinetics,which is beneficial to reduce the average floc size.The chord length resembles a normal distribution somewhat,with a peak value of approximate 20μm.The particle disaggregation con-stant(k_(2))is positively correlated with the agitation rate,and k_(2) is five orders of magnitude greater than the particle aggregation constant(k1).The kinetics model depicts the evolution law of particles over time quantitatively and provides a theoretical foundation for the micromechanics of complicated rheological behavior of paste. 展开更多
关键词 cemented paste backfill particle kinetics ADMIXTURE rheology
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Preparation and Properties of Magnesium Oxysulfide Cement Based Foam Board Absorbing Material
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作者 刘军 崔宝栋 庞博 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2024年第1期118-125,共8页
In order to better solve the problem of electromagnetic pollution in the civil building cement,to improve the absorption capacity of magnesium oxysulfide cement based materials,and to better use sulfur oxide magnesium... In order to better solve the problem of electromagnetic pollution in the civil building cement,to improve the absorption capacity of magnesium oxysulfide cement based materials,and to better use sulfur oxide magnesium cement foamed sheet for improvement of electromagnetic industry,this paper uses the excellent microwave absorbing properties of ferrite and the modified sulfur oxide magnesium cement foam board,and discusses the microwave absorbing performance,aiming at improving the electromagnetic pollution in daily life.The effects of ferrite and silicon carbide doping on microwave absorption properties of modified magnesium oxysulfate cement were studied.At the same time,the wave absorbing properties of the corresponding samples were detected by bow method,and the causes of the corresponding phenomena were analyzed by scanning electron microscopy (SEM).The results show that the lowest reflectance of the material is-17.9 dB at 34.1 GHz and the average reflectance of the whole band is-15.9 dB under the target frequency band of 26.5-40 GHz.Under the action of external magnetic field,the absorbing particles are affected by magnetization force,magnetic dipole and resistance coupling,and play the absorbing effect in the cement base solidified completely in the electromagnetic field environment.The lowest reflectance is-17.3dB at 36.4GHz and the average reflectance is-14.3dB for the whole band. 展开更多
关键词 magnesium oxysulfide cement silicon carbide FERRITE absorption properties
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Effect of Sodium Tripolyphosphate and Silica Fume on Hydration of High Alumina Cement
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作者 WANG Jingran YANG Zongyuan +3 位作者 ZHANG Shuai ZHANG Jinhua HAN Bingqiang KE Changming 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2024年第5期1246-1252,共7页
It was found that silica fume can reduce the maximum hydration heat release rate of cement by microcalorimetry,inhibit CAH_(10),promote the generation of C_(3)AH_(6)and strätlingite C_(2)ASH_(8),or promote the co... It was found that silica fume can reduce the maximum hydration heat release rate of cement by microcalorimetry,inhibit CAH_(10),promote the generation of C_(3)AH_(6)and strätlingite C_(2)ASH_(8),or promote the conversion of CAH_(10)to C_(3)AH_(6).Sodium tripolyphosphate can retard the early hydration of cement,have a slight effect on 1 d hydration products of cement and inhibit the generation hydration products.Sodium tripolyphosphate and silica fume can promote the early hydration of cement,advance the formation of C_(2)ASH_(8)or the conversion from CAH_(10)to C_(3)AH_(6)at 1 d. 展开更多
关键词 high aluminum cement silica fume dispersing agent HYDRATION
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Carbonation of Pure Minerals in Portland Cement:Evolution in Products as a Function of Water-to-solid Ratio
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作者 XIONG Kun SHANG Xiaopeng +1 位作者 LI Hongyan WANG Dan 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2024年第5期1214-1222,共9页
Minerals in Portland cement including tricalcium silicate(C_(3)S),β-dicalcium silicate(β-C_(2)S),tricalcium aluminate(C_(3)A),and tetracalcium ferroaluminate(C_(4)AF),show a significantly different activity and prod... Minerals in Portland cement including tricalcium silicate(C_(3)S),β-dicalcium silicate(β-C_(2)S),tricalcium aluminate(C_(3)A),and tetracalcium ferroaluminate(C_(4)AF),show a significantly different activity and product evolution for CO_(2)curing at various water-to-solid ratios.These pure minerals were synthesized and subject to CO_(2)curing in this study to make an in-depth understanding for the carbonation properties of cement-based materials.Results showed that the optimum water-to-solid ratios of C_(3)S,β-C_(2)S,C_(3)A and C_(4)AF were 0.25,0.15,0.30 and 0.40 for carbonation,corresponding to 2 h carbonation degree of 38.5%,38.5%,24.2%,and 21.9%,respectively.The produced calcite duringβ-C_(2)S carbonation decreased as the water-to-solid ratio increased,with an increase in content of metastable CaCO_(3)of vaterite and aragonite.The thermodynamic stability of CaCO_(3)produced during carbonation was C_(3)A>C_(4)AF>β-C_(2)S>C_(3)S.The carbonation degree of Portland cement was predicted based on the results of pure minerals and the composition of cement,and the error of predicted production of CaCO_(3)was only 1.1%,which provides a potential method to predict carbonation properties of systems with a complex mineral composition. 展开更多
