The exchange performances and the distribution coefficient of Cesium Ion-Sieve (Cs-IS) for cesium and for some rare earth elements were compared. In particula r, the effects of neodymium on the cesium ion exchange an...The exchange performances and the distribution coefficient of Cesium Ion-Sieve (Cs-IS) for cesium and for some rare earth elements were compared. In particula r, the effects of neodymium on the cesium ion exchange and the Cs+ selectivity v ariation on Cs-IS owing to introduction of rare earth elements into HLLW were s tudied. Though rare earth elements exhibit a small influence on the distributio n coefficient for Cs+, they impair Cs-exchange capacity of Cs-IS to some ext ent. This interruption on the selectivity to Cs+ can be significantly eliminat ed provided an appropriate ratio of liquid to solid V:m is used.展开更多
MnO 2 was prepared by column method from normal spinel LiMn 2O 4 with purity of 99.38%.The influence of LiMn 2O 4 grain size and acidity of leaching solution on the lithium leaching process was studied.The result...MnO 2 was prepared by column method from normal spinel LiMn 2O 4 with purity of 99.38%.The influence of LiMn 2O 4 grain size and acidity of leaching solution on the lithium leaching process was studied.The results show that the appropriate range of LiMn 2O 4 grain size was 60-160 meshes and the concentration of leaching solution HCl was 0.1 mol·L -1.The adsorption capacity Q of λ-MnO 2 for lithium increased with the increase of pH and changed markedly at pH 6.0-10.0.It was 3.80mmol/g at pH 12.0.The distribution coefficients K d of Li + and Na + were 3.406×10 4 and 2.300 respectively,and the separation coefficient α Li Na was 1.481×10 4 at pH 6.5.As a result,λ-MnO 2 is a high performance ion-sieve material for lithium ion.展开更多
The shuttle effect is among the most characteristic and formidable challenges in the pursuit of high-performance lithium-sulfur(Li-S)batteries.Herein,phosphorylated cellulose nanofibers(pCNF)are intentionally engineer...The shuttle effect is among the most characteristic and formidable challenges in the pursuit of high-performance lithium-sulfur(Li-S)batteries.Herein,phosphorylated cellulose nanofibers(pCNF)are intentionally engineered to establish an ion-sieving barrier against polysulfide shuttling and thereby improve battery performance.The phosphorylation,involving the grafting of phosphate groups onto the cellulose backbone,imparts an exceptional electronegativity that repels the polysulfide anions from penetrating through the separator.Moreover,the electrolyte wettability and Li^(+)transfer can be significantly promoted by the polar nature of pCNF and the facile Li^(+)disassociation.As such,rational ion management is realized,contributing to enhanced reversibility in both sulfur and lithium electrochemistry.As a result,Li-S cells equipped with the self-standing pCNF separator demonstrate outstanding long-term cyclability with a minimum fading rate of 0.013%per cycle over 1000 cycles at 1 C,and a decent areal capacity of 5.37 mA h cm^(-2) even under elevated sulfur loading of 5.0 mg cm^(-2) and limited electrolyte of 6.0 mL g^(-1).This work provides a facile and effective pathway toward the well-tamed shuttle effect and highly durable Li-S batteries.展开更多
