Resource utilization of drinking water treatment aluminum sludge in green cementing materials: Hydration characteristics and hydration kinetics

As a byproduct of water treatment,drinking water treatment aluminum sludge(DWTAS)has challenges related to imperfect treatment and disposal,which has caused potential harm to human health and the environment.In this paper,heat treatment DWTAS as a supplement cementitious material was used to prepare a green cementing material.The results show that the 800℃ is considered as the optimum heat treatment temperature for DWTAS.DWTAS-800℃ is fully activated after thermal decomposition to form incompletely crystallized highly activeγ-Al2O3 and active SiO_(2).The addition of DWTAS promoted the formation of ettringite and C-(A)-S-H gel,which could make up for the low early compressive strength of cementing materials to a certain extent.When cured for 90 days,the compressive strength of the mortar with 30% DWTAS-800℃ reached 44.86 MPa.The dynamic process was well simulated by Krstulovi′c-Dabi′c hydration kinetics model.This study provided a methodology for the fabrication of environmentally friendly and cost-effective compound cementitiousmaterials and proposed a“waste-to-resource”strategy for the sustainable management of typical solid wastes.

An Effective Hybrid Model of ELM and Enhanced GWO for Estimating Compressive Strength of Metakaolin-Contained Cemented Materials

This research proposes a highly effective soft computing paradigm for estimating the compressive strength(CS)of metakaolin-contained cemented materials.The proposed approach is a combination of an enhanced grey wolf optimizer(EGWO)and an extreme learning machine(ELM).EGWO is an augmented form of the classic grey wolf optimizer(GWO).Compared to standard GWO,EGWO has a better hunting mechanism and produces an optimal performance.The EGWO was used to optimize the ELM structure and a hybrid model,ELM-EGWO,was built.To train and validate the proposed ELM-EGWO model,a sum of 361 experimental results featuring five influencing factors was collected.Based on sensitivity analysis,three distinct cases of influencing parameters were considered to investigate the effect of influencing factors on predictive precision.Experimental consequences show that the constructed ELM-EGWO achieved the most accurate precision in both training(RMSE=0.0959)and testing(RMSE=0.0912)phases.The outcomes of the ELM-EGWO are significantly superior to those of deep neural networks(DNN),k-nearest neighbors(KNN),long short-term memory(LSTM),and other hybrid ELMs constructed with GWO,particle swarm optimization(PSO),harris hawks optimization(HHO),salp swarm algorithm(SSA),marine predators algorithm(MPA),and colony predation algorithm(CPA).The overall results demonstrate that the newly suggested ELM-EGWO has the potential to estimate the CS of metakaolin-contained cemented materials with a high degree of precision and robustness.

RE-USE OF SPENT CATALYST FROM OIL-CRACKING REFINERIES AS SUPPLEMENTARY CEMENTING MATERIAL

Advanced technological achievements and the continuous growth of economy have made the disposal, recycle and reuse of industrial by-products a severe challenge. The cement industry is considered one of the key sectors in this effort in successfully （in terms of not extenuating but improving some of the properties of the final product） absorbing large quantities of solid wastes, either as aggregates or as secondary cementitious materials. This not only contributes to the creation of an energy and CO2-emission depository （as commonly used raw materials are spared）, but also simultaneously alleviates the acute environmental burden caused by the irresponsible disposal of such by-products. In this study, the possibility of reusing spent fluid catalytic-cracking catalyst （FCC） as a supplementary cementing material （SCM） was examined. A series of tests were conducted, initially aiming at characterizing the material and thereafter evaluating its pozzolanic activity and its effect on the mechanical properties of blended cements. Major findings in this investigation revealed that the use of FCC as a mineral admixture in cement is feasible, strengthening the belief that siliceous glassy residues should represent a steady supply for the construction sector.

Improvement of Cemented Gangue Backfill Material with Barium Hydroxide in Acid Mine Water

As a kind of green concrete,the mechanical properties and durability of cemented gangue backfill material(CGBM)will be affected if they are in acid mine water with sulfate ions in the long term.To improve the performance of CGBM in acid mine water with sulfate ions,CGBM specimens with different doses of barium hydroxide were immersed in sulfuric acid solutions of different concentrations for 270 days.The changes of mass,ultrasonic pulse velocity(UPV)and compressive strength of the specimens at different ages were analyzed.Scanning electron microscopy(SEM)and X-ray diffraction(XRD)were used to analyze the microstructure and composition of the specimens.The results show that incorporation of barium hydroxide into CGBM specimen can promote the formation of barium sulfate precipitation and inhibit the generation of corrosion products such as ettringite.Meanwhile,barium sulfate precipitation blocks the pore channel invaded by sulfuric acid solution,delaying the progress of corrosion reaction and making the interior of CGBM specimen more complete.And the specimen with 2.0 kg/m^(3)barium hydroxide was more effective in improving performance.This study provides a basis for the ratio design of CGBM in acid mine water with sulfate ions.