关键词 accelerated carbonation portland cement calcium carbonate water-to-solid ratio
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Microstructural evolution and strengthening mechanism of aligned steel fiber cement-based tail backfills exposed to electromagnetic induction
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作者 Xihao Li Shuai Cao Erol Yilmaz 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2024年第11期2390-2403,共14页
Cemented tailings backfill(CTB)not only boosts mining safety and cuts surface environmental pollution but also recovers ores previously retained as pillars,thereby improving resource utilization.The use of alternative... Cemented tailings backfill(CTB)not only boosts mining safety and cuts surface environmental pollution but also recovers ores previously retained as pillars,thereby improving resource utilization.The use of alternative reinforcing products,such as steel fiber(SF),has continuously strengthened CTB into SFCTB.This approach prevents strength decreases over time and reinforces its long-term durability,especially when mining ore in adjacent underground stopes.In this study,various microstructure and strength tests were performed on SFCTB,considering steel fiber ratio and electromagnetic induction strength effects.Lab findings show that combining steel fibers and their distribution dominantly influences the improvement of the fill’s strength.Fill’s strength rises by fiber insertion and has an evident correlation with fiber insertion and magnetic induction strength.When magnetic induction strength is 3×10^(-4) T,peak uniaxial compressive stress reaches 5.73 MPa for a fiber ratio of 2.0vol%.The cracks’expansion mainly started from the specimen’s upper part,which steadily expanded downward by increasing the load until damage occurred.The doping of steel fiber and its directional distribution delayed crack development.When the doping of steel fiber was 2.0vol%,SFCTBs showed excellent ductility characteristics.The energy required for fills to reach destruction increases when steel-fiber insertion and magnetic induction strength increase.This study provides notional references for steel fibers as underground filling additives to enhance the fill’s durability in the course of mining operations. 展开更多
关键词 electromagnetic induction steel fiber cemented tailings backfill strength microstructure
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Recycling arsenic-containing bio-leaching residue after thermal treatment in cemented paste backfill:Structure modification,binder properties and environmental assessment
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作者 Dengfeng Zhao Shiyu Zhang Yingliang Zhao 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2024年第10期2136-2147,共12页
The substantial arsenic(As)content present in arsenic-containing bio-leaching residue(ABR)presents noteworthy environ-mental challenges attributable to its inherent instability and susceptibility to leaching.Given its... The substantial arsenic(As)content present in arsenic-containing bio-leaching residue(ABR)presents noteworthy environ-mental challenges attributable to its inherent instability and susceptibility to leaching.Given its elevated calcium sulfate content,ABR exhibits considerable promise for industrial applications.This study delved into the feasibility of utilizing ABR as a source of sulfates for producing super sulfated cement(SSC),offering an innovative binder for cemented paste backfill(CPB).Thermal treatment at varying temperatures of 150,350,600,and 800℃ was employed to modify ABR’s performance.The investigation encompassed the examination of phase transformations and alterations in the chemical composition of As within ABR.Subsequently,the hydration characteristics of SSC utilizing ABR,with or without thermal treatment,were studied,encompassing reaction kinetics,setting time,strength development,and microstructure.The findings revealed that thermal treatment changed the calcium sulfate structure in ABR,consequently impacting the resultant sample performance.Notably,calcination at 600℃ demonstrated optimal modification effects on both early and long-term strength attributes.This enhanced performance can be attributed to the augmented formation of reaction products and a densified micro-structure.Furthermore,the thermal treatment elicited modifications in the chemical As fractions within ABR,with limited impact on the As immobilization capacity of the prepared binders. 展开更多