Graphitic carbon nitride(g-C_(3)N_(4))has been extensively doped with alkali metals to enlarge photocatalytic output,in which cesium(Cs)doping is predicted to be the most efficient.Nevertheless,the sluggish diffusion ...Graphitic carbon nitride(g-C_(3)N_(4))has been extensively doped with alkali metals to enlarge photocatalytic output,in which cesium(Cs)doping is predicted to be the most efficient.Nevertheless,the sluggish diffusion and doping kinetics of precursors with high melting points,along with imprecise regulation,have raised the debate on whether Cs doping could make sense.For this matter,we attempt to confirm the positive effects of Cs doping on multifunctional photocatalysis by first using cesium acetate with the character of easy manipulation.The optimized Csdoped g-C_(3)N_(4)(CCN)shows a 41.6-fold increase in visible-light-driven hydrogen evolution reaction(HER)compared to pure g-C_(3)N_(4) and impressive degradation capability,especially with 77%refractory tetracycline and almost 100%rhodamine B degradedwithin an hour.The penetration ofCs+is demonstrated to be a mode of interlayer doping,and Cs–N bonds(especially with sp^(2) pyridine N in C═N–C),along with robust chemical interaction and electron exchange,are fabricated.This atomic configuration triggers the broadened spectral response,the improved charge migration,and the activated photocatalytic capacity.Furthermore,we evaluate the CCN/cadmium sulfide hybrid as a Z-scheme configuration,promoting the visible HER yield to 9.02 mmol g^(−1) h^(−1),which is the highest ever reported among all CCN systems.This work adds to the rapidly expanding field of manipulation strategies and supports further development of mediating served for photocatalysis.展开更多
针对传统自然资源地籍调查依赖大量现场工作和后期数据处理导致的调查周期长、成本高等问题,提出了一种基于Cesium for Unreal的自然资源远程协同调查方法。该方法以倾斜摄影获取的实景三维模型为基础,叠加权属、土地利用等业务数据构...针对传统自然资源地籍调查依赖大量现场工作和后期数据处理导致的调查周期长、成本高等问题,提出了一种基于Cesium for Unreal的自然资源远程协同调查方法。该方法以倾斜摄影获取的实景三维模型为基础,叠加权属、土地利用等业务数据构建调查场景,并通过优化实景三维模型的渲染效果和性能,使自然资源信息以更加直观、真实的方式呈现。在此基础上,自然资源所在地相关政府部门可直接在系统中查看界址、权属等信息,并与实景进行对比核实,然后在线反馈和记录问题;调查单位根据反馈在系统中直接修改数据,完成后即可与政府部门进行线上确认和签字。肇庆某湿地公园的试点应用结果表明,该方法能显著提高自然资源地籍调查效率,压缩工期,具有较好的应用前景。展开更多
文摘The exchange performances and the distribution coefficient of Cesium Ion-Sieve (Cs-IS) for cesium and for some rare earth elements were compared. In particula r, the effects of neodymium on the cesium ion exchange and the Cs+ selectivity v ariation on Cs-IS owing to introduction of rare earth elements into HLLW were s tudied. Though rare earth elements exhibit a small influence on the distributio n coefficient for Cs+, they impair Cs-exchange capacity of Cs-IS to some ext ent. This interruption on the selectivity to Cs+ can be significantly eliminat ed provided an appropriate ratio of liquid to solid V:m is used.
基金theNationalNaturalScienceFoundationofChi na (No .5 9972 0 2 7)theNaturalScienceFoundationofHubeiProvince (No .2 0 0 2AB0 74) )
文摘MnO 2 was prepared by column method from normal spinel LiMn 2O 4 with purity of 99.38%.The influence of LiMn 2O 4 grain size and acidity of leaching solution on the lithium leaching process was studied.The results show that the appropriate range of LiMn 2O 4 grain size was 60-160 meshes and the concentration of leaching solution HCl was 0.1 mol·L -1.The adsorption capacity Q of λ-MnO 2 for lithium increased with the increase of pH and changed markedly at pH 6.0-10.0.It was 3.80mmol/g at pH 12.0.The distribution coefficients K d of Li + and Na + were 3.406×10 4 and 2.300 respectively,and the separation coefficient α Li Na was 1.481×10 4 at pH 6.5.As a result,λ-MnO 2 is a high performance ion-sieve material for lithium ion.
