Materials,preparation,performances and mechanism of polyurethane modified asphalt and its mixture:A systematic review

With the rapid development of asphalt pavement technology,it has attracted considerable attention to improving the durability of asphalt pavement.An effective action is to use modified asphalt with high performance and durability.Polyurethane(PU)has been used in asphalt pavement engineering to enhance the durability and service life of asphalt pavement because of its excellent high-temperature performance,toughness,wear resistance,aging resistance and oil resistance.However,PU modified asphalt technology is still in the exploratory stage.The preparation,modification mechanism and working performances of PU modified asphalt need to be further clarified.Therefore,this paper summarized the research progress of PU modified asphalt and its mixture.The composition of PU modified asphalt was introduced.The addition methods of PU materials and preparation process parameters of the PU modified asphalt were determined.The modification mechanism of PU on asphalt was discussed.The effects of polyurethane on asphalt were analyzed and the road performances of its mixture were evaluated.Finally,the development tendency towards PU modified asphalt and its mixture were forecasted.

Research Progress of Epoxy Asphalt Material for Roads

Asphalt is a semi-solid or solid mixture formed by hydrocarbons and non-metallic elements.It is widely applied in the fields of building waterproofing and road paving.Asphalt is a low noise,durable,and renewable pavement material.However,asphalt materials have some shortcomings such as liquefying at high temperatures and brittleness at low temperatures,which are less adaptable to different environments.Therefore,people have gradually shifted their focus to asphalt modification.This paper presents an in-depth analysis and research on the composition,structure,and performance of epoxy asphalt materials for roads,so that this material can be widely used.

Analysis of New Materials Application in Municipal Road Construction

In order to promote the development of road traffic in our country,it is necessary to strengthen the research on municipal road construction technology,constantly innovate construction technology and construction technique,and then effectively ensure the rapid development of urban traffic.This paper mainly elaborates on asphalt road surface regeneration technology,modified asphalt concrete,concrete road surface anti-cracking technology,three-dimensional printing technology,composite material road surface,polymer composite materials,etc.,to ensure the development of urban transportation and the quality of municipal road projects.

GMA material design and construction quality control for asphalt pavement of steel box girder: Case study of the Hong Kong–Zhuhai–Macao Bridge

To improve the quality of the Hong Kong–Zhuhai–Macao Bridge paving project,a new paving layer material,Guss-mastic asphalt(GMA),was proposed in this paper by combining the advantages of two types of cast asphalt mixtures:mastic asphalt(MA)and Guss asphalt(GA).Based on the characteristics of GMA,to simulate its actual production process,this study developed a small-simulated cooker mixing equipment.Moreover,the flow degree,60C dynamic stability,and impact toughness were proposed to be used to evaluate the construction and ease,high temperature stability,and fatigue resistance of GMA cast asphalt mixtures,respectively.Moreover,the quality control standards for GMA paving materials by indoor tests,field trial mix GMA material performance tests,and accelerated loading tests were finalized.The study showed that the developed simulated cooker yielded consistent mixing results in the same working environment as the engineering cooker device.Increasing the coarse aggregate incorporation rate,coarsening the mastic epure(ME)gradation composition,and using a smaller oil to stone ratio can reduce the flowability of the GMA materials to varying degrees.The four-point bending fatigue life and impact toughness of the different GMA materials are correlated well.A mobility of<20 s,60C dynamic stability of 400–800 times/mm,15C impact toughness of400 N⋅mm,and cooker car mixing temperature control standard of 210C–230C form an appropriate control index system for the design and production of GMA cast asphalt mixtures.Simultaneously,accelerated loading tests verified the accuracy and reliability of the quality control index system that has been used in the GMA paving project of the Hong Kong–Zhuhai–Macao Bridge deck and has achieved good application results.

Generalized Porothermoelasticity of Asphaltic Material

In this work, a mathematical model of generalized porothermoelasticity with one relaxation time for poroelastic half-space saturated with fluid will be constructed in the context of Youssef model (2007). We will obtain the general solution in the Laplace transform domain and apply it in a certain asphalt material which is thermally shocked on its bounding plane. The inversion of the Laplace transform will be obtained numerically and the numerical values of the temperature, stresses, strains and displacements will be illustrated graphically for the solid and the liquid.

Fractional thermoelasticity applications for porous asphaltic materials

A new mathematical model of poro-thermoelasticity has been constructed in the context of a new consideration of heat conduction with fractional order.One-dimensional application for a poroelastic half-space saturated with fluid is considered.The surface of the halfspace is assumed to be traction-free,permeable,and subjected to heating.The Laplace transform technique is used to solve the problem.The inversion of the Laplace transform will be obtained numerically and the numerical values of the temperature,stresses,strains,and displacements will be illustrated graphically for the solid and the liquid.