关键词 cemented paste backfill bio-leaching residue arsenic immobilization binder hydration CALCINATION
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Effect of Sintering Temperature on the Microstructure and Mechanical Properties of Nanocrystalline Cemented Carbide
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作者 陈先富 刘颖 +1 位作者 YE Jinwen WANG Lu 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2024年第3期664-672,共9页
WC-Co nanocrystalline nitrogen-containing cemented carbides were prepared by vacuum sintering and low pressure sintering.The sintering processes of Cr_(2)(C,N)doped nano WC-Co powders were studied by using thermogravi... WC-Co nanocrystalline nitrogen-containing cemented carbides were prepared by vacuum sintering and low pressure sintering.The sintering processes of Cr_(2)(C,N)doped nano WC-Co powders were studied by using thermogravimetric analysis(TGA)and differential scanning calorimetry(DSC).The effect of sintering temperature on the microstructure and mechanical properties of nanocrystalline cemented carbide was studied by scanning electron microscope(SEM),high resolution transmission electron microscope(HRTEM)and mechanical property test.The results showed that the nano WC grains began to grow in the solid phase sintering stage.A high-performance nano-nitrogen-containing cemented carbide with uniform microstructure and good interfacial bonding can be obtained by increasing the sintering temperature to 1380℃.It has a transverse rupture strength(TRS)of 5057 MPa and a hardness of 1956 HV30. 展开更多
关键词 nano nitrogen cemented carbide sintering temperature MICROSTRUCTURE mechanical properties
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Properties and Characterization of Two Clays Raw Material from Mountain District (West of Côte d’Ivoire) for Use in Low-Carbon Cements
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作者 Wedjers Max Robin Manouan Bi Irié Hervé Gouré Doubi +3 位作者 Lébé Prisca Marie-Sandrine Kouakou Atta Kouamé Brice Koffi Alfred Niamien Kouamé Namory Méité 《Advances in Materials Physics and Chemistry》 CAS 2024年第8期137-145,共9页
This work was devoted to the study of the physico-chemical properties of two clay minerals from the Mountain District (West Côte d'Ivoire) referenced ME1 and ME2. These samples were characterized by the exper... This work was devoted to the study of the physico-chemical properties of two clay minerals from the Mountain District (West Côte d'Ivoire) referenced ME1 and ME2. These samples were characterized by the experimental techniques, such as X-ray diffraction (XRD), Infrared spectroscopy (IR), Inductively Coupled Plasma Atomic Emission Spectrometry (ICP-AES), Differential Thermal Analysis and Thermogravimetry (DTA-TG), Brunauer, Emett and Teller method (BET), laser particle size analysis and Scanning Electron Microscope (SEM). The main results of these analyses reveal that the two clay samples mainly contain quartz (52.91% for ME1 and 51.72% for ME2), kaolinite (36.60% for ME1 and 41.6% for ME2) and associated phases, namely goethite and hematite (13.47% for ME1 and 11.00% for ME2). The specific surface values obtained for samples ME1 and ME2 are 34.78 m2/g and 29.18 m2/g respectively. The results obtained show that the samples studied belong to the kaolinite family. After calcination, they could have good pozzolanic activity and therefore be used in the manufacture of low-carbon cements. 展开更多
关键词 QUARTZ KAOLINITE Mountain District Low-Carbon cements
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Preparation and Reinforcement Adaptability of Jute Fiber Reinforced Magnesium Phosphate Cement Based Composite Materials
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作者 刘芯州 郭远臣 +3 位作者 WANG Rui XIANG Kai WANG Xue YE Qing 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2024年第4期999-1009,共11页
To improve the brittleness characteristics of magnesium phosphate cement-based materials(MPC)and to promote its promotion and application in the field of structural reinforcement and repair,this study aimed to increas... To improve the brittleness characteristics of magnesium phosphate cement-based materials(MPC)and to promote its promotion and application in the field of structural reinforcement and repair,this study aimed to increase the toughness of MPC by adding jute fiber,explore the effects of different amounts of jute fiber on the working and mechanical properties of MPC,and prepare jute fiber reinforced magnesium phosphate cement-based materials(JFRMPC)to reinforce damaged beams.The improvement effect of beam performance before and after reinforcement was compared,and the strengthening and toughening mechanisms of jute fiber on MPC were explored through microscopic analysis.The experimental results show that,as the content of jute fiber(JF)increases,the fluidity and setting time of MPC decrease continuously;When the content of jute fiber is 0.8%,the compressive