Physicochemical Characteristics of Some Cameroonian Pozzolans for Use in Sustainable Cement Like Materials

In the present study, physico-chemical investigations have been carried out on the possibility of using Cameroonian volcanic or clay pozzolans as raw material for geopolymer or pozzolanic binder. The research had made some suggestive results and conclusions. Powders of less than 100 μm of five sampled pozzolans from volcanic or clay origins have been subjected to chemical and mineralogical analysis, BET specific surface, absolute density, granulometry and pozzolanic activity in solution tests. The results obtained showed that, geopolymers or pozzolanic binders can be produced from samples studied. The samples contain significant amounts of glassy or amorphous phase ready to dissolve in an alkaline solution. The high alkali content of volcanic pozzolans makes them more appropriate for geopolymer application. Clay pozzolans are the easier to grind in order to obtain the appropriate fineness and can be used for both geo- polymers and pozzolanic binders.

The Cemented Material Dam： A New, Environmentally Friendly Type of Dam

The first author proposed the concept of the cemented material dam （CMD） in 2009. This concept was aimed at building an environmentally friendly dam in a safer and more economical way for both the dam and the area downstream. The concept covers the cemented sand, gravel, and rock dam （CSGRD）, the rockfill concrete （RFC） dam （or the cemented rockfill dam, CRD）, and the cemented soil dam （CSD）. This paper summarizes the concept and principles of the CMD based on studies and practices in projects around the world. It also introduces new developments in the CSGRD, CRD, and CSD.

Early Carbonation Behavior of High-volume Dolomite Powder-cement Based Materials

Combined with DTG analysis, X-Ray diffraction analysis （XRD） and field emission scanning electron microscopy analysis （FSEM） affiliated with energy dispersive spectrometer analysis （EDS）, the early hydration and carbonation behavior of cement paste compacts incorporated with 30% of dolomite powder at low water to cement ratio （0.15） was investigated. The results showed that early carbonation curing was capable of developing rapid early strength. It is noted that the carbonation duration should be strictly controlled otherwise subsequent hydration might be hindered. Dolomite powder acted as nuclei of crystallization, resulting in acceleration of products formation and refinement of products crystal size. Therefore, as for cement-based material, it was found that early carbonation could reduce cement dosages to a large extent and promote rapid strength gain resulting from rapid formation of products, supplemental enhancement due to water release in the reaction of carbonation, and formation ofnanometer CaCO3 skeleton network at early age.

Assessing geological uncertainty of a cement raw material deposit,southern Vietnam,based on hierarchical simulation

Resource modeling plays a crucial role in raw material quality management for cement manufacturing.Research has shown that geological uncertainty in resource modeling is inevitable and results in risk to future extraction planning and operations of the cement plant.This study aims to assess the geological uncertainty and associated risk in modeling a cement raw material deposit in southern Vietnam.For this deposit,soil,clay,laterite,and limestone are the four primary rock types,controlling the occurrence and spatial distribution of chemical grades.In this study,hierarchical simulation method was used to evaluate the uncertainty.Rock types were first simulated,and the chemical grades conditioning to the rock types were then generated.The results demonstrated the capability of the hierarchical simulation approach to incorporate the uncertainty of rock types in resource modeling and to allow evaluating the risks in providing the desired raw material for the cement plant in the form of grade-tonnage curves.

Preparation and Performance Research of Cement-based Grouting Materials with High Early Strength and Expansion

Main performance of the cement grouting materials made up by Portland cement（PC） and sulphoaluminate cement（SAC） was investigated in this program, a kind of expanding agent（EA） which was mainly constituted by metakaolin and alunite was utilized for the compensation of the shrinkage, the hydration products and micro structure of the grouting materials were researched by X-ray diffraction（XRD） and scanning electron microscopy（SEM）. The results showed that a high expansion rate of the grouting materials could be reached as the expanding agent mixed in 6% of PC mass; the addition of SAC in the S2（PC：SAC：EA=34：6：2.25） brought a further improvement of the expansion rate of the grouting materials, the analysis of XRD and SEM showed that due to the reaction of expanding agent and SAC in the grouting materials, more ettringite crystal was generated, which resulted in a higher early strength, the addition of SAC played an expansion and strength reinforcement role in the grouting materials.