基金the financial support from the National Natural Science Foundation of China(22109072)the Natural Science Foundation of Jiangsu Province(BK20210349)+1 种基金the Fundamental Research Funds for the Central Universities(30922010304)the Open Fund of National Forestry and Grassland Administration Key Laboratory of Plant Fiber Functional Materials(2022KFJJ06)。
文摘The shuttle effect is among the most characteristic and formidable challenges in the pursuit of high-performance lithium-sulfur(Li-S)batteries.Herein,phosphorylated cellulose nanofibers(pCNF)are intentionally engineered to establish an ion-sieving barrier against polysulfide shuttling and thereby improve battery performance.The phosphorylation,involving the grafting of phosphate groups onto the cellulose backbone,imparts an exceptional electronegativity that repels the polysulfide anions from penetrating through the separator.Moreover,the electrolyte wettability and Li^(+)transfer can be significantly promoted by the polar nature of pCNF and the facile Li^(+)disassociation.As such,rational ion management is realized,contributing to enhanced reversibility in both sulfur and lithium electrochemistry.As a result,Li-S cells equipped with the self-standing pCNF separator demonstrate outstanding long-term cyclability with a minimum fading rate of 0.013%per cycle over 1000 cycles at 1 C,and a decent areal capacity of 5.37 mA h cm^(-2) even under elevated sulfur loading of 5.0 mg cm^(-2) and limited electrolyte of 6.0 mL g^(-1).This work provides a facile and effective pathway toward the well-tamed shuttle effect and highly durable Li-S batteries.
基金supported primarily by the National Natural Science Foundation of China(Contract No.21975245,51972300,62274155,and U20A20206)the National Key Research and Development Program of China(Grant No.2018YFE0204000)+2 种基金the Strategic Priority Research Program of the Chinese Academy of Sciences(Grant No.XDB43000000)the National Natural Science Foundation of China under Grant No.62175231.Prof.Kong Liu appreciates the support from the Youth Innovation Promotion Association,the Chinese Academy of Sciences(No.2020114)the Beijing Nova Program(No.2020117).
文摘Graphitic carbon nitride(g-C_(3)N_(4))has been extensively doped with alkali metals to enlarge photocatalytic output,in which cesium(Cs)doping is predicted to be the most efficient.Nevertheless,the sluggish diffusion and doping kinetics of precursors with high melting points,along with imprecise regulation,have raised the debate on whether Cs doping could make sense.For this matter,we attempt to confirm the positive effects of Cs doping on multifunctional photocatalysis by first using cesium acetate with the character of easy manipulation.The optimized Csdoped g-C_(3)N_(4)(CCN)shows a 41.6-fold increase in visible-light-driven hydrogen evolution reaction(HER)compared to pure g-C_(3)N_(4) and impressive degradation capability,especially with 77%refractory tetracycline and almost 100%rhodamine B degradedwithin an hour.The penetration ofCs+is demonstrated to be a mode of interlayer doping,and Cs–N bonds(especially with sp^(2) pyridine N in C═N–C),along with robust chemical interaction and electron exchange,are fabricated.This atomic configuration triggers the broadened spectral response,the improved charge migration,and the activated photocatalytic capacity.Furthermore,we evaluate the CCN/cadmium sulfide hybrid as a Z-scheme configuration,promoting the visible HER yield to 9.02 mmol g^(−1) h^(−1),which is the highest ever reported among all CCN systems.This work adds to the rapidly expanding field of manipulation strategies and supports further development of mediating served for photocatalysis.
文摘针对传统自然资源地籍调查依赖大量现场工作和后期数据处理导致的调查周期长、成本高等问题,提出了一种基于Cesium for Unreal的自然资源远程协同调查方法。该方法以倾斜摄影获取的实景三维模型为基础,叠加权属、土地利用等业务数据构建调查场景,并通过优化实景三维模型的渲染效果和性能,使自然资源信息以更加直观、真实的方式呈现。在此基础上,自然资源所在地相关政府部门可直接在系统中查看界址、权属等信息,并与实景进行对比核实,然后在线反馈和记录问题;调查单位根据反馈在系统中直接修改数据,完成后即可与政府部门进行线上确认和签字。肇庆某湿地公园的试点应用结果表明,该方法能显著提高自然资源地籍调查效率,压缩工期,具有较好的应用前景。
