The kinetic process of MmNi3. 55Co0. 75Mn0. 4Al0. 3 alloy absorbing hydrogen in αand α+βphases at the temperature range of 22 ̄ 60℃ has been studied. The results show that the kinetic process is controlled by chem...The kinetic process of MmNi3. 55Co0. 75Mn0. 4Al0. 3 alloy absorbing hydrogen in αand α+βphases at the temperature range of 22 ̄ 60℃ has been studied. The results show that the kinetic process is controlled by chemical reaction in the α phase and the mechanism of hydrogenation kinetics is not affected by initial hydrogen pressure. In the α+β phase region,the speed of hydrogen absorption is controlled by hydrogen diffusion in the hydride.A reaction rate equation and apparent activation energy have been obtained.展开更多
文摘The kinetic process of MmNi3. 55Co0. 75Mn0. 4Al0. 3 alloy absorbing hydrogen in αand α+βphases at the temperature range of 22 ̄ 60℃ has been studied. The results show that the kinetic process is controlled by chemical reaction in the α phase and the mechanism of hydrogenation kinetics is not affected by initial hydrogen pressure. In the α+β phase region,the speed of hydrogen absorption is controlled by hydrogen diffusion in the hydride.A reaction rate equation and apparent activation energy have been obtained.