Degradation of Formaldehyde and Benzene by TiO2 Photocatalytic Cement Based Materials

A novel photocatalytic cement based material was prepared. The distribution of TiO2 on the surface of cement was characterized by scanning electron microscope（SEM） and X-ray diffraction（XRD）, which showed the relationship of photocatalysis and presence of TiO2. TiO2 also had an impact on cement hydration, which was studied by thermal analysis. With 300 W UV illuminations, formaldehyde and benzene were degraded efficiently by the prepared photocatalytic cement based materials. 15wt% TiO2/cement showed the highest degradation efficiency and capability. The results show that formaldehyde and benzene can be degraded within 4 and 9 hours, respectively. Besides, inorganic ions can induce TiO2 agglomeration. As a result, the presence of inorganic ions in cement is unfavorable for degradation. The photocatalytic cement based materials were fabricated and the degradation efficiency of formaldehyde was measured on building roof under sunlight illumination. Formaldehyde in glass chamber can be degraded thoroughly within 10 days.

Effect of Natural Zeolite on Performance of Sulfoaluminate Cement-based Planting Cementitious Material

This paper aimed to improve the water-retention performance and basic physical properties of sulfoaluminate cement（SAC）-based planting cementitious material. The effect of natural zeolite on the performance of SAC-based planting material was investigated. The water-retention performance, porosity, compressive strength, and alkalinity had been tested and TG-DSC analysis had been adopted in this paper. Experimental results showed that zeolite was effective to improve the water-retention capacity and 10%, 20% and 30% natural zeolite increased the pore volume of the hardened pastes by 10.6%, 26.0%, and 38.6%, especially pore size below 0.1 μm was increased by 9.7%, 26.2% and 17.5%. And 10% zeolite was beneficial to the compressive strengths of cementitious material and 1, 3, and 28 d compressive strength reached up to 35.9, 55.0, 80.3 MPa. Furthermore zeolite decreased the alkalinity of pore fluid of hardened cementitious material, while the addition of zeolite reached up to 30%, the alkalinity of pore fluid of hardened cementitious material decreased by 8.9%. Therefore zeolite was suitable for improving the performance of SAC-based planting cementitious material.

MODEL OF CEMENT RAW MATERIAL PROPORTION AND ITS SOLUTION

Cement is a kind of colloid material. This paper introduces a model of raw material proportion and quadratic programming for solving the model when three kinds of raw materials are mixed. The calculation of the raw material proportion is easy, and its result is reliable. This model is apt to be realized on micro-computer. This paper indicates the defects of the least square method and compares these two methods through existing instance.

Performance of the Cement Matrix Composite Material With Rubber Powder

The effect of the deferent rubber content substituted for fine aggregate on the mortar performance was studied.The effects of the rubber coated with the coating materials on the mortar compressive strength,bending strength and impact work were discussed.The optimum rubber powder content and the suitable coating material were found.Through the electrical probe test-BEI,SEI and calcium ion distribution,and the slight crack and the interface between the rubber and cement matrix are analyzed.The results show that the rubber powder coated with the surface treatment materials A,B and C has the capability of absorbing a large amount of energy under the compressive and flexural load and the slight cracks of R-C were controlled and restrained.

PROPORTION OF THE CEMENT RAW MATERIAL CALCULATED BY THE LINEAR PROGRAMING

This paper presents a new method .linear programming method. to calculate the proportion of the cement raw material. Its advanlages are as following : good practicability, convenience for analysis, and being easy for controlling. The mathematical model given in the paper is apt to be realized on computer.

Recovery of Mining Wastes in Building Materials: A Review

The use of materials from waste in buildings compensates for the lack of natural resources, solves the problem of waste management and provides an alternative technique for protection of the environment. There are a large number of industrial wastes that are used for full or partial replacement of raw materials in some construction materials. This review assesses mining waste in concrete as a substitute for aggregates and cement;in fired bricks as a substitute for soil;and in road backfill as a substitute for soil. This paper reviews some mining tailings, mine waste rocks and some slags obtained in the exploitation and/or processing of some ores including iron, gold, lead, phosphate, copper, coal, etc. Different physical properties, mechanical properties, chemical properties, heavy metal content, mineralogic composition, geotechnical properties and environmental properties (leaching test) of the mine wastes were examined. The physical, mechanical and environmental properties of the materials obtained by substitution of raw materials by mine waste were examined and compared to reference materials. Mining waste in cementitious materials offers good compressive strengths, while the porosity of the concrete and/or mortar is a factor influencing its toxicity. As for the waste in fired bricks, fired at a temperature of 900°C or more, it offers convincing compressive and flexural strengths. The few research studies obtained on the use of mining waste in road embankments have shown that mining waste can be used as a sub-base layer and backfill as long as it is not toxic. In addition, several other mining wastes require special attention as substitutes for raw materials in construction materials, such as coltan, cobalt.

