The coarse WC particles ceramic-metal com- posite coatings with WC density of 67 wt-% and thickness of 1.0-1.2 mm have been cladded on 20Ni4Mo steel surface by a 2 kW CO_2 laser.The sintered WC particles with the size...The coarse WC particles ceramic-metal com- posite coatings with WC density of 67 wt-% and thickness of 1.0-1.2 mm have been cladded on 20Ni4Mo steel surface by a 2 kW CO_2 laser.The sintered WC particles with the size of 600-1000 μm are chosen as the main strengthening phase, Ni-base self-flux alloy as the binder in the compo- site coatings.The microstructure and microhardness of both WC particles and binder are analysed.The rigid ball indention with acoustic emission technique is used to evaluate the brittleness of the coating.Finally,the abrasive wear resistance of the coating is tested.Besides,the coatings with the same ratio and size of WC parti- cles in low carbon steel tube rod were cladded on 20Ni4Mo steel by atomic hydrogen welding tech- nique and analysed by the same way,their results are compared.展开更多
The cermet fuel element was achieved by dispersing the UO_(2)particles with or without tungsten(W)coating layer uniformly in the W matrix.It is considered to be a robust and secure fuel for use in nuclear thermal prop...The cermet fuel element was achieved by dispersing the UO_(2)particles with or without tungsten(W)coating layer uniformly in the W matrix.It is considered to be a robust and secure fuel for use in nuclear thermal propulsion in the near future.In this study,the effect of deposition temperature on the densification and grain refinement of the W coating layer was investigated.A high-density(19.24 g·cm^(-3))W layer with a uniform thickness(~10μm)and fine grains(~297 nm)was prepared by spouted-bed chemical vapor deposition.The prepared high-density,fine-grained W layer has the following advantages.It can prevent direct contact between fuel particles,resulting in a more uniform fuel distribution.In addition,it can decrease the reaction probability between the fuel kernel and H2,and prevent the release of fission products from the fuel kernel by extending the diffusion path at grain boundaries more efficiently.Moreover,the high-density,fine-grained W layer showed outstanding thermal and mechanical performance.Its average hardness and Young's modulus were approximately 7 and 200 GPa,respectively.The thermal conductivity of the W film was 101-124 W·m^(-1)·K^(-1)at 298-773 K.This work furthers our understanding of the potential application of the high-density,fine-grained W layer in nuclear thermal propulsion.展开更多
Due to the wide application of ceramics in electronic device packaging,the performance of ceramic metallization layer directly determines the performance of the whole package device.This paper introduces the main prep...Due to the wide application of ceramics in electronic device packaging,the performance of ceramic metallization layer directly determines the performance of the whole package device.This paper introduces the main preparation methods of ceramic metallization,discusses the influence of Mo powder size,metallization formula,sintering temperature and other factors on the performance of ceramic metallization layer prepared by activated Mo-Mn method,and introduces several kinds of methods that can be tested to test the performance of ceramic metallized sealing samples.A new research direction of Ceramic Metallization Technology in the advanced field is put forward.展开更多
A nonlinear finite element method is applied to observe how inclusion shape influence the thermal response of a ceramic-metal functionally graded material (FGM). The elastic and plastic behaviors of the layers which a...A nonlinear finite element method is applied to observe how inclusion shape influence the thermal response of a ceramic-metal functionally graded material (FGM). The elastic and plastic behaviors of the layers which are two-phase isotropic composites consisting of randomly oriented elastic spheroidal Inclusions and a ductile matrix are predicted by cc mean field method. The prediction results show that inclusion shape has remarkable influence on the overall behavior of the composite. The consequences of the thermal response analysis of the FGM are that the response is dependent on inclusion shape and its composition profile cooperatively and that the plastic behavior of each layer should be taken into account in optimum design of a ceramic-metal FGM.展开更多