Performance evaluation of new epoxy resin-based composite phase change materials and their asphalt mixture

In recent years,the temperature-adjusted asphalt pavement has been an extensive concern by scholars in various countries,and this pavement can reduce temperaturerelated diseases.In this study,the shaped composite phase change materials(CPCMs)were successfully synthesized by two processes,which are vacuum impregnation and epoxy curing.Firstly,the applicability of CPCMs in asphalt mixtures was evaluated by microscopic characterization,chemical compatibility,thermal properties,durability,and leakage stability.Secondly,CPCMs were applied to the asphalt mixture to evaluate its temperatureadjusted characteristics and pavement performance.Finally,the performance of the temperature-adjusted asphalt mixture was analyzed by integrating all factors.The research shows that the prepared CPCMs have excellent thermal properties and durability,the phase transition temperature is 48.93℃,and the phase transition enthalpy is 106.5 J/g,which fully meets the requirements for use in pavement.The temperature-adjusted asphalt mixture could alleviate the occurrence of extreme temperature,which was 4.9℃lower than the conventional mixture.The pavement performance of the temperatureadjusted asphalt mixture can meet the specified standards for humid areas.Considering the factors,the recommended amount of CPCMs is 1.5%.The research results provide a basis for the promotion of temperature-adjusted asphalt pavement and effectively support the development of pavement engineering technology.

Preparation of low-cost waterproofing materials

To address the need for producing a cheap,single-component,hot-applied compound joint sealant with high quality for sealing joints and cracks in concrete and flexible pavements without using primer for installation,a hot-applied modified asphalt sealant was produced by blending up about 30% starch into 20% citric acid.The starch and the asphalt cement were mixed at a temperature of above 160 ℃.Thus the waterproofing asphalt was manufactured to protect the surface of various shapes and types from water leakage using the citric acid.Results indicate that this sealant complies with the requirements of ASTM D-1191,D-6690-06a and D-7116-05.The citric acid is a kind of reliable materials for asphalt cement,which can be widely used in paving and waterproofing construction materials,and this offers profound engineering and economic advantages.

Rheological and physicochemical characteristics of asphalt mastics incorporating lime kiln dust and dolomite powder as sustainable fillers

The filler-bitumen interaction mechanism is one of the most essential phases for comprehending the asphalt mixture's performance.However,despite numerous studies,in-depth knowledge of filler-bitumen reciprocity at a microscale level is yet to be ascertained.The goal of this research is to gain a better understanding of the fillerbitumen microscale interaction in terms of the synergy and coaction between the physicochemical and rheological performance of mastics due to filler inclusions.The rheological properties of two sustainable mastics,dolomite powder(DP)and lime kiln dust(LKD),together with a neat PEN 60/70 binder,were analysed based on a temperature sweep at elevated temperature conditions.Meanwhile,frequency sweep and multiple stress creep recovery(MSCR)tests were also conducted at pavement serviceability temperature using the dynamic shear rheometer(DSR).Physicochemical tests using a scanning electron microscope(SEM)and energy dispersive X-rays(EDX)were conducted to analyse the impact of parameters such as particle shape,grain size,texture,and chemical compositions.The DSR test results showcased how the incorporation of fillers in asphalt binder considerably improved the performance of the binder in terms of rutting and fatigue.Likewise,its strain and nonrecoverable compliance parameters were substantially reduced at higher filler and binder concentrations.Physical filler attributes of low rigden voids(R.V),high fineness modulus(FM),and high specific surface area(SSA)led to greater interfacial stiffness and elasticity in LKD mastics compared to DP mastics at different loading frequencies and temperature levels.The SEM/EDX results also indicated that the elemental calcium and carbon composition of each filler component,together with its grain morphology,strongly influenced its rheological performance.

道路沥青紫外老化及抗老化材料研究综述

道路沥青材料在使用过程中由于长期受到太阳光紫外辐射作用会产生紫外老化现象,并且这种现象在紫外辐射强度高的地区更明显。紫外老化会使沥青的物理特性和化学组成发生改变,从而导致沥青黏塑性上升、低温和疲劳性能下降、使用裂缝增加,进而劣化路面的耐久性、影响沥青路面的运营品质和服役寿命。为了防止和延缓紫外老化的产生和发展,可在道路沥青中添加抗老化材料以增强其抵御紫外老化能力,同时延长沥青路面的使用寿命并降低其性能的衰变速率。本文阐述了基于自由基和胶体理论的紫外老化机理;从处理方式、光源与辐射强度选择等方面介绍了室内模拟老化试验条件;总结了紫外老化对沥青物理和流变性能、组分构成、微观形貌、特征峰和官能团等宏微观特性的影响;归纳了现行抗老化材料的优缺点和使用情况。分析表明后期可在老化机理深度、试验方法标准化、室外老化监测、微观数值模拟、抗紫外老化剂针对性和抑制紫外老化措施等方面开展进一步研究。

