Influence of CG With High Content of Metallic Particles as a Cement Admixture on Cement Strength

Copper gangue (CG), containing a large amount of water with grain sizes of 0.037 to 0.10mm,is an inactive industrial waste generated from copper refineries. When it is dried and used as a cement admixture, the influence of the presence of finely dispersed metallic particles in CG on the microstructure and compressive strength of cement paste has been studied.The results show that the higher the replacement of CG is,the lower the compressive strength of cement mortar is.However,the long-term strength of the specimens with 10% CG,especially after being cured for 3 months,approached to that of the plain mortar.Its mechanism was studied by an electron probe X-ray microanalyzer (EPXMA).The results indicate that a small quantity of Fe(OH) 3·nH 2O slowly formed from Fe 2O 3 in the presence of Ca(OH) 2, free CaO and MgO of the clinker also slowly hydrated and formed Ca(OH) 2 and Mg(OH) 2 respectively,so the hardened cement paste became more compact.

Magnetic susceptibility measurements on metakaolin admixtured cement hydrated with ground water and sea water

The role of metakaolin in the properties of Portland cement hydrated with ground water and sea water was described by magnetic susceptibility study. Cement pastes containing 0wt%, 10wt%, 20wt% and 30wt% replacement of metakaolin and in a water/cement （W/C） ratio of 0.4 were prepared. The susceptibility at different hydration periods was determined by Faraday Curie balance and it was related to the changes in setting time and compressive strength of admixtured cement. Compared with sea water-treated cement paste, the magnetic susceptibility of ground water-treated cement paste is higher in value. The observed result shows that, irrespective of water, the magnetic susceptibility increases with increasing metakaolin percentage replacement level in cement.

STRENGTH EFFECT OF F MINERAL ADMIXTURE ON CEMENT CONCRETE

F mineral admixture (FMA) is made of the fin- ely divided powder of natural zeolite with a bit of other agent. When FMA is used to displace about 10% (by weight) of the ordinary portland cement (OPC) (strength grade 575#) in concrete and mixed with a suitable amount of super plasticizer (w/c =0.31-0.35), then a high-strength concrete with compressive strength about 80 MPa and slump about 180 MM can be obtained. The strength of this concrete is about 10-15% higher than that of the corresponding concrete mixing with pure OPC, and its bleeding decreases greatly. It makes no segre- gation and separation, and thus it satisfies the requirement of pumping concrete in construction.

Resource utilization of slag from desulphurization and slag skimming:A comprehensive recycling process of all components

In order to make the slag from desulphurization and slag skimming(SDSS)to be comprehensively recycled and utilized,a combined process of beneficiation and building materials preparation was proposed to recover iron from SDSS,meanwhile to apply the remaining slag tailings as cement admixture.From this process,three iron-rich products were recovered in stages by clean gravity-magnetic separation,slag tailings were left.Slag powder was prepared by ultrafine grinding of slag tailings.The stability,setting time and cement mortar strength of the slag tailings cements(STC)which were mixed with Portland cement and slag powder were studied respectively.The results showed that a proper overall performance still could be obtained at the slag powder content of 30%.Chemical composition analysis,X-ray diffraction(XRD)analysis,metallographic microscope and scanning electron microscope(SEM)analysis were employed to assess the characteristics of the SDSS and the products obtained from the whole process.The results indicated that the three iron-rich products could be used as a raw material for steelmaking and ironmaking and the relatively large amount of calcium silicate(C_(2)S)and tricalcium silicate(C_(3)S)in the slag tailings make the addition of slag powder into the Portland cement feasible.