strength,flexural strength,and bonding strength of MPC at 28 days reach their maximum values,which are increased by 18.0%,20.5%,and 22.6%compared to those of M0,respectively.The beam strengthened with JFRMPC can withstand greater deformation,with a deflection of 2.3 times that of the unreinforced beam at failure.The strain of the steel bar is greatly reduced,and the initial crack and failure loads of the reinforced beam are increased by 192.1%and 16.1%,respectively,compared to those of the unreinforced beam.The JF added to the MPC matrix dissipates energy through tensile fracture and debonding pull-out,slowing down stress concentration and inhibiting the free development of cracks in the matrix,enabling JFRMPC to exhibit higher strength and better toughness.The JF does not cause the hydration of MPC to generate new compounds but reduces the amount of hydration products generated. 展开更多
关键词 magnesium phosphate cement jute fiber reinforcement of damaged beam flexural behavior
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Influence of Recycled Concrete Fine Powder on Durability of Cement Mortar
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作者 Yadong Bian Xuan Qiu +2 位作者 Jihui Zhao Zhong Li Jiana Ouyang 《Fluid Dynamics & Materials Processing》 EI 2024年第1期45-58,共14页
In this paper,the durability of cement mortar prepared with a recycled-concrete fine powder(RFP)was examined;including the analysis of a variety of aspects,such as the carbonization,sulfate attack and chloride ion ero... In this paper,the durability of cement mortar prepared with a recycled-concrete fine powder(RFP)was examined;including the analysis of a variety of aspects,such as the carbonization,sulfate attack and chloride ion erosion resistance.The results indicate that the influence of RFP on these three aspects is different.The carbonization depth after 30 days and the chloride diffusion coefficient of mortar containing 10%RFP decreased by 13.3%and 28.19%.With a further increase in the RFP content,interconnected pores formed between the RFP particles,leading to an acceleration of the penetration rate of CO_(2)and Cl^(−).When the RFP content was less than 50%,the corrosion resistance coefficient of the compressive strength of the mortar was 0.84-1.05 after 90 days of sulfate attack.But the expansion and cracking of the mortar was effectively alleviated due to decrease of the gypsum production.Scanning electron microscope(SEM)analysis has confirmed that 10%RFP contributes to the formation of a dense microstructure in the cement mortar. 展开更多
关键词 Recycled concrete fine powder cement mortar CARBONIZATION SULFATE chloride ion DURABILITY
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An Investigation into the Performances of Cement Mortar Incorporating Superabsorbent Polymer Synthesized with Kaolin
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作者 Xiao Huang Jin Yang 《Fluid Dynamics & Materials Processing》 EI 2024年第6期1393-1406,共14页
Cement-based materials are fundamental in the construction industry,and enhancing their properties is an ongoing challenge.The use of superabsorbent polymers(SAP)has gained significant attention as a possible way to i... Cement-based materials are fundamental in the construction industry,and enhancing their properties is an ongoing challenge.The use of superabsorbent polymers(SAP)has gained significant attention as a possible way to improve the performance of cement-based materials due to their unique water-absorption and retention properties.This study investigates the multifaceted impact of kaolin intercalation-modified superabsorbent polymers(K-SAP)on the properties of cement mortar.The results show that K-SAP significantly affects the cement mortar’s rheological behavior,with distinct phases of water absorption and release,leading to changes in workability over time.Furthermore,K-SAP alters the hydration kinetics,delaying the exothermic peak of hydration and subsequently modifying the heat release kinetics.Notably,K-SAP effectively maintains a higher internal relative humidity within the mortar,reducing the autogenous shrinkage behavior.Moreover,K-SAP can have a beneficial effect on pore structure and this can be ascribed to the internal curing effect of released water from K-SAP. 展开更多
关键词 Superabsorbent polymer KAOLIN cement mortar rheological behavior autogenous shrinkage
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Treatment of Synovial Cysts in Relation to the Tibial Tunnel of Anterior Cruciate Ligament Grafts by Filling the Tunnel with Acrylic Cement
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作者 Saint Luc Mungina Sedou Charlène Tshitala Mbombo +6 位作者 Yannick Toko Kiama Kevin Ndangi Ezechiel Nkodia Dieudonné Mwangala Rossyl Kivudi Dominique Saragaglia Luc Mokassa Bakumobatane 《Surgical Science》 2024年第4期289-298,共10页