Towards green asphalt materials with lower emission of volatile organic compounds: A review on the release characteristics and its emission reduction additives

Recently, researchers in the road field are focusing on the development of green asphalt materials with loweremission of volatile organic compounds (VOCs). The characterization methodology of asphalt VOCs and theinfluencing factors on VOCs release have always been the basic issue of asphalt VOCs emission reduction research.Researchers have proposed a variety of asphalt VOCs characterization methodologies, which also have mutuallyirreplaceable characteristics. Asphalt VOCs volatilization is affected by many factors. In this study, asphalt VOCscharacterization methodologies were summarized, including their advantages, disadvantages, characteristics andapplicable requirements. Subsequently, the influencing factors of VOCs release, such as asphalt types and environment conditions, are summarized to provide theoretical support for the emission reduction research. Theclassification and mechanism of newly-development asphalt VOCs emission reduction materials are reviewed. Thereduction efficiencies are also compared to select better materials and put forward the improvement objective ofnew materials and new processes. In addition, the prospects about development of VOCs release mechanism ofasphalt materials during the full life cycle and feasibility research of high-efficiency composite emission reductionmaterials in the future were put forward.

聚氨酯与稀释沥青相互作用的分子动力学模拟

为从分子尺度深入了解聚氨酯与稀释沥青的相互作用,采用Materials Studio软件,分别构建沥青、聚氨酯、聚氨酯-稀释沥青共混模型,并验证模型准确性。基于分子动力学模拟,开展温度和聚氨酯掺量对稀释沥青内聚能密度、溶解度参数、相互作用能、力学性能的影响研究。结果表明:建立的沥青和聚氨酯分子模型较合理,能够表征沥青和聚氨酯真实特性;随着温度的升高,稀释沥青和稀释沥青-聚氨酯共混体系的内聚能密度均呈下降趋势;在[-10℃,100℃]范围内,聚氨酯添加物能够降低稀释沥青的内聚能密度,不同温度下降低幅度平均为15%;在60℃时,稀释沥青与聚氨酯的溶解度参数δ差值最小,各总相互作用能和范德华势能最大,体系最稳定;聚氨酯能够提高稀释沥青的力学参数,并且力学参数与聚氨酯的掺量呈正相关关系。研究对树脂改性冷补沥青混合料具有参考价值。

吸波沥青混合料的制备及微波自愈合特性

吸波材料具有良好的微波传热能力,可用于沥青路面微裂缝自修复。本研究选取了炭黑粉、羰基铁粉和镍锌铁氧体粉3种吸波材料替换部分矿粉制备了SMA-13吸波沥青混合料。通过车辙试验、低温弯曲破坏试验和冻融劈裂试验对比分析了不同吸波沥青混合料的路用性能,并采用半圆弯曲(SCB)试验研究了吸波材料类型、掺量、微波加热时间等因素对吸波沥青混合料表面温度分布和自愈合性能的影响。利用扫描电子显微镜(SEM)和X射线衍射(XRD)分析吸波材料的微观特性。结果表明,随吸波材料掺量从10%增至30%,炭黑粉沥青混合料的动稳定度和冻融劈裂强度比都呈现出逐渐上升趋势,而低温弯曲应变则表现出先增加后减小的特征;羰基铁粉沥青混合料动稳定度和低温弯曲应变均呈现先增加后减小的趋势,而冻融劈裂强度比表现出逐渐减小的特征;镍锌铁氧体粉沥青混合料动稳定度和低温弯曲应变均呈现逐渐减小趋势,而冻融劈裂强度比则与之相反。吸波沥青混合料的表面温度随着吸波材料掺量和微波加热时间的增加而逐渐上升,能够快速达到沥青混合料裂缝面的愈合温度,从而增强沥青混合料的微波自愈合性能。