Exploration on electrical resistance tomography in characterizing the slurry spatial distribution in cemented granular materials

This study investigated the application of electrical resistance tomography(ERT)in characterizing the slurry spatial distribution in cemented granular materials(CGMs).For CGM formed by self-flow grouting,the voids in the accumulation are only partially filled and the bond strength is often limited,which results in difficulty in obtaining in situ samples for quality evaluation.Therefore,it is usually infeasible to evaluate the grouting effect or monitor the slurry spatial distribution by a mechanical method.In this research,the process of grouting cement paste into high alumina ceramic beads(HACB)accumulation is reliably monitored with ERT.It shows that ERT results can be used to calculate the cement paste volume in the HACB accumulation,based on calibrating the saturation exponent n in Archie’s law.The results support the feasibility of ERT as an imaging tool in CGM characterization and may provide guidance for engineering applications in the future.

The Permeability and Strength of Green High Performance Concrete

The permeability,alkali silica reaction,workability and strength of GHPC(green high performance concrete) were studied in this paper.The results show that GHPC has an excellent durability and the effects of mass ratio of flyash to high calcium slag,water binder ratio,content of water reducer,and crushed coarse aggregate type on the workability and strength of GHPC were considerably evident.A new path for the concretes continuous development was put forward.

Chloride Binding Isotherm from Migration and Diffusion Tests

Chloride binding is often described by chloride binding isotherm, which is closely related to the service life of concrete structures in chloride environments. Many methods have been proposed to determine chloride binding isotherm. Compared to other methods, chloride binding isotherms obtained directly from non- steady-state diffusion tests seem closer to the reality. We studied the chloride binding isotherm from both non- steady-state electrical-accelerated migration and diffusion tests at different temperatures. Twelve concrete mixes with different supplementary cementing materials and water-to-binder ratios of 0.35, 0.48 and 0.6 were cast for study. The specimens after diffusion （or migration） tests were sliced layer by layer, and acid-soluble and free chloride contents of each layer were measured. A chloride binding isotherm was obtained from one specimen. Experimental results indicated that electrical voltage had a slight effect on the chloride binding isotherm of concrete. Temperature had a positive effect on chloride binding. The higher the water-to-binder ratio was, the higher the chloride binding was.

Plastic zone analysis and support optimization of shallow roadway with weakly cemented soft strata

Based on a shallow roadway with weakly cemented soft strata in western China, this paper studies the range and degree of plastic zones in soft strata roadways with weak cementation. Geological radars were used to monitor the loose range and level of surrounding rocks. A mechanical model of weakly cemented roadway was established, including granular material based on the measured results. The model was then used to determine the plastic zone radium. The predicted results agree well with measured results which provide valuable theoretical references for the analysis of surrounding rock stability and support reinforcing design of weakly cemented roadways. Finally, a combined supporting scheme of whole section bolting and grouting was proposed based on the original supporting scheme. It is proved that this support plan can effectively control the deformation and plastic zone expansion of the roadway surrounding rock and thus ensure the long-term stable and safe mining.

Mechanistic Classification of Cement Treated Base in Western Australia

In the past decade alone, the BITRE has indicated an increase of 40% in road users, escalating demands for quality pavements to service tmprecedented traffic conditions. An abundance of crushed rocks are available in Western Australia but do not meet strength requirements for road construction. However, cement treatment of crushed rocks, forming Cement Treated Crushed Rocks （CTCR）, improves the mechanical properties of the material, allowing wider application. In order to streamline the mix design of CTCR, the classification of its behaviour is pivotal. Austroad classifies cement treated pavement materials as either being modified or bound based on its Unconfined Compressive Strength （UCS） and performance attributes. Bound materials are def＇med by its susceptibility to fatigue failure which, in the mechanistic-empirical design for flexible pavements, is dictated by the flexural modulus. However, in the study of damage mechanics, fatigue life is suggested to be an accumulation of micro-scale damage in lieu of dependency to ultimate stresses. Strain dependent damage functions are used phenomologically to explain the evolution of fatigue for various engineering materials. This paper therefore investigates a theoretical relationship between strain and fatigue life prediction supported by a laboratory investigation on the use of UCS for classification. This is achieved by providing regression analysis with strain parameters used in fatigue life prediction. The Indirect Tensile Strength （ITS） test is also employed to this end. It is observed that strain at onset of micro-cracking coalescence （ε30） is independent of test type undertaken and potentially capable of acting as a more superior blanket classification for cemented materials.