Introduction: Synovial cyst of the tibial tunnel in connection with anterior cruciate ligament (ACL) reconstruction is a rare but particularly troublesome complication. Medical treatment is often doomed to failure, an... Introduction: Synovial cyst of the tibial tunnel in connection with anterior cruciate ligament (ACL) reconstruction is a rare but particularly troublesome complication. Medical treatment is often doomed to failure, and surgical treatment usually consists of excising the cyst and filling the tunnel with bone. The aim of this study was to evaluate the results of filling the tunnel with acrylic cement. Hypothesis: Filling the tibial bone tunnel with acrylic cement should eliminate communication between the joint cavity and the pre-tibial surface and prevent cyst recurrence. Patients and Methods: This retrospective series is composed of 13 patients, 9 men and 4 women, mean age 48.5 years (31 to 64) operated on between 2011 and 2019 for an intra- and extraosseous synovial cyst consecutive to the tibial tunnel of an ACL graft. Between 1983 and 2016, 12 of the patients had had a bone graft without bone block fixation (DI-DT or Mac Intosh) and one patient, a bone-bone transplant (KJ). The cyst was of variable size, located on the anteromedial aspect of the proximal end of the tibia, and often painful, warranting consultation. At the time of the initial operation, 9 patients had undergone meniscectomies (6 medial, 2 lateral, 1 double). In 7 knees, there were 7 cartilage lesions in the femorotibial and/or patellofemoral compartments (one stage 1 lesion, 2 stage 2 lesions, 4 stage 3 lesions, and no stage 4 lesions). Only 2 knees had neither cartilage nor meniscus lesions. After curettage of the bone tunnel /− removal of the non-resorbed or PEEK interference screw, the tunnel was filled with acrylic cement /− reinforced with a ligament staple to prevent expulsion. All patients underwent regular follow-up consultations until recovery. Results: At a maximum follow-up of 8 years, only 1 cyst recurred, representing a 7.69% failure rate. It was reoperated with another technique, which involved filling the tibial bone tunnel with bone graft taken from a half-bank head. After recovery, the cyst healed definitively. All patients were able to return to their previous activity within 15 days of surgery. Conclusion: Filling the tibial tunnel with acrylic cement reinforced /− with a ligament staple is a reliable and rapid solution for the treatment of intra- and extra-articular synovial cysts in relation to the tibial tunnel of ACL grafts. 展开更多
关键词 Arthro-Synovial Cyst Tibial Tunnel ACL Graft FILLING Acrylic cement
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Assessment of Heavy Metals Contamination of Topsoil and Street Dust around Cement Factory in Southern Jordan
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作者 Omar Ali Al-Khashman Alia Omar Al-Khashman +2 位作者 Navasingh Rajesh Jesudoss Hynes Hani M. Alnawafleh Pitchumani Shenbaga Velu 《Journal of Environmental Protection》 2024年第6期672-696,共25页
Evaluation of assessment of the metal processes governing the metals distribution in soil and dust samples is very significant and protects the health of human and ecological system. Recently, special attention has gi... Evaluation of assessment of the metal processes governing the metals distribution in soil and dust samples is very significant and protects the health of human and ecological system. Recently, special attention has given to the assessment of metals pollution impact on soil and dust within industrial areas. This study aims to assess the metal contamination levels in the topsoil and street dust around the cement factory in Qadissiya area, southern Jordan. The levels of seven metals (namely Fe, Zn, Cu, Pb, Cr, Cd, and Mn) were analyzed using Flame Atomic Absorption Spec-trophotometer (FAAS) to monitor, evaluate, and to compare topsoil and road dust pollution values of metals of the different types of urban area. The physicochemical parameters which believed to affect the mobility of metals in the soil of the study area were determined such as pH, EC, TOM, CaCO3 and CEC. The levels of metal in soil samples are greater on the surface but decrease in the lower part as a result of the basic nature of soil. The mean values of the metals in soil can be arranged in the following order: Zn > Pb > Mn > Fe > Cu > Cr > Cd. The relatively high concentration of metals in the soil sample was attributed to anthropogenic activities such as traffic emissions, cement factory and agricultural activities. Correlation coefficient analysis and the spatial distribution of indices and the results of statistical analysis indicate three groups of metals: Fe and Mn result by natural origin, Zn, Pb, Cu and Zn result by anthropogenic origin (mainly motor vehicle traffic and abrasion of tires) while Cd is mixed origin. The higher content level values of metals of anthropogenic source in soil samples indicate that it is a source of contamination of air in the studied area. . 展开更多
关键词 cement Dust Heavy Metals Contamination Risk Assessment Statistical Analysis JORDAN
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