不同种类道路沥青材料异味特征及析源分析

随着我国社会经济逐渐向绿色可持续转型,沥青路面铺筑过程中的异味污染成为不可忽视的环境问题。本研究针对八种不同的道路沥青材料使用过程中产生的挥发性物质,通过气相色谱-质谱联用仪(GC-MS)和气体检测仪进行定性与定量分析。在此基础上,结合异味阈值计算各物质异味活度值(OAV),通过异味活度值加和(SOAV)的方法对沥青异味进行分析,并对异味污染物中各组分及其异味贡献进行进一步的析源工作。研究结果表明,沥青挥发物的浓度与异味活度值加和并没有完全的正相关关系,胶粉改性沥青挥发物浓度及异味活度值加和相较于其他沥青均有显著提高。对八种不同种类道路沥青材料异味特征进行分析得出:六种组分对沥青异味的产生有贡献,其中,苯系物、醛类以及硫化氢对沥青异味的贡献较大,烯烃类以及酮类是胶粉改性沥青挥发物中特有的异味贡献组分。

沥青抑烟净味剂功能性验证研究

该研究旨在探究物理吸附材料和化学抑制材料对沥青烟气中颗粒物和苯类有机物释放的影响,以减少沥青烟气对施工人员健康和环境造成的危害。在实验室内模拟了沥青实际使用情况,采用聚四氟乙烯滤膜和环己烷吸收液对沥青烟气进行收集,通过重量法和气相色谱质谱联用试验研究了活性炭和净味剂B的抑制效果,并进一步考虑了二者对沥青路用性能的影响。通过中心复合模型得到了复合抑烟净味剂的最佳配方,即活性炭掺量为3.28%,净味剂B掺量为3‰。通过红外光谱试验和核磁共振氢谱试验得到了抑烟净味剂对沥青微观结构的影响,结果表明净味剂B主要由酯类化合物组成,复合抑烟净味剂的主要原理是通过使支链碳链变长,提高沥青沸点,从而达到了抑烟净味的效果。

动态剪切流变仪校准用标准物质研究分析

为填补我国在动态剪切流变仪校准用黏度标准物质空白,对CANNON公司黏度标准物质N2700000SP进行成分分析、黏温性能、流变性能以及动力黏度测试方法研究。通过红外光谱分析,验证N2700000SP主要成分为聚异丁烯。为量化温度对黏度的影响,通过对标准物质的温度扫描,计算得到其在64℃附近黏温系数为-4.5%℃-1;采用剪切速率、温度扫描模式测定其黏温性和流变性能,明确N2700000SP为假塑性非牛顿流体,测试时必须采用合适的剪切速率或角频率。对毛细管法测得的动力黏度结果与标准值进行比较,结果表明毛细管测量方法可靠。研究可支撑我国动态剪切流变仪检校用标准物质研制。

沥青路面用复合相变材料研究进展

为缓解夏季热岛效应和减少路面病害,“凉爽路面”已从概念得到落实,其中相变材料因其自动控温的特性受到了道路工程研究人员青睐。介绍了相变材料的分类及其特点,概述了路面传热机理模型和影响因素。针对直掺相变沥青性能劣化的问题,提出了复合相变材料技术并展开介绍其应用效果。还总结归纳了相变改性沥青控温效果测试方法的优缺点,综述了复合相变材料对沥青及沥青混合料的降温效果和性能影响,最后指出了当前路用相变材料应深入研究的方向,并对复合相变材料泄漏问题提出了改进方法与展望。

掺钢渣沥青混合料体积膨胀性研究

钢渣作为中国存量较大的工业固体废弃物,目前对其利用率仅为30%,限制钢渣大规模资源化利用的主要原因在于钢渣所含的非稳定性物质在富水条件下易发生水化反应,造成钢渣体积膨胀。通过采用直线位移传感器(linear variable displacement transducer, LVDT)测试法对掺钢渣沥青混合料小梁试件膨胀率进行测定,探究钢渣掺配比例、混合料油石比以及掺入钢渣粒径对混合料膨胀率大小的影响。结果表明:混合料中钢渣掺入不超过50%,混合料实际油石比在最佳油石比基础上提高1.5%,且使用大粒径钢渣,能更有效控制混合料膨胀率。此外,钢渣中的活性物质不断进行水化反应,将导致局部膨胀和集料剥落等损害发生。

沥青路面全深式水泥稳定冷再生混合料性能研究

在半刚性基层沥青路面结构性养护设计中,将基层旧料和沥青路面旧料混合冷再生作为一种低碳工程技术。为探讨冷再生基层旧料和沥青路面旧料的不同比例混合料强度规律,本文以现场取回的沥青层RAP料和基层RBM料为原材料,在调查面层和基层料比例的基础上,就沥青混合料强度进行研究。选择了三种面层和基层混合料比例,以五种水泥掺量占比进行不同种类混合料的无侧限抗压强度试验,得出了其抗压强度的规律。综合考虑混合料强度与稳定性、经济性,采用33∶67的面基层用料比例较优;水泥掺量在5%~8%时随着水泥用量的增加再生混合料的强度增长较快,建议水泥掺量大于5%。