This paper presents a numerical homogenization analysis of a porous piezoelectric composite with a partially metalized pore surface.The metal layers can be added to the pore surfaces to improve the mechanical and elec...This paper presents a numerical homogenization analysis of a porous piezoelectric composite with a partially metalized pore surface.The metal layers can be added to the pore surfaces to improve the mechanical and electromechanical properties of ordinary porous piezocomposites.Physically,constructing that composite with completely metalized pore surfaces is a challenging process,and imperfect metallization is more expected.Here,we investigate the effects of possible incomplete metallization of pore surfaces on the composite’s equivalent properties.We applied the effective moduli theory,which was developed for the piezoelectric medium based on the Hill-Mandel principle,and the finite element method to compute the effective moduli of the considered composites.Using specific algorithms and programs in the ANSYS APDL programming language,we constructed the representative unit cell element models and performed various computational experiments.Due to the presence of metal inclusion,we found that the dielectric and piezoelectric properties of the considered composites differ dramatically from the corresponding properties of the ordinary porous piezocomposites.The results of this work showed that piezocomposites with partially metallized pore surfaces can have a higher anisotropy,compared to the pure piezoceramic matrix,due to the defects in metal coatings.展开更多
The competitiveness of the small gas turbine units (GTUs) (Ne<300 kW) in the world power market is dependent on bath the maintenance expenses and the capital costs of production. Reduction in the maintenance expend...The competitiveness of the small gas turbine units (GTUs) (Ne<300 kW) in the world power market is dependent on bath the maintenance expenses and the capital costs of production. Reduction in the maintenance expenditures could be achieved by increasing the plant efficiency. This task could be solved by some methods: increasing the cycle inlet temperature TIT, getting the cycle more complex (use of heat regeneration and compressed air intermediate cooling), cutting the power consumption on heat-stressed parts cooling. Putting the above into effect is linked with introduction of novel structural materials, a sharp increase in the mass-size values and the plant manufacture expenditures, in particular, at provision of its self-regulation. In connection with the above, the development of the combined metal-ceramic airheaters and standardization of the elemental basis of the metal gas-gas heat exchangers will promote reduction in the expenditures of the maintenance and the manufacture of the small-size independent power GTEs.展开更多
文摘The coarse WC particles ceramic-metal com- posite coatings with WC density of 67 wt-% and thickness of 1.0-1.2 mm have been cladded on 20Ni4Mo steel surface by a 2 kW CO_2 laser.The sintered WC particles with the size of 600-1000 μm are chosen as the main strengthening phase, Ni-base self-flux alloy as the binder in the compo- site coatings.The microstructure and microhardness of both WC particles and binder are analysed.The rigid ball indention with acoustic emission technique is used to evaluate the brittleness of the coating.Finally,the abrasive wear resistance of the coating is tested.Besides,the coatings with the same ratio and size of WC parti- cles in low carbon steel tube rod were cladded on 20Ni4Mo steel by atomic hydrogen welding tech- nique and analysed by the same way,their results are compared.
基金financially supported by the Thorium Molten Salt Reactor Nuclear Energy System under the Strategic Pioneer Sci.&Tech.Project of the Chinese Academy of Sciences(XDA02030200)the Frontier Science Key Program of the Chinese Academy of Sciences(Grant No.QYZDY-SSW-JSC016)+2 种基金the Natural Science Foundation of Shanghai(Grant No.20ZR1468800 and 21ZR1476300)the Natural Science Foundation of Gansu province(Grant No.20JR5RE639)the Shanghai Pujiang Program(Grant No.19pj1431600)。
文摘The cermet fuel element was achieved by dispersing the UO_(2)particles with or without tungsten(W)coating layer uniformly in the W matrix.It is considered to be a robust and secure fuel for use in nuclear thermal propulsion in the near future.In this study,the effect of deposition temperature on the densification and grain refinement of the W coating layer was investigated.A high-density(19.24 g·cm^(-3))W layer with a uniform thickness(~10μm)and fine grains(~297 nm)was prepared by spouted-bed chemical vapor deposition.The prepared high-density,fine-grained W layer has the following advantages.It can prevent direct contact between fuel particles,resulting in a more uniform fuel distribution.In addition,it can decrease the reaction probability between the fuel kernel and H2,and prevent the release of fission products from the fuel kernel by extending the diffusion path at grain boundaries more efficiently.Moreover,the high-density,fine-grained W layer showed outstanding thermal and mechanical performance.Its average hardness and Young's modulus were approximately 7 and 200 GPa,respectively.The thermal conductivity of the W film was 101-124 W·m^(-1)·K^(-1)at 298-773 K.This work furthers our understanding of the potential application of the high-density,fine-grained W layer in nuclear thermal propulsion.
基金The authors are grateful to National Science Foundation of China(51602347)Hunan Natural Science Foundation(2019JJ50282)for financial support.The authors are also grateful to Aid Program for Innovative Group of National University of Defense Technology and Aid Program for Science and Technology Innovative Research Team in Higher Educational Institutions of Hunan Province.
文摘Due to the wide application of ceramics in electronic device packaging,the performance of ceramic metallization layer directly determines the performance of the whole package device.This paper introduces the main preparation methods of ceramic metallization,discusses the influence of Mo powder size,metallization formula,sintering temperature and other factors on the performance of ceramic metallization layer prepared by activated Mo-Mn method,and introduces several kinds of methods that can be tested to test the performance of ceramic metallized sealing samples.A new research direction of Ceramic Metallization Technology in the advanced field is put forward.
基金Funded by National Science Foundation of China(Grant:1987205).
文摘A nonlinear finite element method is applied to observe how inclusion shape influence the thermal response of a ceramic-metal functionally graded material (FGM). The elastic and plastic behaviors of the layers which are two-phase isotropic composites consisting of randomly oriented elastic spheroidal Inclusions and a ductile matrix are predicted by cc mean field method. The prediction results show that inclusion shape has remarkable influence on the overall behavior of the composite. The consequences of the thermal response analysis of the FGM are that the response is dependent on inclusion shape and its composition profile cooperatively and that the plastic behavior of each layer should be taken into account in optimum design of a ceramic-metal FGM.
基金This research was done in the framework of the RFBR project 20-31-90102.
文摘This paper presents a numerical homogenization analysis of a porous piezoelectric composite with a partially metalized pore surface.The metal layers can be added to the pore surfaces to improve the mechanical and electromechanical properties of ordinary porous piezocomposites.Physically,constructing that composite with completely metalized pore surfaces is a challenging process,and imperfect metallization is more expected.Here,we investigate the effects of possible incomplete metallization of pore surfaces on the composite’s equivalent properties.We applied the effective moduli theory,which was developed for the piezoelectric medium based on the Hill-Mandel principle,and the finite element method to compute the effective moduli of the considered composites.Using specific algorithms and programs in the ANSYS APDL programming language,we constructed the representative unit cell element models and performed various computational experiments.Due to the presence of metal inclusion,we found that the dielectric and piezoelectric properties of the considered composites differ dramatically from the corresponding properties of the ordinary porous piezocomposites.The results of this work showed that piezocomposites with partially metallized pore surfaces can have a higher anisotropy,compared to the pure piezoceramic matrix,due to the defects in metal coatings.
文摘The competitiveness of the small gas turbine units (GTUs) (Ne<300 kW) in the world power market is dependent on bath the maintenance expenses and the capital costs of production. Reduction in the maintenance expenditures could be achieved by increasing the plant efficiency. This task could be solved by some methods: increasing the cycle inlet temperature TIT, getting the cycle more complex (use of heat regeneration and compressed air intermediate cooling), cutting the power consumption on heat-stressed parts cooling. Putting the above into effect is linked with introduction of novel structural materials, a sharp increase in the mass-size values and the plant manufacture expenditures, in particular, at provision of its self-regulation. In connection with the above, the development of the combined metal-ceramic airheaters and standardization of the elemental basis of the metal gas-gas heat exchangers will promote reduction in the expenditures of the maintenance and the manufacture of the small-size independent power GTEs.